• 한국세라믹학회지
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• 제28권11호
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• pp.908-916
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• 1991

The characteristics of the carbonized and calcined products made from coal tar pitch coke and coal tar pitch, were investigated in the aspect of the manufacture of isotropic graphite with high density. The mesophase from the pitch was rapidly formed at higher heat-treatment temperature between 410$^{\circ}C$ and 450$^{\circ}C$, where the insolubes in the pitch accelerated the rate of nucleation and growth of the mesophase. The benzene insolubles and the quinoline insolubes were increased as the heat treatment temperature and the heat-treatment time increased. The ratio of benzene insolubles and quinoline solubles (BI/QS) was decreased as the heat-treatment temperature was higher and maintained to be nearly constant regardless of heat-treatment time at fixed heat treatment temperature. The bulk density of the calcined carbon was linearly proportional to the ratio of quinoline solubes to volatile matter in the green coke. Anisotropic ratio of electrical resistance was measured to be between 0.98 and 1.10.

• KIEE International Transactions on Electrophysics and Applications
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• 제5C권5호
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• pp.204-210
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• 2005

Alternating current (AC) losses of two Bi-2223 ([Bi, Pb]: Sr: Ca: Cu: O = 2:2:2:3) tapes [(Tape I, un-twist-pitch) and the other with a twist-pitch of 10 mm (Tape II)] were measured and compared. These samples, produced by the powder-in-(Ag) tube (PIT) method, are multi-filamentary. Also, it's produced by non-twist and different twist pitch (8, 10, 13, 30, 50 and 70 mm). The critical current measurement was carried out under the environment in liquid Nitrogen and in zero-field by 4-probe method. Susceptibility measurements were conducted while cooling in a magnetic field. Flux loss measurements were conducted as a function of ramping rate, frequency and field direction. The AC flux loss increases as the twist-pitch of the tapes decreased, in agreement with the Norris Equation. Neutron-diffraction measurements have been carried out investigate the crystal structure, magnetic structures, and magnetic phase transitions in Bi-2223([Bi, Pb]:Sr:Ca:Cu:O)

• Composites Research
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• 제28권6호
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• pp.361-365
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• 2015

The influence of MWCNTs on fracture toughness properties of MWCNTs/Nickel-Pitch Fibers/epoxy composites (MWCNTs/Ni-PFs/epoxy) was investigated according to MWCNTs content. Nickel-Pitch-based carbon fibers (Ni-PFs) were prepared by electroless nickel-plating. The surface properties of Ni-PFs were determined by scanning electron microscopy (SEM) and X-ray photoelectron spectrometry (XPS). The fracture toughness of MWCNTs/Ni-PFs/epoxy was assessed by critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$). From the results, it was found that the fracture toughness properties of MWCNTs/Ni-PFs/epoxy were enhanced with increasing MWCNTs content, whereas the value decreased above 5 wt.%. MWCNTs content. This was probably considered that the MWCNTs entangled with each other in epoxy due to an excess of MWCNTs.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 추계학술대회 논문집
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• pp.303-304
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• 2007

A comparison study of carbon coating on $LiFePO_4$ was done with two different carbon sources-petroleum pitch and Ketjen black. Raman spectroscopy and transmission electron microscopy (TEM) analysis were applied to the carbon-coated $LiFePO_4$. $LiFePO_4$ which was carbon-coated with petroleum pitch showed more uniform carbon layer and ordered carbon structure. Such uniformity and ordered structure of carbon coating layer resulted in higher initial discharge capacity and better rate capability.

