• Title/Summary/Keyword: Poly (/-lactic acid)

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The Deodorization and Antibacterial Activities of PLA Films Embedded with TiO2 Nanoparticles (TiO2 나노입자를 함유한 PLA 필름의 탈취성과 항균성)

  • Koo, Gwang-Hoe;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.20 no.6
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    • pp.1-7
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    • 2008
  • The effects of $TiO_2$ contents and UV irradiation treatment on the surface properties of PLA films embedded with $TiO_2$ nanoparticle were investigated. Whereas UV irradiation decreased reflectance of the treated PLA films proportionally with increasing UV energy, the reflectance of PLA/$TiO_2$ films increased with increasing UV energy. The UV irradiation treatment caused PLA/$TiO_2$ blend films more polar as indicated in the generation of new carbonyl group and decrease in zeta potentials, which was more pronounced with the introduction of $TiO_2$. Upon UV irradiation, $TiO_2$ particles appeared on the film surface as observed in SEM images. The PLA/$TiO_2$ blend films showed photocatalytic properties such as photobleaching of methylene blue, deodorization of ammonia and antimicrobial activity in comparison with pure PLA films.

Fabrication and Cell Culturing on Carbon Nanofibers/Nanoparticles Reinforced Membranes for Bone-Tissue Regeneration

  • Deng, Xu Liang;Yang, Xiao Ping
    • Carbon letters
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    • v.13 no.3
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    • pp.139-150
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    • 2012
  • Poly-L-lactic acid (PLLA), PLLA/hydroxyapatite (HA), PLLA/multiwalled carbon nanotubes (MWNTs)/HA, PLLA/trifluoroethanol (TFE), PLLA/gelatin, and carbon nanofibers (CNFs)/${\beta}$-tricalcium phosphate (${\beta}$-TCP) composite membranes (scaffolds) were fabricated by electrospinning and their morphologies, and mechanical properties were characterized for use in bone tissue regeneration/guided tissue regeneration. MWNTs and HA nanoparticles were well distributed in the membranes and the degradation characteristics were improved. PLLA/MWNTs/HA membranes enhanced the adhesion and proliferation of periodontal ligament cells (PDLCs) by 30% and inhibited the adhesion of gingival epithelial cells by 30%. Osteoblast-like MG-63 cells on the randomly fiber oriented PLLA/TEF membrane showed irregular forms, while the cells exhibited shuttle-like shapes on the parallel fiber oriented membrane. Classical supersaturated simulated body fluids were modified by $CO_2$ bubbling and applied to promote the biomineralization of the PLLA/gelatin membrane; this resulted in predictions of bone bonding bioactivity of the substrates. The ${\beta}$-TCP membranes exhibit good biocompatibility, have an effect on PDLC growth comparable to that of pure CNF membrane, and can be applied as scaffolds for bone tissue regeneration.

Examination of heat resistant tensile properties and molding conditions of green composites composed of kenaf fibers and PLA resin

  • Ben, Goichi;Kihara, Yuichi;Nakamori, Keita;Aoki, Yoshio
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.361-376
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    • 2007
  • Disposing of conventional fiber-reinforced polymers (FRPs) poses an environmentally challenging problem. Disposal of FRPs by combustion discharges carbon dioxide in the air because the resin of FRPs is made of fossil fuel. When they are disposed of in the ground, FRPs remain semipermanently without decomposing. In response to these problems, green composites are now being developed and are extensively studied as a material that produces a lower environmental burden. In this paper, green composites using kenaf fiber yarn bundles and PLA (poly(lactic acid)) are fabricated and their tensile properties are evaluated in the experiment. The tensile Young's modulus of all of the laminations is larger than that of PLA alone and the tensile strength of some laminations is larger than that of PLA alone. In particular, the value of UD composite of $0^{\circ$ shows double the tensile strength of PLA alone. Furthermore, the molding conditions for fabricating with a hot press are investigated and the heat resistant tensile properties of green composites are also reported.

