• Title/Summary/Keyword: Polarization Control

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Applications of Micro-Droplet Cell to Study of Localized Corrosion Resistance of Stainless Steels (스테인리스강의 국부부식 저항성 연구에 미세방울셀의 응용)

  • Kim Sung-Yu;Kim Hee-San
    • Journal of the Korean Electrochemical Society
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    • v.9 no.2
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    • pp.70-76
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    • 2006
  • Micro-droplet cell with free droplet as a micro-electrochemical technique has been limited to apply to electrochemical systems with high wetting properties such as an acidic solution and low grade stainless steels(Type 316L). By loading negative pressure to a droplet, control of droplet size, and use of hydrophobic gasket, the cell is modified to be allowed to use for electrochemical systems with high wetting properties. For giving the reliability of new cell, studies on local corrosion were conducted for three different systems-an acidic chloride solution and high chromium ferritic stainless steel, the other acidic chloride solution and type 316, and a neutral chloride solution and type 316. stainless steel. Firstly, the modified micro-droplet cell allows the anodic polarization curves in an acidic chloride solution to show the fact that the local corrosion of high chromium stainless steel near the $\alpha/\sigma$ interface is due to the Cr depleted zone. Secondly, the local anodic polarization test of type 316 L in the other acidic chloride solution can be successfully conducted in the cell. Furthermore, the local polarization curves help elucidating the corrosion of type 316 with $\delta-ferrite$ phase. Finally, the polarization curves of type 316 L in a neutral chloride solution indicates that the factor affecting the pitting corrosion resistance was inclusions rather than $\delta-ferrite$.

Functional Analysis of Electrode and Small Stack Operation in Solid Oxide Fuel Cell (고체산화물 연료전지의 전극과 스택운영의 기능적 분석)

  • Bae, Joong-Myeon;Kim, Ki-Hyun;Ji, Hyun-Jin;Kim, Jung-Hyun;Kang, In-Yong;Lim, Sung-Kwang;Yoo, Young-Sung
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.812-822
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    • 2006
  • This study amis to investigate the functional analysis of anode and cathode materials in Anode supported Solid Oxide Fuel Cell. The concentration polarization of single cell was investigated with CFD (Computational Fluid Dynamics) method for the case of the different morphology by using four types of unit cell and discussed to reduce the concentration polarization. The concentration polarization at anode side effected the voltage loss in Anode supported Solid Oxide Fuel Cell and increased contact areas between fuel gas and anode side could reduce the concentration polarization. For intermediate temperature operation, Anode-supported single cells with thin electrolyte layer of YSZ (Yttria-Stabilized Zirconia) were fabricated and short stacks were built and evaluated. We also developed diesel and methane autothermal reforming (ATR) reactors in order to provide fuels to SOFC stacks. Influences of the $H_2O/C$ (steam to carbon ratio), $O_2/C$ (oxygen to carbon ratio) and GHSV (Gas Hourly Space Velocity) on performances of stacks have been investigated. Performance of the stack operated with a diesel reformer was lower than with using hydrogen as a fuel due to lower Nernst voltage and carbon formation at anode side. The stack operated with a natural gas reformer showed similar performances as with using hydrogen. Effects of various reformer parameters such as $H_2O/C$ and $O_2/C$ were carefully investigated. It is found that $O_2/C$ is a sensitive parameter to control stack performance.

Development of 3-Dimensional Sensor Nodes using Electro-magnetic Waves for Underwater Localization (수중 위치 추정을 위한 3차원 전자기파 센서 노드 개발)

  • Kwak, Kyung Min;Kim, Jinhyun
    • Journal of Institute of Control, Robotics and Systems
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    • v.19 no.2
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    • pp.107-112
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    • 2013
  • In this paper, we discuss a 3-dimensional localization sensor node using EM waves (Electromagnetic waves) with RSSI (Received Signal Strength Indicator). Generally EM waves cannot be used in underwater environment, because the signal is highly attenuated by the water medium according to the distance. Although the signal quickly reduces in underwater, the reducing tendency is very clear and uniform. Hence EM waves have possibility as underwater distance sensors. The authors have verified the possibility by theory and several experiments, and developed calibration methods in case of linear and planer environment. For 3-dimensional localization in underwater, it must be known antenna's radiation pattern property in electric plane(called E-plane). In this paper, we proceed experiments to verify attenuation tendency with z axis movement, PLF (Polarization Loss Factor) and ILF (Inclination Loss Factor) with its theoretical approach.

