• Title/Summary/Keyword: Physico-mechanical

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Controlled Release Behavior of Bioactive Molecules from Photo-Reactive Hyaluronic Acid-Alginate Scaffolds

  • Nam, Hye-Sung;An, Jeong-Ho;Chung, Dong-June;Kim, Ji-Heung;Chung, Chong-Pyoung
    • Macromolecular Research
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    • v.14 no.5
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    • pp.530-538
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    • 2006
  • There are three important components in tissue engineering: the cells, signaling factors (cytokines and growth factors), and scaffolds. To obtain finely engineered tissue, all three components should perform their individual functions and be fully integrated with each other. For the past few years, we have studied the characteristics of photodimerizable HA (CHA)/alginate (CA) composite materials. CHA/CA complex hydrogels, which were irradiated under UV light and, then treated with calcium ions, were found to have good biocompatibility, mechanical properties and water resistance for implantable tissue scaffolds. In this study, we introduced a cell growth factor (basic fibroblast growth factor; bFGF) into the CHA/CA scaffolds and studied its release behavior. We also introduced tetracycline hydrochloride and flurbiprofen into the same scaffolds as model activation factors and evaluated their release behaviors from the scaffolds. The drug release rate from the materials was influenced by various parameters, such as the degree of crosslinking, the cross linker type, the physico-chemical properties of the drug, and the amount of the drug in the polymer. The results indicated that the negatively charged CHA/CA composite materials showed sustained release behavior and that HA has a particularly strong negative charge, making it attractive toward tetracycline hydrochloride and bFGF, but repulsive toward flurbiprofen.

Eire-induced Damage to Shield TBM Concrete Segment (터널 화재로 인한 콘크리트 세그먼트의 손상특성 규명)

  • Choi Soon-Wook;Chang Soo-Ho;Lee Gyu-Phil;Bae Gyu-Jin
    • Journal of the Korean Geotechnical Society
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    • v.21 no.5
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    • pp.171-177
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    • 2005
  • Fire in underground space may induce severe structural damage as well as heavy casualties. To protect underground structure and passengers from fire, it is very essential to characterize fire-induced damage on construction materials of underground structures. In this study, the high-temperature furnace was manufactured to evaluate fire-induced damage on underground structure materials. Especially, this study aimed at the evaluation of fire-induced damage on the shield TBM concrete segment. In the fire tests, furnace temperature was set to reach 1,200 degrees at five minutes after Ignition. The temperature of 1,200 degrees was kept during one hour, and the fire was extinguished after two hours elapsed. From the temperature measurement by thermocouples embedded in test specimens, the spatting was estimated to reach approximately 20 cm from the surface exposed to fire. After the fire tests, the alteration of physico-mechanical properties and microstructures of concrete segment was investigated from core specimens. The results showed that apart from spatting, the deterioration depth of the remaining concrete material amounted to approximately 10 cm from the spatting surface.

Thermo-oxidation behaviour of organic matrix composite materials at high temperatures

  • Cinquin, Jacques;Colin, Xavier;Fayolle, Bruno;Mille, Marion;Terekhina, Svetlana;Chocinski-Arnault, Laurence;Gigliotti, Marco;Grandidier, Jean-Claude;Lafarie-Frenot, Marie-Christine;Minervino, Matteo;Cluzel, Christophe;Daghia, Federica;Ladeveze, Pierre;Zhang, Fangzouh
    • Advances in aircraft and spacecraft science
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    • v.3 no.2
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    • pp.171-195
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    • 2016
  • The present paper is a review of the main activities carried out within the context of the COMPTINN' program, a joint research project founded by a FUI program (Fonds $Unifi{\acute{e}}s$ $Interminist{\acute{e}}riels$) in which four research teams focused on the thermo-oxidation behaviour of HTS-TACTIX carbon-epoxy composite at 'high' temperatures ($120^{\circ}C-180^{\circ}C$). The scientific aim of the COMPTINN' program was to better identify, with a multi-scale approach, the link between the physico-chemical mechanisms involved in thermo-oxidation phenomena, and to provide theoretical and numerical tools for predicting the mechanical behaviour of aged composite materials including damage onset and development.

