• Title/Summary/Keyword: Plant O&M

검색결과 859건 처리시간 0.033초

시뮬레이션 기술 적용 해외발전사업 엔지니어링 (Engineering based on Simulation Technique for Overseas Power Plant Projects)

  • 백세현
    • KEPCO Journal on Electric Power and Energy
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    • 제7권1호
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    • pp.63-67
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    • 2021
  • 해외 발전사업의 기술 경쟁력 우위 선점을 위해서는 발전시스템에 대한 최적설계기술 및 발전소 운영 기간 중 최소 비용으로 높은 신뢰도의 설비 관리, 최적 성능 유지를 할 수 있는 O&M 관리 기술이 필요하다. 전력연구원은 해외발전사업 전주기 기술지원을 위한 연구개발을 수행하고 있다.

Improving Electrochemical Performance of Ni-rich Cathode Using Atomic Layer Deposition with Particle by Particle Coating Method

  • Kim, Dong Wook;Park, DaSom;Ko, Chang Hyun;Shin, Kwangsoo;Lee, Yun-Sung
    • Journal of Electrochemical Science and Technology
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    • 제12권2호
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    • pp.237-245
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    • 2021
  • Atomic layer deposition (ALD) enhances the stability of cathode materials via surface modification. Previous studies have demonstrated that an Ni-rich cathode, such as LiNi0.8Co0.1Mn0.1O2, is a promising candidate owing to its high capacity, but is limited by poor cycle stability. In this study, to enhance the stability of the Ni-rich cathode, synthesized LiNi0.8Co0.1Mn0.1O2 was coated with Al2O3 using ALD. Thus, the surface-modified cathode exhibited enhanced stability by protecting the interface from Ni-O formation during the cycling process. The coated LiNi0.8Co0.1Mn0.1O2 exhibited a capacity of 176 mAh g-1 at 1 C and retained up to 72% of the initial capacity after 100 cycles within a range of 2.8-4.3 V (vs Li/Li+. In contrast, pristine LiNi0.8Co0.1Mn0.1O2 presented only 58% of capacity retention after 100 cycles with an initial capacity of 173 mAh g-1. Improved cyclability may be a result of the ALD coating, which physically protects the electrode by modifying the interface, and prevents degradation by resisting side reactions that result in capacity decay. The electrochemical impedance spectra and structural and morphological analysis performed using electron microscopy and X-ray techniques establish the surface enhancement resulting from the aforementioned strategy.

암세포 성장 저해 및 항염증 효능을 나타내는 산여뀌 성분의 분리 (Isolation of the Constituents with Cancer Cell Growth Inhibition and Anti-inflammatory Activity from Persicaria nepalensis)

  • 김동화;이상국;박희준
    • 생약학회지
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    • 제50권4호
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    • pp.245-252
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    • 2019
  • This study was initially explored to procure biomaterials capable of inhibiting cancer cell growth from nine Persicaria species (Polygonaceae). The extract of P. nepalensis that was selected from the initial screenings was further fractionated to identify bioactive compounds. The ethyl acetate (EtOAc) fraction was shown to be the most active in the inhibition of cell growth against six cancer cell lines (IC50 value of 3.77-12.87 ㎍/ml). Phytochemical study led to the isolation of two galactolipids of 1,2-di-O-linolenoyl-3-O-β-D-galactospyranosyl-sn-glycerol (1) and 1-O-linolenoyl-3-O-β-D-galactospyranosyl-sn-glycerol (2) from the hexane fraction and three phenylpropanoyl sucroses of lapathoside A (3), vanicoside B (4) and lapathoside C (5) from the EtOAc fraction. These isolated compounds have not been reported from this plant. Compounds 3 and 4 exhibited the effective growth inhibition against a panel of cancer cell lines (IC50 value of 6.90-18.09 μM). In addition, the anti-inflammatory activity was evaluated to determine lipopolysaccharide (LPS)-induced nitric oxide (NO) formation in RAW264.7 mouse macrophage cells. The EtOAc fraction (IC50; 34.14 ㎍/ml) and its constituents, 3 (8.55 μM) and 4 (7.83 μM) were shown to be effective in the inhibition of LPS-induced NO production. Therefore, compounds 3 and 4 were considered to be active constituents for anti-inflammatory and antitumor activity from P. nepalensis.

