• Transactions on Electrical and Electronic Materials
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• v.7 no.5
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• pp.230-234
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• 2006

One of the methods currently being investigated as a possible non-intrusive diagnostic tool for condition monitoring of power transformer and cable is the recovery voltage measurement, which will be improving the ability to detect the content of water concentration and the ageing process in the insulation system and may thus be an indicator of insulation quality and its ageing status. The polarization phenomenon was studied using RVM with oil-paper samples. In order to interpret its mechanism, the Extended Debye model was introduced. With different circuit parameters, various simulation results were gotten. Furthermore, with the test samples of different ageing condition, measurements are accomplished in the lab. On the basis of this experiment as well as theoretical analysis, correlations between polarizations and ageing were analyzed.

• Bulletin of the Korean Chemical Society
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• v.20 no.9
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• pp.1049-1055
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• 1999

Electrochemical oxidation of silicon (p-type Si(100)) at room temperature in ethylene glycol and in aqueous solutions has been performed by applying constant low current densities for the preparation of thin SiO2 layers. In-situ ac impedance spectroscopic methods have been employed to characterize the interfaces of electrolyte/oxide/semiconductor and to estimate the thickness of the oxide layer. The thicknesses of SiO2 layers calculated from the capacitive impedance were in the range of 25-100Å depending on the experimental conditions. The anodic polarization resistance parallel with the oxide layer capacitance increased continuously to a very large value in ethylene glycol solution. However, it decreased above 4 V in aqueous solutions, where oxygen evolved through the oxidation of water. Interstitially dissolved oxygen molecules in SiO2 layer at above the oxygen evolution potential were expected to facilitate the formation of SiO2 at the interfaces. Thin SiO2 films grew efficiently at a controlled rate during the application of low anodization currents in aqueous solutions.

• Nuclear Engineering and Technology
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• v.55 no.10
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• pp.3659-3664
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• 2023

The electrochemical behavior of dissolved hydrogen (H₂) was investigated at a Pt electrode in a high temperature LiOH-H₃BO₃ solution. The diffusion current of the H₂ oxidation was proportional to the concentration of the dissolved H₂ as well as the reciprocal of the temperature. In the polarization curve, a potential region in which the oxidation current decreases despite an increase in the applied potential between the H₂ oxidation and the water oxidation regions was observed. This potential region was interpreted as being caused by the formation of a Pt oxide layer. Using the properties of the Cl^- ion that reduces the growth rate of the Pt oxide layer, it was confirmed that there is a correlation between the Cl^- ion concentration and the transient current of the H₂ oxidation.

• Proceedings of the KWS Conference
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• 1997.05a
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• pp.35-38
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• 1997

In order to investigate quantitative behavior of galvanic corrosion in the weld joint between stainless steel and carbon steel, electrochemical polarization experiments are performed for various pH, water temperature with boric acid concentration 4000ppm. The corrosion rate of stainless steel was almost independent of the variation of pH. The significant corrosion rates of carbon steel and the weld joint of carbon-carbon steel were observed at pH 4. The corrosion rates in the weld joint of the carbon-stainless steel were observed depending on the variation of pH level.

• Journal of the Korea Safety Management & Science
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• v.3 no.3
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• pp.231-241
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• 2001

The epoxy resin materials used in outdoor high voltage equipments are required to have the high electric performance because of the miniaturization. The frequence dependence of the permittivity and the loss tangent have important information. In this paper we describe the frequency dependence of the permittivity and the loss tangent for epoxy resin filled with silica and the influence of filler shapes on the dielectric properties. The increment of tan $\delta$ in the low frequency region is caused by the increment of both the electrical conductivity and the polarization due to the shape of filler and the water absorbed in and near the interface between fillers and resins. The result of charge current and discharge measure, electric conduction is increased according to voltage.