• 한국음향학회지
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• 제23권1호
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• pp.61-74
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• 2004

본 논문에서는 채널 환경에 강인한 화자 인식 시스템을 위하여 문맥과 화자에 종속적인 켑스트럼 추출 방법과 추출된 켑스트럼에서 화자 정보의 손실을 최소화하는 채널 정규화 방법을 제안하였다. 제안된 추출 방법은 화자의 고유한 피치를 이용한 피치 동기 분석 방법에 기반을 두어 켑스트럼을 추출한다. 따라서 일명 피치 동기 켑스트럼 (PSC)은 유성음 구간에서 성도의 임펄스 응답을 보다 정확하게 표현할 수 있다. 또한 피치는 채널 환경에서 스펙트럼에 비해 강인하므로 피치 동기 켑스트럼은 채널에 의한 스펙트럼의 왜곡을 보상할 수 있다. 제안된 채널 정규화방법인 포먼트 평활화 피치 동기 켑스트랄 평균 차감법 (FBPSCMS)은 포먼트 평활화 켑스트랄 평균 차감법을 PSC에 적용하여 프레임 내 처리의 정확도를 개선시킨다. 제안된 방법들의 화자 인식 성능을 비교하기 위해 남자 112명과 여자 56명에 대해 WMIT과 전화선 환경의 NTIMIT을 이용한 화자 식별을 수행하였다. 실험 결과 피치 동기 LPCC는 기존 단구간 켑스트럼과 비교하여 에러 감소율을 최대 7.7%까지 향상시켰고, FBPSCMS는 극점 필터링 CMS에 비해 보다 안정되고 낮은 에러율을 나타내었다.

• 음성과학
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• 제12권2호
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• pp.17-28
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• 2005

This paper argues that news speech entails a distinct intonational pattern from natural speech, effectively reflecting that it primarily focuses on providing new information. We conducted a phonetic experiment to compare the tonal contours between news speech and natural speech, examining the distributions of pitch accents and the overall pitch ranges. We utilized 70 American Press (AP) radio news utterances and 70 natural utterances extracted from TV dramas. Results show that news speech involves 3.38 H*'s (including L+H* and !H*) within an intonational phrase (IP) or intermediate phrase (ip) whereas natural speech, 1.8 in average. The number of IP/ip's per sentence is 3 in news speech, which is shown in the highest rate of 32.07% of the news speech, but it is merely 1, taking up the highest 41.42% in natural speech. Next, declination tends to be prevented in news speech, and the pitch range is much greater in news speech than in natural speech. Finally, a secondary stress syllable is comparatively frequently given a pitch accent in news speech, explicitly distinct from natural speech. These results can be interpreted as stating that news has the particular purpose of providing new information; every content word tends to be given a H* or its related pitch accent like L+H* or !H* because news speech assumes that every word conveys new information. This definitely brings about more IP/ip's per sentence due to a human physiological constraint; that is, more H*'s will cause more respiratory breaks. Also, greater pitch ranges and pitch accents imposed on secondary stress may be attributed to exaggerating new information.

• 전자공학회논문지
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• 제49권10호
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• pp.83-88
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• 2012

보코더에서의 피치 검색 과정은 매우 중요하다. 일반적으로 먼저 신호의 주기성을 강조한 후 피치를 검색하는 방법을 주로 사용한다. 프레임 내에서 두 개의 펄스 간격을 변화시켜 가며 신호와의 상관관계를 구하는 것으로 상관관계 값이 가장 높을때가 주기가 가장 두드러지는 반복 구간이므로 이때 의 펄스 간격을 피치 주기로 찾는다. 그러나 프레임 내에서의 신호의 진폭이 일정하지 않고 갑자기 변하는 구간이 있는 경우 정확하지 않는 피치가 얻어진다. 이를 해결하기 위해 프레임을 여러 개의 서브프레임으로 다시 나누어 피치를 검색하는 방법을 사용하고 있는데 이 방법은 피치를 정확하게 검색할 수 있지만 계산량이 많아진다. 본 논문에서는 프레임의 에너지 비율로 프레임 내의 진폭 변화율을 예측하여 서브프레임 수를 가변시키는 방법을 제안한다. 이 방법들을 적용하면 합성 음질에는 영향을 주지 않는 상태에서 피치검색 시간을 단축할 수 있고, 피치 검색의 정확도를 높일 수 있어 전반적인 피치 검색에 관한 성능 개선이 된다.