Purification of Antioxidant substance from the stem bark of Rhus verniciflua

  • Kim, Jung-Bae
    • 한국식품영양학회:학술대회논문집
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    • 한국식품영양학회 2001년도 동계 학술심포지움
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    • pp.126-126
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    • 2001
  • The Rhus verniciflua contains alkly(en)-catechol type allergens with a saiurated or unsaturated alkly chain of 15 or 17 carbon atoms. It has been recognized as an extremely active allergen causing skin reactions similar In poison ivy. The allergic contact dermatitis induced by the urushiol is known to be mediated be T lymphocytes whicht specifically recognize the hepten urushiol. Therefore. direct use of this plant as a medicinal purpose might imply a considerable hazard in Korea. In this study, using the established method for the detoxification from the stem bark of Rhus verniciflua, an strong antioxidant substance was isolated and characterized DPPH (diphenypricryl hydrazyl) assay measures hydrogen atom-donating activity and hence provides a measure of free radical scavenging antioxidant activity. DPPH, a purple-colored stable free radical, is reduced to yellow-colored diphenylpicryl hydrazine by antioxidants to deducing agents. Antioxidative effects of the water extract from RV were measured by DPPH assay. Twenty microliters of the extract was added to 1ml of 100mM DPPH solution in ethanol The mixture was shaken and left to stand for 10min at room temperature. The crude water extracts was purified by using HPLC method with a DEAE (anionic type), CN, ODS column. The purified compound remained stable at pH 3.0-6,0, but unstable above pH 6.5. It was stable heat at 10$0^{\circ}C$ for 4 hours, but still had about 80% of residual activity after treatment at 10$0^{\circ}C$ for 5 hours. The elemental composition of the HR-EI mass spectrum at m/z 170.02 was estimated the empirical formula as $C_{7}$ $H_{6}$ $O_{5}$. $C_{10}$ $H_4$ $O_2$N$_1$, $C_{5}$ $H_4$ $O_4$N$_3$, $C_{8}$$H_2O$$_1$N$_4$. In antimicrobial test, no inhibition was observed against Gram-positive and negative bacteria. This compound was stronger than that of commercial antioxidant by DPPH test, such as BHT, BHC at the same concentration (20$\mu$g/ml).ml).

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경주 황성공원의 식생구조 및 관리방안 (Vegetation Structure and Management Proposal of Hwangsong Park in Kyongju)

  • 이영경
    • 한국환경생태학회지
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    • 제14권1호
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    • pp.46-56
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    • 2000
  • 경주 황성공원의 식생구조를 파악하여 생태적 가치를 알아보고, 바람직한 관리방안을 제시하기 위하여 공원 내에 $10m{\times}10m$의 조사구 20개를 설치하고, 군집구조조사를 실시하였다. 군집을 분리하기 위하여 TWINSPAN과 DCA를 이용하였으며, DCA분석결과 소나무군집(A), 소나무군집(B), 참나무류-소나무군집, 아까시나무군집, 그리고 신갈나무군집의 5개로 분리되었다. 종다양도 분석에서 20개 조사구에 걸쳐 목본수종이 총29종 출현하였으나 종조성은 단순하게 나타났다. 각 조사구당 평균출현종수는 $5.32{\pm}2.9$종이었고, 흉고직 경급별 분석에서 소나무는 주로 DBH 27~47cm계급에 분포하였다. 연륜 및 생장분석결과 역사적, 생태적으로 가치가 있는 소나무림이 최근 들어 생장이 둔화되고 있었다. 이상의 조사결과를 바탕으로 관리제언이 제시되었다.