Preparation and Biocompatibility of Composite Bone Scaffolds Using Gnotobiotic Pig Bones (무균돼지뼈를 이용한 복합 골지지체의 제조와 생체적합성 평가)

  • Im, Ae-Lee;Chung, Jong-Hoon;Lim, Ki-Taek;Choung, Pill-Hoon;Hong, Ji-Hyang
    • Journal of Biosystems Engineering
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    • v.32 no.1 s.120
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    • pp.50-56
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    • 2007
  • Highly porous composite bioceramic bone scaffolds were developed using sintered gnotobiotic pig bones. These scaffolds consisted of poly-D,L-lactic acid (P(D,L)LA) and bioceramic materials of pig bone powder. The bone scaffolds were able to promote biocompatibility and possess interconnected pores that would support cell adhesion and proliferation adequately. The composite scaffolds were tested with dental pulp stem cells for cytotoxicity test. Cells seeded on the composite scaffolds were readily attached, well proliferated, as confirmed by cytotoxicity test, and cell adhesion assessment. The composite bone scaffold had no toxicity in cytotoxicity test on the extract of 0.013 g scaffold to 2 ml culture medium. The cells on the composite bone scaffold proliferated better than cells on the P(D,L)LA scaffolds.

Effect of Alkyl Ketene Dimer(AKD) on Red Algae Reinforced Biocomposites (AKD 처리한 홍조류섬유 보강 바이오복합재료의 특성)

  • Lee, Min-Woo;Park, Dong-Hui;Seo, Yung-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.2
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    • pp.66-71
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    • 2011
  • Biocomposites were fabricated with biodegradable polymers and natural fibers. Biocomposites have benefits of low cost, low density, and biodegradability over inorganic fiber composite, and give comparable strength properties. Hydrophobic polymer used for sizing in paper industry, AKD (Akenyl Keten Dimer), was applied to natural fibers, red algae fibers (RAF) in this study, to make fiber surfaces more compatible to hydrophobic nature of matrix polymers. Composites with RAF, kenaf, glass fibers, and carbon fibers have been fabricated by a compression molding method and their thermo-mechanical properties have been studied. Also, the thermal dimensional stability test was done from at 30 to $100^{\circ}C$. The storage moduli and the thermo-mechanical stabilities of polypropylene and poly lactic acid based biocomposites were improved by reinforcing with the RAF and much more with AKD treated fibers. Dimensional stability of biocomposite was also markedly improved by AKD pretrement on RAF.

Characteristics of Biodegradable Plastic Drain Board (생분해성 플라스틱 연직배수재의 특성)

  • Kim, Ju-Hyong;Cho, Sam-Deok;Chai, Jong-Gil;Sato, Hideyuki
    • Journal of the Korean Geosynthetics Society
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    • v.9 no.3
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    • pp.67-75
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    • 2010
  • The tensile strength, permeability and discharge capacity of biodegradable plastic drain boards made with poly lactic acid (PLA) have been tested and verified prior to their usage at field. Based on test results, the tensile strength of biodegradable plastic drain board made with PLA has relatively lower tensile strain and tensile strength than those of plastic drain board. Performance of PLA filter having good permeability and low opening size is proper for the filter of vertical drain board. In case of improving stiffness of PLA filter, biodegradable plastic drain board also satisfies required discharge capacity as use of vertical drain board too.

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In vitro and in vivo Application of PLGA Nanofiber for Artificial Blood Vessel

  • Kim, Mi-Jin;Kim, Ji-Heung;Yi, Gi-Jong;Lim, Sang-Hyun;Hong, You-Sun;Chung, Dong-June
    • Macromolecular Research
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    • v.16 no.4
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    • pp.345-352
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    • 2008
  • Poly(lactic-co-glycolic acid) (PLGA) tubes (5 mm in diameter) were fabricated using an electro spinning method and used as a scaffold for artificial blood vessels through the hybridization of smooth muscle cells (SMCs) and endothelial cells (ECs) differentiated from canine bone marrow under previously reported conditions. The potential clinical applications of these artificial blood vessels were investigated using a canine model. From the results, the tubular-type PLGA scaffolds for artificial blood vessels showed good mechanical strength, and the dual-layered blood vessels showed acceptable hybridization behavior with ECs and SMCs. The artificial blood vessels were implanted and substituted for an artery in an adult dog over a 3-week period. The hybridized blood vessels showed neointimal formation with good patency. However, the control vessel (unhybridized vessel) was occluded during the early stages of implantation. These results suggest a shortcut for the development of small diameter, tubular-type, nanofiber blood vessels using a biodegradable material (PLGA).

