• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.99.1-99.1
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• 2012

The thin-film photovoltaic absorbers (CdTe and $Cu(In,Ga)Se_2$) can achieve solar conversion efficiencies of up to 20% and are now commercially available, but the presence of toxic (Cd,Se) and expensive elemental components (In, Te) is a real issue as the demand for photovoltaics rapidly increases. To overcome these limitations, there has been substantial interest in developing viable alternative materials, such as $Cu_2ZnSnS_4$ (CZTS) is an emerging solar absorber that is structurally similar to CIGS, but contains only earth abundant, non-toxic elements and has a near optimal direct band gap energy of 1.4 - 1.6 eV and a large absorption coefficient of ~104 $cm^{-1}$. The CZTS absorber layers are grown and investigated by various fabrication methods, such as thermal evaporation, e-beam evaporation with a post sulfurization, sputtering, non-vacuum sol-gel, pulsed laser, spray-pyrolysis method and electrodeposition technique. In the present work, we report an alternative aqueous chemical approach based on chemical bath deposition (CBD) method for large area deposition of CZTS thin films. Samples produced by our method were analyzed by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, absorbance and photoluminescence. The results show that this inexpensive and relatively benign process produces thin films of CZTS exhibiting uniform composition, kesterite crystal structure, and some factors like triethanolamine, ammonia, temperature which strongly affect on the morphology of CZTS film.

• 한국정보통신학회:학술대회논문집
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• 한국정보통신학회 2017년도 춘계학술대회
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• pp.735-737
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• 2017

An Off grid or remote solar electric systems are an energy supply to our home or to our companies without the utility of Grid at all. Off grid solar systems are very important for those who live in remote locations especially for developing countries where getting the electric grid is extremely expensive, inconvenient or for those who doesn't need to pay a monthly bill with the electric bill in general. The main critical components of any solar power system or renewable energy harvesting systems are the energy storage systems and its charge controller system. Energy storage systems are the essential integral part of a solar energy harvesting system and in general for all renewable energy harvesting systems. To provide an optimal solution of both high power density and high energy density at the same time we have to use hybrid energy storage systems (HESS), that combine two or more energy storage technologies with complementary characteristics. In this present work, design and simulation we use two storage systems supercapacitor for high power density and lithium based battery for high energy density. Here the system incorporates fast-response supercapacitors to provide power to manage solar smoothing and uses a battery for load shifting. On this paper discuss that the total energy throughout of the battery is much reduced and the typical thermal stresses caused by high discharge rate responses are mitigated by integrating supercapacitors with the battery storage system. In addition of the above discussion the off grid solar electric energy harvesting presented in this research paper includes battery and supercapacitor management system, MPPT (maximum power point tracking) system and back/boost convertors. On this present work the entire model of off grid electric energy harvesting system and all other functional blocks of that system is implemented in MATLAB Simulink.

• KIEAE Journal
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• 제3권3호
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• pp.19-25
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• 2003

The Address No.0 of Eco-friendly Architecture offers unique experience for those who visit the place to envisage the future architecture where nature, human and building exist in harmony. It is open to the general public including the students of elementary and secondary schools. This house has been built to provide opportunities for the general public to experience eco-friendly architecture. It's floor area is 42 pyung($140m^2$) and the overall site has the area of 180 pyung($600m^2$). The following illustrates some of its prominent features : ${\bullet}$ Remodeling of a traditional Korean residence ${\bullet}$ Application of passive solar systems ${\bullet}$ Use of clerestory windows and daylighting systems(washroom and machine room) ${\bullet}$ Operation of solar water heaters with flat plate collectors ${\bullet}$ Construction of Biotop(small ecological world) ${\bullet}$ Water circulation for Biotop by photovoltaic(150W) and wind power(400W) generation ${\bullet}$ Outdoor hot water supplied by all-glass evacuated solar tubes. Through this Address No.0 of Eco-friendly Architeture conclusions are as followings. 1. The array of tubes in collector has the best nice in that the number of tube is nine and the tilt angle is the latitude $+20^{\circ}$. 2. The thermal performance of the all-glass solar vacuum collector was excellent than of the flate-plate solar collector. 3. The adaption of new small wind power systems to buildings were proved to produce a profit if it is considered the expense of environment improvement and the wind speed increasing according to rise of building hight.

