• Title/Summary/Keyword: Phosphorus Removal

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The Photovoltaic Properties & Fabrication of $n^{+}$-p InP Homojunction Diodes ($n^{+}$-p InP 동종접합 다이오드의 제작과 광기전력 특성)

  • 최준영;문동찬;김선태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.05a
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    • pp.110-113
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    • 1992
  • $n^{+}$-p homojunction InP diodes were fabricated using thermal diffusion of Sulfur into p-type InP substrates(Zn doped, LEC grown, p=2.3${\times}$10$^{16}$c $m^{-3}$). The Sulfur diffusion was carried out at 550$^{\circ}C$, 600$^{\circ}C$, 700$^{\circ}C$ for 4 hours in a sealed quartz ampule(~2ml in volume) containing 5mg I $n_2$ $S_3$ and Img of red phosphorus. The formed junction depth was below 0.5$\mu\textrm{m}$. After the removal of diffused layer on the rear surface of the wafer, the beak ohmic contacts to the p-side were made with a vacuum evaporation of An-Zn(2%) followed by an annealing at 450$^{\circ}C$ for 5 minutes in flowing Ar gas. The front contacts were made with a vacuum evaporation of Au-Ge(12%) followed by an annealing at 500$^{\circ}C$ for 3 minutes in flowing Ar gas. The remarkable sprctral response of the cells obtained at the region of 6000-8000${\AA}$ region. The open circuit voltage $V_{oc}$ , short circuit current density $J_{sc}$ , fill factor and conversion efficiency η of the fabricated pattern solar cells(diffusion condition : at 700$^{\circ}C$ for 4 hours) were 0.660V, 14.04㎃/$\textrm{cm}^2$, 0.6536 and 10.09%, respectively.y.

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A Study of Sewage Treatment with a Self-Cleaning Filtration Unit (자기세정 여과 반응장치를 이용한 하수처리에 관한 연구)

  • Mo, Sung-Young;Lee, Pul-Eip;Kim, Bum-Su;Lee, Tae-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.309-316
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    • 2016
  • In this study, sewage was fed with up flow direction into a reactor equipped with a screw to circulate media that had lower specific gravity than water. It was observed that the media in the reactor could be circulated by a screw with reverse flow of the sewage feeding from the top to the bottom direction. Under these conditions, concentrations of inflow and outflow pollutants were measured at the filtration unit. Experimental results revealed stable circulation of the media with a screw in the reactor. Circulation of the media in the reactor showed more efficiency in removing the pollutants (particulate matters and organics) than no circulation. The maximum removal efficiencies of suspended solid (SS), chemical oxygen demand (CODmn), and total phosphorus (T-P) were 96%, 72% and 65%, respectively. Improvements for SS, CODmn and T-P removals with circulation of media were 52.38%, 43.14% and 118.12% respectively, compared to those without circulation.

The Estimating an Effect of Rapid Flux Increase to a Membrane in the Intermittent Aeration MBR Process Using Alum Treatment (응집제를 활용한 간헐포기 MBR공정에서 순간플럭스 증가가 분리막에 미치는 영향 평가)

  • Choi Song-Hyu;Cho Nam-un;Han Myong Su
    • Membrane Journal
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    • v.15 no.1
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    • pp.70-83
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    • 2005
  • By supplying air intermittently in various mode, the effects of oxic/anoxic time ratio and air scrubbing in aeration condition on the membrane flux and permeability were investigated. When suction pump stops, vacuum pressure remains inside the suction pump. Therefore, the effect of remaining vacuum pressure in the suction pump on fouling of membrane was investigated. The effect of EPS (Extra cellular Polymeric Substance) which is generated due to the long SRT and high concentration of MLSS and the dose of coagulant on the membrane were also investigated. The suitable oxic/anoxic time ratio for the best removal efficiency of organic matter and nitrogenous matter was 40 minutes (Oxic) : 20 minutes (Anoxic). At this time ratio, alum was dosed into the aeration tank. The result of dosing alum was that the concentration of alum solution might affect nitrification and denitrification. To remove 1 mg/L of phosphorus in MBR process, it needs 0.75 mg/L of alum solution.

