• Title/Summary/Keyword: Polycarbonate

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Rheology Properties of Belite-rich Cement Mortar Added Blastfurnace Slag and Polycarbonate-based Superplasticizer (고로슬래그와 폴리카르본산계 유기 혼화제를 첨가한 Belite-rich Cement 모르타르 유동특성)

  • 송종택;송종택;조현태;황인수;박춘근
    • Journal of the Korean Ceramic Society
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    • v.37 no.2
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    • pp.145-151
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    • 2000
  • In order to investigate the rheological properties of belite-rich cement(BRC) added polycarbonate-based superplasticizer and blastfurnace slags which have different blaines at 4500, 6000 and 8000$\textrm{cm}^2$/g, the change of minislumps and mortar slumps are measured with time. The rheological properties improve as specific surface area of added slag decreases or amount of polycarbonate-based superplasticizer increases. The slump loss can be controlled effectively by the steric hinderance effect of polycarbonate-based superplasticizer. According to the results, when mix proportion of the mortar is 1.5% mass content of superplasticizer and 30% mass addition of blastfurnace slag which blaine is 4500$\textrm{cm}^2$/g, the best mortar slump can be achieved without any significant segregation of materials.

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Intrinsic UV Reflection and Fluorescence Studies for Water Sorption in Polycarbonate, Polyurethane and Poly(Ethylene Terephthalate) Films

  • Kim Min Sun;Sung Chong Sook Paik
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.127-130
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    • 2005
  • Intrinsic UV reflection and fluorescence behaviors of polycarbonate, polyurethane and poly(ethylene terephthalate) films were investigated in order to characterize the interaction of water in these films. During water sorption process, UV reflection spectra of polycarbonate and polyurethane films showed little peak position changes. Fluorescence emission spectra of polycarbonate films showed red spectral shifts from 332 nm with water immersion time. This red-shifted peak could be due to phenyl-2-phenoxybenzoate, which is one of the major thermal degradation products in polycarbonate. Fluorescence peaks of polyurethane films appeared at two different positions and the ratio of these peak intensities increased with increasing immersion time. In the case of PET films, the UV reflection spectrum showed the peak intensity around 340 nm to change in response to water sorption. The fluorescence near 388 nm probably due to ground state dimer exhibited sensitivity with water sorption, when excited at 340 nm.

A study the ink transition of polycarbonate by using of screen printing technioque (Screen 인쇄기법을 이용한 Polycarbonate의 Ink 전이성에 관한 연구)

  • 신종순;강영립;최명철
    • Journal of the Korean Graphic Arts Communication Society
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    • v.19 no.2
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    • pp.49-57
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    • 2001
  • This thesis attempts to study ink transition for on the polycarbonate multicalculator plate for automobile. For this study, the change of weight by screen printed ink transition on polycarbonate material by ink viscosity(be diluted ; 0%, 5%, 10%, 20%) was observed. The weight by screen printed ink is depended on amount of added solvent. We have studied change of the weight by the transition of the ink that was screen-printed on polycarbonate which is to be printed according to the viscosity of the ink (diluent: undiluted solution 5%, 10%, 15%, 20%). This shows that ink transition become activated since the amount of ink(or/and the viscosity of ink) is increased.

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A Study on Optical Seemless of Discrete LED panels with Focusing Effect of prism Structure (프리즘 구조의 집광효과를 이용한 이산형 LED 패널의 광학적 연속성 구현에 관한 연구)

  • Cho, Sung-Hwan;Kim, Eung-Bo;Choi, Won-Seok;Joung, Yeun-Ho
    • Journal of Satellite, Information and Communications
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    • v.12 no.2
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    • pp.11-14
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    • 2017
  • In this paper, we introduce a method of light focusing effect using prism structure to solve optical discontinuity of conventional external signage LED panels. The prims structures were patterned on a transparent polycarbonate substrate with MEMS and femto-second laser process. We have confirmed that the patterned prism structures on the substrate made artificial LED lights on empty space between the panels by light guide effect of the structure. The artificial light's lateral positions were controlled by thickness of polycarbonate substrate. This cost effective prim patterned transparent film can be utilized on digital signage LED panels to achieve good optical communication.

Synthesis of Bishydroxyethyl Ether of Bisphenol A(BHE-BPA) Through the Depolymerization of Polycarbonate (폴리카보네이트 해중합을 이용한 Bisphenol A계 Bishydroxyethyl Ether 화합물 생성 특성)

  • Heo, Miseon;Kim, Beomsik;Park, Youin;Han, Myungwan
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.164-171
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    • 2010
  • Recently, the waste of Polycarbonate(PC) is increase with the increase in demand of a polycarbonate. It is concerned with producing a new material and diol monomer, bishydroxyethyl ether of bisphenol A(BHE-BPA) through depolymerization of the polycarbonate waste at recycling. BHE-BPA can be used as a good raw material for the synthesis of polycarbonate type polyurethane. PC particles were depolymerized with base-catalyst NaOH, solvent EG, and ethylene carbonate(EC) was formed during the PC depolymerziation. EC was added to promote the conversion from bispenol-A to BHE-BPA. The characteristics of depolymeraion of polycarbonate as well as conversion of bispenol-A to BHE-BPA were investigated. BHE-BPA yield of 92% was obtained at temperature $220^{\circ}C$, 10% catalyst/PC mole ratio, 20 mmol of EC. BHE-BPA purity of better than 99% was achieved by crystallization of BHE-BPA.

Analyses of Additives Applied in a Polycarbonate (폴리카보네이트에 사용된 첨가제의 분석)

  • Kim, Seog-Jun
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.282-290
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    • 2000
  • In this study, polymer additives were extracted and separated by Soxhlet extraction method and the dissolution-precipitation method from a polycarbonate (optical grade) which completely absorbed UV light below 390 nm. Analytical techniques such as UV-Vis spectroscopy, FT-IR, and HPLC were applied to analyze additives in polycarbonate. Separated materials from the polycarbonate may be a complex mixture containing additives such as UV stabilizer, antioxidants (primary and secondary), monomers, and oligomers. Several compounds such as bisphenol A, Irganox 1010, and Cyasorb UV-5411 were identified by chromatograms and UV spectra obtained from RP HPLC analysis using Bondapak $C_{18}$ column, methanol mobile phase, and a photodiode array (PDA) detector. Also, the content of UV-5411 in the polycarbonate was about 0.12 wt% by a quantitative analysis through UV spectroscopy.

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Solvent Induced Crystallization of Polycarbonate in Mixed Solvent (혼합용매에 의한 Polycarbonate의 결정화)

  • 황덕근;이창엽;설용건
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.811-817
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    • 2001
  • Crystallization behaviour of bisphenol A polycarbonate(PC) from amorphous phase was studied by varing solvent/nonsolvent ratios in liquid phase. Chloroform and isopropanol were used as a solvent and a nonsolvent, respectively. Samples were characterized by optical microphotography, scanning electron microscope (SEM), X-ray diffaction (XRD), and differential scanning calorimeter (DSC). DSC and XRD measurement were used to determine the crystallinity of PC. The solubility constant seems to critical to control the PC crystallinity in solvent/nonsolvent mixture. The difference in PC crystallinity is explained by the difference in solubility constant of the mixture depending on the solvent/nonsolvent ratio. PC solution of 75/25 wt% (solvent/nonsolvent) ratio produced PC powder showing maximum crystallinity. At this condition solubility constant (9.85) of the mixed solvent was close to PC (9.9).

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