• Title/Summary/Keyword: Poly propylene

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Development of ultra high voltage-large capacity O.F cable (초고압 대용량 O.F 케이블의 개발)

  • Kang, S.H.;Lee, K.J.;Kim, C.S.;Choi, Y.H.
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.265-267
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    • 1991
  • In this paper, we describe the development of 345kv OF cables to contain also the cable employing new insulation paper, PPLP (Poly propylene Laminated paper). The cables all show very excellent properties, especially PPLP cable has less the dielectric loss and better the impulse & A.C strength than the one employing the conventional paper. Therefore, according to use PPLP cable, it seems to be several advantages such as the compact of system, the increasing capacity, and the decreasing energy loss etc.

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조절방출성 약제를 위한 소프트 하이드로겔 소재의 개발

  • 이승진;구영순
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1994.04a
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    • pp.196-196
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    • 1994
  • DDS에 활용될 수 있는 고분자 소재를 개발할 목적으로 물성 및 응용성이 우수한 고분자 겔에 관한 연구를 수행하였다. Ethylene oxide,propylene oxide 각각의 copolymer인 poloxamer등의 prepolymer들을 triisocyanate로 가교시키고 diisocyanate 로 chain이 연장된 "soft hydrogel"을 제조하였다. 모델 약물을 선정하여 crosslinker와 extender의 조절에 따른 hydrogel의 약물 방출 조절능을 조사하였으며 그 기전을 규명하고자 하였다. 가교부위에 urethane bond를 함유한 soft hydtogel은 건조상태에서도 고무와 같은 전연성을 보여 일반적인 hydrogel과 대비되는 특성을 보였으며 이에 따른 다양한 활용성이 기대되었다. Extender및 crosslinker의 비율에 따라서 이 rubber elasticity가 조절되었다. 가교도가 감소할수록 팽윤도가 상승하였고 이에 따른 약물방출도 증가함을 확인하였다. 또한 Prepolymer의 분자량 및 친수/소수성등의 물성에 따라 약물방출을 조절할 수 있었다. 제조된 hydrogel에 조절방출시 필요한 기능을 부가시키고자 poly(carylic acid)류와 IPN 공중합체를 합성하여 물성을 조사하였고 비이온성/양이온성/음이온성 모델약물을 선정하여 pH에 따른 가변적 팽윤도와 이온성 상호작용등에 근거한 약물 조절방출기전을 조사하였다.기전을 조사하였다.

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Assessment of Radiation Degradation of Insulating Materials using Thermogravimetry Analysis (열중량 분석에 의한 유기절연재료의 방사선 열화 평가)

  • Kim, K.Y.;Ryu, B.H.;Lee, C.;Lim, K.J.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1537-1539
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    • 2001
  • The radiation degradation of five insulating materials such as silicone rubber, ethylene-propylene rubber polybutylene terephthalte, poly carbonate, nylon 66 were evaluated by using thermogravimetry analysis (TGA) and tensile properties as a function of radiation doses. The results of temperature at 5% weight loss and activation energy from TGA showed linearly decreasing and increasing tendency as radiation doses comparing with tensile properties. Consequently, the assessment of TGA for the radiation degradation of materials was effective.

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Characterization of a Cross-linked Polymer Electrolyte Prepared from Oligo(ethylene glycol) methacrylates-Acrylonitrile

  • Lee, Chang-Ryoul;Hyun, Seok-Hee;Lee, Suk-Kee;Kim, Woo-Sik;Moon, Seong-In;Jin, Bong-Soo
    • Macromolecular Research
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    • v.9 no.5
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    • pp.292-295
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    • 2001
  • A cross-linked solid polymer electrolyte was prepared by copolymerizing photochemically acrylonitrile (AN), oligo(ethylene glycol ethyl ether) methacrylate, oligo(ethylene glycol) dimethacrylate in the presence of lithium perchlorate as a lithium salt, ethylene carbonate-propylene carbonate as a mixed plasticizer, and poly(ethylene oxide) as a polymer matrix. The maximum ionic conductivity of the polymer electrolyte was 2.35$\times$10$\^$-3/ S/cm. The interface resistance of the polymer electrolyte was very low compared to that of the polymer electrolyte without AN. The former electrolyte was stable up to 4.3 V and the Ah efficiency was nearly 100% during the charge-discharge cycle.

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The development of biodegradable resin for scaffold fabrication using micro-stereolithography and curing characteristics analysis of the resin (마이크로 광 조형기술을 이용한 인공지지체의 제작을 위한 생분해성 수지의 개발 및 경화 특성 파악)

  • Lee J.W.;Cho D.W.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.147-148
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    • 2006
  • A research on scaffold fabrication has been progressed in many research groups. However, the mechanical properties of existing biodegradable materials are still not satisfactory. But, PPF (poly (propylene fumarate)) has a good mechanical property in comparison to other biodegradable materials. Nevertheless, the viscosity of the synthesized PPF is too high to fabricate structures using micro-stereolithography. Therefore, the viscosity of the resin was made low by adding the diethyl fumarate and this material could be used in micro-stereolithography apparatus. Then, a photoinitiator was added for photo crosslinking of the DEF/PPF resin. 2.5D and 3D scaffolds were fabricated our system and curing characteristics of the resin were analyzed through the experiment.

