• Title/Summary/Keyword: Po

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Photoluminescence properties of core/shell-type $LnPO_4:Eu/LnPO_4$ (Ln=La, Gd) nanophosphors

  • Oh, Jae-Suk;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1551-1554
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    • 2007
  • To overcome defect due to large surface of nanoparticle, a redispersible Eu doped $LnPO_4:LnPO_4$ core/shell nanoparticles were prepared in a highboiling coordinating solvent. The particle size of the synthesized core/shell nanophosphors was estimated to be about 8 nm by TEM. In this core/shell nanoparticle, the concentration of Eu ion was optimized on the basis of the emission intensity under UV ray excitation. Also, the PL properties of the nanophosphors have been compared with those of the $LnPO_4:Eu$ nanoparticles.

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Determination of Polonium Nuclides in a Water Sample with Solvent Extraction Method

  • Lee, M.H.;Lee, C.H.;Song, K.;Kim, C.K.;Martin, P.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2488-2492
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    • 2010
  • A method is described for the determination of the Po nuclides in a water sample. After the Po nuclides were purified from interfering elements in a water sample using a manganese dioxide precipitation followed by a solvent extraction method, the Po nuclides were deposited onto the silver plate. A large volume of the water sample was effectively pretreated with manganese dioxide precipitation method. To determine the optimum conditions for plating Po, the effects of the pH, volume, temperature and time on the Po deposition were investigated in hydrochloric acid solution. The investigated determination method of Po nuclides with solvent extraction was applied to a tap water sample.

Electrochemical Performance of Lithium Iron Phosphate by Adding Graphite Nanofiber for Lithium Ion Batteries

  • Wang, Wan Lin;Jin, En Mei;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.3
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    • pp.121-124
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    • 2012
  • Olivine type $LiFePO_4$ cathode material was synthesized by solid-state reaction method including one-step heat treatment. To improve the electrochemical characteristics, graphite nanofiber (GNF) was added into $LiFePO_4$ cathode material. The structure and morphological performance of $LiFePO_4$ were investigated by X-ray diffraction (XRD); and a field emission-scanning electron microscope (FE-SEM). The synthesized $LiFePO_4$ has an olivine structure with no impurity, and the average particle size of $LiFePO_4$ is about 200~300 nm. With graphite nanofiber added, the discharge capacity increased from 113.43 mAh/g to 155.63 mAh/g at a current density of 0.1 $mA/cm^2$. The resistance was also significantly decreased by the added graphite nanofiber.

Effect of Ph3PO or BCP Between Electron Transport and Emission Layers on the Driving Voltage of Organic Light Emitting Diode (전자수송층과 발광층 사이의 Ph3PO 혹은 BCP가 유기발광다이오드의 구동전압에 미치는 영향)

  • Ha, Mi-Young;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.8
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    • pp.678-681
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    • 2011
  • We have investigated the effect of organic thin film on the driving voltage of OLED (organic light emitting diode) by inserting a 5 nm thick 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) or triphenylphosphineoxide ($Ph_3PO$) between tris-(8-hydroxyquinoline)aluminum ($Alq_3$) electron transport layer and 4,4'-bis(2,2'-diphyenylvinyl)-1,1'-biphenyl (DPVBi) emission layer. The device with 5 nm thick $Ph_3PO$ layer exhibited higher maximum current efficiency and lower driving voltage than the device with BCP layer, resulting from better electron injection from $Alq_3$ to DPVBi in the device with $Ph_3PO$ layer.

A Study on Initial Seeds Selection of K-Means for Big Data Clustering (빅데이터 클러스터링을 위한 K-Means 초기 중심 선정 연구)

  • Kim, Yeong-Ju;Heo, Yu-Gyeong;Back, Jong-Sang;Jeong, Hwan-Jong;Lee, Sung-Ro;Jung, Min-A
    • Proceedings of the Korea Information Processing Society Conference
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    • 2014.11a
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    • pp.750-752
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    • 2014
  • K-Means 알고리즘은 구현이 쉽고, 패턴수가 n일 때 시간 복잡도가 O(n)인 장점을 가져 대용량 데이터에서 널리 이용된다. 그러나, K-Means 알고리즘은 초기 클러스터 중심을 어떻게 선정하는가에 따라 할당-재계산 횟수, 클러스터링 결과를 결정짓는다. 본 논문에서는 K-Means 알고리즘에서 클러스터 초기 중심 선정 연구를 살펴보고 계통임의추출법을 적용하여 K-Means 초기 중심 선정 방법을 제안한다. 제안한 방법은 대용량 데이터의 클러스터링 시간을 감소하고 정확도를 향상시킬 수 있다.