• 음성과학
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• 제10권2호
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• pp.111-128
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• 2003

Aerodynamic study is valuable information about the vocal efficiency in translating airflow to acoustic signal. The purpose of this study was to investigate the differences between trained singers and untrained controls under different two pitch by simultaneous using the airway interruption method and electroglottography (EGG). Under singing a Korean lied 'Gene', 20 (Male 10, Female 10) trained singers were studied on two one-octave different tone. Mean flow rate (MFR) , subglottic pressure (Psub) and intensity were measured with aerodynamic test using the Phonatory function analyzer (Nagashima Ltd. Model PS 77H, Tokyo, Japan). Closed quotients (Qx), jitter and shimmer were also investigated by electroglottography using Lx speech studio (Laryngograph Ltd, London, UK). These data were compared with those of normal controls. MFR and Psub were increased on high pitch tone in all subject groups. Statistically significant increasing of Qx and intensity were observed in male trained singers on high pitch tone (Qx;p = .025, intensity;p < .001). Beacasue of increasing of Qx and intensity, vocal efficiency was also significantly increased in male singers (p < .001). The trained singers' phonation was more efficient than untrained singers. The result means that the trained singers can increase the loudness with little changing of mean flow rate, subglottic pressure but more increasing of glottic closed quotients.

• Journal of the Korean Wood Science and Technology
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• 제15권2호
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• pp.53-66
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• 1987

Korean red pine (Pinus densiflora S. et. Z.) and pitch pine(Pinus rigida Mill) $5{\times}10cm$ dimension lumber were dried in a kiln providing a cross-circulation velocity of 5 m/sec at dry-and wet-bulb temperatures of 116 and $71^{\circ}C$, followed by 3 hours at 91 and $85^{\circ}C$. Compared to dimension lumber dried lumber were as follows. 1. To dry to 10 percent moisture content, the high-temperatures schedule of Korean red pine and pitch pine lumber took less than one seventh the time required by the conventional kiln drying schedule. 2. High-temperature drying rate and conventional drying rate to 10 percent moisture content of Korean red pine lumber were 2.75 and 0.35%/hr, and those of pitch pine lumber were 3.38 and 0.46%/hr respectively. 3. Compared to lumber of both species on conventional schedule, moisture gradient of high-temperature lumber was greater. 4. Compared to lumber on conventional schedule, maximum surface checking of high-temperature lumber of both species was severer, and maximum end checking of high-temperature lumber of both species was similar to that of lumber on conventional schedule. 5. Compard to lumber on conventional schedule, Korean red pine lumber dried at high temperature showed more honeycombing, but pitch pine lumber dried at high-temperature showed significantly slighter honeycombing. 6. Compared to lumber on conventional schedule, the high-temperature lumber showed less warping lumber of both species. 7. Collapse and casehardening of Korean red pine and pitch pine lumber on both scheules were slight.

• Korean Chemical Engineering Research
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• 제57권5호
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• pp.672-678
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• 2019

리튬이차전지용 음극재로서 피치로 코팅된 천연흑연의 전기화학적 특성이 조사되었다. 천연흑연과 피치의 혼합물을 $1000^{\circ}C$에서 소성하여 음극재를 제조하였다. 다양한 연화점의 피치가 탄소전구체로 사용되었다. 제조된 음극재의 물리적 특성은 TGA, SEM, PSA 및 BET로 분석하였다. 피치의 연화점이 증가할수록 코팅 층의 두께가 증가하였고, 비표면적이 감소하였다. 초기 충 방전 효율, 사이클, 순환전압전류, 속도 특성 및 임피던스 테스트를 통해 전기화학적 성능을 조사하였다. 연화점 $250^{\circ}C$의 피치로 탄소 코팅된 천연흑연은 초기 방전용량 361 mAh/g과 쿨롱 효율 92.6%을 보였다. 또한 출력 특성(5 C/0.2 C)은 코팅되지 않은 천연흑연에 비해 1.6배 향상되었으며, 0.5 C로 진행된 사이클 테스트에서 50 사이클 후 90%의 용량 유지율을 나타내었다.