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Enhanced Hydrogen Production from Methanol/Water Photo-Splitting in TiO2 Including Pd Component

  • Kwak, Byeong-Sub;Chae, Jin-Ho;Kim, Ji-Yeon;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1047-1053
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    • 2009
  • The future use of hydrogen as an energy source is expected to increase on account of its environmentally friendliness. In order to enhance the production of hydrogen, Pd ions (0.01, 0.05, 0.1, and 0.5 mol%) were incorporated $TiO_2$ (Pd-$TiO_2$) and used as a photocatalyst. The UV-visible absorbance decreased with increasing level of palladium incorporation without a wavelength shift. Although all the absorption plots showed excitation characteristics, there was an asymmetric tail observed towards a higher wavelength caused by scattering. However, the intensity of the photoluminescence (PL) curves of Pd-$TiO_2$ was smaller, with the smallest case being observed at 0.1 and 0.5 mol% Pd-$TiO_2$, which was attributedto recombination between the excited electrons and holes. Based on these optical characteristics, the evolution of $H_2$ from methanol/water (1:1) photo-splitting over Pd-$TiO_2$ in the liquid system was enhanced, compared with that over pure $TiO_2$. In particular, 2.4 mL of $H_2$ gas was produced after 8 h when 0.5 g of a 1.0 mol% Pd-$TiO_2$ catalyst was used. $H_2$ was stably evolved even after 28 h without catalytic deactivation, and the amount of $H_2$ produced reached 14.5 mL after 28 h. This is in contrast to the case of the Pd 0.1 mol% impregnated $TiO_2$ of $H_2$ evolution of 17.5 mL due to the more decreasedelectron-hole recombination.

Brief history of Korean national forest inventory and academic usage

  • Park, Byung Bae;Han, Si Ho;Rahman, Afroja;Choi, Byeong Am;Im, Young Suk;Bang, Hong Seok;So, Soon Jin;Koo, Kyung Mo;Park, Dae Yeon;Kim, Se Bin;Shin, Man Yong
    • Korean Journal of Agricultural Science
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    • v.43 no.3
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    • pp.299-319
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    • 2016
  • The National Forest Inventory (NFI) is important for providing fundamental data for basic forest planning and the establishment of forest policies for the purpose of implementing sustainable forest management. The purpose of this study is to present the development of Korea's NFI including legal basis, sampling design, and measured variables and to review the usage of NFI data. The survey methods and forestry statistics among the Unites States, Canada, Japan, China, and European countries were briefly compared. Total 140 publications utilizing NFI data between 2008 and 2015 were categorized with 15 subjects. Korea has conducted the NFI 6 times since 1971, but only the $6^{th}$ NFI is comparable with the fifth, the previous NFI, because the permanent sampling plots have been shared between the periods. The Korean Forestry Statistics contains only half as many variables as that of advanced countries in Forestry. More researches were needed to improve consistent measurement of diverse variables through implementation of advanced technologies. Additional data for Forest Health Monitoring since the NFI $6^{th}$ must be under quality control which will be an essential part of the inventories for providing the chronological change of forest health.

Economic Analysis of Growing Ginger (Zingiber officinale) Under Teak (Tectona grandis) Canopy in Southwest Nigeria

