• Title/Summary/Keyword: Physicochemical parameter

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Potential Detection and Quality Properties of ${\gamma}-Irradiated$ Corn Starch of Korean and Chinese Origins by Viscosity Measurement during Storage (저장 기간 중 감마선 조사 옥수수 전분의 검지를 위한 점도 측정법의 적용과 품질특성)

  • Choi, Mal-Gum;Kwon, Joong-Ho;Kim, Hyun-Ku
    • Korean Journal of Food Science and Technology
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    • v.35 no.2
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    • pp.173-181
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    • 2003
  • Physicochemical changes in corn starch caused by irradiation were investigated, and irradiated samples were identified. Viscosity, TBA value, Hunter color, and total viable count were measured after irradiation of corn starch. Corn starches from Korea and China were irradiated at 0, 2.5, 5, 7.5, 10, and 15 kGy using a $Co^{60}$ irradiator and stored for 9 months at $0^{\circ}C$ and $20^{\circ}C$. Viscosity and specific parameter values decreased in all samples with increasing irradiation dosage at 50 rpm, showing a dose-dependent relationship $(above\;R^2=0.80)$ between non-irradiated and irradiated samples during storage. These results suggest that detection of irradiated corn starches is possible using viscometric method during storage. Total viable count, TBA value, and Hunter color were determined as supplemental indices for measuring viscosities of samples. Total viable count and TBA values showed dose-dependent relationship $(2.5{\sim}15 kGy)$. Differences in viscosity and total viable count, and TBA values among non-irradiated samples showed little changes with the lapse of post-irradiation time, but were still distinguishable for more than 6 months at $0^{\circ}C$ and $20^{\circ}C$ for corn starches from korea and China.

Quality Characteristics of White Bread with Arrowroot Powder (칡 분말을 첨가한 식빵의 품질 특성)

  • Han, Gyusang;Hwang, Seong-Yun;Rho, Sujung
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.6
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    • pp.778-788
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    • 2013
  • The objective of this study was to investigate the effects and availability of arrowroot powder in making white bread. The characteristics of pasting, farinogram and alveogram of the dough containing arrowroot powder were analyzed. Further, the physicochemical properties of white bread were analyzed by different mixing ratios (0, 3, 5 and 7%) of arrowroot powder during storage periods. When 7% of arrowroot powder was added, the initial pasting temperature of the dough by using a RVA (rapid visco analyzer) was significantly increased. Peak viscosity, holding strength, break down, final viscosity and set back were decreased by increasing added arrowroot powder. With the increasing amounts of arrowroot powder, the values of farinogram and alveogram parameter for the dough showed a tendency to decrement. The texture profile analysis of the white bread revealed that hardness, springiness, cohesiveness and gumminess were increased by adding arrowroot powder and further, the storage time was longer. By increasing the amount of added arrowroot powder, the L value of the white bread was decreased, whereas the a, b value were increased. In the sensory evaluation, the white bread of the control and that of the added 3% arrowroot powder showed the highest preference in total score.

The effect of physicochemical factors on the coagulation process (응집에 영향을 미치는 물리-화학 인자)

  • Kim, Sung-Goo;Ryu, Jae-Ick;Ryou, Dong-Choon;Kim, Jeong-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.11 no.1
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    • pp.81-87
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    • 1997
  • Coagulation is very important process in water works. The subsequent processes are directly affected by this process. Many factors such as turbidity, alkalinity, pH, hardness, total organic carbon(TOC), velocity gradient and flocculation time effect on coagulation process. Among these factors, specially TOC is being concerned target substance to be removed due to trihalomenthanes(THMs) precursor and alkalinity is being one of the major parameter for removing TOC. We have researched the consumption of coagulant with TOC alkalinity concentration of water and removal efficiency of residual TOC and turbidity with alkalinity. Furthermore we have investigated particle size distributions with velocity gradient and alkalinity. The consumption of coagulant was proportionally increased to TOC and alkalinity concentration and the removal of TOC in Nakdong river water was very difficult more than 150 mg/l in alkalinity but large morecular weight organic such as humic acid could be removed easily. Coagulation of low alkalinity water was more rapidly occured than of high alkalinity water by analyzing the particle size distributions. High alkalinity water needed higher mixing energy for a good coagulation within limited flocculation time.