Fabrication and Characterization of Silk/PVA Hydrogels by Sonication and Freezing-Thawing Technique (초음파와 동결/융해에 의한 실크/PVA 하이드로젤의 제조 및 특성 평가)

  • Lee, Ok Joo;Kim, Jung-Ho;Ju, Hyung Woo;Moon, Bo Mi;Park, Hyun Jung;Sheikh, Faheem A.;Park, Chan Hum
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.717-721
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    • 2013
  • Biomaterials like silk fibroin (SF) and poly(vinyl alcohol) (PVA) have received increasing attention in biomedical applications because of their attractive properties such as hydrophobicity and biocompatibility. In this study, efficient systems consisting of interpenetrating SF/PVA hydrogels were prepared as potential candidate for wound dressing applications. A simple approach consisting of sonication and a freezing-thawing technique was adopted to fabricate the hydrogels. Different blend ratios consisting of SF (100, 75, 50, 25 and 0%) with respect to the weight of PVA were prepared. The produced hydrogels were characterized for physico-chemical investigations using various states of techniques like; FE-SEM, TGA, FTIR and tensile strength. The addition of PVA to SF was proved to be beneficial in terms of reducing the pore size and swelling ratio of hydrogels. The mechanical property of SF had been increased by addition of PVA. These results show that SF/PVA hydrogels may serve as potential candidates for wound dressing application.

Effects of 3 different light-curing units on the physico-mechanical properties of bleach-shade resin composites

  • Azin Farzad;Shahin Kasraei;Sahebeh Haghi;Mahboubeh Masoumbeigi;Hassan Torabzadeh;Narges Panahandeh
    • Restorative Dentistry and Endodontics
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    • v.47 no.1
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    • pp.9.1-9.11
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    • 2022
  • Objectives: This study investigated the microhardness, flexural strength, and color stability of bleach-shade resin composites cured with 3 different light-curing units. Materials and Methods: In this in vitro experimental study, 270 samples were fabricated of bleach and A2 shades of 3 commercial resin composites (Point 4, G-aenial Anterior, and Estelite Sigma Quick). Samples (n = 5 for each trial) were cured with Bluephase N, Woodpecker LED.D, and Optilux 501 units and underwent Vickers microhardness and flexural strength tests. The samples were tested after 24 hours of storage in distilled water. Color was assessed using a spectrophotometer immediately after preparation and 24 hours after curing. Data were analyzed using 3-way analysis of variance and the Tukey test (p ≤ 0.001). Results: Samples cured with Optilux exhibited the highest and those cured with LED.D exhibited the lowest microhardness (p = 0.023). The bleach shade of Point 4 composite cured with Optilux displayed the highest flexural strength, while the same composite and shade cured with Sigma Quick exhibited the lowest (p ≤ 0.001). The color change after 24 hours was greatest for the bleach shade of G-aenial cured with Bluephase N and least for the A2 shade of Sigma Quick cured with Optilux (p ≤ 0.001). Conclusions: Light curing with polywave light-emitting diode (LED) yielded results between or statistically similar to those of quartz-tungsten-halogen and monowave LED in the microhardness and flexural strength of both A2 and bleach shades of resin composites. However, the brands of light-curing devices showed significant differences in color stability.

Effect of Fine Sand and Briquette Ash Dressing on Diluvial Clayey Soils (Hwadong Series) (홍적태지(洪積台地)의 식질답(埴質畓)(화동통(華東統))에 대(對)한 세사(細砂) 및 연탄(煉炭)재의 객토효과(客土效果))