  • Oladele, Adekunle Tajudeen;Popoola, Labode
    • Journal of Forest and Environmental Science
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    • v.29 no.2
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    • pp.147-156
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    • 2013
  • Multiple use forestry is capable of generating income for forest based communities through Non-Timber forest products (NTFPs) which provide food, medicine, materials for domestic use and cash income for communities adjoining forest areas in developing countries. This study evaluates the economics of producing ginger rhizomes under teak canopy in a multiple land use system during 2007 and 2008 in even aged teak plantations in Ibadan and Ife, Nigeria. Twelve $6m^2$ sample plots were randomly selected in Completely Randomized Block Design within and outside the plantation. Average ginger rhizome of (50-60 g) were planted on the slightly tilled soil. NPK 15:15:15 was applied at 180 kg/ha on a split unit dose. ANOVA, Profitability, Benefit-Cost (B/C) ratio were used to analyze data. Results showed no significant differences between sites in ginger rhizome yield, (0.089 and 0.718, ${\rho}{\leq}0.05$) in 2007 and 2008 respectively. Average yield were higher outside teak canopy in both sites and treatments, (Ibadan -40.05 g>32.9 g, Ife -67.6 g>25.2 g and Ibadan -41.3 g>31.5 g, Ife -66.8 g>25.0 g) with and without NPK respectively. NPK had no effect on yields within teak plantation, (Ibadan -31.5<32.9 g, Ife -25 g<25.2 g). Ginger rhizome production was viable financially without inorganic fertilizer during second cropping season within and outside plantation (B/C=1.02, 1.09) respectively. Ginger could be raised profitably under teak canopy, however, studies on insolation requirement of ginger under teak canopy and other tree plantations are recommended.

Impacts of Cropping Systems on the Distribution of Soil Microorganisms in Mid-mountainous Paddy

  • Kang, Ui-Gum;Shin, Woon-Chul;Choi, Jong-Seo;Lee, Yong-Bok;Lee, Young-Han
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.480-488
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    • 2016
  • Soil microbes are widely well known to play an important role for sustainable agriculture in terms of crop healthy cultivation and environmental conservation. In this context, the distributional characteristics of soil microbes according to cropping systems were investigated under rice (R)-rice (R), rice (R)-barley (B)-rice (R), and soybean (S)-barley (B)-soybean (S) cropping condition to get basic informations for sustainable agriculture, where barley was grown for winter, in mid-mountainous loam paddy located at the altitude of 285 m above sea level in Sangju area from 2014 to 2015. Estimating from microbial communities by fatty acid methyl ester (FAME) method, a total biomass of bacteria, actinomycetes, and fungi in R-B-R plot was 37% and 40% higher than that in S-B-S and R-R plots, respectively (p < 0.05). In especial, bacteria and fungi were more in R-B-R plot than those in any other ones. B. japonicum, AMF, and mesophilic Bacillus sp. were also greater in S-B-S plot than those. In the community distribution, however, bacteria and actinomycetes showed comparatively high values in S-B-S plot relative to either R-R or R-B-R plot including rice, in which fungi outstanding. In the correlation between microbial biomass and soil properties changed by the cropping, bacteria was positively correlated with C:N ratio; actinomycetes with exchangeable Ca; fungi with available $P_2O_5$ (p < 0.05). While these microbes showed negative response to water stable aggregates of soil.

Design and Implementation of a Document-Oriented and Web-Based Nuclear Design Automation System (문서중심 및 웹기반 핵설계 자동화 시스템의 설계 및 구현)

  • Park, Yong-Soo;Kim, Jong-Kyung
    • The KIPS Transactions:PartD
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    • v.11D no.6
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    • pp.1319-1326
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    • 2004
  • To automate nuclear design works which are time-consuming and man-power intensive, Innovative Design Processor ($IDP^{TM}$) is being developed. Two basic principles of IDP are the document-oriented design and the web-based design. The document-oriented design is that, if the designer writes a design document called active document and feeds it to a special program which has a robust parser, the finai document with complete analysis, table and plots is made automatically. The active documents can be written with ordinary HTML/XML editors or created automatically on the web, which is another framework of IDP. Using the proper mix-up of server side and client side programming under the LAMP (Linux/Apache/MySQL/PHP) environment, the design process on the web is modeled as a design wizard style so that even a novice designer makes the design document easily.

