• Journal of the Korean institute of surface engineering
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• v.54 no.2
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• pp.62-70
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• 2021

Al2024 aluminum alloy specimens were exposed to atmospheric conditions for maximum 24 months and analyzed by electron microscopes to characterize their corrosion behavior and oxide film characteristics. As the exposure time increased from 12 months to 24 months, the number of pitting sites per 1 mm² increased from ~100 to ~200. The uniform oxidation (or non-pitting) region of the 12-month exposure specimen showed 30~120 nm thick oxide layer, whereas the 24-month exposure specimen showed 170~200 nm thick oxide with the local oxygen penetration region up to 1 ㎛ deep. There was no local corrosion area observed in the 12-month exposure specimen except pitting. However, in the 24-month exposure specimen, local oxygen penetration region was observed beneath the uniform oxide layer and near the pitting cavity. Al2024 showed two times thicker uniform oxide layer but much shallower local oxygen penetration region than Al1050, which appears to be related to low Si concentration. Further research is needed on the effects of Mg segregation near the tip of the oxygen penetration region.

• Corrosion Science and Technology
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• v.19 no.6
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• pp.302-309
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• 2020

This study aimed to predict the pitting corrosion characteristics of AL-6XN super-austenitic steel using multiple linear regression. The variables used in the model are degree of sensitization, temperature, and pH. Experiments were designed and cyclic polarization curve tests were conducted accordingly. The data obtained from the cyclic polarization curve tests were used as training data for the multiple linear regression model. The significance of each factor in the response (critical pitting potential, repassivation potential) was analyzed. The multiple linear regression model was validated using experimental conditions that were not included in the training data. As a result, the degree of sensitization showed a greater effect than the other variables. Multiple linear regression showed poor performance for prediction of repassivation potential. On the other hand, the model showed a considerable degree of predictive performance for critical pitting potential. The coefficient of determination (R2) was 0.7745. The possibility for pitting potential prediction was confirmed using multiple linear regression.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.37-37
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• 2009

Due to their high corrosion resistance and improved mechanical properties super-duplex stainless steel (SDSS) are extensively used in petrochemical plants such as facilities in modern oil platform and off-shore process equipment. It is well known that the best mechanical and corrosion resistance properties of super-duplex stainless steel are obtained with a microstructure having approximately equal amounts of austenite and ferrite. And it is also known that sigma($\sigma$), chi($\chi$), secondary austenite(${\gamma}2$), chromium carbides and nitride affected adversely their properties. Therefore these phases must be avoided. However, effects of succeeding weld thermal cycle on the change of microstructure of weldment at multi-pass weld were not seldom experimentally researched. Therefore in the present work, the change of weldmetal microstructure and the effect of microstructure on pitting corrosion property at $40^{\circ}C$ by succeeding each weld thermal cycle were researched. The thermal history of root side was measured experimentally and the change of microstructure of root weld according to thermal cycle of each weld layer was evaluated. And the relationship between microstructure of root weld and pitting corrosion property at $40^{\circ}C$ was also investigated. Results of the present work are show as below. 1. The ferrite contents of root weld are gradually reduced by succeeding weld thermal cycle. 2. The 2nd phases such as sigma($\sigma$), chi($\chi$), secondary austenite(${\gamma}2$), chromium carbides and nitride are increased gradually by succeeding weld thermal cycle. 3. The pitting corrosion was detected in root weld part and weight loss by pitting corrosion is increased in proportional to the time exposed over $600^{\circ}C$ of the root weld. 4. The succeeding weld thermal cycles affect the microstructure of the former weldments and promote the formation of 2nd phases. That is, the more succeeding welds are added, the more 2nd phases are gradually increased. Consequently, it is thougth that this adversely affects pitting corrosion property.

• Corrosion Science and Technology
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• v.17 no.3
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• pp.129-137
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• 2018

The resistance to corrosion of additive manufactured (3D printing) Ti-6Al-4V alloys was investigated using micro-electrochemical tests. In terms of corrosion resistance, the acicular martensitic ${\alpha}^{\prime}$ phase in such additive manufactured Ti-6Al-4V was the focus of attention, and its behavior was distinct from that of conventional subtractive manufactured Ti-6Al-4V. To order to identify ${\alpha}^{\prime}$ phase, XRD tests were performed and micro Vickers hardness was measured for different grains (bright and dark grains) in the additive manufactured Ti-6Al-4V alloy. Micro-electrochemical tests were performed to measure corrosion resistance of bright and dark grains in the additive manufactured Ti-6Al-4V alloy with specially designed electrochemical micro-droplet cell. Critical pitting temperature (CPT) measurement was performed to evaluate the resistance to pitting corrosion of additive manufactured Ti-6Al-4V alloys with different volumes of ${\alpha}^{\prime}$ phase and subtractive manufactured Ti-6Al-4V alloy. The dark grains of the laminated Ti-6Al-4V alloy distributed broader than the bright grains measured with low microhardness. The dark grains of the Ti-6Al-4V alloy, which was rich in martensite ${\alpha}^{\prime}$, had lower general corrosion and pitting resistance than bright grains. As the fraction of martensite ${\alpha}^{\prime}$ phase increased, the resistance to the pitting corrosion decreased.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.6
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• pp.545-551
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• 2020

Cause analysis of surface pitting crack on a waterjet impeller was conducted. The waterjet impeller was made from stainless steel duplex 2205, which is more resistant to corrosion and local corrosion than typical stainless steel 316L and 317L, and has high mechanical strength, making it a useful material in various marine structures and seawater desalination facilities. The measurements were taken by scanning electron microscopy (SEM) and molecular ecological detection. The chemical composition of S was examined by SEM in the area of pitting corrosion. The dsrAB gene was detected on the sample of the pitting corrosion of the impeller through molecular ecological detection. Therefore, pitting corrosion on the surface of a waterjet impeller was caused by sulphite-reducing bacteria (SRB). To prevent the spread of SRB, management is required through high temperature treatments (over 65℃), pH management, or the insulation of a hull and waterjet.