• E2M - 전기 전자와 첨단 소재
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• 제8권5호
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• pp.619-625
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• 1995

Polycrystalline CdTe thin film has been studied for photovoltaic application due to the 1.45 eV band gap energy ideal for solar energy conversion and high absorption coefficient. The formation of low resistance contact to p-CdTe is difficult because of large work function(>5.5eV). Common methods for ohmic contact to p-CdTe are to form a p+ region under the contact by in-diffusion of contact material to reduce the barrier height and modify a p-CdTe surface layer using chemical treatment. In this study, the surface chemical treatment of p CdTe was carried out by H$\_$3/PO$\_$4/+HNO$\_$3/ or K$\_$2/Cr$\_$2/O$\_$7/+H$\_$2/SO$\_$4/ solution to provide a Te-rich surface. And various thin film contact materials such as Cu, Au, and Cu/Au were deposited by E-beam evaporation to form ohmic contact to p-CdTe. After the metallization, post annealing was performed by oven heat treatment at 150.deg. C or by RTA(Rapid Thermal Annealing) at 250-350.deg. C. Surface chemical treatments of p-CdTe thin film improved metal/p-CdTe interface properties and post heat treatment resulted in low contact resistivity to p-CdTe.Of the various contact metal, Cu/Au and Cu show low contact resistance after oven and RTA post-heat treatments, respectively.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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• pp.110-113
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• 1992

$n^{+}$-p homojunction InP diodes were fabricated using thermal diffusion of Sulfur into p-type InP substrates(Zn doped, LEC grown, p=2.3${\times}$10$^{16}$c $m^{-3}$). The Sulfur diffusion was carried out at 550$^{\circ}C$, 600$^{\circ}C$, 700$^{\circ}C$ for 4 hours in a sealed quartz ampule(～2ml in volume) containing 5mg I $n_2$ $S_3$ and Img of red phosphorus. The formed junction depth was below 0.5$\mu\textrm{m}$. After the removal of diffused layer on the rear surface of the wafer, the beak ohmic contacts to the p-side were made with a vacuum evaporation of An-Zn(2%) followed by an annealing at 450$^{\circ}C$ for 5 minutes in flowing Ar gas. The front contacts were made with a vacuum evaporation of Au-Ge(12%) followed by an annealing at 500$^{\circ}C$ for 3 minutes in flowing Ar gas. The remarkable sprctral response of the cells obtained at the region of 6000-8000${\AA}$ region. The open circuit voltage $V_{oc}$ , short circuit current density $J_{sc}$ , fill factor and conversion efficiency η of the fabricated pattern solar cells(diffusion condition : at 700$^{\circ}C$ for 4 hours) were 0.660V, 14.04㎃/$\textrm{cm}^2$, 0.6536 and 10.09%, respectively.y.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.124-124
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• 2010

Much interest has been focused on InGaN-based materials and their quantum structures due to their optoelectronics applications such as light emitting diode (LED) and photovoltaic devices, because of its high thermal conductivity, high optical efficiency, and direct wide band gap, in spite of their high density of threading dislocations. Build-in internal field-induced quantum-confined Stark effect in InGaN/GaN quantum well LED structures results in a spatial separation of electrons and holes, which leads to a reduction of radiative recombination rate. Therefore, many growth techniques have been developed by utilizing lateral over-growth mode or by inserting additional layers such as patterned layer and superlattices for reducing threading dislocations and internal fields. In this work, we investigated various characteristics of InGaN multiple quantum wells (MQWs) LED structures grown on selectively wet-etched porous (SWEP) GaN template layer and compared with those grown on non-porous GaN template layer over c-plane sapphire substrates. From the surface morphology measured by atomic force microscope, high resolution X-ray diffraction analysis, low temperature photoluminescence (PL) and PL excitation measurements, good structural and optical properties were observed on both LED structures. However, InGaN MQWs LED structures grown on SWEP GaN template layer show relatively low In composition, thin well width, and blue shift of PL spectra on MQW emission. These results were explained by rough surface of template layer, reduction of residual compressive stress, and less piezoelectric field on MQWs by utilizing SWEP GaN template layer. Better electrical properties were also observed for InGaN MQWs on SWEP GaN template layer, specially at reverse operating condition for I-V measurements.