Phytoremediation of the pesticides, endosulfan (${\alpha}$ and ${\beta}$) and fenitrothion, using aquatic plants (수생식물을 이용한 엔도설판(${\alpha},\;{\beta}$) 및 페니트로치온의 제거)

  • Kim, Jong-Hyang;Lee, Bang-Hee;Hur, Jong-Sou;Lee, Geun-Seon;Koh, Sung-Cheol
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.249-256
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    • 2010
  • A phytoremediation study has been conducted to see if some known aquatic plants can remove the pesticides, endosulfan-${\alpha},\;{\beta}$ and fenitrothion which are frequently used in the crop protection and golf course management, and are likely to exist as residual pollutants in the aquatic ecosystems. Among the five aquatic plants tested in the microcosms, water lily Nymphaea tetragona Georgi showed the highest degradation efficacies (85~95%) for the three pesticides as opposed to the control(13~26%). The efficacies for the other plants were in the range of 46~80% in the order of Pistia stratiotes, Cyperus helferi, Eichhornia crassipes, and Iris pseudoacorus. Fenitrothion, an organo-phosphorus pesticide, was much more vulnerable to the phytoremediation than the organo-chlorine pesticides, endosulfan-${\alpha}$ and endosulfan-${\beta}$. The kinetic rate constants ($min^{-1}$) for removal of the three pesticides were more than 10 times higher than the control (non-planting) in case of Nymphaea tetragona Georgi. This aquatic plant showed kinetic rate constants about 2 times as much as the lower kinetic rate constants shown by Iris pseudoacorus. The reason for the highest degradation efficacy of water lily would be that the plant can live in the sediment and possess roots and broad leaves which could absorb or accumulate and degrade more pollutants in association with microbes. These results indicate that some of the selected aquatic plants planted near the agricultural lands and wetlands could contribute to remediation of pesticides present in these places, and could be applicable to protection of the aquatic ecosystems.

Advanced Wastewater Treatment Process Using Aerobic Granular Sludge (AGS-SBR) (호기성 그래뉼 슬러지를 이용한 하수고도처리기술(AGS-SBR))

  • Choi, Han Na;Mo, Woo Jong
    • Journal of Korean Society on Water Environment
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    • v.37 no.1
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    • pp.47-54
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    • 2021
  • Aerobic granular sludge (AGS) can be classified as a type of self-immobilized microbial aggregates measuring more than 0.2 mm. It offers the option to simultaneously remove COD, N, and P that occur in different zones inside a granule. Also, AGS is characterized by high precipitability, treatability with high organic loading, and high tolerance to low temperature. In this study, a sequencing batch reactor inoculated with AGS (AGS-SBR) is a new advanced wastewater treatment process that was proven to grow AGS with integrated nutrient removal and low C/N ratio. A pilot plant, AGS-SBR with a capacity of 225 ㎥/d was installed at an S sewage treatment plant in Gyeonggi-do. The results of the operation showed that the water quality of the effluent indicated that the value of BOD5 was 1.5 mg/L, CODMn was 11.4 mg/L, SS was 6.2 mg/L, T-N was 13.2 mg/L, and T-P was 0.197 mg/L, and all of these values reliably satisfied an effluent standard (I Area). In winter, the T-N treatment efficiency at a lower temperature of less than 11℃ also showed reliability to meet the effluent standard of the I Area (20 mg/L or less). Analysis of microbial community in AGS showed a higher preponderance of beneficial microorganisms involved in denitrification and phosphorus accumulation compared with activated sludge. The power consumption and sludge disposal cost were reduced by 34.7% and 54.9%, respectively, compared to the domestic SBR type sewage treatment plant with a processing capacity of 1,000 ㎥/d or less.

A Study on Energy Usage Monitoring and Saving Method in the Sewage Treatment Plant (공공하수처리시설에서 에너지 사용현황 및 절감방안 연구)

  • Kim, Jongrack;Rhee, Gahee;You, Kwangtae;Kim, Dongyoun;Lee, Hosik
    • Journal of Korean Society on Water Environment
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    • v.36 no.6
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    • pp.535-545
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    • 2020
  • This study aims to conserve and monitor energy use in public sewage treatment plants by utilizing data from the SCADA system and by controlling the aeration rate required for maintaining effluent water quality. Power consumption in the sewage treatment process was predicted using the equipment's uptime, efficiency, and inherent power consumption. The predicted energy consumption was calibrated by measured data. Additionally, energy efficiency indicators were proposed based on statistical data for energy use, capacity, and effluent quality. In one case study, a sewage treatment plant operated via the SBR process used ~30% of energy consumed in maintaining the bioreactors and treated water tanks (included decanting pump and cleaning systems). Energy consumption analysis with the K-ECO Tool-kit was conducted for unit processing. The results showed that about 58.7% of total energy consumed was used in the preliminary and biological treatment rotating equipment such as the blower and pump. In addition, the energy consumption rate was higher to the order of 19.2% in the phosphorus removal process, 16.0% during sludge treatment, and 6.1% during disinfection and discharge. In terms of equipment energy usage, feeding and decanting pumps accounted for 40% of total energy consumed following 27% for blowers. By controlling the aeration rate based on the proposed feedback control system, the DO concentration was reduced by 56% compared pre-controls and the aeration amount decreased by 28%. The overall power consumption of the plant was reduced by 6% via aeration control.

A Study on the Comparison of Phosphorous Removal Efficiency with C : N : P Ratio for Bench-scales STP (Bench-scale 선박용 STP 장치에서 C : N : P 비율에 따른 인의 처리효율 비교에 대한 연구)

  • Choi, Young-Ik;Ji, Hyeon-Jo;Shin, Dae-Yeol;Mansoor, Sana;Lee, Seong-Chul;Jeong, Jin-Hee
    • Journal of Korean Society of Water Science and Technology
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    • v.26 no.6
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    • pp.53-59
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    • 2018
  • Water pollution is drastically increasing day by day, because of the enhancement in use of livestock, urban sewage detergents and fertilizers. Moreover increase in concentration of phosphorous and nitrogen contained in sewage, leads to green tide problem in the rivers and causes marine pollution. For this problem to solve, several technologies are being researched and developed. Among them, this experiment is a study on Bench-scale STP based on internationally certified sewage treatment equipment by MEPC. 227(64) of IMO. The purpose of this study is to compare the biological treatment efficiency of phosphorus of Bench-scale STP. The ratio of C : N : P was set to 10 : 5 : 3 and 10 : 3 : 1 as the operating conditions. And the operation cycle was set to anoxic(mixed) 70 min - aeration 50 min (70-50), anoxic(mixed) 90 min - aeration 60 min (90-60). As a result, the phosphorous treatment efficiency was 88% at average, and the treatment efficiency was steady at 90-60 better than 70-50. The efficiency of the bench-scale STP has been verified through this experiment and additional experiments are required to derive the optimal operating conditions.

Analysis of the current status and implications of nitrogen recovery from livestock manure (가축분뇨로부터 질소 회수 연구 현황 및 시사점 분석)

  • Im, Seongwon;Kim, Sangmi;Kim, Jimin;Kim, Dong-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.1
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    • pp.37-46
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    • 2021
  • Nitrogen and phosphorus in livestock manure are environmental pollutants, but also could be valuable industrial resources. In the present study, we (1) introduced various nitrogen removal technologies such as stripping, thermal method, membrane, and electrodialysis, (2) reviewed relevant studies reported in 2011-2020, in particular, full-scale experiences, and (3) assessed each technologies based on the above survey results. In addition, we provided the information on the appropriate range of the pH, temperature, gas and liquid ratio, and so on in ammonia stripping process, and expected mass balance when it is connected to biogasification process. We hope the content herein can be helpful for making policy and operating full-scale plant in Korea.

