• Bulletin of the Korean Chemical Society
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• 제25권8호
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• pp.1253-1256
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• 2004

• Bulletin of the Korean Chemical Society
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• 제20권6호
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• pp.715-719
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• 1999

The incorporation of cobalt into mesoporous molecular sieves MCM-41 and MCM-48 was carried out. Co-PO/MCM41 and Co-PO/MCM48 were prepared using Co(II) acetate solution adjusted to pH = 3.0 with phosphoric acid by the incipient wetness method. Photoacoustic spectroscopy (PAS) was used to study the local environments of Co(II) incorporated into mesopores. The band around 500 nm in PAS of as-prepared Co-PO/MCM41 and Co-PO/MCM48 with Co(II) acetate solution was changed to triplet bands around 600 nm. This could be assigned to the 4 A2(F)-> 4T1(P) transition of Co(II) surrounded tetrahedrally by oxygen ions after calcination. It may be attributable to that the octahedral cobalt species containing phosphate ligands in coordination sphere reacting with framework's silanol groups to be dispersed atomically onto the surface of mesoporous molecular sieves as a tetrahedral species. This is unlike that the Co in Co-Cl/MCM41 and direct-synthesized Co-MCM41 transforms to Co oxide phase upon calcination. Co-PO/MCM41 and Co-PO/MCM48 were stable while treated with water.

• Bulletin of the Korean Chemical Society
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• 제20권3호
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• pp.291-296
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• 1999

The immobilization of APTMS(3-(2-aminoethylamino)propyltrimethoxysilane) and AAPTMS(3-(2-(2-aminoethyl)aminoethylanino)propyltrimethoxysilane) on the surface of high quality mesoporous molecular sieves MCM-41 and MCM-48 have been confirmed by F.T.-IR spectroscopy, Raman spectroscopy, 29Si solid state NMR, and a surface polarity measurement using Reichardt's dye. The formation of metal (Co(Ⅱ), Ni(Ⅱ), and Cu(Ⅱ)) complexes by immobilized aminosilanes have been investigated by photoacoustic spectroscopy(PAS). The assignment of UV-Vis. PAS bands makes it possible to identify the structure of metal complexes within mesoporous molecular sieves. Co(Ⅱ) ion may be coordinated mainly in a tetrahedral symmetry by two APTMS onto MCM-41, and in an octahedral one by two AAPTMS. Both Ni(Ⅱ) and Cu(Ⅱ) coordinated by aminosilanes within MCM-41 form possibly the octahedral complexes such as [Ni(APTMS)2(H20)2]2+, [Ni(AAPTMS)2]2+, [Cu(APTMS)2(H2O)2]2+, and [Cu(AAPTMS)(H2O)3]2+, respectively. The PAS band shapes of complexes onto MCM-48 are similar to those of corresponding MCM-41 with the variation of PAS intensity. Most of metal ion(Ⅱ) within MCM-41 and MCM-48 are coordinated by aminosilanes without the impregnation on the surface.

• 한국음향학회:학술대회논문집
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• 한국음향학회 1984년도 추계학술발표회 논문집
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• pp.27-32
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• 1984

When chopped light inpinges on some condenced matters such as HgS, HgI2 and GaSe semiconductors, in an enclosed cell, the acoustic signals are produced within the cell. These acoustic signals were detected by using a gas-phase microphone in order to investigate the physical properties of the samples. In order to carry out investigation, PA-cell was first designed and made so as to produce higher sensitivity to acoustic signals. Second, an analysis of the photoacoustic spectrum of the various compounds was carried out to obtain the intensity of the PA-signal in terms of light wavelength and to calculate the energy band gaps occuring according to energy transitions. The agreement between the results obtained by this conventional PAS technique and the results obtained by the optical spectrum method was good. In additional analysis conducted on the basis of the R-G theory and the Sze theory are capable of determining the characteristics of energy transition of semiconductors.

• 한국정보통신학회논문지
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• 제17권10호
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• pp.2431-2438
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• 2013

본 논문에서는 휴대용 유중가스 분석기에 대해 연구 및 개발 하였다. 제안된 휴대용 유중가스 분석기는 전력기기로부터 절연유 내의 소량의 가스를 추출하여 비정상적인 열적 정보를 얻어 분석하는데 유용하게 쓰인다. 분석된 정보로부터 전력기기의 안정성을 평가할 수 있다. 본 논문에서는 기존의 고가의 시설기반의 고정형 유중 가스 분석기를 사용함으로써 발생되는 직간접적인 문제점을 해결하기 위해서 광음향 분광법 기반의 소형화된 휴대용 유중가스 분석기를 제안하고 실험적으로 검토하였다. 제안된 휴대용 유중 가스 분석기는 사용하기 편하고 실시간으로 전력기기의 열적 정보를 분석할 수 있다. 제안된 휴대용 유중가스 분석기가 현재의 전력기기 유중가스 분석에 사용된다면, 전력기기의 유중가스 분석주기를 줄임으로써 안정성을 향상 시키고 열적 이상 정보에 대하여 긴밀하게 대응할 수 있다.

• Bulletin of the Korean Chemical Society
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• 제13권6호
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• pp.593-595
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• 1992

To improve the lifetime and output power in a sealed-off $CO_2$ laser, a series of Nd$_{1-x}$Sr$_x$CoO$_3$(x = 0.0, 0.25, 0.40, 0.50, 0.60, 0.75) perovskite-type compounds has been synthesized and used for a cathode material. Using a typical method samples were sintered at 1150$^{\circ}$C and their structures were determined as a cubic form by means of XRD analysis. The degrees of $CO_2$ dissociation were measured by PAS (photoacoustic spectroscopy) with the lapse of time. In the case of $Nd_{0.4}$Sr$_{0.6}$$CoO_3$, which showed the highest catalytic cathode effect, only 7% of the initial $CO_2$ concentration were dissociated at 30 torr of gas mixture and 5 mA of discharge current. The more the gas pressure decreased and the discharge current increased, the more the degree of dissociation occurred. The ability of catalytic cathode to regenerate CO$_2$ in the laser cavity lies in order for x, 0.60 > 0.50 > 0.40 > 0.75 > 0.25 ${\gg}$ 0.0. Except for the case of x = 0.0 the amounts of $CO_2$ dissociation were found to be within 7-15% of the initial $CO_2$ concentration.

• 한국기후변화학회지
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• 제8권3호
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• pp.231-237
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• 2017

In this study, the $N_2O$ emission factor of the facility was developed by measuring the kiln type pyrolysis melting facility. This used PAS (Photoacoustic Spectroscopy) method and measured the $N_2O$ emission concentration. From March 2016 to April 2016, it was measured over a total of two times and $N_2O$ concentrations were measured continuously for 24 hours using a 24 hour continuous measuring instrument (LSE-4405). The measured $N_2O$ emission concentration of the pyrolysis melting facility was 0.263 ppm on average and the emission concentration distribution in the range of 0.013~0.733 ppm was obtained. Therefore, the $N_2O$ emission factor of the kiln-type pyrolysis melting facility was estimated to be $0.829gN_2O/ton$-Waste. As a result of comparing the $N_2O$ emission factor of the thermal kiln type pyrolysis melting facility and the previous study, previous studies were about 18 times higher. It is estimated that this is due to the difference of furnace temperature, oxygen concentration and denitrification facilities. It is considered that the study of the emission factor of pyrolysis melting facility is an important factor in improving the credibility of greenhouse gas inventory in waste incineration sector.