유기물자원화 (Journal of the Korea Organic Resources Recycling Association)

  • 제29권1호
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  • Pages.37-46
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  • 2021
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  • 1225-6498(pISSN)
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  • 2508-3015(eISSN)
유기성자원학회 (Korea Organic Resources Recycling Association)
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가축분뇨로부터 질소 회수 연구 현황 및 시사점 분석

Analysis of the current status and implications of nitrogen recovery from livestock manure

  • 임성원 (인하대학교 사회인프라공학과) ;
  • 김상미 (인하대학교 사회인프라공학과) ;
  • 김지민 (인하대학교 사회인프라공학과) ;
  • 김동훈 (인하대학교 사회인프라공학과)
  • Im, Seongwon (Department of Civil Engineering, Inha University) ;
  • Kim, Sangmi (Department of Civil Engineering, Inha University) ;
  • Kim, Jimin (Department of Civil Engineering, Inha University) ;
  • Kim, Dong-Hoon (Department of Civil Engineering, Inha University)
  • 투고 : 2021.02.26
  • 심사 : 2021.03.08
  • 발행 : 2021.03.30
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초록

가축분뇨에 함유된 질소와 인은 환경오염 유발 물질이지만 다양한 산업에서 사용되는 필수 자원이기도 하다. 본 연구에서는 가축분뇨에서 질소 회수에 활용되고 있는 스트리핑, 건조 및 탄화, 이온 교환, 전기투석에 대해 소개하였고, 2011년부터 2020년도까지 국내·외에서 수행한 실규모 연구 현황과 해외 실증플랜트 운영 사례를 분석하였으며 상기 조사결과를 바탕으로 공정별 평가를 실시하였다. 또한, 대표적인 기술인 스트리핑의 주요 운전인자인 pH, 온도, 기액비 등의 적정 범위를 제시하였고, 바이오가스화 공정 연계 시 예상되는 물질수지를 제공하였다. 본 연구에서 제시한 정보는 향후 관련 국내 정책 수립 및 실규모 플랜트 운전 시 유용한 자료로 활용이 가능할 것으로 판단된다.

Nitrogen and phosphorus in livestock manure are environmental pollutants, but also could be valuable industrial resources. In the present study, we (1) introduced various nitrogen removal technologies such as stripping, thermal method, membrane, and electrodialysis, (2) reviewed relevant studies reported in 2011-2020, in particular, full-scale experiences, and (3) assessed each technologies based on the above survey results. In addition, we provided the information on the appropriate range of the pH, temperature, gas and liquid ratio, and so on in ammonia stripping process, and expected mass balance when it is connected to biogasification process. We hope the content herein can be helpful for making policy and operating full-scale plant in Korea.

