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Conformational Transition of Form II to Form Ⅰ PoLy(L-proline) and the Aggregation of Form Ⅰ in the Transition: Water-Propanol Solvent System

  • 김현돈
    • Bulletin of the Korean Chemical Society
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    • v.18 no.9
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    • pp.922-928
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    • 1997
  • The conformational transition of poly(L-proline) (PLP), Form Ⅱ → Form Ⅰ and the intermolecular aggregation of the product, Form Ⅰ, during and after the transition in water-propanol (1:7, 1:9, 1:15.7, and 1:29 v/v) were studied. For the study, the viscosity change and excess light scattering intensity were measured in the course of the transition which was determined by the Form Ⅰ fraction, fI of the sample solution. For the PLP sample of molecular weight Mv=31,000 the experimental results show that the reaction course is roughly divided into three regions: in the first region [fI=0.27 to 0.40 (- [α]D=400 to 330)], the conformational change of Form Ⅱ → Form Ⅰ occurs with decrease of viscosity, in the second region [fI=0.40 to 0.80 (- [α]D=330 to 120)], a partial side-by-side (p-S-S) type aggregation in which Form Ⅰ blocks interact with each other, which induces the increase of viscosity, starts to occur, and in the third region [fI=0.80 to 1.00 (- [α]D=120 to 15)], a side-by-side type (raft like) aggregation of Form Ⅰ or an end-to-end (E-E) type aggregation occurs according to the solvent situation, i.e., in a water-rich medium [water-propanol (1:9 or 1:7 v/v)], the (S-S) type aggregation with a gross decrease in viscosity occurs while in a water-poor medium [water-propanol (1:29 or 1:15.7 v/v), the (E-E) type aggregation with a large increase in viscosity occurs. The (S-S) type aggregation was promoted at high temperatures. Based on the structure of PLP, a reasonable mechanism for the (p-S-S) and (S-S) aggregation which occurs with the transition of Form Ⅱ → Form Ⅰ is considered. The suggested mechanism was also supported by the result of chain length effect of PLP for the aggregation.

Comparative Verification of Accelerated Degradation Mechanism of Heat-Resistant Steel for High Temperature Plant with that Used in the Field (고온 플랜트용 내열 합금강 가속열화 기구의 현장 사용재 비교 검증)

  • Lee, Seung-Mi;Kim, Jae-Yeon;Byeon, Jai-Won
    • Journal of Applied Reliability
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    • v.15 no.4
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    • pp.262-269
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    • 2015
  • Accelerated degradation mechanism of the heat-resistant steel for high temperature plant was analysed in terms of microstructure and hardness. In order to simulate the microstructure of the steel actually used at $540^{\circ}C$ in the field, isothermal exposure was carried out at $630^{\circ}C$ up to 4,800 hours. The artificial degradation mechanism was comparatively verified to successfully simulate degradation of the long-time used field material. For the artificially degraded specimens, databases including size and aspect ratio of carbide, chemical composition (i.e., Cr/Mo ratio) of grain boundary carbide were built up. These degradation parameters were suggested as fingerprints for PHM (i.e., prognostics health management) of power plants.

Isolation and its effect of a second organism for single cell protein(SCP) production (세균 단세포단백질(SCP) 생산을 위한 보조균주의 분리와 그 효과)

  • 권오진;양성호
    • Journal of Environmental Health Sciences
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    • v.22 no.2
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    • pp.10-18
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    • 1996
  • Experiments were carried out to find the possibility of an economic production of single cell protein(SCP) in mixed culture by Cellulomonas sp. KL-6 and a second organism. The second organism, strain LI-10, was isolated from the large intestines of a mouse. 1. When these strains were mixed, cell growth and carboxymethyl cellulase (CMCase) activity were increased to about 63% and 161%, respectively compared with that of single culture of strain KL-6. We found the mixed culture as a proper method of degradation of cellulose in our study. 2. Strain LI-10 was identified as E. coli. 3. This strain produced trace amounts of cellobiose, but glucose was not found in detectable amounts in the filter paper(FP) medium. 4. $CaCO_3$ injected in the medium at the ratio of 0.1% not only enhanced cell growth but also was effective as an acid neutralizing agent. 5. When this organism was cultured under the optimal medium (glucose 0.1%, $NH_4Cl$ 0.1%, yeast extract 2.0%, $KH_2PO_4$ 0.1%, KCl 0.05%, pH 7.2 and a temperature 30$\circ$C) for 5 days, a cell mass produced 1.18 g/l. The results showed the increase of cell mass up to 300% compared to 0.28 g/l produced in CMC medium.

