• 제목/요약/키워드: Photovoltaics

검색결과 286건 처리시간 0.028초

Synthesis and Characterization of CZTS film deposited by Chemical Bath Deposition method

  • Arepalli, Vinaya Kumar;Kumar, Challa Kiran;Park, Nam-Kyu;Nang, Lam Van;Kim, Eui-Tae
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.99.1-99.1
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    • 2012
  • The thin-film photovoltaic absorbers (CdTe and $Cu(In,Ga)Se_2$) can achieve solar conversion efficiencies of up to 20% and are now commercially available, but the presence of toxic (Cd,Se) and expensive elemental components (In, Te) is a real issue as the demand for photovoltaics rapidly increases. To overcome these limitations, there has been substantial interest in developing viable alternative materials, such as $Cu_2ZnSnS_4$ (CZTS) is an emerging solar absorber that is structurally similar to CIGS, but contains only earth abundant, non-toxic elements and has a near optimal direct band gap energy of 1.4 - 1.6 eV and a large absorption coefficient of ~104 $cm^{-1}$. The CZTS absorber layers are grown and investigated by various fabrication methods, such as thermal evaporation, e-beam evaporation with a post sulfurization, sputtering, non-vacuum sol-gel, pulsed laser, spray-pyrolysis method and electrodeposition technique. In the present work, we report an alternative aqueous chemical approach based on chemical bath deposition (CBD) method for large area deposition of CZTS thin films. Samples produced by our method were analyzed by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, absorbance and photoluminescence. The results show that this inexpensive and relatively benign process produces thin films of CZTS exhibiting uniform composition, kesterite crystal structure, and some factors like triethanolamine, ammonia, temperature which strongly affect on the morphology of CZTS film.

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태양광발전시스템 성능 시뮬레이션을 통한 하수처리장 에너지자립율 산정 (Estimation of energy self-sufficiency in municipal wastewater treatment plant using simulated solar photovoltaic performance)

  • 안영섭;김성태;채규정;강지훈;양희정
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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    • pp.291-296
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    • 2011
  • This paper presents energy self-sufficiency simulated in municipal wastewater treatment plants (WWTPs) by adopting solar energy production systems that vary with installation conditions. Relative to the national average energy consumption in WWTPs, the employment of 100 kW photovoltaics (PVs) was simulated to achieve 2.75% of energy self-sufficiency. The simulated results suggested that the installation of PVs toward South or South west would produce the highest energy self-sufficiency in WWTPs. When super-hydrophilic coating was employed in the conventional PVs, 5% of additional solar energy production was achievable as compared to uncoated conventional PVs. When 100 kW of PVs were installed in a future test-bed site, Kihyeung Respida located in Yougin, Sourth Korea, the energy self-sufficiency by solar energy was simulated to be 1.77% (2010). The simulated energy self-sufficiency by azimuth(direction) will be useful reference for practitioners in designing the solar PV systems in the WWTPs.

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Flexible ITO/PEDOT:PSS Hybrid Transparent Conducting Electrode for Organic Photovoltaics

  • Lim, Kyounga;Jung, Sunghoon;Kang, Jae-Wook;Kim, Jong-Kuk;Kim, Do-Geun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.299-299
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    • 2013
  • Indium Tin Oxide (ITO) has widely been used as a transparent conductive oxide (TCE) for photovoltaic devices. Lately, flexibility of ITO becomes an issue as demand of flexible device increases. Several scientists have tried to substitute ITO to different materials such as conductive polymer, graphene, CNT, and metal nanowire because of ITO brittleness. Among the substitute materials, PEDOT:PSS has mostly paid attention because PEDOT:PSS has excellent flexibility and good conductivity. The conductivity of PEDOT:PSS increases up to 1000 S/cm with additives such as DMSO, EG, sorbitol, and so on. In our research group, we introduce a conductive polymer PEDOT:PSS as a buffer layer to improve not only flexibility but also conductivity. As PEDOT:PSS layer forms beneath ITO thin film (20 nm), sheet resistance decreases from $230{\Omega}$/${\Box}$ to $85{\Omega}$/${\Box}$ and crack initiation decreases from 4.5 mm to 3.5 mm as well. We have fabricated organic photovoltaic device and power conversion efficiencies using conventional ITO electrode and ITO/PEDOT:PSS hybrid electrode. The photovoltaic property such as power conversion efficiency for ITO/PEDOT:PSS hybrid electrode is comparable to the value obtained using conventional ITO electrode on glass substrate.

