• 제목/요약/키워드: Pollutants

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유기오염물의 분해에 의한 오염토양내 비소종 변화 영향

  • 천찬란;이상훈
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2002년도 총회 및 춘계학술발표회
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    • pp.347-350
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    • 2002
  • Arsenic speciation changes between As(V) and As(III) are subject to changes in accordance with redox conditions in the environment. It is common to find contaminated sites associated with mixed wastes including both organic pollutants and heavy metals. We conducted microcosm experiment under hypothesis that the co-disposed organic pollutants would influence on the arsenic forms and concentrations, via degradation of the organic pollutants and the consequent impact on the redox conditions in soil. Artificially contaminated soil samples were run for 40 days with control samples without artificial contamination. We noticed arsenic in the contaminated soil showed different behaviour compared with the arsenic in the control soil. The findings indicate degradation of organic pollutants in the contaminated soil influenced on the arsenic speciation and concentrations. A further work is needed to understand the process quantitatively. However, we could confirm that degradation of organic pollutants can influence on the abiotic processes associated with geochemical reactions in contaminated soil. Degradation of organic pollutants can increase the mobility and toxicity of arsenic in soil and sediment by changing redox conditions in the geological media and subsequently from As(V) to As(III).

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기상조건에 따른 부산지역 대기오염물질 농도변화와 예측에 관한 연구 (On the Prediction and Variation of Air Pollutants Concentration in Relation to the Meteorological Condition in Pusan Area)

  • 정영진;이동인
    • 한국대기환경학회지
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    • 제14권3호
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    • pp.177-190
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    • 1998
  • The concentrations of air pollutants In large cities such as Pusan area have been increased every year due to the increasing of fuels consumption at factories and by vehicles as well as the gravitation of the population. In addition to the pollution sources, time and spatial variation of air pollutants concentration and meteorological factors have a great influence on the air pollution problem. Especially , its concentration is governed by wind direction, wind speed, precipitation, solar radiation, temperature, humidity and cloud amounts, etc. In this study, we have analyzed various data of meteorological factors using typical patterns of the air pressure to investigate how the concentration of air pollutants is varied with meteorological condition. Using the relationship between meteorological factors (air temperature, relative humidity, wind speed and solar radiation) and the concentration of air pollutants (SO2, O3) , experimental prediction formulas for their concentration were obtained. Therefore, these prediction formulas at each meteorological factor in a pressure pattern may be roughly used to predict the air pollutants concentration and contributed to estimate the variation of its value according to the weather condition in Pusan city.

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관개기 대구획 광역논에서의 오염부하 원단위 (Unit Loads of Pollutants in a Paddy Fields Area with Large-Scaled Plots during Irrigation Seasons)

  • 오승영;김진수;김규성;김선종;윤춘경
    • 한국농공학회지
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    • 제44권2호
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    • pp.136-147
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    • 2002
  • Characteristics of unit loads of pollutants were investigated at a paddy fields area(Soro-ri) with large-scaled plots on loam soil during irrigation seasons of 1999 ∼2000. The average irrigation requirement of experimental paddy area are estimated at over 3,000 mm. The unit loads of pollutants in paddy fields area are determined by subtracting irrigation water load from outflow load (percolated and surface outflow loads). Surface outflow load in rainy days was calculated using the relationships of discharge and load, which are grouped into fertilizing and non-fertilizing periods. The ratios of the surface outflow load in rainy days to the total surface outflow load are 16.4% for T-N, 26.8% for T-P, and 23.3% far CODc,. The unit loads of pollutants show month-to-month and year-to-year variations, and monthly unit load of pollutants can show negative values, indicating that the paddy area acts as the pollutants sink. The average unit loads of the pollutants during irrigation seasons were estimated at 18.2 kg/ha fur T-N, 0.31 kg/ha for T-P, and 43.3 kg/ha for CODc,, which are smaller than the reported values for Kosei area in Japan.

Electro-Oxidation in Combination with Biological Processes for Removal of Persistent Pollutants in Wastewater: A Review

  • Navarro-Franco, Javier A.;Garzon-Zuniga, Marco A.;Drogui, Patrick;Buelna, Gerardo;Gortares-Moroyoqui, Pablo;Barragan-Huerta, Blanca E.;Vigueras-Cortes, Juan M.
    • Journal of Electrochemical Science and Technology
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    • 제13권1호
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    • pp.1-18
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    • 2022
  • Persistent organic pollutants (POPs) and emerging pollutants (EP) are characterized by their difficulty to be removed through biological oxidation processes (BOPs); they persist in the environment and could have adverse effects on the aquatic ecosystem and human health. The electro-oxidation (EO) process has been successfully used as an alternative technique to oxidize many kinds of the aforementioned pollutants in wastewater. However, the EO process has been criticized for its high energy consumption cost and its potential generation of by-products. In order to decrease these drawbacks, its combination with biological oxidation processes has been reported as a solution to reduce costs and to reach high rates of recalcitrant pollutants removal from wastewaters. Thus, the location of EO in the treatment line is an important decision to make, since this decision affects the formation of by-products and biodegradability enhancement. This paper reviews the advantages and disadvantages of EO as a pre and post-treatment in combination with BOPs. A perspective of the EO scale-up is also presented, where hydrodynamics and the relationship of A/V (area of the electrode/working volume of the electrochemical cell) experiments are examined and discussed.

