• 제목/요약/키워드: Polyamide-6(PA-6)

검색결과 62건 처리시간 0.031초

나일론 6과 폴리프로필렌 수지에 유리섬유가 보강된삼상 복합재료에 관한 연구 (A Study on the Three Phase Glass Fiber/Nylon 6/Polyproylene Composites)

  • 서문호
    • 유변학
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    • 제10권2호
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    • pp.57-64
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    • 1998
  • A pultrusion resin impregnation (PRI) die, which has been developed recently in our laboratory, was used to pre-pare various composite system. The continuous fiber reinforced composites of glass fiber/polypropylene(GFPP) and glass fiber/polyamide 6 (GFPA) were first manufactured by means of the PRI die and then cut into chopped pellets of predet-ermined length. These pellets and either virgin or modified thermoplastic resin were melt-mixed by a twin screw extruder to prepare GF/PA/PP and GF/PA/PPMA system. The mechanical properties of these blends were investigated and discussed in terms of their morphological observations. These preliminary results revealed that this new impregnation die could be suc-cessfully applied to produce prepregs suitavle for the final shaping process.

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Poly(trimethylene terephthalate)/Polyamide 6 및 6,6의 용융블렌드시 블렌드조건에 따른 에스테르-아미드 교환반응 정도와 유변특성 (The effect of blending condition on the ester-amide exchange reactions and their rheological properties of Poly(trimethylene terephthalate)/Polyamide 6 or 6,6 Blends)

  • 이현주;김학성;임경율;김병철
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2001년도 가을 학술발표회 논문집
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    • pp.183-186
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    • 2001
  • 폴리에스테르/폴리아미드의 블렌드는 두 고분자의 단점을 상호 보완할 수 있을 뿐만 아니라 조성비에 의해 원하는 물성을 부여할 수 있는 장점이 있다. 이들 블렌드 중에서 폴리(에틸렌 테레프탈레이트)(PET)/폴리아미드(PA)의 블렌드의 경우 일반적인 폴리에스테르계의 블렌드에서 일어나는 에스테르 교환반응과 마찬가지로 에스테르-아미드 교환반응이 일어나며 이를 이용하여 두 고분자간의 상용성을 향상시키려는 연구가 보고된 바 있다. (중략)

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탄성중합체 함유량 변화에 따른 폴리아미드-6,6/탄성중합체 블랜드물의 특성 (Properties of PA 6,6/Elastomer Blends with Various Elastomer Content)

  • 이융;이창우;차윤호;함영민
    • Elastomers and Composites
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    • 제34권1호
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    • pp.20-30
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    • 1999
  • 본 연구는 용융법에 의한 폴리아미드 6,6(PA 6,6)과 에틸렌-프로필렌 고무(EPM) 및 무수 말레인산 그라프팅 EPM(EPM-g-MA)과 블랜딩시 탄성중합체 함유량 변화에 따른 이성분 PA 6,6/ EPM[EPM-g-MA] 블랜드물과 EPM:EPM-g-MA 조성비(wt%) 변화에 따른 삼성분 PA 6,6/ EPM/EPM-g-MA 블랜드물을 제조하여 블랜드물 내 탄성중합체의 평균 입자크기, 입자 형상 및 분포 등의 변화를 분석하고 이에 따른 블랜드물의 기계적, 열적 특성변화를 고찰하였다. 본 연구결과, 이성분 블랜드물 중 PA 6,6/EPM-g-MA 블랜드물은 PA 6,6/EPM 블랜드물에 비하여 EPM-g-MA의 평균 입자크기와 분포, 충격강도 및 상대결정화도 등이 향상되었고 PA 6,6/ EPM-g-MA 블랜드물 중 가장 큰 충격강도의 향상을 보인 PA 6,6/EPM-I-MA(70/30) 블랜드물은 폴리아미드 6,6의 충격강도에 비하여 약 25배 향상되었으며 상대결정화도는 약 7배 증가하였다. 그리고 삼성분 블랜드물 중 조성비가 70:15:15(PA 6,6 :EPM:EPM-g-MA)일 때 블랜드물 내탄성중합체 평균 입자크기는 $0.56{\mu}m$이면서 고른 입자분포를 얻을 수 있었을 뿐만 아니라 이러한 블랜드물의 충격강도는 제조된 모든 블랜드물의 충격강도에 비하여 가장 높았다.

