• Title/Summary/Keyword: Polarity value

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A Study on the Hand of the Fabrics Treated with Chitosan-polyurethane Mixture Solution -Thermal Curing of Cotton, Polyester, and Nylon Fabrics- (Chitosan-polyurethane 혼합 용액으로 처리된 직물의 태 연구 - 면, 폴리에스터, 나일론 직물의 열 Curing -)

  • Kwak Jung-Ki;Jeon Dong-Won;Kim Jong-Jun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.7 s.144
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    • pp.997-1007
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    • 2005
  • The textile finishing methods utilizing chitosan have been mostly focused on the applications in the improvement of the dyeing of cotton fabrics, or the improvement of hand of the cotton or wool fabrics. On the other hand, it Is difficult to find the application examples in the synthetic fiber fabrics including polyester and nylon fabrics. The aim of this study is to improve the stiffness and the poor wash fastness of the fabrics treated only with chitosan. We tried to improve the softness by employing chitosan and polyurethane mixture solution and to prevent the detachment of the chitosan from the fabric. The treatment was applied to cotton, polyester, and nylon fabrics. The change of the properties of the treated fabrics were investigated. The optimum finishing condition was sought by changing the mixture ratio of the chitosan/PU(polyurethane) solutions. The adjusted ratios of the chitosan/PU solutions were 1 : 0, 1 : 0.25, 1 : 0.5, and 1 : 2 during the mixture solution preparation. Using the KES(Kawabata Evaluation System), the physical and mechanical properties of the finished fabric specimens were analyzed, and hand values of the specimens were calculated through the use of translational formulas. According to the chemical composition of the fibers, chitosan solution or chitosan/PU mixture exhibited wide range of coating effect. Since the chitosan acid solution has high polarity, the bonding force with the cotton fibers is high. By the appropriate addition of PU in the chitosan treatment of cotton, KOSHI and HARI values of the fabric improved. The air permeability of the chitosan/PU treated cotton fabric specimen improved, resulting in the highest value at the mixture of chitosan : PU=1:0.25.

Paleomagnetic Study on the Volcanic and Sedimentary Rocks of Jeju Island (제주도(濟州道)에 분포(分布)하는 화산암류(火山岩類) 및 퇴적암류(堆積岩類)에 대(對)한 고지자기(高地磁氣) 연구(硏究))

  • Min, Kyung Duck;Won, Joong Sun;Hwang, Suk Yeon
    • Economic and Environmental Geology
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    • v.19 no.2
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    • pp.153-163
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    • 1986
  • Paleomagnetic and geological studies of volcanic and sedimentary rocks of Jeju Island have been carried out to determine the position of virtual geomagnetic pole(VGP), and to estimate the geological sequence and their age. As a result of paleomagnetic studies, the reversal polarities are measured in the Sanbangsan trachyte and Hwasun formation, and the normal are the rest. In case of normal polarity, the mean values of declination and inclination are $2.3^{\circ}$ and $48.4^{\circ}$, respectively, and the average value of VGP is $85.4^{\circ}N$ and $79.9^{\circ}W$. The locations of VGP's are coincident with those obtained from world-wide Plio-Pleistocene rocks. The Hwasun formation and Seongsan formation which have been known to be sedimented in the similar time in the 2nd-stage of volcanic eruption, possess reversal and normal polarities, respectively. This fact brings about the result that two formations should be separated in a sense of geological sequence. Consequently, the geological sequence of the 2nd-stage of volcanic eruption is Pyoseonri basalt-Seoguipo hawaiite-Hwasun formation-Seongsan formation-Jungmun hawaiite-Sanbangsan trachyte. Referring to the paleomagnetic studies and the previous and present geological studies, Seoguipo formation corresponds to the Gauss normal epoch, the 2nd-stage of volcanic eruption to Matuyama reversed epoch, and the 3rd-, 4th-, and 5th-stages to Brunhes normal epoch. Therefore, the Seoguipo formation is mostly sedimented during late Pliocene and/or presumably extended to the early Pleistocene. The rocks of the 2nd- to 5th-stage are formed later than this.

