• Title/Summary/Keyword: Polarization of water

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Controlling Water Splitting Characteristics of Anion-Exchange Membranes by Coating Imidazolium Polymer (이미다졸륨 고분자 코팅을 통한 음이온교환막의 물분해 특성 제어)

  • Kim, Do-Hyeong;Park, Jin-Soo;Kang, Moon-Sung
    • Membrane Journal
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    • v.25 no.2
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    • pp.152-161
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    • 2015
  • In this study, novel pore-filled anion-exchange membranes (PFAEMs) with low electrical resistance, high permselectivity, and low water-splitting flux property under a concentration polarization condition have been developed for the enhancement in the efficiency of electrochemical water treatment processes. The base membranes have been prepared by filling a copolymer containing quaternary ammonium groups with an excellent ion-exchange capability into a porous polyolefin substrate, showing a high performance superior to that of a commercial membrane. In addition, it was confirmed that the electrochemical membrane performances are preserved while the water-splitting flux is effectively controlled by coating an imidazolium polymer onto the surface of the base membrane. The prepared PFAEMs revealed remarkably low electrical resistances of about 1/6~1/8 compared to those of a commercial membrane, and simultaneously low water-splitting flux comparable with that of cation-exchange membranes under a concentration polarization condition.

The Study on the Electrochemical Polarization Characteristics of Hydrogen Embrittlement for Ferrite Stainless Steel with Welding Conditions (용접조건에 따른 페라이트 스테인리스강에 대한 수소취성의 전기화학적 분극특성에 관한 연구)

  • Choi, Byung-Il;Lim, Uh-Joh
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.30-35
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    • 2005
  • In order to examine the electrochemical polarization characteristics of hydrogen embrittlement far STS444 with welding conditions, this paper carried out the accelerated hydrogen osmosis test and the electrochemical polarization test. That is, in $0.5M\; H_2SO_4+0.001M\;As_2O_3$ solution, the hydrogen embrittlement behavior of STS444 added to load of $1,400kg/cm^2$ together with hydrogen osmosis by current of $30mA/cm^2$ far 60 min. was considered. In researching the electrochemical polarization characteristics of hydrogen embrittlement for STS444 with welding conditions, the previous study clarified that tensile strength or elongation became low influenced by absorption of oil or water before welding. In this paper, we proposed the advanced mechanism of hydrogen embrittlement that integrated electrochemical corrosion with the existing mechanism of hydrogen embrirtlement.

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Crevice Corrosion Evaluation of Cold Sprayed Copper (저온분사코팅구리의 틈새부식 특성 평가)

  • Lee, Min-Soo;Choi, Heui-Joo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.3
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    • pp.247-260
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    • 2010
  • The developement of a HLW disposal canister is under way in KAERI using Cold Spray Coating technique. To estimate corrosion behavior of a cold sprayed copper, a creivice corrosion test was conducted at Southwest Research Institute(SWRI) in the United State. For the measurement of repassivation potential needed for crevice corrosion, three methods such as (1) ASTM G61-86 : Cyclic Potentiodynamic Polarization Measurements, (2) Potentiodynamic Polarization plus intermediate Potentiostatic Hold method, and (3) ASTM G192-08 (THE method) : Potentiodynamic- Galvanostatic-Potentiostatic Method, were introduced in this report. In the crevice corrosion test, the occurrence of corrosion at crevice area was optically determined and the repassivation potentials were checked for three kind of copper specimens in a simulated KURT underground water, using a crevice former dictated in ASTM G61-86. The applied electrochemical test techniques were cyclic polarization, potentiostatic polarization, and electrochemical impedance spectroscopy. As a result of crevice corrosion tests, every copper specimens including cold sprayed one did not show any corrosion figure on crevice areas. And the open-cell voltage, at which corrosion reaction initiates, was influenced by the purity of copper, but not their manufacturing method in this experiment. Therefore, it was convinced that there is no crevice corrosion for the cold sprayed copper in KURT underground environment.