• 한국진공학회지
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• 제21권4호
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• pp.205-211
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• 2012

인듐주석산화막/폴리에틸렌 테레프탈레이트(ITO/PET: indium tin oxide/polyethylene terephthalate) 유연 기판 위에 성장된 산화아연(ZnO) 나노로드(nanorods)를 이용하여 형성된 은(Ag) 입자의 광학적 특성 및 소수성 표면에 대해 조사하였다. 시료를 준비하기 위해 스퍼터링법(sputtering)으로 코팅된 산화아연 씨드층(seed layer)을 이용하여 전기화학증착법(electrochemical deposition)으로 산화아연 나노로드를 성장시킨 후, 열증발증착법(thermal evaporation)을 사용하여 은을 증착하였다. 산화아연 나노로드의 불연속적인 표면 특성 때문에 은이 증착되면서 나노크기를 갖는 입자로 형성되었다. 비교를 위해 같은 조건으로 은을 평평한 ITO/PET에 증착하여 시료를 준비하였으며, 증착되는 은의 양을 조절하기 위해 100초에서 600초까지 열증발증착시간을 변화시켰다. 은 증착시간이 증가할수록 산화아연 나노로드 표면에 형성되는 은 입자의 크기와 양이 증가하였으며, 또한 빛의 흡수율이 가시광 영역에서 크게 증가하는 것을 확인하였다. 이는 은 입자의 국소표면플라즈몬공명(localized surface plasmon resonance)에서 기인된 것으로 짐작한다. 또한 물방울 테스트실험에서 평평한 ITO/PET에 증착된 은에서의 접촉각(contact angle)보다 산화아연 나노로드에 증착된 은 입자에서의 접촉각이 크게 증가함을 보여, 개선된 소수성 표면을 가질 수 있음을 확인하였다. 이러한 광학적 특성과 소수성 표면 결과는 산화아연 나노로드의 기반의 염료감응형 태양전지 또는 자정효과(self-cleaning)를 갖는 표면구조로 유연소자에 유용하게 응용할 수 있을 것으로 기대된다.

• 에너지공학
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• 제25권2호
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• pp.94-100
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• 2016

에너지저장장치(ESS)는 전력수급 불균형 해소, 신재생에너지의 출력안정, 주파수 조정용 등 전력공급 안정성 향상 및 효율적 전기에너지사용 등에 기여하는 중요자원으로, 전세계적으로 '23년까지 '14년 설치용량의 약 30배가 증가한 55.9GWh의 보급이 전망되고 있다. 이와 같이 급증하는 세계시장에서 국내 ESS 업계의 경쟁력 확보를 위해서는 자국내 설치실적(Track Record) 확보가 필요한데, 우리나라는 주파수 조정용(FR용(用))과 그간 지속되어 왔던 전력수급 불균형 상황에 대비하기 위한 부하이동용 중심으로 ESS를 보급하여 왔다. 하지만, 주파수 조정용의 경우 통상적으로 화력발전소 정격용량의 약 5% 범위에서 설치효용이 발생하는 것으로 평가되고 있어, 화력발전이 비약적으로 증가하지 않는 한 국내 시장의 확장성이 부족하다고 할 수 있으며, 여유로운 예비력 확보정책에 따라 부하이동용에 대해서도 보급필요성이 저하되고 있는 바, 새로운 방식의 보급확대 대상이 필요하다고 할 수 있다. 유망한 신규보급대상은 간헐적 출력의 약점은 있으나, 신기후체제 대응과 산업육성을 위해 지속적으로 추진예정인 신재생에너지와의 연계설치를 통해 신재생에너지의 출력을 안정화 하고, 신재생에너지 발전량의 계통투입시기 조절을 통한 이산화탄소 저감효과를 기대할 수 있는 분야라고 할 수 있다. 본 연구에서는 향후 에너지정책의 최대 화두인 신기후체제 대응을 위한 온실가스 감축수단을 활용할 수 있도록, 태양광 연계형 ESS 충방전모드를 온실가스 저감효과를 고려토록 설계한 후, 투자유도를 위한 REC 가중치 산정방법에 대한 정책대안을 제시하였다.

