• Title/Summary/Keyword: Plastic viscosity

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Liquid-phase Thermal Degradation Properties of Waste Plastic Film (폐플라스틱 필름의 액상 열분해 특성에 관한 연구)

  • Hwang, T.S.;Kim, Y.S.;Kang, T.W.;Hwang, E.H.
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.116-121
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    • 2003
  • In this study, the thermal degradation process has been investigated at various reaction temperature$(350{\sim}400^{\circ}C)$ and times$(30{\sim}120\;min)$ in order to recycle waste plastic films as solid state wax. Waste plastic films were easily melted by adding a small amount of waxes. The effects of wax addition and nitrogen flow rate on their thermal degradation properties were investigated. FT-IR, GPC and viscometer were used to analyze properties of the solid wax including the structure, molicular weight distribution and melt viscosity. The average molecular weight of solid wax was decreased with increasing the reaction time, temperature and amount of wax added, Also, the viscosity of solid wax decreased with increasing the stirring speed at a constant reaction temperature and time, and its viscosity got close to zero above $390^{\circ}C$.

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Fluidity Performance Evaluation of Low Viscosity Typed Superplasticizer for Cement-Based Materials Incorporating Supplementary Cementitious Materials (혼화재료를 치환한 시멘트 계열 재료에 대한 저점도형 고성능 감수제의 유동 성능 평가)

  • Son, Bae-Geun;Lee, Hyang-Seon;Lee, You-Jeong;Han, Dong-Yeop
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.3
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    • pp.219-228
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    • 2019
  • The aim of the research is to provide a fundamental data of low viscosity typed superplasticizer (SP) on cement-based materials incorporating various supplementary cementitious materials (SCMs). As a relatively new product, low-viscosity typed SP has introduced for high performance concrete with high viscosity due to its high solid volume fraction with various SCMs. However, there are not enough research or reports on the performance of the low viscosity typed SP with cement-based materials incorporting SCMs. hence, in this research, for cement paste and mortar, fluidity and rheological properties were evaluated when the mixtures contained various SCMs such as fly ash, blast furnace slag, and silica fume. From the experiment conducted, it was checked that the low viscosity typed superplasticizer decreased the plastic viscosity of the mixture as well as the yield stress. From the results of this research, it is expected to contribute on introduction of new type SP for high performance concrete or high-viscous cementitious materials.

Effect Analysis of Mix Designing Factors on Workability and Rheological Parameters of Self-Compacting Concrete (배합요인이 자기충전 콘크리트의 워커빌리티 및 레올로지 파라미터에 미치는 영향 분석)

  • Yoon, Seob;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.235-242
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    • 2018
  • The objective of the paper is to investigate the effect of mix designing factors on the workability and rheological parameters of self compacting concrete in order to facilitate the difficulties of quality control of high sensitivity of SCC. Mix proportions of SCC were prepared with various conditions of coarse, and fine aggregate, and unit water content, and the SCC mixtures were tested on workability, rheological properties to provide basic data for quantitative evaluation. Test results indicated that the yield stress of SCC decreased with increasing the coarse aggregate volume ratio, and increased with increasing the amount of VMA. However, unit water content, fine aggregate type, and air content didn't affect the yield stress value. The plastic viscosity according to the mixing factors showed a similar tendency to the yield stress. In addition, there was no correlation between yield stress and workability (flow, T50, V-lot). However, there was closely correlation among plastic viscosity and T50 and V-lot. Especially, T50 and V-lot time decreased with decreasing plastic viscosity.

Collodial Properties and Acid Consuming Capacity of Hydrous Aluminum Oxide Suspension (제산제 알루미나수화물의 콜로이드성과 제산능)

  • 이계주;이기명
    • YAKHAK HOEJI
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    • v.35 no.4
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    • pp.277-282
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    • 1991
  • Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

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Rheological Characteristics of Debris Flows (토석류 이동의 레올로지적 특성)

  • 김상규;서홍석
    • Geotechnical Engineering
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    • v.13 no.5
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    • pp.125-132
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    • 1997
  • It is observed that debris mitred with a wide range of soil particles and water moves downwards like viscous fluid soon after a landslide has triggered. An Assumption can be made from the field observation that the debris flow behaves as a kind of non(non-Newtoniron) Newtonian fluid which has non linear viscosity. In this study, a series of viscosity tests are carried out to measure rheological properties of debris by using a viscometer with semples taken from a landslide site. It is proved that debris flows behave as Bingham plastic mod el of non-Newtonian fluid. This model can be used predict the movement of debris flows.