국내 잔류성유기오염물질(Persistent Organic Pollutants) 배출목록 개발 - 부산물 PCBs, HCB, PAHs를 중심으로 - (Development of National Emission Inventories for Persistent Organic Pollutants (Unintentionally Formed PCBs, HCB and PAHs))

  • 조규탁;이동수;이지윤;김경미;이지은
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2003년도 추계학술대회 논문집
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    • pp.221-222
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    • 2003
  • 잔류성유기오염물질(Persistent Organic Pollutants, 이하 POPs)은 환경에 노출되면 장기간 잔류하면서 인체 및 생태계에 악영향을 끼치며 또한 장거리 이동하는 특징으로 인하여 전지구적인 규제ㆍ관리의 필요성이 제기되고 있다. 이러한 필요에 부응하여 UNEP를 중심으로 국제적인 관리를 위한 논의가 이루어져 2001년 5월 스톡홀름협약(Stockholm convention for Persistent Organic Pollutants)이 당사국회의에서 채택되었고, 우리나라는 외교적 서명을 함으로써 협약가입의사를 분명히 하였다. (중략)

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환경유래 식품오염물질의 우선순위 선정 기법 (Food-CRS-Korea)의 개발과 적용 (Development of Korean Food-Chemical Ranking and Scoring System (Food-CRS-Korea) and Its Application to Prioritizing Food Toxic Chemicals Associated with Environmental Pollutants)

  • 양지연;장지영;김수환;김윤관;이효민;신동천;임영욱
    • Environmental Analysis Health and Toxicology
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    • 제25권1호
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    • pp.41-55
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    • 2010
  • The aims of this study were to develop the suitable "system software" in chemical ranking and scoring (CRS) for the food hazardous chemicals associated with environmental emission and to suggest the priority lists of food contamination by environmental-origined pollutants. Study materials were selected with reference to the priority pollutants list for environment and food management from domestic and foreign research and the number of study materials is 103 pollutants (18 heavy metals, 10 PBTs, 10 EDs, and 65 organic compounds). The Food-CRS-Korea system consisted of the environmental fate model via multimedia, transfer environment to food model, and health risk assessment by contaminated food intake. We have established that health risks of excess cancer risks, hazard quotients (HQs) by chronic toxicity and HQs by reproductive toxicity convert to score, respectively. The creditable scoring system was designed to consider uncertainty of quantitative risk assessment based on VOI (Value-Of-Information). The predictability of the Food-CRS-Korea model was evaluated by comparing the presumable values and the measured ones of the environmental media and foodstuffs. The priority lists based on emissions with background-level-correction are 15 pollutants such as arsenic, cadmium, and etc. The priority lists based on environmental monitoring date are 17 pollutants including DEHP, TCDD, and so on. Consequently, we suggested the priority lists of 13 pollutants by considering the several emission and exposure scenarios. According to the Food-CRS-Korea system, arsenics, cadmium, chromes, DEHP, leads, and nickels have high health risk rates and reliable grades.

전기비저항과 투수계수 측정을 통한 celite가 가미된 필터의 투과 성능 모니터링 (Monitoring the performance of a celite-based filter by using electrical resistivity and permeability measurements)

  • 김규원;권태혁;조계춘
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2009년도 춘계 학술발표회
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    • pp.673-676
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    • 2009
  • Non-point pollutants, which mainly originate from high traffic roads and rural areas, contaminate the environment by flowing into various rivers and lakes and thus are of interest as an environmental issue. Accordingly, efforts have been made to design and maintain efficient filter systems for the control of the non-point pollutants. Meanwhile, clay-type materials are widely used for the absorption of chemicals included in pollutants and the absorption performances of various clays have been reported in the literature. Thus, the present study proposes a non-destructive monitoring method for the performance of a clay-type filter using electrical resistivity measurement. A series of experimental tests is performed on celite-based particulate filters with infiltrating non-point source pollutants having the same characteristics as pollutants on high traffic roads. Each test measures permeability, resistivity of the filter materials and resistivity of the filtrated water. As the particulate filter materials filtrate pollutants and absorb heavy chemicals (e.g., $Cr^{6+}$, lead, nickel, among others), ionic concentration increases resulting as the electrical resistivity decrease. When the filter systems approach the end of their lifetime, the electrical resistivity of the filter material converges to a very low value due to lowered filter absorption efficiency. Hence, the electrical resistivity of the filtrated water also converges to a low value due to high concentrations of heavy metals. The permeability converges to a very low value because of significantly reduced porosity due to clogging and absorption of pollutants on the filter material. The experimental results show that electrical resistivity monitoring of filter materials is a promising approach to estimation of filter performance and its life expectancy.