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Band Gap Tuning in Nanoporous TiO2-ZrO2 Hybrid Thin Films

  • Kim, Chang-Sik;Jeong, Hyun-Dam
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2333-2337
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    • 2007
  • Nanoporous TiO2 and ZrO2 thin films were spin-coated using a surfactant-templated approach from Pluronic P123 (EO20PO70EO20) as the templating agent, titanium alkoxide (Ti(OC4H9)4) as the inorganic precursor, and butanol as a the solvent. The control of the electronic structure of TiO2 is crucial for its various applications. We found that the band gap of the hybrid nanoporous thin films can be easily tuned by adding an acetylacetonestabilized Zr(OC4H9)4 precursor to the precursor solution of Ti(OC4H9)4. Pores with a diameter of 5 nm-10 nm were randomly dispersed and partially connected to each other inside the films. TiO2 and ZrO2 thin films have an anatase structure and tetragonal structure, respectively, while the TiO2-ZrO2 hybrid film exhibited no crystallinity. The refractive index was significantly changed by varying the atomic ratio of titanium to zirconium. The band gap for the nanoporous TiO2 was estimated to 3.43 eV and that for the TiO2-ZrO2 hybrid film was 3.61 eV.

Icefex: Protocol Format Extraction from IL-based Concolic Execution

  • Pan, Fan;Wu, Li-Fa;Hong, Zheng;Li, Hua-Bo;Lai, Hai-Guang;Zheng, Chen-Hui
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.7 no.3
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    • pp.576-599
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    • 2013
  • Protocol reverse engineering is useful for many security applications, including intelligent fuzzing, intrusion detection and fingerprint generation. Since manual reverse engineering is a time-consuming and tedious process, a number of automatic techniques have been proposed. However, the accuracy of these techniques is limited due to the complexity of binary instructions, and the derived formats have missed constraints that are critical for security applications. In this paper, we propose a new approach for protocol format extraction. Our approach reasons about only the evaluation behavior of a program on the input message from concolic execution, and enables field identification and constraint inference with high accuracy. Moreover, it performs binary analysis with low complexity by reducing modern instruction sets to BIL, a small, well-specified and architecture-independent language. We have implemented our approach into a system called Icefex and evaluated it over real-world implementations of DNS, eDonkey, FTP, HTTP and McAfee ePO protocols. Experimental results show that our approach is more accurate and effective at extracting protocol formats than other approaches.

Spatiotemporal Routing Analysis for Emergency Response in Indoor Space

  • Lee, Jiyeong;Kwan, Mei-Po
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.32 no.6
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    • pp.637-650
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    • 2014
  • Geospatial research on emergency response in multi-level micro-spatial environments (e.g., multi-story buildings) that aims at understanding and analyzing human movements at the micro level has increased considerably since 9/11. Past research has shown that reducing the time rescuers needed to reach a disaster site within a building (e.g., a particular room) can have a significant impact on evacuation and rescue outcomes in this kind of disaster situations. With the purpose developing emergency response systems that are capable of using complex real-time geospatial information to generate fast-changing scenarios, this study develops a Spatiotemporal Optimal Route Algorithm (SORA) for guiding rescuers to move quickly from various entrances of a building to the disaster site (room) within the building. It identifies the optimal route and building evacuation bottlenecks within the network in real-time emergency situations. It is integrated with a Ubiquitous Sensor Network (USN) based tracking system in order to monitor dynamic geospatial entities, including the dynamic capacities and flow rates of hallways per time period. Because of the limited scope of this study, the simulated data were used to implement the SORA and evaluate its effectiveness for performing 3D topological analysis. The study shows that capabilities to take into account detailed dynamic geospatial data about emergency situations, including changes in evacuation status over time, are essential for emergency response systems.

