• Title/Summary/Keyword: Polyamide-6(PA-6)

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Effect of Fiber Type and Combination on the Reinforcement of Heat Polymerized Denture Base Resin (섬유의 종류와 조합이 열중합 의치상 레진의 강화에 미치는 영향)

  • Yu, Sang-Hui;Kim, Young-Im
    • Journal of dental hygiene science
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    • v.10 no.6
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    • pp.445-450
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    • 2010
  • The aim of this study was to evaluate the effect according to the fiber type and combination on the reinforcement of heat-polymerized denture base resin. The heat-polymerized resin(Vertex RS, Dentimax, Netherlands) was used in this study. Glass fiber(GL; ER 270FW, Hankuk Fiber Glass, Korea), polyaromatic polyamide fiber(PA; aramid; Kevlar-49, Dupont, U.S.A.) and ultra high molecular weight polyethylene fiber(PE, polyethylene; P.E, Dong Yang Rope, Korea) were used to reinforce the denture base resin specimens. The final size of test specimen was $64mm{\times}10mm{\times}3.3mm$. The specimens of each group were stored in distilled water at $37^{\circ}C$ for 50 hours before measurement. The flexural strength and flexural modulus were measured by an universal testing machine(Z020, Zwick, Germany) at a crosshead speed of 5 mm/min in a three-point bending mode. In this study, all fibers showed reinforcing effects on denture base resin(p<0.05). In terms of flexural strength and flexural modulus, glass fiber 5.3 vol.% showed most effective reinforcing effect on heat polymerized denture base resin. For flexural modulus, PA/GL was the highest in denture base resin specimen for hybrid FRC using two combination (p<0.05). Glass fiber 5.3 vol.% and PA/GL are considered to be applied effectively in reinforcing the heat polymerized denture base resin.

Effect of Pallet Size Modified Atmosphere Packaging Using Polyamide Film and Linear Low Density Polyethylene Film on the Shelf Life of Strawberries (PA와 LLDPE 필름을 이용한 딸기 저장용 Modified Atmosphere Pallet Packaging 연구)

  • Kim, Jinse;Jung, Hyun Kyung;Nam, So Young;Son, Jae Yong;Park, Seok Ho;Choi, Dong Soo;Kim, Yong Hoon;Lee, Soo Jang;Park, Chun Wan
    • Food Engineering Progress
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    • v.23 no.1
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    • pp.55-61
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    • 2019
  • For the vessel export of strawberries, modified atmosphere package (MAP) using polyamide (PA) film and linear low density polyethylene (LLDPE) film was investigated to extend the shelf life of strawberries. Because the temperature and relative humidity changes of the MAP were lower than the changes of the control, the weight loss of the MAP were lower than that of the control. The low oxygen level and high carbon dioxide level were effective to decrease the fungal decay rate and to increase the hardness of strawberries. The Hunter's color differences before and after storage showed no distinct difference between the MAP and the control. The lightness had a tendency to decrease while the redness increased. There were no significant changes of the soluble solids during the storage. The shelf life of strawberries could be extended to 16 days using the MAP considering the weight loss and the fungal decay rate. Thus, this MAP method using PA film and LLDPE film was effective to extend the shelf life of strawberries.

Characteristics of $SiO_2$ Scale Removal by Chemical Cleaning in Reverse Osmosis Membrane Process (역삼투막 공정에서 화학적 세정에 의한 $SiO_2$ scale 제거특성)

  • DockKo, Seok;Lee, Hyung-Jib
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.1
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    • pp.93-101
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    • 2010
  • Reverse osmosis (RO) membranes have been widely used for desalination as well as water and wastewater treatment facilities. Cleaning process is important to maintain stable operation as well as prevention of membrane fouling. Purpose of this research is to analyze electrostatistic and chemical characteristics after cleaning of RO membrane against $SiO_2$ scale. Four RO membranes of polyamide are used and examined about effect of chemical cleaning. EDTA (ethylene diamine tetraacetic acid) and SDS (sodium dodecil sulfate) and NaOH are applied for cleaning process after operation in synthetic water. Then, cleaning was performed with chemicals such concentration as 6hr, 12hr and 24hr, respectively. As a result, transmittances of FT-IR of four membranes are compared at each cleaning concentration. Ta/Tv shows difference of chemical composition between new membrane and cleaning membrane after cleaning. Type B of RO membrane is turned out to be most vulnerable to cleaning among four membranes. In terms of zeta potential, new membrane has -16 mV to +6 mV on pH while scaled membrane has -18 mV to 2 mV. However, it changed -23mV to 0.9 mV after cleaning. In comparison with existing salt rejection of RO membranes after cleaning, the rejection of the membranes goes down 0.7% maximum. Though cleaning changes the characteristics of membrane surface, it does not greatly affect salt rejection. pH is a critical factor to flux change in PA (polyamide) membrane.