A Study of Changes in the Water Quality of Agricultural Reservoirs due to Drought (가뭄으로 인한 농업용 저수지의 수질 변화 연구)

  • Cho, SungHyen;Hwang, Soonho;Lee, Dongguen;Lee, Guntaek;Choi, Jung-Hoon
    • Journal of the Korean earth science society
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    • v.43 no.1
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    • pp.110-118
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    • 2022
  • Frequent drought damage has resulted in the polarization of water resources. In Korea, local periodic abnormal droughts continued to occur between 2011 and 2017, resulting in decreased water storage rates of small-scale reservoirs designed with a frequency of 10-year droughts. This decrease can degrade water quality and limit the use of already secured quantities. Therefore, to prepare for and overcome drought, quality management and recalculation of drought frequency are required. This study estimates the potential pollutants causing quality changes in the reservoir. In addition, it reviews the decrease in storage and consequent changes in the quality of a reservoir during drought.

Calculation of Multiple Scattering in Water Cloud and Application in Remote Measurement of Cloud Physical Properties (구름에서의 다중산란효과 계산 및 이를 이용한 구름 물리변수 원격 추출 방법 연구)

  • Kim, Dukhyeon;Park, Sunho;Choi, Sungcheol
    • Korean Journal of Optics and Photonics
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    • v.25 no.1
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    • pp.1-7
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    • 2014
  • Multiple scattering effects in cloud are important error sources of the Mie scattering Lidar inversion method, which should be measured to correct the Lidar equation in single wavelength Mie Lidar. We have calculated the multiple scattering effects in liquid water clouds by using a Monte Carlo method, and we have applied these multiple scattering effects in measuring water cloud effective size and LWC (Liquid Water Content). When cloud effective size is less than $2.5{\mu}m$, we can easily extract cloud effective size and LWC by using two wavelength Lidar such as extinction coefficients measured at 355nm and 1064nm. For a larger size cloud, we can find that saturated degree of linear polarization is strongly correlated with cloud effective size, LWC, and extinction coefficients. From these correlations we know that we can measure LWC and cloud effective size if we use single wavelength Rotational Raman Lidar and Mie scattering polarization Lidar.

Evaluation of hydrological applicability for rainfall estimation algorithms of dual-polarization radar (이중편파 레이더의 강우 추정 알고리즘별 수문학적 적용성 평가)

  • Lee, Myungjin;Lee, Choongke;Yoo, Younghoon;Kwak, Jaewon;Kim, Hung Soo
    • Journal of Korea Water Resources Association
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    • v.54 no.1
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    • pp.27-38
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    • 2021
  • Recently, many studies have been conducted to use the radar rainfall in hydrology. However, in the case of weather radar, the beam is blocked due to the limitation of the observation such as mountain effect, which causes underestimation of the radar rainfall. In this study, the radar rainfall was estimated using the Hybrid Sacn Reflectivity (HSR) technique for hydrological use of weather radar and the runoff analysis was performed using the GRM model which is a distributed rainfall-runoff model. As a result of performing the radar rainfall correction and runoff simulation for 5 rainfall events, the accuracy of the dual-polarization radar rainfall using the HSR technique (Q_H_KDP) was the highest with an error within 15% of the ground rainfall. In addition, the result of runoff simulation using Q_H_KDP also showed an accuracy of R2 of 0.9 or more, NRMSE of 1.5 or less and NSE of 0.5 or more. From this study, we examined the application of the dual-polarization radar and this results can be useful for studies related to the hydrological application of dual-polarization radar rainfall in the future.

Characteristics of Flux Decline in Forward Osmosis Process for Asymmetric Cellulose Membrane (정삼투 공정에 있어 비대칭 셀룰로오즈 막의 투과유속 감소특성)