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Characterization of composted chicken manures discharged from farms in South Korea

  • Nguyen, Xuan Phuc;Jho, Hoon;Jeong, Yeon-Jae;Jo, Young-Tae;Islam, Mohammad Nazrul;Park, Jeong-Hun
    • Environmental Engineering Research
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    • v.20 no.3
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    • pp.254-259
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    • 2015
  • In this study, the characteristics as well as the maturity and stability of chicken manure collected from nine chicken farms in South Korea during the summer and winter seasons of 2014 are evaluated. The physicochemical parameter values of the manure, such as BOD, $NO_3-N$ and $PO_4-P$ etc. were determined using the Korea Standard test Method, HPLC, and APHA standard methods. The results showed that the alkalinity content and COD concentration in winter chicken manure were higher than those of summer chicken manure. The moisture content of summer manure was positively correlated with almost all of the other parameters of the manure, whereas it was negatively correlated with almost all of the other parameters in the winter manure. According to the criterion of C/N ratio, chicken manure indicated good quality compost. However, composted chicken manure showed immature and unstable compost when considering the criteria of the $NH_4-N/NO_3-N$ ratio and $NH_4-N$ concentrations.

Development of new agrochemicals by qnantitative structure-activity relationship (QSAR) methodology. II. The linear free energy relationship (LFER) and descriptors (정량적인 구조-활성상관(QSAR) 기법에 의한 새로운 농약의 개발 II. 자유에너지 직선관계(LFER)와 설명인자들)

  • Sung, Nack-Do
    • The Korean Journal of Pesticide Science
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    • v.6 no.4
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    • pp.231-243
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    • 2002
  • Starting with linear free energy relationships (LFER), drug design to mimic of the activated complexes at transition state, and hydrolysis mechanisms to control the potency and residual properties of pesticides were introduced and summarized for the necessity. In order to understand the searching or development of new agrochemicals by two dimensional quantitative structure-activity relationship (2D QSAR) methodology, a series of the various descriptors, steric constants, electronic constants including quantum pharmacological parameters and hydrophobic constants were classified and discussed for results of the several studied cases. In addition, the processes of development of new agrochemicals by QSAR techniques were introduced simply.

Effect of Polyethylene Glycol on Physicochemical Property in Dispersing Film Formulation (분산형 필름제형의 물리적 특징에 미치는 폴리에틸렌글리콜의 영향)

  • Cho, Young Ho;Lee, Jong-Hwa;Lee, Gye Won
    • KSBB Journal
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    • v.31 no.4
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    • pp.291-299
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    • 2016
  • In this study, Indomethacin, the poorly water soluble drug, was selected and prepared dispersing oral disintegrating films according to the molecular weight of polyethylene glycol (PEG) which are sort of dispersing agents. Also the molecular weight and content of PEG were evaluated effect on the degree of dispersion, physical property and dissolution when making oral dispersing film containing indomethacin to find appropriate condition and suggested guidelines of making oral dispersing film. The appropriate dispersing ratio of the amount of surfactants and dispersing agent were 1% and 4%, also the stability dropped in the PEG molecular weight of 4000 or more. Drying time of oral dispersing film was $90^{\circ}C$ for 10 minutes to 12 minutes that dispersing film's property about flexibility, detachability were very good. The oral dispersion film's content used PEG 400 was $98.6{\pm}0.5%$ and the most uniform. As the molecular weight of PEG increased, dissolution time also increased. On the basis of evaluation parameter, PEG with 400~600 of molecular weight was selected as good dispersing agent in oral dispersing film. Therefore, it can be suggested guideline of preparation application study in oral dispersing film.

Physico-Chemical Characterization of the Layered Double Hydroxide as Pillar Host Material (Pillar Host Material로써 Layered(Mg/Al) Double Hydroxide의 물리화학적 특성화)

  • 형경우;이용석
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.443-450
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    • 1998
  • Layered double hydroxides(LDHs) [{{{{ {Mg }_{1-x } }}{{{{ {Al }_{x } }}({{{{ {OH}_{2 } }})]ζ+({{{{ {CO }`_{3 } ^{2- } ){ }_{x/2 } }}$.${{{{ { yH}_{2 }O }} wioth variation of layer charge densitywere synthesized by co-precipitation methdo since their charge densities have a very important role to be det-ermined the physicochemical properties of layered materials. The XRD IR and thermal studies of them were discussed and the kinetic study for the decarbonation reaction was also carried out. From the results of XRD analysis we found that the lattice parameter and the unit cell volume were linearly decreased with the amount of Al substituents(x) in the vicinity of x=2∼10${\times}$1/3${\times}$10-1 but they had nearly constant values when the x are far from these vicinit. The activation energies for the decarbonation reaction of x=6.8, 10${\times}$1/3${\times}${{{{ { 10}^{-1 } }} were estimated to be 47.0, 37.6, 39.3 kcal/mol The specific surface areas(90-120 m2/g) of stable hy-drotalcite-type LDHs were dractically decreased with increasing of layer charge density.