  • Jung, Youn-Tae;No, Young-Pal;Park, Eun-Ho;Park, Chang-Young;Seong, Jae-Duk
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.2
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    • pp.90-95
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    • 1984
  • To improve the physico-mechanical characteristics of heavy clayey paddy soils(Hwadong series) on Diluvial terrace after application of fine sand and briquette ashes, barley and rice were cultivated for 2 years. The influences of sand and briquette ashes on soil properties and on the crops were summarized as follows: 1. Application of the adding materials could not affect the yield of rice but barley yields were increased significantly about 18-19% in the plots of sand 100t/10a(clay 15% adjusted) and in the plots of briquette ashes. 2. The porosity and the content of water stable aggregates were decreased in the plots of sand and briquette ash adding. The chemical properties were slightly decreased in the plots of sands while the contents of av. $SiO_2$: and extr K were increased in the plots of briquette ashes. 3. Soil mechanical properties such as cone penetration resistance, shearing resistance and plastic index etc. were decreased while the friction resistance increased in the plots of sand and briquette ash treatments. Consequently, the adaptability to mechanization was increased. 4. The content of rice roots in subsoils (10-20cm) were increased in the plots of sand and briquette ash treatments.

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Studies on Change of Physico-chemical Properties due to Ripening degrees in the Reclaimed Tidle Deposits I. With reference to Munpo and Pori series (간척지토양(干拓地土壤)의 숙성화정도별(熟成化程度別) 이화학성(理化學性) 변화연구(變化硏究) I. 문포(文浦) 및 포이통(浦里統)에 관(關)하여)

  • Yoo, Chul-Hyun;Cho, Guk-Hyun;Choi, Jeong-Weon;Park, Keon-Ho;Kim, Yeong-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.3
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    • pp.180-190
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    • 1989
  • In order to obtain basic information on soil inprovement and management of two reclaimed paddy soils, Munpo and Pori series, this study was carried out by investigating the change of physico-chemical and soil mechanical properties. 1. In the Munpo series, the contents of salt in the soil and ground water before paddy rice transplanting at 6 years after reclamation were 0.60 and 1.84%, respectively, and the safty cultivation of paddy rice was possible after 20 years, while that of the Pori series was after 12 years. 2. In the Munpo series, the change of the soil particle size according to the ages after reclamation showed negative correlation with sandy contents, but clay contents had positive correlation both in the surface and subsurface soils. The pori series showed reverse tendency. 3. Between the N-value and Atterberg limits and the ages showed negative correlation in both Munpo and Pori series, but clay-activity showed positive. Arid the cole values showed positive correlation in the Munpo series, but negative in the Pori series. 4. Cone penetrating resistance in the surface of the Munpo series after 6 years of reclamation was 62.9, after 20 years 24.5 and $16.7kg/cm^2$ in 15cm of soil depth at depth of 22.5cm after 27 years. In the Pori series, it was $3kg/cm^2$ at 15-20cm of soil depth after 12 years and it used after being creation of hard pan layer after 23 years. 5. Change of the clay minerals by the different year after accomplishment of tidal reclamation did not show. The major clay minerals were illite and kaolinite, and accessory clay minerals were montmorillonite and vermiculite in both Munpo and Pori series.

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Changes of Physico-Chemical Properties of Tidal soils on Their Mafurities -II. Gwanghwal and Poseung Series (간척지(干拓地) 토양(土壤)의 숙성화(熟成化) 정도별(程度別) 이화학성(理化學性) 변화(變化) 연구 -II. 광활(廣活) 및 포승통(浦升統)에 관(關)하여)

  • Yoo, Chul-Hyun;Kim, Jong-Gu;Lee, Jong-Sik;Kang, Jong-Gook;So, Jae-Don;Park, Keon-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.4
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    • pp.259-267
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    • 1990
  • This study was carried out by investigating the changes of physico-chemical and mechanical properties of Gwanghwal and Poseung series in order to obtain basic information on the soil improvement and management. 1. In Gwanghwal series, the content of salt in soil and ground water before rice transplanting at the 21st year after reclamation were 0.29 and 1.02 percent respectively, and the safty cultivation of paddy rice was possible after 33 years of reclamation in both soil series. 2. Clay contents. atterberg limits and clay activity according to the age of reclaimation showed negative correlation. but sand content and N-value were positive in them. 3. Cone index was lower than $3kg/cm^2$ for the first 5 years after reclaimation in both soil series, and the formation of hard pan were 33rd and 49th year after reclamation in Gwanghwal and Poseung series respectively, and its thickness was more in Poseung than in Gwanghwal series. 4. Shearing resistance decreased with the age of reclaimation in both soil series. and friction resistance increased in Gwanghwal than Poseung siries. 4. Shearig resistance decreased with the age of reclaimation in both soil series, and friction resistance increased in Gwanghwal than Poseung series. 5. Soil pH. available, $SiO_2$, $Mg^2$, $K^+$, $Na^+$ and C. E. C showed negative correlation. with the year cultivated paddy rice. but O. M. ava ilable $P_2O_5Ca^{2+}$ and T-N had positive one in both soil series. Contents of O. M and $Ca^{2+}$ and T-N had positive one in both soil series. Contents of O. M and $Ca^{2+}$ were high in Gwanghwal, but C. E. C. was in Poseung series.

