• Title/Summary/Keyword: Physico/chemical processes

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Physico-chemical Properties of leaf tobacco by expansion processes. (잎담배의 팽화방법에 따른 팽화율 및 내용성분 특성)

  • 김병구;김기환;정한주;이경구;이태호
    • Journal of the Korean Society of Tobacco Science
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    • v.18 no.1
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    • pp.76-84
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    • 1996
  • Flue-cured tobaccos(cv. NC82, grade AB3O-1) expanded by super steam, volatile organic solvents(tricuorofluoromethane, propane), carbon dioxide, nitrogen, and by freeze-drying were examined for their physico-chemical properties. The expanding rate by using the organic solvents or carbon dioxide at the impregnated pressure was 70% or more, whereas the rate by super steam and freeze-drying was 49.4 and 42.9%, respectively. The contents of total sugar, alkaloid and ether extracts of the expanded tobacco by organic solvents or carbondioxide were decreased to 27.6, 20% or more, and 13%, respectively, when compared to non-expanded one. The contents of citric acid of the tobacco expanded by using trichlorofluoromethane and carbon dioxide were increased to 19.1, 14.0%, respectively. Linoleic acid in the tobacco expanded by super steam or trichlorofluoromethane was also increased to 17.3%, but malonic acid in the tobacco expanded by super steam was 18.5% less than that in the non-expanded one. Nineteen essential oil among 22 assayed in this experiment were decreased in the expanded tobaccos. Key words : expanding method, tobacco, physico-chemical properties.

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Microbial Metal Transformations

  • Gadd, Geoffrey M.
    • Journal of Microbiology
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    • v.39 no.2
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    • pp.83-88
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    • 2001
  • There is considerable interest in how microbiological processes can affect the behaviour of metal contaminants in natural and engineered environments and their potential for bioremediation. The extent to which microorganisms can affect metal contaminants is dependent on the identity and chemical form of the metal and the physical and chemical nature of the contaminated site or substance. In general terms, microbial processes which solubilize metals increase their bioavailability and potential toxicity, whereas those that immobilize them reduce bioavailability. The balance between mobilization and immobilization varies depending on the metal, the organisms, their environment and physico-chemical conditions.

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유기물 분리용 투과증발막

  • 박현채
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.03a
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    • pp.69-90
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    • 1996
  • In the chemical industry, in the pharmaceutical industry, and in a number of other industries separation processes are necessary to separate and purify products and raw materials [1,2]. Separation processes are also widely used in other applications such as in recycling valuable materials from waste streams. Unit operations for separation processes can be classified in phase separation techniques and component separation techniques based on the nature of the feed mixtures to be separated. The former techniques are used for the separation of heterogeneous mixtures, in which the feed is already present in two or more separated phases on a micro-scale. The latter are suitable for the separation of homogeneous mixtures such as gaseous mixtures and mixtures of completely miscible liquids. tn these cases the separation into individual components is generally achieved by utilizing the differences in physico-chemical properties of components, and is much more difficult compared to phase separation techniques. Separation processes such as distillation, evaporation, liquid-liquid extraction, and crystallization belong to this class.

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Effect of Earthworms on Collembola Abundance in Temperate Forest Soil Ecosystem (온대 숲 토양 생태계에서 지렁이가 톡토기류 개체수에 미치는 영향)

  • Lee, Ju-Hyung;Park, Ji-Hyun;Yoo, Ji-Yeon;Han, Su-Hyun;Nam, Bo-Eun;Kim, Jae-Geun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.13 no.6
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    • pp.97-106
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    • 2010
  • Earthworm, a prominent ecosystem engineer within many terrestrial ecosystems, can exert profound influences on various abiotic/biotic environments through bioturbation processes such as burrowing, casting and mixing of litter and soil. In this study, we investigated how the presence or absence of earthworm (Oligochaeta) can alter the soil physico-chemical conditions and ultimately the distribution and abundance of Collembola which constitutes a large proportion of the soil fauna. During September 2010, soil organisms along with soil samples were collected from randomly installed 20 plots in Mt. Gwan-ak. We examined the differences in the abundance of Collembola among plot samples in respect to the presence/absence of earthworm and soil physico-chemical conditions (i.e., pH, $PO_4^{3-}$, $NO_3^{2-}$, organic matter (OM), electrical conductance and water content). Analysis of soil physico-chemical environment revealed a significantly higher organic matter content and electrical conductance in plots with earthworm compared to plots without earthworm. Abundance of Collembola were not only higher in plots with earthworm than in plots without earthworm, but were also positively correlated with availability of OM present in the environment. The results suggest that positive impacts of earthworm on the abundance of Collembola in this study may have been due to their ability to effectively modify soil physico-chemical conditions favored by Collembola. Such conspicuous influence of earthworm's activity on below-ground community suggests their potential significance in forest restoration or revegetation process.