Smart Mobile Blackbox DVR in Car Environment (자동차 환경에서 스마트 모바일 블랙박스 DVR)

  • Choi, Sun-O;Kim, Young-Po;Im, Yong-Soon;Kim, Young-Ja;Kang, Eun-Young
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.13 no.5
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    • pp.9-15
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    • 2013
  • In this paper, automatic recognition of an accident and whether service delivery and risk driving through the giving of the driver to correct driving habits before and after the accident to reproduce highly scalable video Smart Mobile Blackbox DVR (SMBD, Smart Mobile Blackbox DVR) Computer of the model was designed. SMBD on embedded systems equipped with wireless capabilities to sleep in the car accident point and the image information by wireless communications, by notification in the control center, 24-hour emergency rescue service and traffic information can be provided. The vehicle ECU (Electronic Control Unit) of the vehicle information and sensor data in conjunction with wireless eCall (Emergency Call) services can be realized.

Shear Strength Evaluation in Masonry Assemblages by Reinforcing Materials in Joint (줄눈 보강을 통한 면내 방향의 조적조 사인장 전단강도 평가)

  • Woo, Jong-Hun;Shin, Kyung-Jae;Lee, Jun-Seop;Han, Seung-Yun
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.9
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    • pp.191-198
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    • 2019
  • All over the Republic of Korea, there are many masonry buildings which have been built since 1970s. When the earthquake at Po-Hang occurred, this is the main cause of huge damage because the masonry buildings have not seismic capacity. When masonry buildings are failed, two type of the failure modes can be shown, which are in-plane mode and out-plane mode. In-plane mode can have seismic capacity in masonry so diagonal shear test is performed in this study. The purpose of this study was to find the best way to reinforce the materials through the diagonal shear test. Through the test, shear stress and shear modulus of elasticity will be calculated, referred to the ASTM E 519-02. The variables in this test are ${\phi}3$ wire, three types of wire meshes, polypropylene strap and different types of brick. Each variable is applied to the same condition of the $1.2m{\times}1.2m$ masonry walls which are made by ASTM E 519-02. Compared to each variable with shear stress and shear modulus of elasticity, the best way of reinforcing method to have seismic capacity will be proved in this study.

Shift of Vietnamese Consumer E-purchasing Behavior During and After Covid-19 Pandemic

  • Pham Thi Cam ANH;Nguyen Mai PHUONG;Nguyen Huong GIANG;Pham Ngoc Mai LINH;Nguyen Huong GIANG
    • Journal of Distribution Science
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    • v.22 no.1
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    • pp.47-59
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    • 2024
  • Purposes: The study aimed at examining the impact of the COVID-19 pandemic on the shift of online consumer purchasing behavior and whether the new behaviors would be maintained after the epidemic season. The study also aims to investigate how online customers change based on perceived risks. Research design and Methodology: The study investigated purchasing behavior of the same 377 online Vietnamese consumers during two periods: (1) during the period of social distancing and (2) one and half year after that, allowing data to be collected in real time, so that consumers do not have to recall their behavior. Results: Purchasing behavior appeared to be more influenced by gender, age and household size. Aged consumers are more concerned about risks than those in the younger group, who only worry about the risks during the pandemic. Consumers in households with two or more people are more concerned about the risks than those living alone. Female appeared to be more influential in both during and after pandemic than male. Conclusions: The findings contribute to clarify shift of online consumer purchasing behavior, which helps business to develop effective marketing strategies and enhance their presence in the e-commerce sector.

Optical properties of LK-99 and Cu2S

  • Hong Gu Lee;Yu-Seong Seo;Hanoh Lee;Yunseok Han;Tuson Park;Jungseek Hwang
    • Progress in Superconductivity and Cryogenics
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    • v.26 no.2
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    • pp.1-4
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    • 2024
  • We investigated Pb10-xCux(PO4)6 (0.9 < x < 1.1) (LK-99) and Cu2S, presumed to be contained as an impurity in LK-99, in a wide spectral range from far infrared to ultraviolet using optical spectroscopy. The optical conductivity spectra of both samples were obtained from measured reflectance spectra at various temperatures from 80 to 434 K. Both samples showed several infrared-active phonons in the far and mid-infrared regions. LK-99 showed typical insulating features with a band gap of ~1 eV. Cu2S showed a nonmonotonic temperature-dependent trend and two energy gaps: one energy gap of ~93 meV and a band gap of 2.42 eV. Our results indicate that LK-99 cannot be a superconductor because it is an insulator with a large band gap.