수처리용 분리막 모듈 설계 및 오염 방지

  • 정건용
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.04a
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    • pp.87-109
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    • 1997
  • Reverse osmosis(R/O), ultrafiltration(UF) and microfiltration (MF) processes are widely used for water treatment. In the seminar, characteristics of typical membrane modules including tubular, hollow fiber, plate and frame and spiral wound types will be discussed in detail. The design methods based on hydrodynamics for hollow fiber and spiral wound modules will be introduced analytically. Concentration polarization (CP) and membrane fouling mechnism as well as the techniques for CP reduction will be handled. The CP control techniques contain chemically modified membrane surface, pretreatment of feed water, operation of low trans-membrane pressure, chemical or physical cleaning methods and artificial production of various fluid turbulences near the membrane surface, etc. In especially, the recent commercial membrane modules for CP control including module rotation, vibration and Taylor or Dean vortex system will be introduced and discussed in detail.

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Corrosion Resistance Properties of Rice Husk Ash Blended Concrete

  • Ganesan, K.;Rajagopal, K.;Thangavel, K.
    • Corrosion Science and Technology
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    • v.6 no.1
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    • pp.12-17
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    • 2007
  • Portland cement incorporating supplementary cementing material develops excellent mechanical properties and long term durability characteristics. India is a leading rice producing country and rice husk is considered as waste in the rice milling industries. In this present work, the rice husk ash (RHA) was added to concrete as cement replacement from 0 to 30%. Corrosion performance of reinforcing steel embedded in RHA blended concretes was studied using linear polarization, AC impedance and gravimetric methods. The corrosion rate of steel bars embedded in RHA concretes were compared with control concrete. The results clearly indicate that the corrosion rate of reinforcing steel embedded in concrete is significantly reduced with the incorporation of RHA. A good correlation among gravimetric method and electrochemical methods was observed. Electrochemical impedance study showed 98 percentage reduction in corrosion rate to the RHA blended concrete with 15% replacement than control concrete.

BITSE Ground Software

  • Baek, Ji-Hye;Park, Jongyeob;Choi, Seonghwan;Kim, Jihun;Yang, Heesu;Kim, Yeon-Han;Swinski, Joseph-Paul A.;Newmark, Jeffrey S.;Gopalswamy, Nat.
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.58.1-58.1
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    • 2019
  • We have developed Ground Software (GSW) of BITSE. The ground software includes mission operation software, data visualization software and data processing software. Mission operation software is implemented using COSMOS. COSMOS is a command and control system providing commanding, scripting and data visualization capabilities for embedded systems. Mission operation software send commands to flight software and control coronagraph. It displays every telemetry packets and provides realtime graphing of telemetry data. Data visualization software is used to display and analyze science image data in real time. It is graphical user interface (GUI) and has various functions such as directory listing, image display, and intensity profile. The data visualization software shows also image information which is FITS header, pixel resolution, and histogram. It helps users to confirm alignment and exposure time during the mission. Data processing software creates 4-channel polarization data from raw data.

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Development of Integrated Corrosion Monitoring and Control System (통합 부식 모니터링 및 통합 제어 시스템의 개발)

  • Yoo, Nam-Hyun;Kim, Young-Hun
    • Journal of Ocean Engineering and Technology
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    • v.27 no.3
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    • pp.8-14
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    • 2013
  • Although there are various factors that threaten the security of ships, one of the most harmful is corrosion. It is not easy to find corroding areas and the status of corrosion, even though corrosion causes serious problems such as submergence and marine pollution as a result of leaking oil and polluted water. To monitor the corrosion of ships, non-destructive inspection, weight loss coupons, electrical resistance, linear polarization resistance, zero resistance ammeter, and electrochemical impedance spectroscopy have been developed. However, these methods require much time to detect corrosion, and most are not appropriate for real time monitoring. Coating, sacrificial anode, and impressed current cathodic protection (ICCP) methods have been developed to control corrosion. The ICCP and sacrificial anode methods are the most popular ways to prevent ship corrosion. However, ICCP is only appropriate for the outside of a ship and cannot be used for complex structures such as ballast tanks because these are composed of many separate chambers. Sacrificial anodes have to be replaced periodically. This paper proposes an integrated corrosion monitoring and control system (ICMCS) that can detect corrosion in real time and is appropriate for complex structures such as ballast tanks. Because the system uses titanium for an anode, exhausted anodes do not need to be replaced.