Development of double injection mold for fuel-tube holder (자동차 연료튜브 홀더용 이중사출 금형·성형기술)

  • Kim, Gun-Hee;Yoon, Gil-Sang;Heo, Young-Moo;Jung, Woo-Chul;Shin, Kwang-Ho
    • Design & Manufacturing
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    • v.1 no.1
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    • pp.1-5
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    • 2007
  • Double injection molding process is very efficient molding-method for molding the products which is consist of multi-materials. Fuel-tube holder which is necessary for automobil power train and circulation systems is composed of plastic and rubber materials to minimize the vibration and pulsation noises. In existing process, fuel-tube holder was made by the insert molding process or assembly process after molding. If fuel-tube holder is manufactured by double injection molding process, it may be realize to improve the product quality, efficiency of molding-process and retrenchment of manufacturing cost. In this study, for manufacturing fuel-tube holder by double injection molding process, the analysis of joining characteristics between PA6(polyamide 6) and TPE(thermoplastic elastomer) was executed and the double injectin mold for molding fuel-tube holder with core toggle mechanism was fabricated. Finally, fuel-tube holder was molding using fabricated double injection mold.

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Preparation of Forward Osmosis Membranes with Low Internal Concentration Polarization (농도 분극이 저감된 정삼투 분리막 제조)

  • Kim, Nowon;Jung, Boram
    • Membrane Journal
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    • v.24 no.6
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    • pp.453-462
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    • 2014
  • Thin film composite (TFC) polyamide (PA) membranes were prepared on polyester (PET) nonwoven reinforced polysulfone supports for forward osmosis (FO) processes. PSF (polysulfone) supports were prepared via the phase inversion process from PSF casting solutions in dimethyl formamide (DMF) solvents (19 wt%) by using a PET nonwoven (thickness of $100{\mu}m$) as a mechanical reinforcing material for reverse osmosis (RO) membrane. The PSF support from 19 wt% of DMF/PSF casting solution showed sponge-like morphology and asymmetric internal structure. To reduce the internal concentration polarization in FO operation, thin ($20{\mu}m$ of thickness) nonwoven-supported PSF supports were prepared by using PSF/DMF casting solution (9~19 wt%). A desirable support structure with a highly porous sponge-like morphology were achieved from the thin nonwoven-supported PSF layer prepared with 9~12 wt% casting solution. A crosslinked aromatic polyamide layer was fabricated on top of each support to form a TFC PA membrane. The tested sample from 12 wt% of DMF/PSF casting solution presented outstanding FO performance, almost 5.5 times higher water flux (24.3 LMH) with low reverse salt flux (RDF, 1.5 GMH) compared to a thick nonwoven rainforced membrane (4.5 LMH of flux and 3.47 GMH of RSF). By reducing the thickness of the nonwoven and optimizing PSF concentration of casting solution, the morphology of the prepared membranes were changed from a dense structure to a porous sponge structure in the boundary area between nonwoven and PET support layer.

Preparation of Nylon Elastomer and Its Application in the Electrospinning Process (나이론탄성체 제조와 전기방사응용)

  • Park, Jun-Seo;Ketpang, Kriangsak
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.274-281
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    • 2009
  • Nylon 6 and nylon elastomer were prepared by anionic polymerization route. Nylon elastomers, composed of hard segment of polyamide(PA) and soft segment of polyether(PE), were synthesized by use of TDI terminated polyol with caprolactam. The morphology of the electrospun webs of nylon and nylon elastomers, observed by FE-SEM, showed that the porous electrospun web was composed of nanofibers, whose diameter were in the range of 100 to 180 nm. Their behavior of melting and crystallization and the chemical structure of nylon elastomers were investigated by DSC and ATR FT-IR. Result of tensile testing indicated that nylon has higher tensile strength and lower elongation than nylon elastomers. Atmospheric plasma(APP) with $O_2$ and $N_2$ as reactive gas modified the surface of electrospun nylon and electrospun nylon elastomers allowing them higher hydrophilicity, while APP with $CH_4$ as reactive gas modified the surface of polymers allowing higher hydrophobicity.

Study on the Fouling Reduction of the RO Membrane by the Coating with an Anionic Polymer (역삼투막 표면에 음이온 고분자 코팅을 통한 파울링 현상 감소연구)

  • Cho, Eun Hye;Cheong, Seong Ihl;Rhim, Ji Won
    • Membrane Journal
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    • v.22 no.6
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    • pp.481-488
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    • 2012
  • The anionic exchange polymer, poly(vinyl amine)(PVAm), was coated onto polyamide (PA) reverse osmosis (RO) membranes by using 'salting-out' method. The effects of the fouling phenomena for these PVAm coated membranes were investigated using the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA). The surface coating and the fouling phenomena were observed by the scanning electron microscopy. And the flux was measured for each 100 ppm of above foulant aqueous solution at the operating pressure, 2, 4, 8 bar. The PVAm-coated PA membranes showed somewhat fouling improvements and the fouling reduction was shown in the order of HA > SA > BSA, particularly HA case was distinct.