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Phenol removal by tailor-made polyamide-fly ash composite membrane: Modeling and optimization

  • Vandana, Gupta;Anandkumar, J.
    • Membrane and Water Treatment
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    • 제10권6호
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    • pp.431-440
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    • 2019
  • A novel composite membrane was synthesized using crosslinked polyamide and fly ash ceramic substrate for phenol removal. Glutaraldehyde was used as crosslinker. Characterization shows that synthesized membrane possesses good permeability ($0.184l.m^{-2}.h^{-1}.kPa^{-1}$), MWCO (1.7 kDa), average pore size (1.08 nm) and good chemical stability. RSM was adopted for phenol removal studies. Box-Behnken-Design using quadratic model was chosen for three operating parameters (feed phenol concentration, pH and applied pressure) against two responses (phenol removal, flux). ANOVA shows that model is statistically valid with high coefficient of determination ($R^2$)value for flux (0.9897) and phenol removal (0.9302). The optimum conditions are obtained as pH 2, $46mg.l^{-1}$ (feed phenol concentration) and 483 kPa (applied pressure) with 92.3% phenol removal and $9.2l.m^{-2}.h^{-1}$ flux. Data validation with deviation of 4% confirms the suitability of model. Obtained results reveal that prepared composite membrane can efficiently separate phenol from aqueous solution.

이성분계 고분자 블렌드의 형태학에 미치는 사출 조건의 영향 (Effect of injection molding conditions on morphology of binary polymer blends)

  • 손영곤
    • 한국산학기술학회논문지
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    • 제9권1호
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    • pp.165-169
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    • 2008
  • 사출 조건이 이성분계 고분자 블렌드의 형태학에 미치는 영향을 관찰하기 위해 폴리페닐렌옥사이드 (PPO)/폴리아마이드 6 (PA 6) 블렌드를 선정하였다. 두께가 3.2 mm이고 한 변의 길이가 15 cm인 정사각형의 평판 형태의 사출물을 여러 사출 조건에서 제조하고 각 위치별로 파단시편을 제조하여 형태학을 관찰하였다. 그 결과 수지가 스크류, 노즐 스프루 게이트를 지나 최종위치에 자리 잡을 때까지 복잡한 온도, 전단력과 신장력의 영향으로 복잡한 형태학을 가짐을 알 수 있었다.

Investigation of Surface Morphology for Nylon 4,6 Thin Film by Molecular Layer Deposition

  • 권덕현;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.419-419
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    • 2012
  • We fabricated the Polyamide 4,6 (PA46) thin film using Adipoyl chloride and 1,4-butadiamine. PA46 film was grown at $70^{\circ}C$ by Molecular Layer Deposition (MLD) method. MLD is sequential and self-terminating fabrication method for organic thin film. The growth rate of PA46 is $3.5{\acute{\AA}}$ cycle. The thickness of PA46 film was measured by Ellipsometer. Surface morphology of this film was investigated by Atomic Force Microscopy (AFM) and roughness is directly proportional to number of growing cycles.

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사출 성형공정 압력에 따른 PA6/GF 복합재료의 물리적 특성 및 성능 예측 시뮬레이션에 관한 연구 (A Study on the Mechanical Properties and Performance Prediction Simulation of PA6/GF Composite Materials with Injection Molding Pressure)

  • 유성훈;김민성;윤현성;박종수;전성민;심지현
    • 한국염색가공학회지
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    • 제34권1호
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    • pp.46-57
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    • 2022
  • In this study, the relationship between fiber orientation and mechanical properties with the injection pressure of polyamide-6/glass fiber composite materials manufactured by the injection molding process was investigated. Also, an actual experimental data and finite element model-based simulation data were analyzed. Specimens were manufactured through the injection molding process setting the injection pressure differently to 700, 800, 900, and 1000 bar, respectively. A morphological analysis and orientation of the PA6/GF composite material were observed using Optical microscope. Through tensile and flexural strength tests, the mechanical properties of the PA6/GF composite materials with the injection pressure were studied. As a result, it was confirmed that the mechanical properties were the superior under the injection pressure of 900 bar molding conditions. In addition, the mechanical properties of the actually manufactured specimen (PA6/GF) and virtual engineering S/W((Digimat, Abaqus) were used to compare and analyze the analysis results for the mechanical properties, and based on the reliable DB, the physical properties of the PA6/GF composite characteristics were studied.