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SiGe Nanostructure Fabrication Using Selective Epitaxial Growth and Self-Assembled Nanotemplates

  • Park, Sang-Joon;Lee, Heung-Soon;Hwang, In-Chan;Son, Jong-Yeog;Kim, Hyung-Jun
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 춘계학술발표대회
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    • pp.24.2-24.2
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    • 2009
  • Nanostuctures such as nanodot and nanowire have been extensively studied as building blocks for nanoscale devices. However, the direct growth of the nanostuctures at the desired position is one of the most important requirements for realization of the practical devices with high integrity. Self-assembled nanotemplate is one of viable methods to produce highly-ordered nanostructures because it exhibits the highly ordered nanometer-sized pattern without resorting to lithography techniques. And selective epitaxial growth (SEG) can be a proper method for nanostructure fabrication because selective growth on the patterned openings obtained from nanotemplate can be a proper direction to achieve high level of control and reproducibility of nanostructucture fabrication. Especially, SiGe has led to the development of semiconductor devices in which the band structure is varied by the composition and strain distribution, and nanostructures of SiGe has represented new class of devices such nanowire metal-oxide-semiconductor field-effect transistors and photovoltaics. So, in this study, various shaped SiGe nanostructures were selectively grown on Si substrate through ultrahigh vacuum chemical vapor deposition (UHV-CVD) of SiGe on the hexagonally arranged Si openings obtained using nanotemplates. We adopted two types of nanotemplates in this study; anodic aluminum oxide (AAO) and diblock copolymer of PS-b-PMMA. Well ordered and various shaped nanostructure of SiGe, nanodots and nanowire, were fabricated on Si openings by combining SEG of SiGe to self-assembled nanotemplates. Nanostructure fabrication method adopted in this study will open up the easy way to produce the integrated nanoelectronic device arrays using the well ordered nano-building blocks obtained from the combination of SEG and self-assembled nanotemplates.

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비정형 건물일체형 태양광 발전 시스템 규칙기반 BIM설계 지원 도구 개발 (Development of a Rule-based BIM Tool Supporting Free-form Building Integrated Photovoltaic Design)

  • 홍성문;김대성;김민철;김주형
    • 한국BIM학회 논문집
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    • 제5권4호
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    • pp.53-62
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    • 2015
  • Korea has been at the forefront of green growth initiatives. In 2008, the government declared the new vision toward 'low-carbon society and green growth'. The government subsidies and Feed-in Tariff (FIT) increased domestic usage of solar power by supplying photovoltaic housing and photovoltaic generation systems. Since 2000, solar power industry has been the world's fastest growing source with the annual growth rate of 52.5%. Especially, BIPV(Building Integrated Photovoltaic) systems are capturing a growing portion of the renewable energy market due to several reasons. BIPV consists of photovoltaic cells and modules integrated into the building envelope such as a roof or facades. By avoiding the cost of conventional materials, the incremental cost of photovoltaics is reduced and its life-cycle cost is improved. When it comes to atypical building, numerous problems occur because PV modules are flat, stationary, and have its orientation determined by building surface. However, previous studies mainly focused on improving installations of solar PV technologies on ground and rooftop photovoltaic array and developing prediction model to estimate the amount of produced electricity. Consequently, this paper discusses the problem during a planning and design stage of BIPV systems and suggests the method to select optimal design of the systems by applying the national strategy and economic policies. Furthermore, the paper aims to develop BIM tool based on the engineering knowledge from experts in order for non-specialists to design photovoltaic generation systems easily.

Coordinated Voltage Control Scheme for Multi-Terminal Low-Voltage DC Distribution System

  • Trinh, Phi Hai;Chung, Il-Yop;Kim, Taehoon;Kim, Juyong
    • Journal of Electrical Engineering and Technology
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    • 제13권4호
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    • pp.1459-1473
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    • 2018
  • This paper focuses on voltage control schemes for multi-terminal low-voltage direct current (LVDC) distribution systems. In a multi-terminal LVDC distribution system, there can be multiple AC/DC converters that connect the LVDC distribution system to the AC grids. This configuration can provide enhanced reliability, grid-supporting functionality, and higher efficiency. The main applications of multi-terminal LVDC distribution systems include flexible power exchange between multiple power grids and integration of distributed energy resources (DERs) using DC voltages such as photovoltaics (PVs) and battery energy storage systems (BESSs). In multi-terminal LVDC distribution systems, voltage regulation is one of the most important issues for maintaining the electric power balance between demand and supply and providing high power quality to end customers. This paper focuses on a voltage control method for multi-terminal LVDC distribution system that can efficiently coordinate multiple control units, such as AC/DC converters, PVs and BESSs. In this paper, a control hierarchy is defined for undervoltage (UV) and overvoltage (OV) problems in LVDC distribution systems based on the control priority between the control units. This paper also proposes methods to determine accurate control commands for AC/DC converters and DERs. By using the proposed method, we can effectively maintain the line voltages in multi-terminal LVDC distribution systems in the normal range. The performance of the proposed voltage control method is evaluated by case studies.