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A Study on the Factors Affecting the High Fluid Mortar Containing Ground Granulated Blast-furnace Slag (고로슬래그 미분말을 함유한 고유동 모르터의 유동성상에 미치는 영향 요인에 관한 연구)

  • 김재훈;윤상천;지남용
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2002.11a
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    • pp.29-36
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    • 2002
  • High fluid concrete unlike OPC concrete is made with various material, and the phase of fresh concrete is considerably different. In order to understand fluidity phase and mix properties of high fluid concrete, concrete is required to access as suspension structure which consists of aggregate and paste. The focus of this paper is to analyze the test results and quantify the effect of mix proportions of molar and fineness modulus of ,and on the properties of fresh mortar. The effect of water-binder ratio, sand-binder ration, content; of ggbs (by mass of total cementitious materials), and various contents of water reducing agent on the yield stress and plastic viscosity of the mix is studied. Based on the experimental results, the following conclusion; can be drawn: (1) The mixing time needed (or high fluid mortar was approximately two times more than that of ordinary portland mortar. (2) The fluidity phase of mortar could be explained by yield stress of mix and the fluidity of mortar. (3) As the content of ggbs increased, yield stress of mortar was decreased and plastic viscosity of it was increased. (4) For the high fluid mortar, it was appeared that sand-binder ratio should be below 1.5.

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Rheological Properties of Cement Paste Containing Ultrafine Blastfurnace Slag (초미분말 고로슬래그를 혼합한 시멘트 페이스트의 유동특성)

  • You, Chang-Dal;Byun, Seung-Ho;Song, Jong-Taek
    • Journal of the Korean Ceramic Society
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    • v.44 no.8
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    • pp.430-436
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    • 2007
  • Rheological properties of cement paste containing ultrafine blastfurnace slag (UBS, $9600cm^2/g$) were investigated by mini-slump test, pH meter, conduction calorimeter and coaxial cylinder viscometer. In order to improve rheological properties of the cement paste, granulated blastfurnace slag (GBS, $3500cm^2/g$) and polycarboxylate type superplasticizer (PC) were also used in this experiment. The fluidity of cement paste containing UBS was decreased. The yield stress and plastic viscosity of cement paste was increased with increasing UBS. But the rheological properties were improved when GBS and PC were added to UBS blended cement paste. In the relationship between the yield stress and the plastic viscosity or the mini-slump value, the yield stress of the cement paste was proportional to the plastic viscosity of it. However the cement paste mini-slump value was in inverse proportional to the yield stress.

3-Dimensional Consolidation Analysis Considering Viscosity on Soft Clay Ground improved by Plastic Board Drain (점성을 고려한 PBD 타설 연약점토지반의 3차원 압밀해석)

  • You, Seung-Kyong;Han, Jung-Gun;Jo, Sung-Min;Kim, Ji-Yong
    • Journal of the Korean Geosynthetics Society
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    • v.4 no.4
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    • pp.39-46
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    • 2005
  • A series of numerical analyses on soft clay ground improved by plastic board drain(PBD) were carried out, in order to investigate the consolidation behavior considering viscosity of the improved ground. The applicability of numerical analyses, in which an elasto-viscoplastic three-dimensional consolidation finite element method is applied in this study, was confirmed through comparison between experimental and analytical results. As the analytical results, consolidation behavior of both settlement and excess pore pressure and effective stress in clay were elucidated. Then secondary consolidation characteristics of improved ground were estimated through compare with results of typical one-dimensional consolidation analysis.

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Rheological Properties of Cement Paste Blended Blast Furnace Slag or Fly Ash Powder (고로슬래그 및 플라이 애시 분말을 혼합한 시멘트 페이스트의 유동특성)

  • Song, Jong-Taek;Park, Hyo-Sang;Byun, Seung-Ho;Yoo, Dong-Woo
    • Journal of the Korean Ceramic Society
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    • v.45 no.6
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    • pp.336-344
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    • 2008
  • Rheological properties of cement pastes containing blast furnace slag (BFS: 3,900, $7,910\;cm^2/g$) or fly ash powder (FA: 4,120, $8,100\;cm^2/g$) according to the ratio of water/binder (W/B) and the dosage of polycarboxylate type superplasticizer (PC) were investigated by a mini slump and a coaxial cylinder viscometer. In this experiment, the ratio of replacing OPC with BFS or FA was 30 wt%, the W/B was from 30 to 70 wt%. As a result, the fluidity of cement paste containing BFS or FA was improved with increasing W/B and the dosage of PC. BFS or FA replaced cement paste with W/B 70% and PC 0.3% showed the highest fluidity. The segregation range of cement paste was occurred below $10\;d/cm^2$ of the yield stress and below 50 cPs of the plastic viscosity by the coaxial cylinder viscometer. And also it was formed that the plastic viscosity and the yield stress of FA replaced cement paste were higher than them of BFS replaced cement paste.

Performance Analysis of Low-viscosity type Superplasticizer (저점도형 감수제의 성능 분석)

  • Han, Dongyeop
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.35-36
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    • 2016
  • Recently, with the increasing demand of high performance of concrete, the mix design of concrete mixture has became low water-to-binder ratio with high binder content. To compensate these trend of mix design, high range water reducer, or superplascizier has been invented to achieve high flowable concrete. Although this superplasticizer provides favorable workability based on its dispersing action on the components of concrete mixture, it has an limitation of decreasing viscosity of the mixture, and thus it is difficult to secure sufficient workability for high performance concrete mixtures with high binder content. To improve the workability of concrete with high viscosity, recently, low-viscosity type superplasticizer was introduced, and in this research, a fundamental properties of low-viscosity type superplasticizer is evaluated.

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