Charge Transport and Electroluminescence in Insulating Polymers (절연층 폴리머의 전하 전송 및 EL 특성)

  • Choi, Yong-Sung;Ahn, Seong-Soo;Kim, Byung-Chul;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.91-97
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    • 2008
  • Polymers submitted to thermo/electrical stress suffer from ageing that can drastically affect their functional behaviour. Understanding the physico/chemical processes at play during ageing and defining transport regimes in which these mechanisms start to be critical is therefore a prime goal to prevent degradation and to develop new formulation or new materials with improved properties. It is thought that a way to define these critical regimes is to investigate under which conditions (in terms of stress parameters) light is generated in the material by electroluminescence (EL). This can happen through impact excitation/ionization involving hot carriers or upon bi-polar charge recombination (a definition that excludes light from partial discharges, which would sign an advanced stage in the degradation process). After a brief review of the EL phenomenology under DC, we introduce a numerical model of charge transport postulating a recombination controlled electroluminescence. The model output is critically evaluated with special emphasize on the comparison between simulated and experimental light emission. Finally, we comment some open questions and perspectives.

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A Study on Settling Properties of Cohesive Sediments in Shihwa Lake (시화호 점착성 퇴적물의 침강 특성에 관한 연구)

  • LEE YOUNG-JAE;LEE SANG-HWA;HWANG KYU-NAM;RYU HONG-RYUL
    • Journal of Ocean Engineering and Technology
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    • v.19 no.4 s.65
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    • pp.42-48
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    • 2005
  • The sediment of Shihwa Lake contains an abundant quantity of cohesive sediments. The transport processes of the cohesive sediments are complex and difficult to predict, quantitatively. The cohesive sediments are the primary reason for the pollution of the environment and water quality in the coastal region. In this study, a column test has been performed. In order to quantify the settling velocities of sediment from Shihwa Lake, an experiment was conducted using a specially designed 1.8m tall settling column. A series of settling tests and physico-chemical property tests on Shihwa Lake cohesive sediments has been conducted to investigate the correlation between settling properties and their physico-chemical properties, which are represented as grain size distribution, mineralogical composition, and percentage oj organic contents. Experimental results of physico-chemical property tests show that Shihwa Lake sediments are relatively large in average grain $size(74\mu m)$ contain very small organic $material(6\%)$, and are dominantly composed of Quarts, which has relatively low cohesion. Thus, Shihwa Lake sediments might be specified as those whose settling properties are more influenced by gravity than cohesion. It is concluded that the magnitude of settling velocities of muddy sediments can be quite different, regionally, and it implies that field or laboratory experiments for settling velocity measurement should be preceded over the numerical modeling of muddy sediment transport, in order to obtain the reliable prediction results for a given specific site.

The Pollution Potential of Animal Production Systems : Origin and Atmospheric Cycling of Their Pollutants (축산환경의 오염 잠재력 : 축산오염 물질의 발생과 대기환경계 순환)

  • 김기현;김동균;윤종만
    • Journal of Animal Environmental Science
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    • v.1 no.2
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    • pp.155-164
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    • 1995
  • Despite considerable progresses made in our understanding of environmental fate of pollutants stemming from animal production systems, relatively little is known about the processes and mechanisms regulating their dispersement (via emission) into and deposition from the earth's atmospheric system. Here we present and summarize up-to-date knowledge on this topic with a main emphasis on their origin, physico-chemical characteristics, and geochemical distribution behavior.