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The Permeation Properties of $O_{2}\;and\;N_{2}$ for BPSf/TMSPSf Blend Membrane (BPSf/TMSSf 블렌드막을 통한 산소와 질소의 투과특성)

  • Kim Hyunjoon;Hong Suk-In
    • Journal of the Korean Institute of Gas
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    • v.5 no.1
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    • pp.29-36
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    • 2001
  • The permeation properties of $O_2\;and\;N_2$ were measured for bromobisphenol A polysulfone(BPSf), bisphenol A trimethylsilylated polysulfone(TMSPSf) and their blend membrane to investigate the structure-properties relationships. BPSf shows relatively high permselectivity. It can be explained that the strong polarity of bromine in BPSf increases chain packing ability. In this case the distance of polymer chains is reduced by increasing of interchain interaction by induced dipole. TMSPSf shows relatively high permeability. The higher value of permeability coefficients for TMSPSf is due to the substitution of very bulky trimethylsilyl groups. The replacement of phenyl hydrogens of bisphenol A polysulfone(PSf) with trimethylsilyl groups results in higher fractional free volume(FFV). In this work, taking into account the complimentary features of BPSf and TMSPSf, BPSf/TMSPSf blend was prepared and the compatibility in mixing are examined. The BPSf/TMSPSf blend shows higher permeability than commercial PSf, with minimum loss of selectivity. The miscibility of the BPSf/TMSPSf blend is confirmed by the single glass transition temperature.

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Analysis of Partial Discharge Characteristics in SF6 Gas Insulation (SF6 가스절연에서 부분방전의 특성분석)

  • Kim, Sun-Jae;Wang, Guoming;Park, Seo-Jun;Kil, Gyung-Suk;An, Chang-Hwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.7
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    • pp.429-434
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    • 2016
  • This paper deals with the characteristics of partial discharge (PD) for the purpose of a condition based maintenance (CBM) of gas insulated switchgears (GIS) in power equipment. Four types of electrode systems such as a protrusion on enclosure (POE), a particle on spacer (POS), a free particle (FP) and a Floating were designed and fabricated. PD pulses were measured using UHF sensor with a frequency range of 300 MHz~1.4 GHz and a DAQ with a sampling rate of 250 MS/s. Discharge inception voltage (DIV), discharge extinction voltage (DEV), and phase resolved partial discharge (PRPD) were analyzed depending on electrode systems. The average DIV in the POS was 28.8 kV. It was about 1.7 times higher than that in the FP, which was the lowest value of 17.2 kV. The FP shuffled and jumped at the applied voltage of 23.5 kV. Over 95% of PD pulses in the POE were generated in the negative polarity ($181^{\circ}{\sim}360^{\circ}$) of applied voltage. The results showed the phase (${\Phi}$)-magnitude (dBm) of PD pulses by UHF sensor, a cluster was formed separately depending on electrode systems.

"All This is Indeed Brahman" Rammohun Roy and a 'Global' History of the Rights-Bearing Self

  • Banerjee, Milinda
    • Asian review of World Histories
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    • v.3 no.1
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    • pp.81-112
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    • 2015
  • This essay interrogates the category of the 'global' in the emerging domain of 'global intellectual history'. Through a case study of the Indian social-religious reformer Rammohun Roy (1772/4-1833), I argue that notions of global selfhood and rights-consciousness (which have been preoccupying concerns of recent debates in intellectual history) have multiple conceptual and practical points of origin. Thus in early colonial India a person like Rammohun Roy could invoke centuries-old Indic terms of globality (vishva, jagat, sarva, sarvabhuta, etc.), selfhood (atman/brahman), and notions of right (adhikara) to liberation/salvation (mukti/moksha) as well as late precolonial discourses on 'worldly' rights consciousness (to life, property, religious toleration) and models of participatory governance present in an Indo-Islamic society, and hybridize these with Western-origin notions of rights and liberties. Thereby Rammohun could challenge the racial and confessional assumptions of colonial authority and produce a more deterritorialized and non-sectarian idea of selfhood and governance. However, Rammohun's comparativist world-historical notions excluded other models of selfhood and globality, such as those produced by devotional Vaishnava, Shaiva, and Shakta-Tantric discourses under the influence of non-Brahmanical communities and women. Rammohun's puritan condemnation of non-Brahmanical sexual and gender relations created a homogenized and hierarchical model of globality, obscuring alternate subaltern-inflected notions of selfhood. Class, caste, and gender biases rendered Rammohun supportive of British colonial rule and distanced him from popular anti-colonial revolts and social mobility movements in India. This article argues that today's intellectual historians run the risk of repeating Rammohun's biases (or those of Hegel's Weltgeschichte) if they privilege the historicity and value of certain models of global selfhood and rights-consciousness (such as those derived from a constructed notion of the 'West' or from constructed notions of various 'elite' classicized 'cultures'), to the exclusion of models produced by disenfranchised actors across the world. Instead of operating through hierarchical assumptions about local/global polarity, intellectual historians should remain sensitive to and learn from the universalizable models of selfhood, rights, and justice produced by actors in different spatio-temporal locations and intersections.

