• Journal of Adhesion and Interface
• /
• v.8 no.1
• /
• pp.8-14
• /
• 2007

Poly(urethane-methyl methacrylate) hybrid emulsions can be controlled with their thermal, mechanical and anti-chemical properties as plastic coating materials. In this study, water dispersed poly(urethane-methyl methacrylate) hybrid emulsions were prepared by prepolymer synthesis and soap free emulsion polymerization. For imparting hydrophilicity on polyurethane prepolymer, 2,2-bis (hydroxymethyl) propionic acid was added to the polyurethane prepolymer with methyl methacrylate monomer and was neutralizated by triethylamine (TEA). After neutralization, the prepolymer mixture was dispersed in the water phase with stable droplets. The synthesis was carried out with chain extension from the ethylene diamine and initiation of methyl methacrylate by soap free emulsion polymerization. Stable poly(urethane-methyl methacrylate) hybrid emulsion was successfully obtained with different synthetic conditions and acrylic monomer contents. Poly(urethane-methyl methacrylate) hybrid emulsion were characterized and compared with tensile strength, viscosity, and adhesion properties.

• Journal of Adhesion and Interface
• /
• v.24 no.2
• /
• pp.69-75
• /
• 2023

Recently, the application of paint protection films (PPFs) for automobiles having a self-recovery coating layer has been grown up. In this study, we report the evaluation results on the basic physical properties of a poly(vinyl chloride)- based PPF containing poly(urea-urethane) hybrid self-recovery coating layer. Depending on the main chemical composition and the thickness of poly(urea-urethane)-based coating layer for PPF, the self-recovery performance by an optical microscope and the stain resistance through color difference value are measured. To improve the surface properties and show its easy-cleaning effect against the polluted things, silicone-modified polyacrylate is introduced to the self-recovery coating composition. The contact angle of water on the coated surface is confirmed to show its hydrophobic surface. Finally, accelerated weathering test of paint protection film with poly(urea-urethane) hybrid coating layer is performed to check the possibility of discoloration and deformation due to long-term exposure on harsh condition.

• Journal of Korean Ophthalmic Optics Society
• /
• v.11 no.1
• /
• pp.49-53
• /
• 2006

Acrylate -PDMS(Polydimethylsiloxane)-Urethane Prepolymer is synthesized through treating diisocynate, HEMA(2-hydroxyethylmethacrylate) and bis(hydroxyalkyl)terminated Poly(dimethylsiloxane) having high oxygen permeability under the DBTDL(Dibutylitin dilaurate) catalyst. Modification of HEMA on bis(hydroxyalkyl)terminated Poly(dimethylsiloxane) is to be able to polymerize with other contact lens materials. And modification of urethane on bis(hydroxyalkyl)terminated Poly(dimethylsiloxane) is to increase elastic property and oxygen transmissibility. This material is analyzed by FT-IR and also will be used to make hydrogel contact lens.

• Polymer(Korea)
• /
• v.36 no.5
• /
• pp.643-650
• /
• 2012

In order to improve the thermal stability of polyurethane, we synthesized poly(adipate urethane) (PAU) and three PAU composites, PAU/30B (2.7 wt% 30B), PAU/MP (2.2 wt% MP), PAU/30B/MP (2.2 wt% 30B and 2.2 wt% MP), from poly(oxydiethylene adipate)-diol (PAD), 4,4'-methylene diphenyl diisocyanate (MDI), Cloisite 30B (30B), and melamine phosphate (MP). 30B and MP were introduced into the reactant mixture at the initial stage of the esterification between adipic acid and diethylene glycol, so 30B and MP were evenly dispersed in the PAU composites for long period. At temperatures lower than $250^{\circ}C$, the PAU composites were degraded faster than pristine PAU, mainly due to the decomposition of 30B and MP. At higher temperatures, the 30B and MP enhanced the thermal stability of the PAU composites. Compared with the pristine PAU, the thermal decomposition rates of the PAU composites decreased by 13~17%. In air, the residual weights of PAU/30B, PAU/MP, and PAU/30B/MP were 2.4, 2.3, and 7.3 wt% at $700^{\circ}C$, respectively.

• Journal of agriculture & life science
• /
• v.45 no.4
• /
• pp.59-63
• /
• 2011

The symptoms such as weaken shape, partial and full death in nurse- and old- trees have been mostly caused by the occurrence of cavity. In general, the adaption of poly-urethane has been practised routinely in the way of treatment in cavity. However, the use of poly-urethane was not an effective, but it was related to pollution materials. Here, the experiment was conducted to identify the effects of the treatments of loess or micro-organisms for the alternatives of poly-urethane. The cavities which occurred in Zelkova serrata, Prunus yedoensis and Quercus myrsinaefolia were treated by poly-urethane, loess, mixtured loess and micro-organism (Rhadobacter), and mixtured loess and micro-organism (Rhodobacter + bacillus). As the results of this experiment, it was shown that the treatment of mixtured loess and micro-organism (Rhodobacter + bacillus) induced to develop greater callus formation in the cavity up to 97% in Zelkova serrata, up to 87% in Prunus yedoensis, and by 73% in Quercus myrsinaefolia than the treatment of poly-urethane. But the only loess and mixtured loess and micro-organism (Rhadobacter) was a similar or lower callus formation ratio than poly-urethane.

