• 한국전산유체공학회:학술대회논문집
• /
• 2008.03a
• /
• pp.208-214
• /
• 2008

The equilibrium molecular-dynamic simulations have been performed to estimate the properties of the three kinds of fluids (the Lennard-Jones fluid, water and aqueous sodium-chloride solution) confined between two plates that are separated by 1.086 nm; included in the equilibrium properties are the density distribution and the static structure, and the diffusivity in the dynamic property. Three kinds of fluids considered in this study are. The water molecules are modeled by using the SPC/E model and the ions by the charged Lennard-Jones particle model. To treat the water molecules, we combined the quaternion coordinates with Euler angles. We also proposed a plausible algorithm to assign the initial position and direction of molecules. The influence of polarization of water molecules as well as the presence of ions in the solution on the properties will be addressed in this study. In addition, we performed the non-equilibrium molecular-dynamic simulation to compute the flow velocity for the case with the gravitational force acting on molecules.

• 한국전산유체공학회:학술대회논문집
• /
• 2008.10a
• /
• pp.208-214
• /
• 2008

The equilibrium molecular-dynamic simulations have been performed to estimate the properties of the three kinds of fluids (the Lennard-Jones fluid, water and aqueous sodium-chloride solution) confined between two plates that are separated by 1.086 nm; included in the equilibrium properties are the density distribution and the static structure, and the diffusivity in the dynamic property. Three kinds of fluids considered in this study are. The water molecules are modeled by using the SPC/E model and the ions by the charged Lennard-Jones particle model. To treat the water molecules, we combined the quaternion coordinates with Euler angles. We also proposed a plausible algorithm to assign the initial position and direction of molecules. The influence of polarization of water molecules as well as the presence of ions in the solution on the properties will be addressed in this study. In addition, we performed the non-equilibrium molecular-dynamic simulation to compute the flow velocity for the case with the gravitational force acting on molecules.

• Journal of Soil and Groundwater Environment
• /
• v.19 no.3
• /
• pp.39-46
• /
• 2014

Hydraulic conductivity is an important parameter, representing permeable property of the groundwater in aquifers, in the issues of groundwater development, groundwater contamination, and groundwater flow, etc. We estimated a relationship between hydraulic conductivity and electrical properties (formation factor, chargeability, and time constant) of silty sand in the laboratory. For this study, we conducted grain size analysis, constant head permeameter test, and measured electrical resistivity and spectral induced polarization of silty sand samples collected from the riverside alluvium of the Nakdong River in Nogok-ri area, Dasan-myeon, Goryeong-gun in Gyeongbook Province, Korea. In the laboratory test, we used soil samples of approximately uniform porosity with 0.5% error range, and kept the electrical resistivity of pore water with 100 ohm-m. As a result, the relationship between effective particle size and hydraulic conductivity agrees fairly well with the existing empirical formulas. Hydraulic conductivity was correlated with formation factor, chargeability, and time constant: hydraulic conductivity increased with increasing formation factor and time constant as well as with decreasing chargeability.

• Membrane and Water Treatment
• /
• v.13 no.2
• /
• pp.63-72
• /
• 2022

Choline chloride-glycerol (1:2 mol), a natural deep eutectic solvent (NADES) is examined as a draw solution in forward osmosis (FO) for dewatering application. The NADES is easy to prepare, low in toxicity and environmentally benign. A polyamide thin film composite membrane was used. Characterization of the membrane confirmed porous membrane structure with good hydrophilicity and a low structural parameter (722 ㎛) suitable for FO application. A dilute solution of 20% (v/v) NADES was enough to generate moderate water flux (14.98 L m^-2h^-1) with relatively low reverse solute flux (0.125 g m^-2h^-1) with deionized water feed. Application in dewatering industrial wastewater feed showed reasonably good water flux (11.9 L m^-2h^-1) which could be maintained by controlling the external concentration polarization and fouling/scaling mitigation via simple periodic deionized water wash. In another application, clarified sugarcane juice could be successfully concentrated. Recovery of the draw solute was accomplished easily by chilling utilizing thermo responsive phase transition property of NADES. This study established that low concentration NADES can be a viable alternative as a draw solute for dewatering of wastewater and other heat sensitive applications along with a simple recovery process.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.21 no.9
• /
• pp.1422-1431
• /
• 1997

When the structures are exposed to their own an application for a long period, a number of variables such as strength properties and corrosion resistance, so on are expected to change. In the present investigation the corrosion behavior and resistance for the original and degraded materials of Ni-Cr-Mo-V steel were evaluated under the conditions of pH 3, 6, 9 and 12 in a distilled water environment. The electrochemical polarization technique was employed in this investigation. Based upon the experimental results obtained, the following conclusions were drawn. A severe and uniform corrosion was observed for both original and degraded materials under the condition of pH 3. At pH 6 and pH 9, these materials showed the degradation by a pitting corrosion. The materials under pH 12 environment were degraded by a uniform corrosion. The corrosion rate per year were the highest in the pH 3 environment, followed by pH 12, pH 6 and pH 9 environment in order. The corrosion resistance was decreased from the original material, slow cooled material (10.deg. C/hr) and step cooled material in order.