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CoMFA vs. Topomer CoMFA, which One is better a Case Study with 5-Lipoxygenase Inhibitors

  • Gadhe, Changdev G.
    • Journal of Integrative Natural Science
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    • v.4 no.2
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    • pp.91-98
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    • 2011
  • Quantitative structure-activity relationships (QSAR) have been applied for two decades in the development of relationships between physicochemical properties of chemical substances and their biological activities to obtain a reliable statistical model for prediction of the activities of new chemical entities. The fundamental principle underlying the QSAR is that the structural difference is responsible for the variations in biological activities of the compounds. In this work, we developed 3D-QSAR model for a series of 5-Lipoxygenase inhibitors, utilizing comparative molecular field analysis (CoMFA) and Topomer CoMFA methodologies. Our developed models addressed superiority of Topomer CoMFA over CoMFA. The CoMFA model was obtained with $q^2$=0.593, $r^2$=0.939, $Q^2$=0.334 with 6 optimum number of components (ONC). Higher statistical results were obtained with the Topomer CoMFA model ($q^2$=0.819, $r^2$=0.947, ONC=5). Further robustness of developed models was checked with the ANOVA test and it shows F=113 for CoMFA and F=162.4 for Topomer CoMFA model. Contour map analysis indicated that the more requirement of electrostatic parameter for improved potency.

Studies for the osmotic parameter of liposomes

  • Yu, Byung-Sul;Seo, Weon-Gyo;Jeon, Young-Ho
    • Archives of Pharmacal Research
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    • v.10 no.2
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    • pp.94-99
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    • 1987
  • By using the former equation (8), we modified the equation which can show the dissimilar osmotic behavior of liposome with composition change. The slope of the new equation was presented as the ratio of osmotically active volume (V$_{act}$= ) to the total volume (V$_{totel}$= $_{acl}$+ V$_{dead}$ ; V$_{dead}$ is osmotically inactive volume) of loposomes, we defined is as a Z-value, which can elucidate the dissimilarity of the osmotic activity of multilamellar liposomes with the change of phospholipid composition and the differences of physicochemical properties of liposomes. Z-value was applied for studying the physico-chemical properties of liposomal membrane. The factor that affects on the Z-value was not the lipid concentration of liposome stock dispersion but the lipid composition of liposomal membrane. As the content of dicetylphosphate, the negative charged phospholipid, was increased, the osmotic activity, represented by Z-value, of multilamellar liposome was decreased. Using the hypertonic conditions (shrinking region), Z-value steadily increased and reached a maximum at 10 mole percent cholesterol with increasing the cholesterol content.

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A Study on Adhesive Properties of Cellulose Triacetate Film by Argon Low Temperature Plasma Treatment (아르곤 저온 플라즈마 처리에 의한 CTA 필름의 접착성 연구)

  • Koo Kang;Park Young Mi
    • Textile Coloration and Finishing
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    • v.16 no.5
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    • pp.28-34
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    • 2004
  • The polarizing film application exploits the unique physicochemical properties between PVA(Poly vinyl alcohol) film and CTA(Cellulose triacetate) film. However, hardly any research was aimed at improving the adhesion characteristics of the CTA film by radio frequency(RF) plasma treatment at argon(Ar) gaseous state. In this report, we deal with surface treatment technology for protective CTA film developed specifically for high adhesion applications. After Ar plasma, surface of the films is analyzed by atomic force microscopy(AFM), roughness parameter and peel strength. Furthermore, the wetting properties of the CTA film were studied by contact angle analysis. Results obtained for CTA films treated with a glow discharge showed that this technique is sensitive to newly created physical functions. The roughness and peel strength value increased with an increase in treatment time for initial treatment, but showed decreasing trend for continuous treatment time. The result of contact angle measurement refer that the hydrophilicity of surface was increased. AFM studies indicated that no considerable change of surface morphology occurred up to 3 minutes of treatment time, but a considerable uneven of surface structure resulted from treating time after 5 minutes.