• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.2897-2902
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• 2012

New photovoltaic donor materials, 4,4'-(2,2'-bithiazole-5,5'-diyl)bis(N,N-diphenylbenzenamine) (BDT) and 4-(2,2'-bithiazol-5-yl)-N,N-diphenylbenzenamine (BT), were synthesized. A solution processable triphenylamine-containing bithiazole (BDT and BT) was blended with a [6,6]-phenyl $C_{61}$ butyric acid methyl ester (PCBM) acceptor to study the performance of small-molecule-based bulk heterojunction (BHJ) photovoltaic devices. Optimum device performance was achieved after annealing, for device with a BDT/PCBM ratio of 1:4. The open-circuit voltage, short-circuit current, and power conversion efficiency of the device with the aforementioned BDT/PCBM ratio were 0.51 V, 4.10 $mA\;cm^{-2}$, and 0.68%, respectively, under simulated AM 1.5 solar irradiation (100 $mW\;cm^{-2}$).

• 전기학회논문지P
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• 제66권3호
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• pp.144-149
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• 2017

There is a little research on DC arc detection when compared to a large number of literature and patents on AC arc detection. However, as DC energy sources such as photovoltaic power generation facilities and fuel cells are introduced, research on DC arc has become as important as AC arc detection in terms of circuit protection and system reliability enhancement. In this paper, we have developed an arc detection method for photovoltaic system using frequency analysis. Through various experiments, it was confirmed that the proposed method effectively detects the arc.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.460-460
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• 2014

Organic photovoltaic cells (OPV) have been extensively studied due to their unique properties such as flexibility, light-weight, easy processability, cost-effectiveness, and being environmental friendly. These advantages make them an attractive candidate for application in various novel fields and promising development with new features. Photovoltaic cell-integrated textiles have greatly attractive features as a power source for the smart textile solutions, and OPV is most ideal form factor due to advantage of flexibility. In this study, we develop a textile-based OPV through various experimental methods and we suggest the direction for the design of the photovoltaic textile. We used a textile electrode and tried to various layouts for textile-based OPV. Finally, we determined the contact area by using Hertzian theory for the calculation of power conversion efficiency (PCE). Based on the results of calculation, the short circuit current density, Isc, was $13.11mA/cm^2$ under AM 1.5condition and the PCE was around 2.5%.

• Transactions on Electrical and Electronic Materials
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• 제6권3호
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• pp.115-118
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• 2005

Organic photovoltaic properties were studied in $CuPc/C_{60}$ and $ZnPc/C_{60}$ heterojunction structure by varying the organic layer thicknesses. Current density-voltage characteristics of organic photovoltaic cells were measured using Keithley 236 source-measure unit and a 500 W xenon lamp (ORIEL 66021) for a light source. From the analyses of current-voltage characteristics such as short-circuit current density, open-circuit voltage and power conversion efficiency, optimum thickness of the organic layer were obtained.

• 한국산학기술학회논문지
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• 제10권9호
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• pp.2221-2226
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• 2009

본 논문에서는 태양전지를 기본 전력공급원으로 사용하는 대형건물용 옥외간판 LED 표식장치를 시스템을 구현하였다. 부하 발전 배터리 용량을 산정하고, 상용 예비전력을 도입한 계통연계형 태양광발전시스템을 설계하였다. 표식장치인 LED 부하에 대한 사전 휘도 시뮬레이션 및 균일성 검사를 거친 후, 이를 태양광발전시스템과 함께 설치하였다. 태양전지-LED 표식장치 현장 시험운영을 통하여 시스템의 신뢰성과 성능 및 제반 문제점을 파악하였다.

• Bulletin of the Korean Chemical Society
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• 제32권2호
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• pp.559-565
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• 2011

The following noble series of statistical copolymers, poly[(2-(3-thienyl)ethanol n-butoxycarbonylmethylurethane)-co-3-hexylthiophene] (PURET-co-P3HT), were synthesized by the chemical dehydrogenation method using anhydrous $FeCl_3$. The structure and electro-optical properties of these copolymers were characterized using $^1H$-NMR, UV-visible spectroscopy, elemental analysis, GPC, DSC, TGA, photoluminescence (PL), and cyclic voltammetry (CV). The statistical copolymers, PURET-co-P3HT (1:0, 2:1, 1:1, 1:2, 1:3), were soluble in common organic solvents and easily spin coated onto indium-tin oxide (ITO) coated glass substrates. Hybrid bulk heterojunction photovoltaic cells with an ITO/G-PEDOT/PURET-co-P3HT:PCBM:Ag nanowires/$TiO_x$/Al configuration were fabricated, and the photovoltaic cells using PURET-co-P3HT (1:2) showed the best photovoltaic performance compared with those using PURET-co-P3HT (1:0, 2:1, 1:1, 1:3). The optimal hybrid bulk heterojunction photovoltaic cell exhibits a power conversion efficiency (PCE) of 1.58% ($V_{oc}$ = 0.82 V, $J_{sc}$ = 5.58, FF = 0.35) with PURET-co-P3HT (1:2) measured by using an AM 1.5 G irradiation (100 mW/$cm^2$) on an Oriel Xenon solar simulator (Oriel 300 W).

