• Title/Summary/Keyword: Phosphorus Release Rate

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Mass Loss Rates and Nutrient Dynamics of Decomposing Fine Roots in a Sawtooth Oak and a Korean Pine Stands

  • Kim, Choonsig
    • The Korean Journal of Ecology
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    • v.25 no.4
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    • pp.235-239
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    • 2002
  • