• 한국태양에너지학회:학술대회논문집
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• 2009.11a
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• pp.98-103
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• 2009

In this paper, we test the electrical resistance of flat wire in the PV module. normally solar cell has two kind of flat wire(inter connection ribbon and bus bar ribbon). we found the phenomenon that has a unbalance with resistance when we make a wiling between of string. So, we measurement the resistance of flat wire each other. and analysis of missmatch with resistance between flat wires on PV module. next to survey of IR picture on missmatch flat wire samples for analyze of missmatch with current in the wire. and we perform IR test with solar cell that has a connection with flat wire for test the effect of missmatch resistance on solar cell. Finally we perform the Dark I-V test for survey of effect by the unbalance of resistance. By the result of Dark I-V test, the series resistance of existing connection sample is large more then innovated connection sample.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.36 no.2
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• pp.186-190
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• 2023

We studied the various characteristics of Sn-In (wt%) Pb-free solders for photovoltaic ribbon application. The solders near the eutectic composition of Sn₄₈In₅₂ (wt%) existed in InSn₄ and In₃Sn alloy phases, and in In crystal phase, but not in Sn crystal phase. In addition, the InSn₄ phase (γ-alloy) existed separately from the In₃Sn (β-alloy) and the In phase confirmed by an SEM-EDS-mapping. The melting temperature of the eutectic solder of Sn₄₈In₅₂ (wt%) was 119.2℃, and when the Sn content decreased in reference to the eutectic composition, it slightly increased to 121.4℃, but when the Sn content increased, it remained almost constant at 119.1℃. The peel strength of the ribbon plated with the Sn₄₂In₅₈ (wt%) solder was 38.7 N/mm², and it tended to increase when the Sn content increased. The peel strength of the eutectic Sn₄₈In₅₂ (wt%) solder was 53.6 N/mm², and that of the Sn₅₁In₄₉ (wt%) solder was 61.6 N/mm² that was the highest.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.1
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• pp.74-78
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• 2024

We have studied the effects of Ag on the characteristics of Sn₄₈In₅₂Ag_x (wt%) low-melting solders for photovoltaic ribbons. The Sn₄₈In₅₂ (wt%) solder coexisted in the InSn₄ and In₃Sn alloys. Ag atoms added in the solder formed an AgIn₂ alloy by reacting with some part of In atoms, while they did not react with Sn atoms. The addition of Ag atoms in the Sn₄₈In₅₂Ag_x (wt%) solders showed useful results; an increase in peel strength and a decrease in melting temperature. The peel strength of the ribbon plated with the Sn₄₈In₅₂ (wt%) solder was 53.6 N/mm², and that of the Sn₄₈In₅₂Ag₁ (wt%) solder largely increased to 125.1 N/mm². In the meanwhile, the melting temperature of the Sn₄₈In₅₂ (wt%) solder was 119.2℃, and that of the Sn₄₈In₅₂Ag₁ (wt%) solder decreased to 114.0℃.

• Current Photovoltaic Research
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• v.11 no.4
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• pp.114-117
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• 2023

Transparent Photovoltaic (PV) modules have recently been in the spotlight because they can be applied to buildings and vehicles. However, crystalline silicon (c-Si) solar modules, which account for about 90% of the PV module market, have the disadvantage of applying transparent PV modules due to their unique opacity. Recently, a see-through type PV module using a crystalline silicon solar strap has been developed. However, there is a problem due to a decrease in aesthetics due to the metal ribbon in the center of the see-through type PV module and difficulty bonding the metal ribbon due to the low voltage output of the strap. In this study, to solve this problem, we developed a fabrication process of series connected c-Si solar strap cells using the c-Si solar cells. We succeeded in fabricating a series connected strap with a width of 2-10 mm, and we plan to manufacture an aesthetic see-through type c-Si PV module.

• Resources Recycling
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• v.22 no.5
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• pp.50-55
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• 2013

The recovery of copper from spent photovoltaic ribbon was conducted using thermal treatment method at the range of temperature of $300^{\circ}C$ to $600^{\circ}C$ under inert atmosphere. The coating layer consisted of lead of 68.99 wt.% and tin of 31.21 wt.% was melted down at elevated temperatures and was collected on the bottom of crucible. The chemical composition of copper ribbon after thermal treatment was analyzed by ICP-MS (Inductively coupled plasma mass spectrometry) and the purity of copper was found to be obtained up to about 96 wt.% regardless of temperatures. The cross-sectional area of the specimen was also examined by SEM (scanning electron microscopy) and EDX (energy dispersive X-ray microscopy).