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국내 EGR과 SCR 장착 중형트럭 대기오염물질 배출 특성 (Characteristics of Air Pollutants Emission from Medium-duty Trucks Equipped EGR and SCR in Korea)

  • 손지환;김정화;정성운;유흥민;홍희경;문선희;최광호;이종태;김정수
    • 한국분무공학회지
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    • 제21권3호
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    • pp.130-136
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    • 2016
  • NOx and PM are important air pollutants as vehicle management policy aspect. Medium-duty truck is the main source of the pollutants although the vehicle market share is only 3.5%. National emission portion of NOx and PM form the mobile sourece are 14% and 16% respectively. In this study it was investigated that characteristics of air pollutants emission on medium duty truck equipped with EGR and SCR system. Vehicle's test reflected driving cycle on the chassis dynamometer, and applied test cycle was WHVC(World Harmonized Vehicle Cycle) mode. The test cycle include three segments, represent urban, rural and motorway driving. Based on the test results NOx, PM, HC were less emitted form SCR vehicle than EGR vehicle. And CO was less emitted form EGR vehicle than SCR vehicle due to CO oxidation reaction on DPF surface. And most air pollutants reduced as average vehicle speed increased. Pollutants were less emitted on motorway section than urban and rural sections. But highly NOx emission on motorway section was verified according to increased EGR ratio on fast vehicle speed. HC and CO additional emission was identified as 68%, 58% respectively during SCR vehicle's cold engine start emission test. NOx additional emission was detected by 24% on SCR vehicle's condition of engine cold start while not detected on vehicle equipped with EGR. SCR vehicle's additional NOx emission was derived from low reaction temperature during engine cold start condition. medium-duty truck emission characteristics were investigated in this study and expected to used to improve air pollutants management policy of medium-duty truck equipped with SCR & EGR.

이동측정차량을 활용한 부천시 대기오염의 공간 분포 특성 연구 (A study on spatial distribution characteristics of air pollutants in Bucheon-si using mobile laboratory)

  • 김종범;김창혁;노수진;황은영;박덕신;이정주;김정호
    • 한국입자에어로졸학회지
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    • 제17권1호
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    • pp.9-20
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    • 2021
  • As a large city advanced, the urban environment is becoming an issue. The contribution of vehicle emissions in air pollutants was very high according to the clean air policy support system (CAPSS). In order to improve the air quality in large cities, it is necessary to establish improvement measures by sources, analyzing the air quality of roadside. We divided Bucheon city into 4 regions to investigate the roadside pollutants of each district using the mobile laboratory (ML) and air quality monitoring station (AQMS). ML was used to measure pollutants emitted from vehicles and AQMS data was used as a comparison group of ML data. As a measurement result of pollutants in the roadside, the concentration of air pollutants in industrial & engineering complex area was the highest and concentration of air pollutants in residential & forest complex area was lower. By street, Bucheon-ro, Sinheung-ro, Sosa-ro, and Gyeongin-ro were identified as high concentrations. Therefore, further researches on preparing management measures for roads in the hot-spot area are needed.

황해 직선 항로상 대기오염물질의 측정 (Shipboard Measurements of Air Pollutants across the Yellow Sea)

  • 이승복;배귀남;진현철;김영성;문길주;심상규
    • 한국대기환경학회지
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    • 제20권1호
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    • pp.33-46
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    • 2004
  • Air pollutants were measured eight times from June 1999 to June 2002 on regular ferries cruising across the Yellow Sea between Incheon in Korea and Qingdao or Tianjin in China. PM$_{10}$ and PM$_{2.5}$ were measured as particulate matters and SO$_2$, CO, and NO$_{x}$ were measured as gaseous pollutants. On each route, sampling was made, starting two hour after departure and ending two hour before arrival. Low concentrations of gaseous pollutants that were not much varied according to sampling period and location revealed that atmosphere over the sea was not directly affected by anthropogenic emissions. However, concentrations of fine particles were generally higher than those measured at Deokjeok Island, 50km west of the western seashore, at similar periods. It was believed that considerable influence of China in the form of secondary pollutants was exerted over the sea.a.a.a.