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참고문헌

  1. Ministry of Environment, "Livestock manure treatment statistics" (2019).
  2. Daejeon Sejong Research Institute, "The study of the livestock manure characteristics analysis and utilization in Sejong City" (2017).
  3. Korea Rural Economic Institute, "Directions for introducing total maximum nutrient loading system of cultivated land", (2015).
  4. National Institute of Environmental, "The study on the status of resource recovery system of livestock manure", (2014).
  5. Degermenci, N., Ata, O. N. and Yildiz, E., "Ammonia removal by air stripping in a semi-batch jet loop reactor. J", Ind. Eng. Chem, 18(1), pp. 399-404. (2012). https://doi.org/10.1016/j.jiec.2011.11.098
  6. Kinidi, L., Tan, I. A. W., Abdul Wahab, N. B., Tamrin, K. F. B., Hipolito, C. N. and Salleh, S. F., "Recent development in ammonia stripping process for industrial wastewater treatment", International Journal of Chemical Engineering, 2018, pp. 1-14. (2018).
  7. Montalvo, S., Huilinir, C., Castillo, A., Pages Diaz, J. and Guerrero, L., "Carbon, nitrogen and phosphorus recovery from liquid swine wastes: a review", J. Chem. Technol. Biotechnol, 95, pp. 2335-2347. (2020). https://doi.org/10.1002/jctb.6336
  8. Menkveld, H. W. H. and Broeders, E., "Recovery of ammonia from digestate as fertilizer", Water Pract. Technol, 13(2), pp. 382-387. (2018). https://doi.org/10.2166/wpt.2018.049
  9. Cantrell, K. B., Hunt, P. G., Uchimiya, M., Novak, J. M. and Ro, K. S., "Impact of pyrolysis temperature and manure source on physicochemical characteristics of biochar", Bioresour. Technol, 107, pp. 419-428. (2012). https://doi.org/10.1016/j.biortech.2011.11.084
  10. Lucian, M. and Fiori, L., "Hydrothermal carbonization of waste biomass: Process design, modeling, energy efficiency and cost analysis", Energies, 10(2), p. 211. (2017). https://doi.org/10.3390/en10020211
  11. Marchetti, R., and Castelli, F., "Biochar from swine solids and digestate influence nutrient dynamics and carbon dioxide release in soil", Journal of environmental quality, 42(3), pp. 893-901. (2013). https://doi.org/10.2134/jeq2012.0352
  12. Darestani, M., Haigh, V., Couperthwaite, S. J., Millar, G. J. and Nghiem, L. D., "Hollow fibre membrane contactors for ammonia recovery: Current status and future developments". Journal of environmental chemical engineering, 5(2), pp. 1349-1359. (2017). https://doi.org/10.1016/j.jece.2017.02.016
  13. Mandowara, A. and Bhattacharya, P. K., "Simulation studies of ammonia removal from water in a membrane contactor under liquid-liquid extraction mode", J. Environ. Manage., 92(1), pp. 121-130. (2011). https://doi.org/10.1016/j.jenvman.2010.08.015
  14. Tan, X., Tan, S. P., Teo, W. K. and Li, K., "Polyvinylidene fluoride (PVDF) hollow fibre membranes for ammonia removal from water", J. Membr. Sci., 271(1-2), pp. 59-68. (2006). https://doi.org/10.1016/j.memsci.2005.06.057
  15. Ippersiel, D., Mondor, M., Lamarche, F., Tremblay, F., Dubreuil, J. and Masse, L., "Nitrogen potential recovery and concentration of ammonia from swine manure using electrodialysis coupled with air stripping", J. Environ. Manage., 95, pp. 165-169. (2012).
  16. Liu, R., Wang, Y., Wu, G., Luo, J. and Wang, S., "Development of a selective electrodialysis for nutrient recovery and desalination during secondary effluent treatment", Chemical Engineering Journal, 322, pp. 224-233. (2017). https://doi.org/10.1016/j.cej.2017.03.149
  17. Mondor, M., Masse, L., Ippersiel, D., Lamarche, F. and Masse, D. I., "Use of electrodialysis and reverse osmosis for the recovery and concentration of ammonia from swine manure", Bioresource technology, 99(15), pp. 7363-7368. (2008). https://doi.org/10.1016/j.biortech.2006.12.039
  18. Kangwon National University, "Farm scale verification of developed technology for control and recovery of nitrogen and phosphorus from animal manure", (2012).
  19. EPS SOLUTION INC., "Advanced wastewater treatment system using membrane distilation and selective N,P Recovery Technology", (2017).
  20. Korea University, "High-end solid fertilizer recovery using integrated zeolite-MAP process", (2017).
  21. Ecodays, "Development of the removal and recovery system for high concentration ammonium nitrogen and phosphorus using ammonia stripping and magnetic Iron Oxide", (2017).
  22. Laureni, M., Palatsi, J., Llovera, M. and Bonmati, A., "Influence of pig slurry characteristics on ammonia stripping efficiencies and quality of the recovered ammonium sulfate solution", J. Chem. Technol. Biot., 88, pp. 1654-1662. (2012).
  23. Liu, L., Pang, C., Wu, S. and Dong, R., "Optimization and evaluation of an air-recirculated stripping for ammonia removal from the anaerobic digestate of pig manure", Process Saf. Environ. Prot., 94, pp. 350-357. (2015). https://doi.org/10.1016/j.psep.2014.08.006
  24. Song, Y. H., Qiu, G. L., Yuan, P., Cui, X. Y., Peng, J. F., Zeng, P., Duan, L., Xiang, L. C. and Qian, F., "Nutrients removal and recovery from anaerobically digested swine wastewater by struvite crystallization without chemical additions", J. Hazard. Mater., 190, pp. 140-149. (2011). https://doi.org/10.1016/j.jhazmat.2011.03.015
  25. Qiu, B., Fan, S., Tang, X., Qi, B., Deng, L., Wang, W., Liu, J., Wang, Y. and Xiao, Z., "Simultaneous recovery of phosphorus and nitrogen from liquid digestate by vacuum membrane distillation with permeate fractional condensation", Chinese J. Chem. Eng., 28, pp. 1558-1565. (2020). https://doi.org/10.1016/j.cjche.2020.01.019
  26. Adam, G., Mottet, A., Lemaigre, S., Tsachidou, B., Trouve, E. and Delfosse, P., "Fractionation of anaerobic digestates by dynamic nanofiltration and reverse osmosis: An industrial pilot case evaluation for nutrient recovery", J. Environ. Chem. Eng., 6, pp. 6723-6732. (2018). https://doi.org/10.1016/j.jece.2018.10.033
  27. Bolzonella, D., Fatone, F., Gottardo, M. and Frison, N., "Nutrients recovery from anaerobic digestate of agro-waste: techno-economic assessment of full scale applications", J. Environ. Manage., 216, pp. 111-119. (2018). https://doi.org/10.1016/j.jenvman.2017.08.026
  28. Errico, M., Sotoft, L. F., Nielsen, A. K. and Norddahl, B., "Treatment costs of ammonia recovery from biogas digestate by air stripping analyzed by process simulation", Clean Technol. Environ. Policy, 20(7), pp. 1479-1489. (2018). https://doi.org/10.1007/s10098-017-1468-0
  29. Nasir, I. M., Mohd Ghazi, T. I. and Omar, R., "Anaerobic digestion technology in livestock manure treatment for biogas production: A review", Eng. Life Sci., 12(3), pp. 258-269. (2012). https://doi.org/10.1002/elsc.201100150