• Journal of Korea Multimedia Society
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• v.12 no.8
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• pp.1142-1154
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• 2009

The brand new type of mobile terminal services are kept being introduced in accordance with the development of mobile communication technology. Among many kinds of mobile application services, the PoC application standard which is using instant messaging service and group calls method with the existing walkie-talkie technology has been finished as the version 1.0 after tremendously active discussion and is being continued to be confirmed as 2.0 and 2.1. The PoC Box, which is discussed for replacing the PoC client and intermediate object as a voice messaging box, is currently being introduced and the biggest issues for PoC Box technology topics include the part of saved informations' processing and effective multimedia contents' transmission in the PoC Box system. In this research, we propose that the PaC client could effectively transmit the media to the end-user by specifying the playback location or range, focusing on the contents and the methods of dynamic controlling for saved media in PoC Box. This paper deals with the way of dynamic controlling method using the RTSP which is appropriate for PoC Box and the effective method for generation, expression, processing of various multimedia contents including audio and video objects.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.137.1-137.1
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• 2011

올리빈 구조의 $LiFePO_4$ 정극 활물질은 $650^{\circ}C$에서 고상법으로 제조되었다. $LiFePO_4$의 전자전도도를 향상시키기 위하여 graphite nanofiber(GNF)를 각각 3wt%, 5wt%, 7wt%, 9wt% 첨가하여 $LiFePO_4$-C를 제조하였다. 제조된 분말의 입자 형태를 확인하기 위하여 X-ray diffraction(XRD)과 File Electronic Scaning Electromicroscopy(FE-SEM)를 측정하였다. XRD결과로부터 제조된 분말은 모두 순수한 결정 구조를 나타내었고 입자의 크기는 약 200nm였다. 5wt% GNF를 첨가한 $LiFePO_4$-C는 기타 첨가량에 비해 방전용량이 가장 높았다. 첫 사이클의 용량은 151.73mAh/g 나타났고 50 사이클 뒤에도 92% 이상을 유지하고 있었다. 첨가하지 않은 것에 비해 43% 증가하였다. $LiFePO_4$-C(3wt%), $LiFePO_4$-C(7wt%), $LiFePO_4$-C(9wt%)의 첫 사이클 방전용량은 각각 147.94mAh/g, 136.64mAh/g, 121.07mAh/g 나타났다. $LiFePO_4$-C(5wt%)에 비해 용량은 떨어쪘지만 순수한 $LiFePO_4$보다 많이 높았다. 임피던스 결과를 보면 기타 첨가량에 비해 $LiFePO_4$-C(5wt%)의 저항 제일 낮았다. 이는 충방전 결과와 일치하였다. graphite nanofiber의 첨가로 인하여 $LiFePO_4$ 정극 활물질의 전자전도도가 높아지고, 따라서 전기화학적 특성도 크게 향상되었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.361-362
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• 2007

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD) and FE-SEM. $LiFePO_4/SPE/Li$ and $LiFePO_4$-C/SPE/Li cells were characterized electrochemically by charge/discharge experiments. The results showed that the discharge capacity of $LiFePO_4$-C/SPE/Li cell was 103 mAh/g at the first cycle. The discharge capacity of $LiFePO_4$-C/SPE/Li cell with 5 wt% carbon black was the largest among $LiFePO_4$-C/SPE/Li cells, 126 mAh/g at the first cycle and 123 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4$-C/SPE/Li cell with 5 wt% carbon black was better than that of $LiFePO_4$/SPE/Li cell.

• Resources Recycling
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• v.5 no.3
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• pp.50-55
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• 1996

The synthesis of Ca,,(PO,),(OH), by adding (NFIa)J),HPO, to lhe solution of Ca(NO,), dlssolvad CaO in HNO, and contmlled pH with NH,OH was carried out for certain time at room temperahire and atmosphere. Ca,,(PO,),(OH), was rorrned at the range from pN 10 to pH 13. The particle s~zeof Ca,,(PO,),(OH)i was 0.1-0.5 &In. Thc optimum reaction lime was 30 min, and the temperature was 40-70$^{\circ}$C. the shape also was not changed in spite of heating to iDVC hr 1 hour the c~ystalliratian temperature was 90$^{\circ}$C Ca,,(PO,),(OH), was calcinatcd and the shape also was not changzd, in spile of hcaling to 500$^{\circ}$C for 1 hour. But Ca,,(PO,),(OH), calcinated for lhour al 800$^{\circ}$C was changed to the spheric particle of Ca,,,(PO,),(OH),, CaO and Ca,(PO,),.

• Journal of Korea Multimedia Society
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• v.14 no.1
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• pp.54-75
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• 2011

PoC(Push-to-talk Over Cellular) is an integrated technology of group voice calls, video calls and internet based multimedia services. If a PoC user can not participate in the PoC session for various reasons such as an emergency situation, lack of battery capacity, then the user can use the PoC Box which has a similar functionality to the MM Box in the MMS(Multimedia Messaging Service). The RTSP(Real-Time Streaming Protocol) method is recommended to be used when there is a transmission session between the PoC box and a terminal. Since the existing VOD service uses a wired network, the packet size of RTSP-based VOD service is huge, however, the PoC service has wireless communication environments which have general characteristics to be used in RTSP method. Packet loss in a wired communication environments is relatively less than that in wireless communication environment, therefore, a buffering latency occurs in PoC service due to a play-out delay which means an asynchronous play of audio & video contents. Those problems make a user to be difficult to find the information they want when the media contents are played-out. In this paper, the following techniques and methods were proposed and their performance and superiority were verified through testing: cross-over dual reception buffering technique, advance partition multi-reception buffering technique, and on-demand multi-reception buffering technique, which are designed for effective picking up of information in media content being transmitted in short amount of time using RTSP when a user searches for media, as well as for reduction in playback delay; and same-priority packetization transmission method and priority-based packetization transmission method, which are media data packetization methods for transmission. From the simulation of functional evaluation, we could find that the proposed multiple receiving buffering and packetizing methods are superior, with respect to the media retrieval inclination, to the existing single receiving buffering method by 6-9 points from the viewpoint of effectiveness and excellence. Among them, especially, on-demand multiple receiving buffering technology with same-priority packetization transmission method is able to manage the media search inclination promptly to the requests of users by showing superiority of 3-24 points above compared to other combination methods. In addition, users could find the information they want much quickly since large amount of informations are received in a focused media retrieval period within a short time.