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.1
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• pp.84-94
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• 2007

As a reactor coolant pump(RCP) is operated in the nuclear power system for a long time. so its surface is continuously contaminated by radioactive scales. In order to perform regular or emergency repair about RCP internals a special decontamination process should be used to reduce the radiation from the RCP surface by means of chemical cleaning. In this study, applicable possibility in chemical decontamination for RCP was investigated on the various materials. The STS 304 showed the best electrochemical properties for corrosion resistance than other materials. However, the pitting corrosion was slightly generated in both STS 415 and STS 431 with the increasing numbers of cycle and intergranular corrosion were sporadically observed. The size of their pitting corrosion and intergranular corrosion were also increased with increasing cycle numbers.

• Computers and Concrete
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• v.15 no.4
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• pp.643-671
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• 2015

Chloride induced reinforcement corrosion is widely accepted to be the most frequent mechanism causing premature degradation of reinforced concrete members, whose economic and social consequences are growing up continuously. Prevention of these phenomena has a great importance in structural design, and modern Codes and Standards impose prescriptions concerning design details and concrete mix proportion for structures exposed to different external aggressive conditions, grouped in environmental classes. This paper focuses on reinforced concrete column section load carrying capacity degradation over time due to chloride induced steel pitting corrosion. The structural element is considered to be exposed to marine environment and the effects of corrosion are described by the time degradation of the axial-bending interaction diagram. Because chlorides ingress and consequent pitting corrosion propagation are both time-dependent mechanisms, the study adopts a time-variant predictive approach to evaluate residual strength of corroded reinforced concrete columns at different lifetimes. Corrosion initiation and propagation process is modelled by taking into account all the parameters, such as external environmental conditions, concrete mix proportion, concrete cover and so on, which influence the time evolution of the corrosion phenomenon and its effects on the residual strength of reinforced concrete columns sections.

• Journal of the Korean Electrochemical Society
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• v.6 no.4
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• pp.271-281
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• 2003

The present article is concerned with pitting corrosion of Inconel alloy 600 at elevated solution temperatures. This article first summarized the previous works on the characteristics and the growth models of oxide film grown on alloy 600 at elevated solution temperatures. Thereafter, this article reviewed previous works on the morphological study on pitting corrosion of alloy 600 as functions of solution temperature and such anion additives as thiosulphate, sulphate, nitrate and bicarbonate ions in terms of pit morphology and its fractal dimension.

• Journal of the Korean Society for Heat Treatment
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• v.22 no.2
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• pp.67-74
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• 2009

440A martensitic stainless steels which were modified with reduced carbon content (${\sim}$0.5%) and addition of small amount of nickel, vanadium, tungsten and molybdenum were manufactured. Effects of alloying elements and heat treatment on the pitting corrosion in 3.5% NaCl were investigated through the electrochemical polarization tests. The lowest pitting potential, $E_p$, was obtained when austenitizing temperature was $1250^{\circ}C$ and this is because of the grain coarsening. When austenitized at $1050^{\circ}C$ and tempered at $350{\sim}750^{\circ}C$, the highest $E_p$ was obtained at $350^{\circ}C$, while the lowest at $450^{\circ}C$ and $550^{\circ}C$ regardless of alloying elements added. But $E_p$ was increased a little at the tempering temperature of $450^{\circ}C$ and $550^{\circ}C$ when 0.4 wt.% of tungsten was added. More pitting was observed at $450{\sim}550^{\circ}C$, and pitting was formed at regions where Cr concentration is low or grain boundaries are intersecting and showed irregular shape.

• Corrosion Science and Technology
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• v.18 no.2
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• pp.39-48
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• 2019

The feasibility of using benzotriazole (BTAH) to inhibit pitting corrosion in the sprinkler copper tubes was investigated by filling the tubes with BTAH-water solution in 829 households at an eight-year-old apartment complex. The water leakage rate was reduced by approximately 90% following BTAH treatment during 161 days from the previous year. The leakage of one of the two sprinkler copper tubes was investigated with optical microscopy, scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction analysis to determine the formation of Cu-BTA film inside the corrosion pits. All the inner components of the corrosion pits were coated with Cu-BTA films suggesting that BTAH molecules penetrated the corrosion products. The Cu-BTA film was about 2 nm in thickness at the bottom of a corrosion pit. A layer of CuCl and $Cu_2O$ phases lies under the Cu-BTA film. This complex structure effectively prevented the propagation of corrosion pits in the sprinkler copper tubes and reduced the water leakage.