Advanced Low-k Materials for Cu/Low-k Chips

  • Choi, Chi-Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.71-71
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    • 2012
  • As the critical dimensions of integrated circuits are scaled down, the line width and spacing between the metal interconnects are made smaller. The dielectric film used as insulation between the metal lines contributes to the resistance-capacitance (RC) time constant that governs the device speed. If the RC time delay, cross talk and lowering the power dissipation are to be reduced, the intermetal dielectric (IMD) films should have a low dielectric constant. The introduction of Cu and low-k dielectrics has incrementally improved the situation as compared to the conventional $Al/SiO_2$ technology by reducing both the resistivity and the capacitance between interconnects. Some of the potential candidate materials to be used as an ILD are organic and inorganic precursors such as hydrogensilsequioxane (HSQ), silsesquioxane (SSQ), methylsilsisequioxane (MSQ) and carbon doped silicon oxide (SiOCH), It has been shown that organic functional groups can dramatically decrease dielectric constant by increasing the free volume of films. Recently, various inorganic precursors have been used to prepare the SiOCH films. The k value of the material depends on the number of $CH_3$ groups built into the structure since they lower both polarity and density of the material by steric hindrance, which the replacement of Si-O bonds with Si-$CH_3$ (methyl group) bonds causes bulk porosity due to the formation of nano-sized voids within the silicon oxide matrix. In this talk, we will be introduce some properties of SiOC(-H) thin films deposited with the dimethyldimethoxysilane (DMDMS: $C_4H_{12}O_2Si$) and oxygen as precursors by using plasma-enhanced chemical vapor deposition with and without ultraviolet (UV) irradiation.

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Electrotransport of Donepezil Hydrochloride from Poly(ethylene oxide) Hydrogel (폴리에틸렌옥사이드 하이드로겔을 이용한 도네페질염산염의 이온토포레시스 피부투과)

  • Choi, Yu-Ri;Oh, Seaung-Youl
    • Journal of Pharmaceutical Investigation
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    • v.40 no.2
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    • pp.91-100
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    • 2010
  • The objective of this work is to study transdermal delivery of donepezil hydrochloride (DH) using iontophoresis and to evaluate various factors which affect the transdermal transport. After the flux study using 4 kinds of hydrogel, hydrogel containing 8% poly(ethylene oxide) (PEO) was chosen as the hydrogel for further studies. Under experimental condition, DH was stable. We have studied the effect of polarity, current density, drug concentration and current profile on transdermal flux and compared the results. In vitro flux study was performed at $33^{\circ}C$, using side-by-side diffusion cell and full thickness hairless mouse skin. DH is positively charged at pH 7.4, and anodal delivery was much larger than cathodal and passive delivery at all current densities studied (0.2, 0.4 and 0.6 mA/$cm^2$). Cathodal delivery showed higher flux than passive flux. Flux increased as the concentration of DH in hydrogel increased. Pulsatile application of current showed smaller flux value than the application of continuous current. Based on these results, we have evaluated the possibility of delivering enough amount of DH to reach the therapeutic level. The maximum cumulative amount of DH transported for 12 hours was 455 ${\mu}g/cm^2{\cdot}hr$ when the amount of DH in the hydrogel was 3 mg/mL and the current density was 0.4 mA/$cm^2$. If the patch size is 10 $cm^2$, then we can deliver 4.6 mg for 12 hours. Because the daily dosage of DH is 5 mg, it seems possible to deliver clinically effective amount of DH using iontophoresis. This study also provides some information about the role of electrorepulsion and electroosmosis during the transport through skin.

Novel Erbium(III)-Encapsulated Complexes Based on ${\pi}$-Extended Anthracene Ligands Bearing G3-Aryl-Ether Dendron: Synthesis and Photophysical Studies