Outlier Distinction Algorithm via Vessel Representative Trajectory Extraction (선박 대표 궤적 추출을 통한 Outlier 판별 알고리즘)

  • Park, Jin-Gwan;Oh, Joo-Seong;Kim, Bum-Mu;Jeon, Sung-Min;Lee, Sung-Ro;Jeong, Min-A
    • Proceedings of the Korea Information Processing Society Conference
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    • 2014.11a
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    • pp.102-104
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    • 2014
  • 본 논문은 해상 교통량 증가로 급증하는 선박 사고 위험을 줄이기 위해 안전 운항을 위한 대규모 선박 궤적 클러스터링을 제안한다. 선박의 위도와 경도, 이름 및 상태, 속도, 선수 방향 등이 기록된 대용량의 데이터집합을 바탕으로 선박 궤적 클러스터링을 통해 총 2개의 선박 대표 궤적을 추출한다. 해당 선박의 이전까지의 대표 궤적, 그리고 해당 해상의 모든 선박의 대표 궤적을 추출한 후 현재 해당 선박의 궤적패턴과 비교하여 유사하지 않으면 Outlier로 판별하여 이상 거동 및 불규칙 움직임, 충돌상황을 대비할 수 있도록 의사결정에 도움을 줄 수 있는 알고리즘을 제안하였다.

The electrochemical properties of $LiFe_xMn_{1-x}PO_4$ cathode materials for lithium polymer batteries (리튬 폴리머 전지용 $LiFe_xMn_{1-x}PO_4$ 정극활물질의 전기화학적 특성)

  • Jun, Dae-Kyoo;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.424-425
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    • 2005
  • The purpose of this study is to research and develop $LiFe_xMn_{1-x}PO_4$ cathode for lithium polymer batteries. $LiFe_xMn_{1-x}PO_4$ cathode active materials were prepared using a solid-state reaction by adding carbon black to the synthetic precursors. We investigated cyclic voltammetry and charge/discharge cycling of $LiFe_xMn_{1-x}PO_4$/SPE/Li cells. The discharge capacity of $LiFe_{0.5}Mn_{0.5}PO_4$ was l26mAh/g and 110mAh/g at 1st and 10th cycle.

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Effective Carbon Coating on $LiFePO_4$ Using Petroleum Pitch (석유 핏치를 이용한 $LiFePO_4$의 효율적인 탄소 코팅방법)

  • Lee, Jae-Won;Oh, Chi-Hoon;Park, Sun-Min
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.303-304
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    • 2007
  • A comparison study of carbon coating on $LiFePO_4$ was done with two different carbon sources-petroleum pitch and Ketjen black. Raman spectroscopy and transmission electron microscopy (TEM) analysis were applied to the carbon-coated $LiFePO_4$. $LiFePO_4$ which was carbon-coated with petroleum pitch showed more uniform carbon layer and ordered carbon structure. Such uniformity and ordered structure of carbon coating layer resulted in higher initial discharge capacity and better rate capability.

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ON SOME CLASSES OF REGULAR ORDER SEMIGROUPS

  • Gao, Zhenlin;Zhang, Guijie
    • Communications of the Korean Mathematical Society
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    • v.23 no.1
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    • pp.29-40
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    • 2008
  • Here, some classes of regular order semigroups are discussed. We shall consider that the problems of the existences of (multiplicative) inverse $^{\delta}po$-transversals for such classes of po-semigroups and obtain the following main results: (1) Giving the equivalent conditions of the existence of inverse $^{\delta}po$-transversals for regular order semigroups (2) showing the order orthodox semigroups with biggest inverses have necessarily a weakly multiplicative inverse $^{\delta}po$-transversal. (3) If the Green's relation $\cal{R}$ and $\cal{L}$ are strongly regular (see. sec.1), then any principally ordered regular semigroup (resp. ordered regular semigroup with biggest inverses) has necessarily a multiplicative inverse $^{\delta}po$-transversal. (4) Giving the structure theorem of principally ordered semigroups (resp. ordered regular semigroups with biggest inverses) on which $\cal{R}$ and $\cal{L}$ are strongly regular.

Photoacoustic Spectroscopic Study on Cobalt Incorporation onto the Surface of Mesoporous Molecular Sieves

  • 박동호;박성수;최상준
    • Bulletin of the Korean Chemical Society
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    • v.20 no.6
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    • pp.715-719
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    • 1999
  • The incorporation of cobalt into mesoporous molecular sieves MCM-41 and MCM-48 was carried out. Co-PO/MCM41 and Co-PO/MCM48 were prepared using Co(II) acetate solution adjusted to pH = 3.0 with phosphoric acid by the incipient wetness method. Photoacoustic spectroscopy (PAS) was used to study the local environments of Co(II) incorporated into mesopores. The band around 500 nm in PAS of as-prepared Co-PO/MCM41 and Co-PO/MCM48 with Co(II) acetate solution was changed to triplet bands around 600 nm. This could be assigned to the 4 A2(F)-> 4T1(P) transition of Co(II) surrounded tetrahedrally by oxygen ions after calcination. It may be attributable to that the octahedral cobalt species containing phosphate ligands in coordination sphere reacting with framework's silanol groups to be dispersed atomically onto the surface of mesoporous molecular sieves as a tetrahedral species. This is unlike that the Co in Co-Cl/MCM41 and direct-synthesized Co-MCM41 transforms to Co oxide phase upon calcination. Co-PO/MCM41 and Co-PO/MCM48 were stable while treated with water.