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Charge transport and electroluminescence in insulating polymers (절연물 폴리머의 전하이동과 전계발광)

  • Yun, Ju-Ho;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.351-352
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    • 2007
  • Polymers submitted to thermo/electrical stress suffer from ageing that can drastically affect their functional behaviour. Understanding the physico/chemical processes at play during ageing and defining transport regimes in which these mechanisms start to be critical is therefore a prime goal to prevent degradation and to develop new formulation or new materials with improved properties. It is thought that a way to define these critical regimes is to investigate under which conditions (in terms of stress parameters) light is generated in the material by electroluminescence (EL). This can happen through impact excitation/ionization involving hot carriers or upon bi-polar charge recombination (a definition that excludes light from partial discharges, which would sign an advanced stage in the degradation process). After a brief review of the EL phenomenology under DC, we introduce a numerical model of charge transport postulating a recombination controlled electroluminescence. The model output is critically evaluated with special emphasize on the comparison between simulated and experimental light emission. Finally, we comment some open questions and perspectives.

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Upgrading of Iron from Waste Copper Slag by A Physico-chemical Separation Process (Physico-chemical 분리 공정에 의한 폐동슬래그로부터 철의 품위향상)

  • Lee, Kwang-Seok;Jo, Seul-Ki;Shin, Doyun;Jeong, Soo-Bock;Lee, Jae-Chun;Kim, Byung-Su
    • Resources Recycling
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    • v.23 no.3
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    • pp.30-36
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    • 2014
  • A large amount of waste copper slag containing about 35 ~ 45% iron has been generated and discarded every year from pyrometallurgical processes for producing copper from copper concentrate. Thus, recovery of iron from the waste copper slag is of great interest for comprehensive use of mineral resource and reduction of environment problems. In this study, a physico-chemical separation process for upgrading iron from the waste copper slag discharged as an industrial waste has been developed. The process first crushes the waste copper slag below 1 mm (first crushing step), followed by carbon reduction at $1225^{\circ}C$ for 90 min (carbon reduction step). And then, resulting material is again crushed to $-104{\mu}m$ (second crushing step), followed by wet magnetic separation (wet magnetic separation step). Using the developed process, a magnetic product containing more than 66 wt.% iron was obtained from the magnetic separation under a magnetic field strength of 0.2 T for the waste copper slag treated by the reduction reaction. At the same conditions, the percentage recovery of iron was over 72%. The iron rich magnetic product obtained should be used as a iron resource for making pig iron.

A Study on the Reduction of Color in Dye Wastewaters by Physico-chemical Processes (물리, 화학적 처리방법에 의한 염색폐수의 색도제거에 관한 연구)

  • 이준석;김민호;김영규
    • Journal of Environmental Health Sciences
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    • v.19 no.3
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    • pp.29-35
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    • 1993
  • This study was performed to obtain optimal conditions for reduction of color in dye wastewaters using coagulation-sedimentation processes with redox reactions. The reduction of color as well as organic matters variation was observed after coagulation-sedimentation processes using FeSO$_4$ $\cdot$ 7H$_2$O and NaOCl. Coagulation-redox reaction was done with the dose of Coagulant and oxidant at various pH values. Redox reaction was done through jar-mixing and aeration. The results of study were as follows: 1. In the coagulation-sedimentation processes using FeSO$_4$ $\cdot$ 7H$_2$O, color reduction was heigher at pH 3. With variance of dosage of FeSO$_4$ $\cdot$ 7H$_2$O, color reduction was higher at 250 mg/l. When coagulation-sedimentation using FeSO$_4$ $\cdot$ 7H$_2$O 250 mg/l was added at pH 3, the reduction of color, COD$_{Mn}$, and COD$_{Cr}$ showed 47.6%, 21.3% and 22.1%, respectively. 2. When NaOCI was added at level of 100 ppm in raw wastewater at pH 3, the reduction of color, COD$_{Mn}$, and COD$_{Cr}$ showed 30.2%, 5.5% and 6.2%, respectively. 3. After coagulation-sedimentation processes by addition of FeSO$_4$ $\cdot$ 7H$_2$O, when NaOCl was added at level of 250 mg/l in supernant, color reduction was 47.8% in aeration and 37.5% in jar-mixing. 4. Color reduction by aeration was higher than that by jar-mixing.

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