  • Lee, Keun-Woo;Han, Myeong-Jin;Nam, Suk-Tae
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.328-334
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    • 2014
  • This study examined the effect of concentration polarization on permeate flux in forward osmosis (FO) membrane process for saline and sucrose solution. The reduction in permeate flux during the FO membrane process is largely due to the formation of concentration polarization on membrane surfaces. The flux reduction due to internal concentration polarization formed on the porous support layer was larger than that due to the external concentration polarization on the active membrane surface. Water permeate flux through the FO membrane increased nonlinearly with the increase in osmotic pressure. The water permeability coefficient was $1.8081{\times}10^{-7}m/s{\cdot}atm$ for draw solution on active layer (DS-AL) mode and $1.0957{\times}10^{-7}m/s{\cdot}atm$ for draw solution on support layer (DS-SL) mode in NaCl solution system. The corresponding membrane resistance was $5.5306{\times}10^6$ and $9.1266{\times}10^6s{\cdot}atm/m$, respectively. With respect to the sucrose solution, the permeate flux for DS-AL mode was 1.33~1.90 times higher than that for DS-SL mode. The corresponding variation in the permeation flux (J) due to osmotic pressure (${\pi}$) would be expressed as $J=-0.0177+0.4506{\pi}-0.0032{\pi}^2$ for the forward and $J=0.0948+0.3292{\pi}-0.0037{\pi}^2$ for the latter.

Corrosion behaviors of cement mortar specimens with different cover thickness in natural sea water

  • Jeong, Jin-A;Jin, Chung-Kuk;Jeong, Eun-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.2
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    • pp.107-111
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    • 2016
  • This paper presents electrochemical corrosion behaviors of cement mortar specimens in the high salinity condition. Chloride ion is known as the most detrimental parameter to cause the corrosion in reinforced concrete. Increasing the concrete cover thickness is one of the corrosion protection methods against chloride ion; so, this study mainly focuses on the effects of mortar cover thickness on corrosion protection. In specimens, rebar, which was a height of 200 mm and a diameter of 10 mm, was installed at the center of the small size form. Later on, mortar was injected into the form, and 10, 20, 30, 40, and 50 mm of the different mortar cover thicknesses were selected. Potential measurements, linear polarization resistance tests, and cyclic potentiodynamic polarization tests were performed for specimens that were exposed to seawater. These results were compared with visual inspection results of rebar. The results show that an increase in the cover thickness contributes to corrosion protection. In addition, the result of electrochemical corrosion tests generally agreed with that of an autopsy visual inspection.

Study on Ship Detection Using SAR Dual-polarization Data: ENVISAT ASAR AP Mode

  • Yang, Chan-Su;Ouchi, Kazuo
    • Korean Journal of Remote Sensing
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    • v.24 no.5
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    • pp.445-452
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    • 2008
  • Preliminary results are reported on ship detection using coherence images computed from cross-correlating images of multi-look-processed dual-polarization data (HH and HV) of ENVISAT ASAR. The traditional techniques of ship detection by radars such as CFAR (Constant False Alarm Rate) rely on the amplitude data, and therefore the detection tends to become difficult when the amplitudes of ships images are at similar level as the mean amplitude of surrounding sea clutter. The proposed method utilizes the property that the multi-look images of ships are correlated with each other. Because the inter-look images of sea surface are covered by uncorrelated speckle, cross-correlation of multi-look images yields the different degrees of coherence between the images and water. In this paper, the polarimetric information of ships, land and intertidal zone are first compared based on the cross-correlation between HH and HV images, In the next step, we examine the technique when the dual-polarization data are split into two multi-look images, It was shown that the inter-look cross-correlation method could be applicable in the performance improvement of small ship detection and the land masking, It was also found that a simple combination of coherence images from each co-polarised (HH) inter-look and cross-polarised (HV) inter-look data can provide much higher target-detection possibilities.

Study on the Damage Behavior of 304 Stainless Steel for Gas Boiler with Specific Resistance (비저항에 따른 가스보일러용 304스테인리스강재의 손상거동에 관한 연구)

  • Yun, Byoung-Du;Lim, Uh-Joh;Jeong, Ki-Cheol
    • Journal of the Korean Institute of Gas
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    • v.9 no.4 s.29
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    • pp.6-10
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    • 2005
  • This paper was studied on the damage behavior of stainless steel (STS 304) for gas boiler with specific resistance. The electrochemical polarization test of STS304 for gas boiler was carried out. And the anodic polarization and damage aspect, such as pitting corrosion, was considered. With being low specific resistance, the passive current density of STS 304 increases, passive region and pitting potential is low. Also, the patting aspect of STS304 In specific resistance $74{\Omega}{\cdot}m$ water little appears, the pitting number increases and the damage behavior, such as pitting aspect, gradually grow bigger with being low specific resistance.

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