• Corrosion Science and Technology
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• v.2 no.5
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• pp.219-224
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• 2003

Crevice corrosion of stainless steels in natural seawater was investigated for several post weld treatments; as-annealed, as-welded, pickled, and ground. The results confirmed the effect of the biofilm on the cathodic reaction leading to an ennoblement of the rest potential. The degree of ennoblement of corrosion potential depends on the surface finish. As-annealed and pickled samples show stable corrosion potential approaching to 200 ~ 300 mV (SCE) while as-welded and ground samples show the fluctuating corrosion potential. This points to a situation where there are conflicting effects determining the trend in free corrosion potential. Crevice corrosion initiation will tend to pull the free corrosion potential in the active direction, whereas the presence of biofilm will tend to ennoble corrosion potential. There was no visible attack on UNS S31803, S32550, and 2205W. Therefore, those stainless steel grades appeared to be resistant to crevice corrosion in natural seawater on condition of weld metal.

• Journal of Advanced Marine Engineering and Technology
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• v.25 no.2
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• pp.344-350
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• 2001

This paper was studied on the characteristics of galvanic corrosion and its protection on heat exchanger tube plate in the sea water. In this paper, behavior of pitting corrosion of Ni-al bronze connected with Ti tube was measured af flow velocity of 0 m/s and 2.4 m/s. To protect galvanic corrosion, the protection characteristics of Ni-Al bronze connected with Ti tube by Zn-base alloys galvanic anode and hexagonal nylon insert was investigated. Main results obtained asre al follows: 1) The galvanic corrosion of Ni-Al bronze connected with Ti-tube is more active than single Ni-al bronze. 2) As the circuit resistance increase under the cathodic protection employing Zn-base alloys galvanic anode, Ni-al bronze connected with Ti tube is cathodically unpolarized. 3) The corrosion of Ni-Al bronze connected with Ti tube by nylon insert controls approximately 73% than not nylon insert.

• Journal of Advanced Marine Engineering and Technology
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• v.25 no.2
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• pp.345-345
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• 2001

This paper was studied on the characteristics of galvanic corrosion and its protection on heat exchanger tube plate in the sea water. In this paper, behavior of pitting corrosion of Ni-al bronze connected with Ti tube was measured af flow velocity of 0 m/s and 2.4 m/s. To protect galvanic corrosion, the protection characteristics of Ni-Al bronze connected with Ti tube by Zn-base alloys galvanic anode and hexagonal nylon insert was investigated. Main results obtained asre al follows: 1) The galvanic corrosion of Ni-Al bronze connected with Ti-tube is more active than single Ni-al bronze. 2) As the circuit resistance increase under the cathodic protection employing Zn-base alloys galvanic anode, Ni-al bronze connected with Ti tube is cathodically unpolarized. 3) The corrosion of Ni-Al bronze connected with Ti tube by nylon insert controls approximately 73% than not nylon insert.

• Korean Journal of Materials Research
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• v.12 no.2
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• pp.103-111
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• 2002

The thermally insulated underground pipelines have been used for district heating system. The sensor wire embedded in the insulation was used for monitoring the insulating resistance between the sensor wire and the pipe. The resistance measurement system detects corrosion of steel pipe under insulation. The corrosion and stress corrosion cracking(SCC) characteristics of sensor wire in synthetic ground water were investigated using the electrochemical methods and constant load SCC tests. The polarization tests were used to study the electrochemical behavior of sensor wire. The sensor wire was passivated at temperatures ranging from 25 to $95^{\circ}C$. However, the applied sensing current larger than passive current resulted in breakdown of passive film. The constant load SCC tests were performed to investigate the effects of applied current and load on the fracture behavior. Stress-corrosion cracks initiated at pits that were produced by sensing current. The growth of the pit involves a tunnelling mechanism, which leads to ductile fracture.

• Journal of Welding and Joining
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• v.17 no.3
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• pp.66-70
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• 1999

In order to investigate the quantitative behavior of galvanic corrosion in weld joints between stainless std이 and carbon steel, electrochemical polarization experiments were performed at pH4, pH7 and pH10 with boric acid concentration 4000ppm, and water temperature were selected as $35^{\circ}$C and $60^{\circ}$C. As the results, the galvanic corrosion phenomena of carbon steel weld material at $60^{\circ}$C was revealed $2{1\over2}$ times higher corrosion rate than that at $35^{\circ}$C condition. The corrosion rate of stainless steel was almost inedependent of the variation of pH. The significant corrosion rates of carbon steel and the weld joint of carbon-carbon steel were observed at pH 4.