• 한국태양에너지학회 논문집
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• 제34권2호
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• pp.32-43
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• 2014

This study set out to identify the importance of each factor influencing facility selection with a survey among public medical facilities under the category of public buildings and apply the importance of economy, technology and environment with the weighting factor method, thus proposing optimal application plans. The research content of each section can be summarized as follows:1) Estimated energy consumption according to the energy simulation was 65,129MWh/yr, which was 18.7% higher than that according to the calculation equation. Of the energy consumption, more than 80% was used by heating and cooling facilities and construction facilities, and 20% was used by electronics such as medical equipments and in and outdoor lighting. 2) The results of a survey on the factors influencing the importance when selecting a new and renewable energy system reveal that the upper items had a priority in economy, environment, and technology in the descending order and that the lower item shad a priority in initial investments, maintenance and repair costs=energy costs, supply reliability, energy efficiency and $CO_2$ emissions in the descending order. 3) The application alternatives were analyzed in economy, technology, and environment. As a result, a geothermal system turned out to be the most excellent one a cross all the upper and lower comparison items. Of the other systems, a solar thermal system was superior in initial investments, maintenance and repair costs, and energy efficiency, where as a photovoltaic system was superior in energy costs, supply reliability, and $CO_2$ emissions. 4) As for the mixed application ratio among economy, technology, and environment, when the percentage of a geothermal system was approximately 80% or higher in anew and renewable energy system, it was the best and most optimal application plan.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.213-213
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• 2012

It has been known that quantum confinement effect of CdSe nanocrystal was observed by increasing the number of deposition cycle using successive ionic layer adsorption and reaction (SILAR) method. Here, we report on thermally-induced quantum confinement effect of CdSe at the given cycle number using spin-coating technology. A cation precursor solution containing $0.3\;M\;Cd(NO_3)_2{\cdot}4H_2O$ is spun onto a $TiO_2$ nanoparticulate film, which is followed by spinning an anion precursor solution containing $0.3\;M\;Na_2\;SeSO_3$ to complete one cycle. The cycle is repeated up to 10 cycles, where the spin-coated $TiO_2$ film at each cycle is heated at temperature ranging from $100^{\circ}C$ to $250^{\circ}C$. The CdSe-sensitized $TiO_2$ nanostructured film is contacted with polysulfide redox electrolyte to construct photoelectrochemical solar cell. Photovoltaic performance is significantly dependent on the heat-treatment temperature. Incident photon-to-current conversion efficiency (IPCE) increases with increasing temperature, where the onset of the absorption increases from 600 nm for the $100^{\circ}C$- to 700 nm for the $150^{\circ}C$- and to 800 nm for the $200^{\circ}C$- and the $250^{\circ}C$-heat treatment. This is an indicative of quantum size effect. According to Tauc plot, the band gap energy decreases from 2.09 eV to 1.93 eV and to 1.76 eV as the temperature increases from $100^{\circ}C$ to $150^{\circ}C$ and to $200^{\circ}C$ (also $250^{\circ}C$), respectively. In addition, the size of CdSe increases gradually from 4.4 nm to 12.8 nm as the temperature increases from $100^{\circ}C$ to $250^{\circ}C$. From the differential thermogravimetric analysis, the increased size in CdSe by increasing the temperature at the same deposition condition is found to be attributed to the increase in energy for crystallization with $dH=240cal/^{\circ}C$. Due to the thermally induced quantum confinement effect, the conversion efficiency is substantially improved from 0.48% to 1.8% with increasing the heat-treatment temperature from $100^{\circ}C$ to $200^{\circ}C$.