• Transactions on Electrical and Electronic Materials
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• v.8 no.1
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• pp.41-45
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• 2007

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). $LiFePO_4$/Li and $LiFePO_4$-C/Li cells were characterized electrochemically by cyclic voltammogram (CV), charge/discharge experiments and ac impedance spectroscopy. The results showed that the discharge capacity of $LiFePO_4$/Li cell was 147 mAh/g at the first cycle and 118 mAh/g after 30 cycles, respectively. The discharge capacity of $LiFePO_4$-C/Li cell with 5 wt% carbon black was the largest among $LiFePO_4$-C/Li cells, 133 mAh/g at the first cycle and 128 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4$-C/Li cell with 5 wt% carbon black was better than that of $LiFePO_4$/Li cell.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.12a
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• pp.48-52
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• 2006

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity' of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). $LiFePO_4$/Li and $LiFePO_4-C$/Li cells were characterized electrochemically by cyclic voltammogram (CV), charge/discharge experiments and ac impedance spectroscopy. The results showed that the discharge capacity of $LiFePO_4$/Li cell was 147 mAh/g at the first cycle and 118 mAh/g after 30 cycles, respectively. The discharge capacity of $LiFePO_4-C$/Li cell with 5wt% carbon black was the largest among $LiFePO_4-C$/Li cells, 133 mAh/g at the first cycle and 128 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4-C$/Li cell with 5wt% carbon black was better than that of $LiFePO_4$/Li cell.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.137.2-137.2
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• 2011

Poly (sodium 4-styrenesulfonate) (PSS) is ionomer based on polystyrene that is electrical conductivity and isoviscosity. LiFePO4 has been a promising electrode material however its poor conductivity limits practical application. To enhance the electronic conductivity of LiFePO4, in this study we prepared LiFePO4- PSS composite by the hydrothermal method. LiFePO4 was heated at $170^{\circ}C$ for 12h and then different wt% PSS (0%, 2.91%, 4.75%, 7.36%, 10%) are added to LiFePO4 and milled at 300rpm for 10h. And then the obtained powders were subsequently heated at $500^{\circ}C$ for 1h under argon flow. The cathode electrode were made from mixtures of LiFePO4-PSS: SP-270- PVDF in a weighting ratio 75%: 25%:5%. The electrochemical properties of LiFePO4- PSS/Li batteries were analyzed by cyclic voltammetry and charge/discharge tests. LiFePO4-C/Li battery with 4.75 wt% PSS displays discharge capacity of 128 mAh g-1 at room temperature that is considerably higher than pure LiFePO4/Li battery ( 113.48 mAhg-1).

• Journal of the Korean Chemical Society
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• v.28 no.3
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• pp.149-154
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• 1984

The electrical conductivity of p-type yttrium sesquioxide has been measured as a function of temperature and of oxygen partial pressure at temperatures from 650 to 1050$^{\circ}C$C and oxygen partial pressures from $1 {\times}10^{-5}\;to\;2{\times}10^{-1}$atm. Plots of log conductivity vs. 1/T at constant oxygen partial pressures are found to be linear with low-and high-temperature dependences of conductivity. The high-temperature dependence of conductivity shows two different defect structures. The plots of log conductivity vs. log $Po_2$ are found to be linear at $Po_2$'s of $10^{-5}\;to\;10^{-1}$ atm. The electrical conductivity dependences on $Po_2$ are found to be ${{\sigma}{\propto}Po_2}^{1/6}$at $850{\sim}950^{\circ}C,\;{{\sigma}{\propto}Po_2}^{3/16}$ at $950{\sim}1050^{\circ}C\;and\;{{\sigma}{\propto}Po_2}^{1/7.5}{\sim}{{\sigma}{\propto}Po_2}^{1/8.3}\;at\;650{\sim}800^{\circ}C$, respectively. The defect structures are$O_i{''}$ at $850{\sim}950^{\circ}C$ and $V_M{'''}$ at $950{\sim}1050^{\circ}C$. The electron hole is main carrier type, however, ionic contribution is found at lower temperature portion.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.7
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• pp.4878-4883
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• 2015

The IP Multimedia Subsystem(IMS) is a framework that provides access to the content of Internet and Telecom services anytime and anywhere with guaranteed Quality of Service(QoS) and manageability by separating control functions from bearer and services. The Service Delivery Platform(SDP) provides common interfaces and protocols to deploy existing or new services in an efficient way. Therefore SDP over IMS plays a role of bridge between established network and new IMS network by simplifying the interaction among application services. In order to enrich the multimedia network communication, we try to deploy the Push-to-talk over Cellular(PoC) service which is considered as the outstanding and distinguished half-duplex Voice over IP(VoIP) application service among deployable candidate services over mobile network. In this paper we investigate the advantages of PoC service and PoC architecture firstly, and then focus on the its practical implementation for the prototype to validate the feasibility of its deployment and realization.