• Korean Journal of Construction Engineering and Management
• /
• v.6 no.3 s.25
• /
• pp.128-134
• /
• 2005

Up to now, the various water proofing methods and materials have been developed. For the water proofing methods, poly-urethane membrane method is one of the commonly used and increase market share in water proofing industry due to it's many advantages. However, in spite of it's many advantages over other water proofing methods, water proofing defect occurs frequently. With this respect, the study investigate water proofing defect causes in roof water proofing. The study investigate 13 water proofing construction site in Sunchon city in oder to find urethane membrane defection causes and their type. As a results of the study, the followings are founded. 1) Among various water proofing defection causes, problems of water remain phenomenon due to surface horizontal level defect which occupy $25\;\%$ of total defect causes is the most commonly occur. 2) The second defect cause which occupy $15\;\%$ of total defect causes is the swell up phenomenon due to surface dry problem. For the prevention of water proofing defection in roof using urethane membrane, the followings are recommended. 1) Faultless surface treatment before using urethane membrane 2) Develop improved urethane membrane material 3) Improve urethane membrane construction technique

• Journal of the Korean Applied Science and Technology
• /
• v.32 no.4
• /
• pp.718-723
• /
• 2015

For the fabrication of the Si negative electrode in Li-ion batteries (LIBs) containing the cross-linking polymer binder, in this work, the urethane acrylate (UA) oligomer was synthesized via a simple synthetic process. The cross-linked poly(urethane acrylate) (CPUA)/carbone black (CB)/Si composite (CPUA/CB/Si composite) was fabricated through reactions between their reactive vinyl segments in the UA oligomer. Interestingly, the CPUA/CB/Si composite showed better cycle performance than the poly(vinylidene fluoride) (PVdF)/CB/Si composite (PVdF/CB/Si composite) and the polyurethane (PU)/CB/Si composite (PU/CB/Si composite). The CPUA/CB/Si composite had the best lithiation of about $2586mAh\;g^{-1}$. The UA oligomer showed a good compatibility with the electrode materials and current collector after and before a curing process.

• Elastomers and Composites
• /
• v.53 no.2
• /
• pp.86-94
• /
• 2018

The effect of the NCO index and catalyst type on the thermal stability of poly(urethane-isocyanurate) (PUIR) foams was investigated to identify a method for enhancing the flame resistance of PUIR. PUIR foams were prepared using 4,4-diphenylmethane diisocyanate (MDI) and [(diethylene glycol)adipate]diol, which were synthesized by esterification of adipic acid and diethylene glycol. Dabco K-15, Dabco TMR-30, and Toyocat RX-5 were used as the catalysts for trimerization and gelation. The amount of urea and isocyanurate groups in PUIR was semi-quantitatively determined by normalizing their absorbance with the phenyl absorbance measured by FT-IR. The normalization data showed that Dabco TMR-30 effectively generated isocyanurate groups in PUIR. As a result, Dabco TMR-30 effectively raised the decomposition temperature and increased the 800 K and 900 K residues of the PUIR foam synthesized with an NCO index of 200.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2006.05a
• /
• pp.43-46
• /
• 2006

In this study on the appliable Asphalt sheet of monolithic and inorganic matter waterproofing material using of field because of problem of complex waterproofing sheet. Before this cement polymer modified waterproof coating and appliable asphalt sheet of monolithic whether have stability by method of construction about all style waterproofing that evaluate to new method of construction development naturally big emphasis put and try to approach. Did performance test item first at, as a result, drew by suitable thing in all KS items. This is considered to have more effective spot construction work because if means that have stability by material as well as method of construction.

• Korean Journal of Applied Biomechanics
• /
• v.25 no.3
• /
• pp.363-370
• /
• 2015

Objective : The purpose of this study was to give the basic data for the cutting movement with the various angels on the poly urethane. Method : Ten healthy men voluntarily participated in this study. A three-dimensional motion analysis system (VICON) and force plates were used to analyze the movements of the joints for the lower extremities. For the statistical analysis the IBM SPSS 21.0 was used to perform repeated measured ANOVA and post-hoc comparison result was used to perform the Scheffe and the level of significance was set up at ${\alpha}=.05$. Results : There were significant differences for the time required for the increasing angles of the cutting movement(p<.05). In addition, there were significant differences for the maximum dorsiflexion, plantarflexion of ankle joint, maximum flexion of knee joint and hip joint with the increasing the angles of cutting movement(p<.05). Also, there were significant differences for the maximum adduction and abduction angle of the hip joint with the increasing of the angles of cutting movement. There was signigicant difference for the resultant utilized coefficient of friction(RuCOF) for the increasing angles of cutting movement(p<.05). Conclusion : There was a pattern to increase the coefficient friction with the angle of cutting direction. Also, it would be possible to use the poly urethane for the outdoor floor with the results of this study.