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Fisheries Resources in Garolim Bay (가로림만 어업자원에 관하여)

  • HUR Sung Bum;KIM Jong Man;YOO Jae Myung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.17 no.1
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    • pp.68-80
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    • 1984
  • Garolim Bay is not only important fishing ground but also expected area for the tidal power plant. The construction and operation of tidal power plant will make change the ecosystem of this bay. Therefore, the actual fisheries stocks should be precisely understood for the effect estimation and overall utilization of the bay after the construction of the tidal power plant. During the study period from January through December in 1981, forty-six adult fishes species, 3 species of fish egg and 25 fishes larvae species have occurred in the bay. Considering the result on monthly distribution of eggs and larvae, the inner area of the bay seems to be important as nursing ground of larvae spawned at the outside bay in winter, e. g., Ammodytes personatus, and Enedrias sp. This inner bay is also major spawning ground for many species spawning in spring and summer, e. g., Gobiidae, Konosirus punctatus, Engraulis japonica, etc. Taking into consideration the annual mean production for three years($1978{\sim}1980$), there are two major fishing seasons. The one is in May-June for Enedrias larvae stock, and the another in October-November for big eyed herring stock. For the mariculture stocks, short necked clam, oyster and laver are important species. After construction of the tidal power plant, the migratory species, i. e., larvae of Enedrias and Ammodytes personatus, Mugil cephalus, Konosirus punctatus, etc. will be directly damaged by the interuption of migration route. On the otter hand, the change of physico-chemical factors of seawater will also affect the ecosystem of the bay. Consequently, for the overall utilization of the bay after construction, the actual ecosystem including the fisheries stocks, must bs precisely revealed, and the mechanical designs, e. g., sluice position and its demension, should be also considered with these biological characters of the bay.

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Physico-mechanical Properties and Optimum Manufacturing Conditions of Bi-Sn Metal Alloy Impregnated Wood Composites (Bi-Sn 용융합금주입 목재복합체의 최적제조조건 및 물리·기계적 특성)

  • Park, Kye-Shin;Lee, Hwa-Hyoung;Kang, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.6
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    • pp.691-699
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    • 2014
  • In order to improve the dimensional stability and durability of wood, this study attempted to impregnate bismuth (Bi) - tin (Sn) alloy metal with low melting temperature into solid woods of three species such as radiata pine, red oak and white oak, and investigated to determine an optimum condition of manufacturing the metal alloy-wood composites with natural wood grains. These Bi-Sn alloys were chosen for this study because they were harmless to human and melting at low temperatures. The composites resulted in high dimensional stability and low thickness swelling, and also showed much improved performance such as high bending strength, high hardness, high electric conductivity, and high thermal conductivity as floor materials. A proper impregnating condition of all specimens was determined as 10 minutes of the preliminary vacuum time, and $185^{\circ}C$ of the heating temperature. The proper processing condition for radiata pine wood was 2.5 minutes of the pressuring time at the pressure of $10kgf/cm^2$. For red oak wood, 10 minutes of the pressuring time at the pressure of $30kgf/cm^2$ were the proper condition. The proper manufacture conditions for white oak wood was determined as 10 minutes of the pressuring time at the pressure of $50kgf/cm^2$.