Cu(In,Ga)Se2 박막의 저온 성장 및 NaF 후속처리를 통한 태양전지 셀 특성 연구 (Low-temperature Growth of Cu(In,Ga)Se2 Thin Film and NaF Post Deposition Treatment for Cu(In,Ga)Se2 Solar Cells)

  • 김승태;정광선;윤재호;박병국;안병태
    • Current Photovoltaic Research
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    • 제3권1호
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    • pp.21-26
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    • 2015
  • High efficiency $Cu(In,Ga)Se_2$ solar cells are generally prepared above $500^{\circ}C$. Lowering the process temperature can allow wider selection of substrate material and process window. In this paper, the three-stage co-evaporation process widely used to grow CIGS thin film at high temperature was modified to reduce the maximum substrate temperature. Below $400^{\circ}C$ the CIGS films show poor crystal growth and lower solar cell performance, in spite of external Na doping by NaF. As a new approach, Cu source instead of Cu with Se in the second stage was applied on the $(In,Ga)_2Se_3$ precursor at $400^{\circ}C$ and achieved a better crystal growth. The distribution of Ga in the films produce by new method were investigated and solar cells were fabricated using these films.

복합식 태양광 발전 및 난방장치 개발 (Development of Hybrid Device for Photovoltaic Power Generation and Heating)

  • 이동일;백승욱
    • 대한기계학회논문집B
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    • 제38권11호
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    • pp.907-914
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    • 2014
  • 본 연구는 센서식 및 프로그램식의 태양추적장치를 이용하여 집광형 태양전지의 발전효율을 증가시키는 연구를 진행하였다. 또한 집광형 태양전지에서 발생된 열은 히트파이프를 포함한 흡열기로 회수함으로써 온수나 난방에 사용할 수 있었다. 실험 결과 집광형 태양전지의 평균 전기효율은 16%, 히트파이프를 포함한 흡열기의 열효율은 62% 로 복합효율이 78%를 나타내었다. 태양위치에 따른 실시간 추적, 일몰 이후 난방장치의 동쪽방향 원상복귀, 원상복귀후 자동종료는 Simulink 프로그램으로 구현하였다. 히트파이프 유무, 집광비, 흡열기 입구 속도에 따른 집광형 태양전지 및 흡열기 온도를 해석하였으며 실험결과와 일치하였다.

고출력 슁글드 태양광 모듈 제작을 위한 스트링 연결에 관한 연구 (Study on Shingled String Interconnection for High Power Solar Module)

  • 김주휘;김정훈;정채환;최원용;이재형
    • 한국전기전자재료학회논문지
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    • 제34권6호
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    • pp.449-453
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    • 2021
  • Interest and investment in renewable energy have increased worldwide, highlighting the need for renewable energy. Solar energy was the most promising energy of all renewable energy sources, and it has the highest investment value. Because photovoltaics require a certain amount of area for installation, high density and high output performance are required. Shingled module is a promising technology in that they are featured by higher density and higher output compared to the conventional modules. Shingled technology uses a laser scribing to divide solar cells that are to be bonded with electrically conductive adhesive (ECA) to produce and connect strings, which has a higher output in the same area than the conventional modules. In the process of producing solar modules, metal ribbons are used to interconnect cells, but they are also needed for string connections in shingled solar cells. Accordingly, in this study, we researched the interconnection that best suits the connector that joins the string to the string. The module outputs produced under the conditions of the string interconnection were compared and analyzed.

집광 조건에서의 GaInP/AlGaInP 이종접합 구조 태양전지 특성 연구 (Study on the Characteristics of GaInP/AlGaInP Heterojunction Photovoltaic Cells under Concentrated Illumination)

  • 김정환
    • 공업화학
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    • 제30권4호
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    • pp.504-508
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    • 2019
  • GaInP/AlGaInP 이종접합 구조를 제안하고 집광 조건에서 가장 높은 효율을 달성한 III-V 화합물 반도체 다중접합 태양전지의 맨 위 subcell에 주로 사용되는 GaInP 동종접합 구조를 대체해 이종접합 구조가 응용될 가능성에 대하여 조사하였다. $2^{\circ}$ off 된 웨이퍼와 $10^{\circ}$ off 된 서로 다른 off-cut 방향을 갖는 두 종류의 GaAs 기판 위에 성장된 태양전지의 특성을 집광 조건에서 측정하고 비교하였다. $10^{\circ}$ off 된 태양전지에서 더 높은 단락전류와 변환효율을 얻었다. 1 sun 조건에서 $10^{\circ}$ off 된 기판 위에 제작된 $2{\times}2mm^2$ 면적의 태양전지에서 $9.21mA/cm^2$의 단락전류밀도와 1.38 V의 개방 전압이 측정되었다. $10^{\circ}$ off 기판 위에 제작된 $5{\times}5mm^2$ 태양전지에서 집광도 증가에 따라 곡선인자(fiill factor)가 감소하여 변환효율은 6.03% (1 sun)에서 5.28% (20 sun)로 측정되었다.