Development of smart transducer with embedded sensor for automatic process control of ultrasonic wire bonding

  • Or, Siu Wing;Chan, Helen Lai Wa;Liu, Peter Chou Kee
    • Smart Structures and Systems
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    • v.1 no.1
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    • pp.47-61
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    • 2005
  • A ring-shaped lead zirconate titanate (PZT) piezoceramic sensor has been integrated with the Langevin-type piezoceramic driver of an ultrasonic wire-bonding transducer to form a smart transducer for in-situ measurement of three essential bonding parameters: namely, impact force, ultrasonic amplitude and bond time. This sensor has an inner diameter, an outer diameter and a thickness of 12.7 mm, 5.1 mm and 0.6 mm, respectively. It has a specifically designed electrode pattern on the two major surfaces perpendicular to its thickness along which polarization is induced. The process-test results have indicated that the sensor not only is sensitive to excessive impact forces exerted on the devices to be bonded but also can track changes in the ultrasonic amplitude proficiently during bonding. Good correlation between the sensor outputs and the bond quality has been established. This smart transducer has good potential to be used in automatic process-control systems for ultrasonic wire bonding.

Enhanced magnetic properties of FeCo alloys by engineering crystallinity and composition (FeCo의 결정성 및 조성 제어를 통한 자기 특성 향상)

  • Kim, Dan-Bi;Kim, Ji-Won;Eom, Nu-Si-A;Park, Seong-Heum;Im, Jae-Hong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.32.1-32.1
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    • 2018
  • Novel soft magnetic materials can be achieved by altering material properties such as morphology, composition, crystallinity, and grain size of soft magnetic alloys. Especially, magnetic properties (i.e., saturation magnetization, coarcivity) of soft magnetics are significantly affected by grain boundaries which act as a control of magnetic domain wall movement. Thus, we herein develop a two-step electroless plating method to control morphology and grain size of FeCo films for excellent magnetic properties. Accordingly, the chemical composition to control the degree of polarization of FeCo alloys was altered by electroless deposition parameters; for example, electrolyte concentration and temperature. The grain size and crystallinity of FeCo alloys was dramatically affected by the reaction temperature because the grain growth mechanism dominantly occurs at $90^{\circ}C$ where as the neucleation only happens at $50^{\circ}C$. By simply controlling the temperature, the micron-sized FeCo grains embedded FeCo film was synthesized where the large grains allow high magnetization originated from larger magnetic domain with low corecivity and the nano-sized grains allow excellent soft magnetic properties due to the magnetic correlation length.

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Characterization of RTMOCVD Fabricated PbO/ZrO2/TiO2 Multilayer Thin Films (RTMOCVD로 제조된 PbO/TiO2/ZrO2 다층박막의 특성 연구)

  • Kang, Byung-Sun;Lee, Won-Gyu
    • Journal of Industrial Technology
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    • v.25 no.A
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    • pp.157-162
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    • 2005
  • In this study, the fabrication of PZT films was performed from a multilayer structure comprising $TiO_2$, $ZrO_2$ and PbO thin films prepared by rapid themal chemical vapor deposition(RTMOCVD). $TiO_2$, $ZrO_2$ and PbO are the component layers of oxide multilayer system for a single phase PZT thin film. The composition control of PZT thin film was done by the thickness control of individual component layer. The composition ratio of Pb:Ti:Zr with thickness were 1:0.94:0.55. Occurrence of a single-phase of PZT was initiated at around $550^{\circ}C$ and almost completed at $750^{\circ}C$ under the fixed time of 1hr. As the concentration of Pb increased, the roughness and crystallization in the film increased. From the as result of using XPS and TEM, the single phase formation through annealing is evident. The electrical properites of the prepared PZT thin film(Zr/Ti=40/60, 300 nm) on a Pt-coated substrate were as follow: dielectric constant ${\varepsilon}_r=475$, coercive field Ec=320 kV/cm, and remanant polarization $P_r=11{\mu}C/cm^2$ at an applied voltage of 18 V.

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