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Flavonoid Compounds from the Leaves of Kalanchoe prolifera and Their Cytotoxic Activity against P-388 Murine Leukimia Cells

  • Aisyah, Lilis Siti;Yun, Yenny Febriani;Herlina, Tati;Julaeha, Euis;Zainuddin, Achmad;Nurfarida, Ida;Hidayat, Ace Tatang;Supratman, Unang;Shiono, Yoshihito
    • Natural Product Sciences
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    • 제23권2호
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    • pp.139-145
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    • 2017
  • Seven flavonoid compounds, kaempferol (1), quercetin (2), quercetin-3-O-${\beta}$-D-glucopyranoside (3), kaempferol-3-O-${\beta}$-D-glucopyranoside (4), kaempferol-3-O-${\alpha}$-L-rhamnoside (5), quercetin-3-O-sophoroside (6) and quercetin-3-O-rutinoside (7), were isolated from the methanolic extract of leaves of Kalanchoe prolifera. Compounds 1-7 were isolated for first time from this plant. These compounds were evaluated their cytotoxic activity against P-388 murine leukimia cells in vitro. Among those compounds kaempferol (1) and quercetin (2) showed strongest cytotoxic activity with $IC_{50}$ values of $4.45{\pm}0.05$ and $6.28{\pm}0.02{\mu}g/mL$, respectively.

광량과 온도 변화에 따른 고추(Capsicum annuum L.) 잎 광계 II의 광억제

  • 홍영남
    • Journal of Plant Biology
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    • 제38권4호
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    • pp.373-380
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    • 1995
  • $25^{\circ}C,\;100\;{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$의 광량 조건에서 25일 동안 키운 고추의 제 1엽에서 광억제를 유도하였다. $25^{\circ}C에서\;0~3000\;{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$의 광량으로 0~70분 동안 처리하여 얻은 photon exposure [mol photons.m-2, 광량과 빛 조사 시간의 곱, Bell과 Rose (1981)]에 대한 산소 발생의 광양자 수율과 QA 환원의 광화학 효율(형광 파라미터 Fv/Fm)을 조사하여 광계II 기능의 변화를 조사하였다. Photon exposure가 증가함에 따라 산소 발생의 광양자 수율은 곡선적으로, Fv/Fm은 일치 직선형으로 감소하였는데, 각각은 $5.5\;mol\;photons{\cdot}m^{-2},\;10\;mol\;photons{\cdot}m^{-2}$에서 광계II의 활성이 50% 감소하였다. 저온($15^{\circ}C$)과 고온($45^{\circ}C$)에서 광합선능을 조사하였을 때 저온에서는 광양자수율과 Fv/Fm 비율의 변화가 거의 없었으나 고온에서는 이들의 감소가 뚜렷하게 일어났다. 그러나 빛과 온도를 함께 처리하였을 경우, 저온과 고온조건 모두에서 현저한 광억제가 일어났다. 이로 미루어 보아 저온과 고온에서 나타나는 광억제의 촉진 현상은 서로 다른 메카니즘을 통해 일어나는 것으로 사료된다.

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개나리와 미선나무의 새로운 자생지 보고 (Recently Augmented Natural Habitats of Forsythia koreana (Rehder) Nakai and Abeliophyllum distichum Nakai in Korea)