Quantitative Determination of Total Bile Acids from Bezoar and Bezoar-containing Liquid Preparation by Enzymatic Technique (효소반응법을 이용한 우황 및 우황함유 액상 제제 중 총담즙산의 정량)

  • Ha, In-Sik;Kim, Seung-Hwan;Cha, Bong-Jin;Kwon, Jong-Won;Yang, Joong-Ik;Min, Shin-Hong
    • Journal of Pharmaceutical Investigation
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    • v.21 no.2
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    • pp.67-71
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    • 1991
  • A simple and sensitive method was developed for the quantification of free and conjugated bile acids in bezoar without prior hydrolysis. $3{\alpha}-Hydroxy$ bile acids are first oxidized to 3-keto bile acids in the reaction catalyzed by $3{\alpha}-hydroxysteroid$ $dehydrogenase(3{\alpha}-HSD)$. During this oxidative reaction, an equimolar quantity of nicotinamide adenine dinucleotide(NAD) is reduced to NADH and subsequently oxidized to NAD with concomitant reduction of nitrotetrazolium blue(NTB) to diformazan by the catalytic action of diaphorase. The diformazan has an absorbance maximum at 540 nm. The intensity of the color produced is directly proportional to bile acids concentration in the bezoar extracts. The optimum conditions for the enzymatic reaction such as effects of reaction time, reaction temperature and pH, and stability were investigated. Calibration plots for the sodium chelate observed to be linear and intra-, inter-assay analytical recovery of bile acids averaged $97.65{\pm}3.4%(S.D.)$. Therefore, it is considered that the quality control of total bile acids from bezoar or bezoar-containing liquid preparation using this simple and sensitive assay system will be acceptable. Also current bezoars and bezoar-containing liauid preparations were examined their total bile acids from this method.

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Investigation on Selective Mechanization for Wet Season Rice Cultivation in Bangladesh

  • Islam, AKM Saiful;Islam, Md Tariqul;Rahman, Md Shakilur;Rahman, Md Abdur;Kim, Youngjung
    • Journal of Biosystems Engineering
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    • v.41 no.4
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    • pp.294-303
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    • 2016
  • Purpose: This study aimed to evaluate the profitability of four selective mechanization systems in rice cultivation. Methods: Field experiments were conducted in the farmers' field during the wet season (June to November) of 2015 in Bangladesh. Mechanization systems were applied to evaluate four different selective levels (treatment) in eleven consequent operations. Seedlings were raised in a traditional seedbed and trays for manual and mechanical transplanting, respectively. Land preparation, irrigation, fertilizer, pesticide, carrying, and threshing and cleaning operations were performed using the same method in all the experimental plots. The mechanical options in the transplanting, weeding, and harvesting operations were changed. The mechanization systems were $S_1$ = hand transplanting + hand weeding + harvesting by sickle, $S_2$ = mechanical transplanting + Bangladesh Rice Research Institute (BRRI) weeder + reaper, $S_3$ = mechanical transplanting + BRRI power weeder + reaper, and $S_4$ = mechanical transplanting + herbicide + reaper. This experiment was performed in a randomized complete block design with four replications. Power tiller, rice transplanter, BRRI weeder, BRRI power weeder, self-propelled reaper, BRRI open drum thresher, and BRRI winnower were used in the respective operations. Accordingly, the techno-economic performances of the different technologies were calculated and compared with those of the traditional system. Results: The mechanically transplanted plot produced 6-10% more yield than the hand transplanted plot because of the use of tender-aged seedlings. Mechanical transplanting reduced 61% labor and 18% cost compared to manual transplanting. The BRRI weeder, BRRI power weeder, and herbicide application reduced 74, 91, and 98% labor, respectively. The latter also saved 72, 63, and 82% cost, respectively, compared to hand weeding. Herbicide application reduced the substantial amount of labor and cost in the weeding operation. Mechanical harvesting also saved 96% labor and 72% cost compared to the traditional method of harvesting using sickle. Selective mechanization saved 15-17% input cost compared to the traditional method of rice cultivation. Conclusions: Mechanical transplanting with the safe use of herbicide and harvesting by reaper is the most cost- and labor-saving operation. The method might be the recommended set of selective mechanization for enhancing productivity.