  • Baek, Nam-Seob;Kim, Yong-Hee;Roh, Soo-Gyun;Lee, Dong-Hyun;Seo, Kang-Deuk;Kim, Hwan-Kyu
    • Macromolecular Research
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    • v.17 no.9
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    • pp.672-681
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    • 2009
  • A series of inert and photo-stable Er(III)-encapsulated complexes based on ${\pi}$-extended dendritic anthracene ligands bearing G3-aryl-ether dendron ([G3-AnX]-$CO_2H$), which retain different ${\pi}$-bridging systems, such as single (X= S), double (X= D) and triple (X= T) bonds was designed and synthesized to establish the structure-property relationship. The near infrared emission intensities of Er(III)-encapsulated complexes were enhanced dramatically by increasing the ${\pi}$-conjugated extension of anthracene ligands. The time-resolved luminescence spectra show monoexponential decays with a lifetime of $2.0{\sim}2.4ms$ for $Er^{3+}$ ions in thin films, and calculated intrinsic quantum yields of $Er^{3+}$ ions are in the range of $0.025{\sim}0.03%$. As a result, all Er(III)-encapsulated dendrimer complexes exhibit the near IR emission with the following order: $Er^{3+}-[G3-AnD]_3$(terpy) > $Er^{3+}-[G3-AnS]_3$(terpy) ${\approx}$ $Er^{3+}-[G3-AnT]_3$(terpy), because $Er^{3+}-[G3-AnD]_3$(terpy) has a higher relatively spectral overlap J value and energy transfer efficiency. In addition, the lack of detectable phosphorescence and no significant spectral dependence of the ${\pi}$-extended anthracene moieties on the solvent polarity support energy transfer from their singlet state to the central $Er^{3+}$ ion taking place in $Er^{3+}-[G3-AnX]_3$(terpy).

Air-Conditioner Power Source Device to Meet the Harmonic Guide Lines (고조파 규제값에 적합한 에어컨 전원장치)

  • Mun, Sang-Pil;Park, Yeong-Jo;Seo, Gi-Yeong
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.51 no.10
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    • pp.581-586
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    • 2002
  • To improve the current waveform of diode rectifiers, we propose a new operating principle for the voltage-doubler diode rectifiers. In the conventional voltage-doubler rectifier circuit, relatively large capacitors are used to boost the output voltage, while the proposed circuit uses smaller ones and a small reactor not to boost the output voltage but improve the input current waveform. A circuit design method is shown by experimentation and confirmed simulation. The experimental results of the proposed diode rectifier satisfies the harmonic guide lines. A high input power factor of 97(%) and an efficiency of 98[%] are also obtained. The new rectifier with no controlled switches meet the harmonic guide lines, resulting in a simple, reliable and low-cost at-to dc converters in comparison with the boost-type current-improving circuits. This paper proposes a nonlinear impedance circuit composed by diodes and inductors or capacitors. This circuit needs no control circuits and switches, and the impedance value is changed by the polarity of current or voltage. And this paper presents one of these applications to improve the input current of capacitor input diode rectifiers. The rectifier using the nonlinear impedance circuit is constructed with four diodes and four capacitors in addition to the conventional rectifiers, that is, it has eight diodes and five capacitors, including a DC link capacitor. It makes harmonic components of the input current reduction and the power factor improvement. Half pulse-width modulated (HPWM) inverter was explained compared with conventional pulse width modulated(PWM) inverter. Proposed HPWM inverter eliminated dead-time by lowering switching loss and holding over-shooting.

A Study on Combustion and Emission Characteristics of Diesel Generator Fuelled with Coffee Ground Pyrolysis Oil (커피박 열분해유를 연료로 사용하는 디젤 발전기의 연소 및 배출물 특성에 관한 연구)

  • PARK, JUNHA;LEE, SEOKHWAN;KANG, KERNYONG;LEE, JINWOOK
    • Journal of Hydrogen and New Energy
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    • v.30 no.6
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    • pp.567-577
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    • 2019
  • Due to the depletion of fossil fuels and environmental pollution, demand for alternative energy is gradually increasing. Among the various methods, a method to convert biomass into alternative fuel has been proposed. The bio-fuel obtained from biomass through pyrolysis process is called pyrolysis oil (PO) or bio-oil. Because PO is difficult to use directly in conventional engines due to its poor fuel properties, various methods have been proposed to upgrade pyrolysis-oil. The simplest approach is to mix it with conventional fossil fuels. However, due to their different polarity of PO and fossil fuel, direct mixing is impossible. To resolve this problem, emulsification of two fuels with a proper surfactant was proposed, but it costs additional time and cost. Alternatively, the use of alcohol fuels as an organic solvent significantly improve the fuel properties such as fuel stability, calorific value and viscosity. In this study, blends of diesel, n-butanol, and coffee ground pyrolysis oil (CGPO) which is one of the promising PO, was applied to diesel generator. Combustion and emissions characteristics of blended fuels were investigated under the entire load range. Experimental results show that ignition delay is similar to that of diesel at high load. Although, hydrocarbon and carbon monoxide emissions are comparable to diesel, significant reduction of nitrogen oxides and particulate matter emissions were observed.