Preparation of Collagen/Poly(L-lactic acid) Composite Material for Wound Dressing

  • Lee, Jung-Soo;Kim, Jae-Kyung;Park, So-Ra;Chang, Yoon-Ho
    • Macromolecular Research
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    • v.15 no.3
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    • pp.205-210
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    • 2007
  • Collagen is the major structural protein of connective tissues. It can be used as a prosthetic biomaterial applicable to artificial skin, tendon, ligaments, and collagen implants. The objective of this study is to investigate the possibility of realizing wound dressing medical products by the synthesis of composite materials with collagen and a biodegradable polymer, PLLA, via a surface modification process. Type I collagen was obtained from pig skin by a separation process. The structural characteristics of the extracted collagen were confirmed by SDS-polyacrylamide (PAcr) gel electrophoresis (PAGE) and FTIR. Also, PLLA-g-PAcr was synthesized by the radical polymerization of acrylamide initiated by AIBN in the presence of PLLA. The surface of PLLA was modified by the presence of the acrylamide residues. The structural characteristics of the copolymer were analyzed by FTIR, $^1H-NMR$ and contact angle measurements. The water uptake and WVTR of the collagen/PLLA-g-PAcr composite tended to increase with increasing collagen concentration and with decreasing EDC concentration.

A study of mechanical properties with FDM 3D printing layer conditions (FDM 3D Printing 적층조건에 따른 기계적 물성의 연구)

  • Kim, Bum-Joon;Lee, Hong-Tae;Sohn, Il-Seon
    • Design & Manufacturing
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    • v.12 no.3
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    • pp.19-24
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    • 2018
  • Fused deposition Modeling (FDM) is one of the most widely used for the prototype of parts at ease. The FDM 3D printing method is a lamination manufacturing method that the resin is melted at a high temperature and piled up one by one. Another term is also referred to as FFF (Fused Filament Fabrication). 3D printing technology is mainly used only in the area of prototype production, not in production of commercial products. Therefore, if FDM 3D printer is applied to the product process of commercial products when considered, the strength and dimensional accuracy of the manufactured product is expected to be important. In this study, the mechanical properties of parts made by 3D printing with FDM method were investigated. The aim of this work is to examine how the mechanical properties of the FDM parts, by changing of processing FDM printing direction and the height of stacking layer is affected. The effect of the lamination direction and the height of the stacking layer, which are set as variables in the lamination process, by using the tensile specimen and impact specimen after the FDM manufacturing process were investigated and analyzed. The PLA (Poly Lactic Acid) was used as the filament materials for the 3D printing.

Long-term Follow-up of Extensive Peri-anchor (Poly-L/D-lactic Acid) Cyst Formation after Arthroscopic Rotator Cuff Repair: A Case Report

  • Kim, Jong-Ho;Kim, Jong-Ick;Lee, Hyo-Jin;Kim, Dong-Jin;Sung, Gwang Young;Kwak, Dong-Ho;Kim, Yang-Soo
    • Clinics in Shoulder and Elbow
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    • v.22 no.2
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    • pp.100-105
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    • 2019
  • Suture anchors are commonly used in shoulder surgeries, especially for rotator cuff tears. Peri-anchor cyst formation, however, is sometimes detected on follow-up radiologic image after surgery. The purpose of this report is to discuss the case of a patient who presented with regression of extensive peri-anchor cyst on postoperative 4-year follow-up magnetic resonance imaging and had good clinical outcome despite peri-anchor cyst formation after arthroscopic rotator cuff repair.