• Korean Journal of Remote Sensing
• /
• v.33 no.1
• /
• pp.47-60
• /
• 2017

The permafrost active layer plays an important role in permafrost dynamics. Ecological patterns, processes, and water and ice contents in the active layer are spatially and temporally complex depending on landscape heterogeneity and local-scale variations in hydrological processes. Although there has been emerging interest in the application of optical remote sensing techniques to permafrost environments, optical sensors are significantly limited in accessing information on near surface geo-cryological conditions. The primary objective of this study was to investigate capability of L-band SAR data for monitoring spatio-temporal variability of permafrost ecosystems and underlying soil conditions. This study exploits information from different polarimetric SAR observables in relation to permafrost environmental conditions. Experimental results show that each polarimetric radar observable conveys different information on permafrost environments. In the case of the dual-pol mode, the radar observables consist of two backscattering powers and one correlation coefficient between polarimetric channels. Among them, the dual-pol scattering powers are highly sensitive to freeze/thaw transition and can discriminate grasslands or ponds in thermokarst area from other permafrost ecosystems. However, it is difficult to identify the ground conditions with dual-pol observables. Additional backscattering powers and correlation coefficients obtained from quad-pol mode help understanding seasonal variations ofradar scattering and assessing geo-cryological information on soil layers. In particular, co-pol coherences atHV-basis and circular-basis were found to be very usefultools for mapping and monitoring near surface soil properties.

• Proceedings of the Korean Society of Marine Engineers Conference
• /
• 2006.06a
• /
• pp.265-266
• /
• 2006

The chemical conversion coating formed on magnesium alloy investigated for low cost and harmless in environment by using the colloidal silica as the main component. The film formed in 298 K is thick, the film, which was thought combination of Si-O, was formed. The film formed in 313 K is thinner than that in 298 K. The quantity of film formed at high temperature such as 333 K and 353 K is smaller than dissolved quantity. At the anodic polarization experiment, corrosion resistance in sealing by hot water after chemical conversion treatment in basic solution condition get worse than that in comparison with basic solution condition. In salt spray test, the ratio of black rust on specimen that did not conducted chemical conversion treatment was five times or more compared with those of chemical conversion treated specimen. The film thickness of chemical conversion coating produced by alkali treatment process is thinner than in comparison with that of specimen produced in basic chemical conversion treatment solution condition. It is thought, however, that it showed good corrosion resistance during salt spray test because the area of microcracks is small.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.14 no.6
• /
• pp.1018-1025
• /
• 2011

The improved properties of corrosion for 90Cu10NiFe alloy in natural seawater were explained by sodium diethyl dithio carbamate(NaDDC), namely organic compound, which is reagent for heavy metal extractions of waste water. The efficiency of NaDDC as corrosion inhibitor for 90Cu10NiFe alloy has been investigated in seawater after immersion in various concentrations of NaDDC solutions for 12~36hrs at pH 8.2 by weight loss test and electrochemical techniques including potentiodynamic polarization and SEM-EDS measurements. The results showed that the corrosion resistance of 90Cu10NiFe alloy improves with the increasing concentration of NaDDC but it did not improves with increasing time any more, so the highest inhibition efficiency was 93% at 100mg/L, 36hrs. The results obtained from weight losses and corrosion rates in polarization curve measurements were in good agreement. Therefore, it showed that NaDDC is a good inhibitor for copper corrosion of 90Cu10NiFe alloy.

• Corrosion Science and Technology
• /
• v.21 no.2
• /
• pp.138-146
• /
• 2022

The cavitation and potentiodynamic polarization experiments were conducted simultaneously to investigate the effect of cavitation amplitude on the super austenitic stainless steel (UNS N08367) electrochemical behavior in seawater. The results of the potentiodynamic polarization experiment under cavitation condition showed that the corrosion current density increased with cavitation amplitude increase. Above oxygen evolution potential, the current density in a static condition was the largest because the anodic dissolution reaction by intergranular corrosion was promoted. In the static condition, intergranular corrosion was mainly observed. However, damage caused by erosion was observed in the cavitation environment. The micro-jet generated by cavity collapse destroyed the corrosion product and promoted the repassivation. So, weight loss occurred the most in static conditions. After the experiment, wave patterns were formed on the surface due to the compressive residual stress caused by the impact pressure of the cavity. Surface hardness was improved by the water cavitation peening effect, and the hardness value was the highest at 30 ㎛ amplitude. UNS N08367 with excellent mechanical performance due to its high hardness showed that cavitation inhibited corrosion damage.

• Journal of Korean Society of Environmental Engineers
• /
• v.39 no.8
• /
• pp.441-448
• /
• 2017

A method for measuring the concentration of surfactant in water was developed. In this technique, microbubbles were used as light scatterers. The polarization change of light scattered by microbubbles was analyzed by Mueller matrix analysis. $M_{11}$, one of the Mueller matrix elements, was found to be a key parameter inferring the surfactant concentration within the concentration range of 0 ppm to 60 ppm. The best results for this measurement were obtained when the scattering angle was $150^{\circ}$ and the extinction ratio was 56.2. This experimental result shows that the EPLS can be effectively used as a real time inspection method for water quality monitoring in lakes or rivers.