  • 신현탁;이명훈;김용식;이병천;윤정원
    • 식물분류학회지
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    • 제40권4호
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    • pp.274-277
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    • 2010
  • 본 연구는 개나리와 미선나무의 새로운 자생지의 보고이다. 개나리의 자생지는 경상북도 청송군 부동면에서 발견하였다. 자생지의 규모는 $5m{\times}5m$크기로 12개체가 생육 중이었으며 그 중 3개체는 7-10 cm 정도의 유묘였다. 자생지의 식생은 주로 소나무와 아까시나무가 우점하는 2차림으로 교목층의 피도는 15% 정도였으며, 관목층의 피도는 40%로 조팝나무가 우점하였다. 경상북도 의성읍에서 발견한 미선나무는 하천변에 위치하여, 전석지 혹은 돌이 많은 곳으로, 하천을 따라 15개의 패치(patch)상으로 분포하고 있다. 자생지 크기는 $50m{\times}15m$로 약 $750m^2$이며, 교목과 아교목층은 굴참나무가 우점하고, 관목층은 산팽나무가 우세하였다. 기존의 보고 및 새롭게 밝혀진 개나리와 미선나무의 자생지를 대상으로 세계자연보전연맹 종보전위원회의 적색목록 평가기준의 하나인 분포역(EoO)를 적용하여 미선나무에 대한 분포역을 검토하였다. 검토한 결과 면적$21,513Km^2$로 산출하였다.

MgO-KH2PO4 몰비 변화에 따른 마그네시아-인산염 모르타르의 배합실험 (Tests on Magnesium Phosphate Composite Mortar Mixtures with Different Molar Ratios of MgO-to-KH2PO4)

  • 윤현섭;이경호;양근혁
    • 한국건축시공학회지
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    • 제17권3호
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    • pp.211-217
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    • 2017
  • 본 연구에서는 중성급 pH와 30 MPa 이상의 압축강도를 갖는 마그네시아-인산칼륨 복합체(Magnesia-potassium phosphate composites, MKPC) 모르타르의 배합설계를 위하여 마그네시아(MgO)와 인산칼륨($KH_2PO_4$)의 혼합 몰비($M_{mp}$)를 30.4에서 3.4로 변화하였다. MKPC 모르타르의 응결시간은 $M_{mp}$가 감소함에 따라 짧아졌다. 재령 28일 강도로 일반화된 강도 발현율은 $M_{mp}$가 7.9이하인 배합의 경우 재령 1일에서 50~61% 수준이었으며, 재령 3일에서는 60~73% 수준으로서 초기재령에서 빠른 강도발현성능을 나타냈다. MKPC의 수화생성물인 스트루바이트-K의 양은 $M_{mp}$가 감소할수록 증가하였는데, 이로 인해 거대공극 분포도 감소하였다. MKPC 모르타르의 목표로 했던 성능을 고려하면, $M_{mp}$의 값은 5.1 이하가 요구되었다.

Free Radical Scavenging Activity of Butanol Fraction from the Fruit of Citrus junos

  • Cho, Eun-Ju;Li, Li;Piao, Xiang-Lan;Lee, Sang-Hyun;Kim, Hyun-Young
    • Preventive Nutrition and Food Science
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    • 제14권1호
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    • pp.86-89
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    • 2009
  • In this study, we investigated the free radical [1,1-diphenyl-2-picrylhydrazyl (DPPH), hydroxyl radical (${\cdot}OH$) and superoxide anion (${O_2}^-$)] scavenging activity of MeOH extract and 3 fractions of Citrus junos. Of the tested fractions, the BuOH fraction showed the strongest DPPH scavenging activity, showing the $IC_{50}$ values of 63.4 mg/mL. Therefore, we continuously carried out DPPH, ${\cdot}OH$ and ${O_2}^-$ scavenging activity tests of BuOH fraction of Citrus junos. The BuOH fraction of Citrus junos inhibited DPPH radical to 97.5% at a concentration of 1000 mg/mL and the scavenging activities were increased concentration-dependently. In addition, BuOH fraction from Citrus junos also scavenged ${\cdot}OH$ in a concentration dependent manner from 5 to 1000 mg/mL. Furthermore, BuOH fraction showed about 56% ${O_2}^-$-scavengimg activity at 25 mg/mL concentration but, the scavenging activities were not enhanced in a dose dependent manner. The present results suggest that BuOH fraction of Citrus junos would have the protective potential from oxidative stress induced by free radicals.