• Resources Recycling
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• v.29 no.2
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• pp.69-77
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• 2020

With rapid increasing production and installation, recycling of photovoltaic modules has become the main issue. According to the research, the accumulation of waste modules will reach to 8600 tons in 2030. Moreover, Crystalline-silicon (c-Si) Photovoltaic modules account for more than 90% of the waste. C-Si PV modules contain 1.3% of weight of photovoltaic ribbon inside which contains the most of lead, tin and copper in the PV modules, which would cause environmental and humility problem. This study provided a valuable metal separation process for PV ribbons. Ribbons content 82.1% of Cu, 8.9% of Sn, 5.2% of Pb, and 3.1% of Ag. All of them were leached by 3M of hydrochloric acid in the optimal condition. Ag was halogenated to AgCl and precipitated. Cu ion was extracted and separated from Pb and Sn by Lix984N then stripped by 3M H2SO4. The effect of the optimal parameters of extraction was also studied in this essay. The maximum extraction efficiency of Cu ion was 99.64%. The separation condition of Pb and Sn were obtained by adjusting the pH value to 4 thought ammonia to precipitate and separate Pb and Sn. The recovery of Pb and Sn can reach 99%.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.3
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• pp.365-370
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• 2013

Generally, photovoltaic modules consist of glass, EVA, Solar Cell, back sheet and ribbon. But EVA, solar cell, ribbon affect electric output with temperature. EVA is a change in the transmittance of light from the sun. In addition, the solar cell output is decreased with temperature and the ribbon increases resistance. Transmittance and reflectance of glass and EVA were measured. In this paper, the characteristics of the components of PV module as EVA and Glass, ribbon were studied by variable temperature. effects on material properties investigated. As a result, glass is independent in temperature variation. EVA was the reduction 1~4% in transmittance. Solar cell decrease 0.469[%/$^{\circ}C$] in electric output by temperature variation. Other factors was controlled in solar cell..

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.1057_1058
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• 2009

현재 양산중인 태양전지모듈의 효율은 일반적으로 태양전지보다 2~3% 낮은 상황이다. 이것은 태양전지모듈의 구성 부품 및 공정기술 등 여러가지 요인에 의한 것으로 태양전지 모듈의 고 효율화를 위해서는 이러한 요소에 대한 분석이 필요하다. 본 논문에서는 태양전지 모듈 구성 부품 중 PV-ribbon이 태양전지모듈에 적용되는 과정에서 발생하는 저항에 대한 분석을 통해 PV-ribbon의 저항이 모듈 효율에 미치는 영향을 실험을 통해 검토하고자 하였다.

• Current Photovoltaic Research
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• v.8 no.1
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• pp.12-16
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• 2020

This study investigates the degradation characteristics of different material types of ethyl vinyl acetate (EVA) and polyolefin (POE) with combining transparent backsheet. To this end, we fabricated samples with structure of glass/encapsulant/transparent backsheet for each type of encapsulants, and shingled Si modules with the same structure. The samples were then subjected to accelerated test by storing under damp heat condition of 85℃ and 85% RH. As a result, encaplsulant discoloration was observed, which the transmittance of the samples with EVA decreased in a rapid rate than the samples with POE. The discoloration also affected a power degradation of the shingled modules with a reduction of current density, resulting that the module with EVA showed more drop on the efficiency than the modules with POE. Furthermore, corrosion of the soldered ribbon caused by acetic acid produced from the degraded EVA also contributed in fill factor reduction.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.9-10
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• 2007

In this paper, we investigated the effect of solar cell breakage on maximum output power of PV module. The test result using artificial light source didn't give any change in output power in case of crack near electrical ribbon. Also, there was a reduction in output power in case of increasing of crack area far from electrical ribbon. But, this experiment is under artificial light source test method. So, when such a PV module is outdoor for a long time, there would be problems on electrical output power and durability because of thermal aging phenomenon of solar cell breakage.