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Polarized Raman Spectroscopic Studies of Syndiotactic Polypropylene (편광 Raman 분광법을 이용한 Syndiotactic Polypropylene에 관한 연구)

  • 진정희;임현주;김성수;송기국
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.745-751
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    • 2002
  • The anisotropic Raman scattering properties of oriented syndiotactic poly propylene have been investigated using FT-Raman spectrometer in which the fluore scent problem of polymer samples can be removed. To assign the observed Raman bands to their respective symmetry species, the anisotropic scattering results for four different combinations of incident and scattered polarization were compared with those predicted by normal coordinate analysis and infrared dichroism measurement data.

Quality Characteristics of Lightweight Cement Composite using Lightweight Aggregates and Expanded Perlite (경량골재와 팽창펄라이트를 활용한 경량 시멘트복합체의 특성)

  • Kim Duck-Mo;Mun Kyoung-Ju;Soh Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.533-536
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    • 2004
  • This study aims to manufacture and to evaluate lightweight cement composite using lightweight aggregate and expanded perlite. The expanded perlite and lightweight aggregates were mixed with cement, water, SP(superplasticizer), forming-agent and poly-propylene fiber. The specimens were cured at $20^{\circ}C$ for 24h and then at steam curing of $60^{\circ}C$, RH $100\%$ for 12h. As a result, We could make lightweight cement composite of satisfaction about ALC properties. However it is need to improve the properties of density and water absorption.

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A Study on PolyPropylene-base Functionalized Polyolefin for Secondary Battery Lead Tab Tape (이차전지 리드 탭 테이프용 폴리프로필렌 기반 기능성 폴리올레핀에 관한 연구)

  • Deok-Ho Kim
    • Journal of the Korean Society of Industry Convergence
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    • v.27 no.3
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    • pp.619-627
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    • 2024
  • By analyzing the structure of the currently used Lead Tab tape structure, the outermost layer, low-temperature fusion functionalized olefin, was composed of pp base. To determine whether this could be used as the outermost layer of tab tape, the adhesive strength to metal foils such as copper and aluminum was measured and the adhesive strength was compared with commercially available functionalized olefin. When chlorine was grafted onto PP among the PP used in the composition, the average adhesive strength was similar to that of commercially available LT200T and superior to RE140R and LE320V. The maximum adhesive strength exceeded that of LE200T. When it comes to solvents, xylene has been shown to be better than any other. Physical methods such as substitution of other monomers, switching of additives or let-down hardly changed the adhesion of grafted PP, and the selection of PP is an important factor in preparing functional polymers.

Polymeric Additive Influence on the Structure and Gas Separation Performance of High-Molecular-Weight PEO Blend Membranes (고분자량 PEO 기반 분리막에 대한 다양한 고분자 첨가제의 영향 분석)

  • Hyo Jun Min;Young Jae Son;Jong Hak Kim
    • Membrane Journal
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    • v.34 no.3
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    • pp.192-203
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    • 2024
  • The advancement of commercially viable gas separation membranes plays a pivotal role in improving CO2 separation efficiency. High-molecular-weight poly(ethylene oxide) (high-Mw PEO) emerges as a promising option due to its high CO2 solubility, affordability, and robust mechanical attributes. However, the crystalline nature of high-Mw PEO hinders its application in gas separation membranes. This study proposes a straightforward blending approach by incorporating various polymeric additives into high-Mw PEO to address this challenge. Four commercially available, water-soluble polymers, i.e. poly(ethylene glycol) (PEG), poly(propylene glycol) (PPG), poly(acrylic acid) (PAA), and poly(vinyl pyrrolidone) (PVP) are examined as additives to enhance membrane performance by improving miscibility and reducing PEO crystallinity. Contrary to expectations, PEG and PPG fail to inhibit the crystalline structure of PEO and result in membrane flaws. Conversely, PAA and PVP demonstrate greater success in altering the crystal structure of PEO, yielding defect-free membranes. A thorough investigation delves into the correlation between changes in the crystalline structure of high-Mw PEO blend membranes and their gas separation performance. Drawing from our findings and previously documented outcomes, we offer insights into designing and selecting additive polymers for high-Mw PEO, aiming at the creation of cost-effective, commercially viable CO2 separation membranes.

Preparation of Magnetite Nanoparticles Encapsulated with Biodegradable Polymer (PLGA) (생분해성 고분자(PLGA)로 캡슐화한 Magnetite 나노입자의 제조)

  • Lee, Ho-Seok;Choung, Il-Yeop;Song, Ki-Chang;Ahn, Yang-Kyu;Choi, Eun-Chung
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.107-110
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    • 2006
  • Magnetite nanoparticles encapsulated with biodegradable polymer [poly(D,L-lactide-co-glycoiide), PLGA] were prepared by an emulsification-diffusion method. To investigate the effect of type of organic solvents on the mean particle sizes of obtained composite particles, different organic solvents [ethyl acetate (EA), propylene carbonate (PC) and acetone (ACE)] were used with a stabilizer [didodecyl dimethyl ammonium bromide (DMAB)]. The particle size of nanoparticles was observed by the dynamic light scattering method. When EA and PC as partially water-soluble solvents were used, small composite nanoparticles below 80nm were obtained, while large composite nanoparticles above 330nm were prepared for ACE as a fully water-soluble solvent.