Enhancement of bioactivity and osseointegration in Ti-6Al-4V orthodontic mini-screws coated with calcium phosphate on the TiO2 nanotube layer

  • Byeon, Seon-Mi;Kim, Hye-Ji;Lee, Min-Ho;Bae, Tae-Sung
    • The korean journal of orthodontics
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    • v.52 no.6
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    • pp.412-419
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    • 2022
  • Objective: This study evaluated the effect of cyclic pre-calcification treatment on the improvement of bioactivity and osseointegration of Ti-6Al-4V mini-screws. Methods: The experimental groups were: an untreated group (UT), an anodized and heat-treated group (AH), and an anodized treatment followed by cyclic pre-calcification treatment group (ASPH). A bioactive material with calcium phosphate was coated on the mini-screws, and its effects on bioactivity and osseointegration were evaluated in in vitro and in vivo tests of following implantation in the rat tibia. Results: As a result of immersing the ASPH group in simulated body fluid for 2 days, protrusions appearing in the initial stage of hydroxyapatite precipitation were observed. On the 3rd day, the protrusions became denser, other protrusions overlapped and grew on it, and the calcium and phosphorus concentrations increased. The removal torque values increased significantly in the following order: UT group (2.08 ± 0.67 N·cm), AH group (4.10 ± 0.72 N·cm), and ASPH group (6.58 ± 0.66 N·cm) with the ASPH group showing the highest value (p < 0.05). In the ASPH group, new bone was observed that was connected to the threads, and it was confirmed that a bony bridge connected to the adjacent bone was formed. Conclusions: In conclusion, it was found that the surface treatment method used in the ASPH group improved the bioactivity and osseointegration of Ti-6Al-4V orthodontic mini-screws.

Anaerobic Digestion Biochemical Sludge Produced from Municipal Sewage Treatment Process (하수처리시설에서 발생된 약품 잉여슬러지의 혐기성 소화 특성)

  • Cho, Sang Sun;Kang, Ho;Lim, Bong Su
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.561-569
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    • 2014
  • This study was carried out to get the characteristics of anaerobic digestion for chemical/biological sludge produced from municipal sewage treatment plant for phosphorus. Anaerobic mesophilic batch tests showed that the ultimate biodegradability of waste activated sludge showed 31%, PACl sludge 24%, Alum sludge 26%, respectively. At the S/I 1.0, 75% of total biodegradable volatile solids (TBVS) of waste activated sludge was degraded with an initial rapid decay coefficient, k1 of $0.1129day^{-1}$ and 74% of TBVS of PACl sludge with k1 of $0.0998day^{-1}$, and 76% of TBVS of Alum sludge with k1 of $0.1091day^{-1}$ for 20 days. During the operation of SCFMRs, the 3 reactor (Control, PACl, Alum) pH maintained 6.7~7.0 and the reactor alkalinity maintained 1,800~ 2,200 mg/L as $CaCO_3$. The average biogas production rates of SCFMRs fed with PACl sludge and Alum sludge were 0.089 v/v-d and 0.091 v/v-d, respectively, which was 27~28% lower than that of the control (0.124 v/v-d) at an HRT (hydraulic retention times) of 20 days. And the methane content during the operation ranged 70~76% in 3 reactor. The average TVS removal efficiency of SCFMRs fed with PACl sludge and Alum sludge were 19.6% and 19.9%, respectively, at an HRT of 20 days, which showed 4% lower than that of the control (23.8%). The average BVS removal efficiency of SCFMRs fed with PACl sludge and Alum sludge were 25.8% and 26.9%, respectively, at an HRT of 20 days, which was 8~9% lower than that of the control (34.5%).