• 한국재료학회지
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• 제19권5호
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• pp.245-252
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• 2009

Changes in the surface morphology and light scattering of textured Al doped ZnO thin films on glass substrates prepared by rf magnetron sputtering were investigated. As-deposited ZnO:Al films show a high transmittance of above 80% in the visible range and a low electrical resistivity of $4.5{\times}10^{-4}{\Omega}{\cdot}cm$. The surface morphology of textured ZnO:Al films are closely dependent on the deposition parameters of heater temperature, working pressure, and etching time in the etching process. The optimized surface morphology with a crater shape is obtained at a heater temperature of $350^{\circ}C$, working pressure of 0.5 mtorr, and etching time of 45 seconds. The optical properties of light transmittance, haze, and angular distribution function (ADF) are significantly affected by the resulting surface morphologies of textured films. The film surfaces, having uniformly size-distributed craters, represent good light scattering properties of high haze and ADF values. Compared with commercial Asahi U ($SnO_2$:F) substrates, the suitability of textured ZnO:Al films as front electrode material for amorphous silicon thin film solar cells is also estimated with respect to electrical and optical properties.

• 한국정보통신학회:학술대회논문집
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• 한국정보통신학회 2015년도 추계학술대회
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• pp.484-487
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• 2015

본 논문에서는 진동에너지와 빛에너지를 이용한 MPPT 기능을 갖는 이중 입력 충전기 회로를 제안한다. 빛에너지는 photovoltaic cell로부터 수확하고, 진동에너지는 piezoelectric cell로부터 수확하여 각각 커패시터에 저장된다. Charger 블록에 의해 배터리 전압이 승압되며 이때 두 가지 에너지원이 모두 입력으로 사용되어 충전하게 된다. 승압하는 방법은 DC-DC boost converter를 사용하였으며 시간 구간에 따라 하나의 인덕터를 공유하는 방법을 적용하였고, 진동에너지와 빛에너지를 입력으로 사용하는 비율은 8:1로 설계하였다. 제안된 회로는 0.35um CMOS 공정으로 설계하였고 배터리 관리블록에 의해 배터리 커패시터의 충전 상태가 제어되며 최대 3V의 전압까지 충전할 수 있다. 설계된 회로의 최대 효율은 88.56%이며, 칩 면적은 패드를 포함하여 $1230um{\times}1330um$이다.

• Current Photovoltaic Research
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• 제4권1호
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• pp.12-15
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• 2016

Screen printing technique followed by firing has commonly been used as metallization for both laboratory and industrial based solar cells. In the solar cell industry, the firing process is usually conducted in a belt furnace and needs to be optimized for fabricating high efficiency solar cells. The printed-Al layer on the silicon is rapidly heated at over $800^{\circ}C$ which forms a layer of back surface field (BSF) between Si-Al interfaces. The BSF layer forms $p-p^+$ structure on the rear side of cells and lower rear surface recombination velocity (SRV). To have low SRV, deep $p^+$ layer and uniform junction formation are required. In this experiment, firing process was carried out by using conventional tube furnace with $N_2$ gas atmosphere to optimize $V_{oc}$ of laboratory cells. To measure the thickness of BSF layer, selective etching was conducted by using a solution composed of hydrogen fluoride, nitric acid and acetic acid. The $V_{oc}$ and pseudo efficiency were measured by Suns-$V_{oc}$ to compare cell properties with varied firing condition.

• Current Photovoltaic Research
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• 제6권2호
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• pp.43-48
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• 2018

The traditional silicon heterojunction solar cells consist of intrinsic amorphous silicon to prevent recombination of the silicon surface and doped amorphous silicon to transport the photo-generated electrons and holes to the electrode. Back contact solar cells with silicon heterojunction exhibit very high open-circuit voltages, but the complexity of the process due to form the emitter and base at the backside must be addressed. In order to solve this problem, the structure, manufacturing method, and new materials enabling the carrier selective contact (CSC) solar cell capable of achieving high efficiency without using a complicated structure have recently been actively developed. CSC solar cells minimize carrier recombination on metal contacts and effectively transfer charge. The CSC structure allows very low levels of recombination current (eg, Jo < 9fA/cm2), thereby achieves high open-circuit voltage and high efficiency. This paper summarizes the core technology of CSC solar cell, which has been spotlighted as the next generation technology, and is aiming to speed up the research and development in this field.