Comparison of Daily Soil Water Contents between Energy BalanceWater Budget Approach and TDR (에너지와 물수지 연계방법과 TDR로부터 얻어진 매일 토양 함수량의 비교)

  • 임창수
    • Water for future
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    • v.29 no.4
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    • pp.119-129
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    • 1996
  • The daily soil water contents were obtained from the time domain reflectometry (TDR) method and energy balance-water budget approach with eddy correlation at the two small semiarid watersheds of Lucky Hills and Kendall during the summer rainy period. There was a comparison of daily soil water content measured and estimated from these two different approaches. The comparison is valuable to evaluate the accuracy of current soil water content measuring system using TDR and energy balance-water budget approach using eddy correlation method at small watersheed scale. The degree of similarity between the regressions of these two methods of measuring soil water content was explained by determining the correlations between these methods. Simple linear regression analyses showed that soil water content measured from TDR method was responsible for 58% and 63% of the variations estimated from energy balance-water budget approach with eddy correlation at Lucky Hills and Kendall, respectively. The scatter plots and the regression analyses revealed that two different approaches for soil water content measurement at small watershed scale have no significant difference.

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Effect of Soil Microorganisms on Chinese Cabbage(Brassica Campestris L) Yield in Fall Cropping (土壤微生物劑處理가 가을배추의 收量에 미치는 影響)

  • Kim, Kyung-Je
    • Korean Journal of Organic Agriculture
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    • v.7 no.2
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    • pp.107-114
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    • 1999
  • This study was carried out to investigate the effect of microbial fertilizers on yields of Chinese cabbage(Brassica campestris L.). Six microbial fertilizers, MPK+Husk+Palma, Husk+Palma, MPK+Compost, Compost, Bio livestock cattle system(BLCS) cattle dropping, and Tomi, were used. All of the microbial fertilizers were very effective to increase yields of Chinese cabbage. As a result of analysis of plant chemical components, MPK+Compost treated plot showed higher concentrations of Fe and Zn than other microbial fertilizers plot. In a chemical components of soil, concentrations of K, Mg were increased with Tomi treatment, however, the other concentrations of plant and soil chemical components were not different. In a microbial properties of soil, Tomi, Husk+Palma, and MPK+Husk+Palma treated plots increased in numbers of total bacteria and bacillus. Tomi treated plot increased in numbers of actinomycetes and fungi, also. The other microbial properties of soil were not different, however. The microbial fertilizers may affect the useful microbial properties, therefore, it would be increase yield of Chinese cabbage treated with them.

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Effects of harvest intervals and seeding rates on dry matter yield and nutritive value of alfalfa cultivars

  • Xu, Xuan;Min, Doohong;McDonald, Iryna
    • Journal of Animal Science and Technology
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    • v.63 no.5
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    • pp.1098-1113
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    • 2021
  • Maturation process of alfalfa (Medicago sativa L.) could be prevented by the reduction of lignin content in terms of conventional breeding or transgenic technology. Alfalfa could exhibit higher leaf/stem ratio, with a concern of yield loss. The objective of this study was to compare forage yield and nutritive value of low lignin alfalfa and two reference varieties subjecting to two harvest intervals and three seeding rates. The experimental design was a randomized complete block in a split-split plot arrangement with four replicates, where harvest intervals (28-day and 35-day) were assigned to whole plots, seeding rates were subplots, and varieties were sub-subplots. The weighted mean nutritive value was applied to two production years of 2016 and 2017. Hi-Gest 360 (low lignin alfalfa) provided similar yield potential and increased nutritive value compared to two reference varieties. Over a two-year production period, alfalfa harvested at every 28-day interval provided more economic returns than those at 35-day interval. For the seeding year and first production year, five cuts made by the 28-day interval produced more yield than four cuts by the 35-day interval. Due to limited rainfall in May 2017, a sharp drop of the first cutting overturned the advantage of the five-cut system. Shorter intervals between harvests generally increased crude protein (CP) concentrations. The differences of relative feed value (RFV) between two harvest intervals tended to be great during the first and second cuttings. Overall, harvest interval had a large effect on nutritive value and a more significant effect on alfalfa dry matter yield than variety selection. Seeding rate did not affect alfalfa yield and nutritive value.