Desalting enhancement for blend polyethersulfone/polyacrylonitrile membranes using nano-zeolite A

  • Mansor, Eman S.;Jamil, Tarek S.;Abdallah, Heba;Youssef, H.F.;Shaban, Ahmed M.;Souaya, Eglal R.
    • Membrane and Water Treatment
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    • 제10권6호
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    • pp.451-460
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    • 2019
  • Thin film composite membranes incorporated with nano-sized hydrophilic zeolite -A were successfully prepared via interfacial polymerization (IP) on porous blend PES/PAN support for water desalination. The thin film nanocomposite membranes were characterized by SEM, contact angle and performance test with 7000 ppm NaCl solution at 7bar. The results showed that the optimum zeolite loading amount was determined to be 0.1wt% with permeate flux 29LMH.NaCl rejection was improved from 69% to 92% compared to the pristine polyamide membrane where the modified PA surface was more selective than that of the pristine PA. In addition, there was no significant change in the permeate flux of the thin film nanocomposite membrane compared with that of the pristine PA in spite of the formation of the dense polyamide layer. The stability of the polyamide layer was investigated for 15 days and the optimized membrane presented the highest durability and stability.

Reactive blends of poly(butylene terephthalate)/polyamide-6 with ethylene glycidyl methacrylate

  • Han, M.S.;Lim, B.H.;Jung, H. C.;Hyun, J.C.;Kim, S.R.;Kim, W.N.
    • Korea-Australia Rheology Journal
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    • 제13권4호
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    • pp.169-177
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    • 2001
  • Morphological, thermal, rheological, and mechanical properties of reactive compatabilized blends of poly(butylene terephthalate) (PBT) and Polyamide-6 (PA) containing EGMA copolymer were investigated using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), advanced rheometric expansion system (ARES), and universal testing machine (UTM). From the results of thermal analysis by DSC, the melting point of the 30/70 PBT-PA blend was broadened after EGMA was added in the blends, since the enthalpy of melting of the PBT-PA somewhat decreased with the increase of EGMA content. From this result, it is suggested that the EGMA affected to the crystallization behavior and crystallinity of the PBT-PA blends. From SEM micrographs of the 70/30, 50/50, and 30/70 PBT-PA blends, the droplet size of the 30/70 PBT-PA blend was about 0.8 ${\mu}{\textrm}{m}$ which was smaller than that of the 50/50 and 70/30 PBT-PA blends. The complex viscosity of the 30/70 PBT-PA blend observed to be higher than that of the 50/50 and 70/30 PBT-PA blends. From the results of the morphology and rheological properties for the PBT-PA blends, it is suggested that the compatibility is increased in the 30/70 PBT-PA blend than the 50/50 and 70/30 PBT-PA blends. From the results of mechanical properties, it was found that the tensile strength of the 30/70 PBT-PA blend increased with the increase of EGMA up to 2 phr, while tensile strength of the blend in which EGMA content was higher than 2 phr decreased with the increase of EGMA content. From the results of morphological, thermal, rheological, and mechanical properties for the PBT-PA-EGMA blends, it is suggested that the EGMA could be used as a compatibilization role in the blends.

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In-situ Synthesis of Polyamide-6/POSS Nanocomposites

  • Ramasundaram Subramaniya Pillai;Kim Kap-Jin
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.303-303
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    • 2006
  • In-situ ring opening polymerization of ${\varepsilon}-caprolactum$ was carried out in the presence of aminoethylaminopropylisobutyl POSS and stoichiometric amount of adipic acid. The covalent bond formation of POSS on the polyamide was confirmed by the appearance of FT-IR peak at $1123\;cm^{-1}$ that corresponds to the Si-O stretching of POSS structures. Gradual decrease in melting endotherm peak was observed on loading POSS in PA6/POSS nanocomposites. Sharp increase in intrinsic viscosity was observed upto 2.5 wt % loading POSS in the polyamide 6 nanocomposites. These nanocomposites were further characterized using nuclear magnetic resonance, melt viscosity and X-ray diffraction.

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