A Study on the Mechanical Properties Experiment for Architectural Application of Polyamide-12 MJF 3D Printing Material - Focusing on the Change in Tensile Properties According to the 3D Printing Orientation - (MJF 3D 프린팅 기반 폴리아미드-12 소재의 건축적 활용을 위한 기계적 특성 실험에 관한 연구 - 출력 방향에 따른 인장 특성 변화를 중심으로 -)

  • Park, Sangjae;Yoo, Seungkyu;Kim, Munhwan;Kim, Jaejun
    • Korean Journal of Construction Engineering and Management
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    • v.21 no.6
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    • pp.95-102
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    • 2020
  • The number of use cases in machinery, aviation, and other industries that manufacture precise parts is increasing, and the construction industry is also increasingly using 3D printing technology. Although various materials for 3D printing are currently being developed and utilized, 3D printing manufacturing has a problem that the mechanical properties of the product may change when compared with conventional manufacturing methods such as injection and molding. This paper verifies the effect of the printing orientation on the mechanical properties of the product in the manufacture of PA12 material and providing basic data on the practical use of the materials as building subsidiary materials and structural materials. The results of the experiment showed that the product printed in the orientation of 0° showed the lowest overall strength and elongation rate, and the product printed in the orientation of 45° showed the highest figure. Overall, tensile strength and yield strength increased between 0° and 45°, and tended to decrease somewhat at 45° to 90°.

Characteristics on the Motion of Purse Seine(I) -The Sinking Behaviour of Model Purse Seine by Different Netting Material- (건착망의 운동특성(I) -그물감이 다른 건착망의 침강거동-)

  • Kim, Suk-Jong;ImaiI, Takehiko;Park, Jeong-Sik
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.4
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    • pp.362-371
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    • 1995
  • This study describes with the sinking behaviour for the purse seine. The experiment was carried out using three model purse seines of knotless netting. The nettings were woven in same leg length(10.5mm) of polypropylene 170 denier, polyamide 210 denier and polyester 250 denier two thread ply twine, each of the seines were named PP seine, PA seine and PES seine. Dimension of Purse seine models were 420cm for corkline and 85cm for seine depth, each models rigged 65.8g, 50.6g and 35.8g(weight in water) of lead for a leadline, seine models will have the same weight in water. Experiments carried out in the observation channel in a flume tank under still water conditions. Sinking motion was recorded by the one set of TV-camera for VTR, and reading coordinate carried out by the video digitization system. The results obtained were as follows: 1) Netting bundle for PP seine was existence on the surface of the water, spread out a netting by sinking force of sinkers. 2) Netting bundle for PES seine was existence in the middle of corkline and leadline. 3) Average sinking speed of seine margin was fastest for 10.7cm/s of PP seine, followed by 9.7cm/s of PA and 9.2cm/s of PES seines. 4) In all seines, the force of horizontal movement for the seine setting was values of ranged in disregard.

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A Study on the applicability of ultrasonic knife for processing CFRTP materials (CFRTP 소재 가공을 위한 초음파 나이프 적용 가능성에 관한 연구)

  • Ki-Hyeok Song;Hye-Jin Kim;Ji-young Park;Si-Myung Sung
    • Design & Manufacturing
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    • v.17 no.2
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    • pp.9-14
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    • 2023
  • In this study, an experiment was conducted to confirm the applicability of the external shape control of the ultrasonic knife to the CFRTP material, which is the base material of thermoplastic. TC910 based on polyamide6 (PA6) was used as the material. The slope 와 and tool transfer speed of the material and tool were selected as process factors for processing, and the following results were obtained. Under all cutting conditions using an ultrasonic knife, friction heat caused by high-frequency vibration was issued at 150℃ at the contact part between the material and the knife during cutting. As a result of the cutting force analysis, the faster the transfer speed, the higher the cutting force as the angle of entry of the blade increased, and the size of the cutting force changed during cutting. As for the size of the burr in accordance with the transfer speed condition, the smallest burr occurred at 150mm/min in the side part, and the smallest burr occurred at 150mm/min and 200mm/min in the case of the outlet burr. The size of the burr according to the entry angle tended to decrease as the tool entry angle increased, and the side part tended to increase as the tool entry angle increased. As a result of the cutting surface analysis, it was confirmed that the base material was eluted under all conditions, and the faster the transfer speed, the lower the elution phenomenon of the base material. Based on the above results, cutting the CFRTP material with an ultrasonic knife is possible, but the effect on heat generation caused by friction needs to be minimized, and further research needs to be conducted on this.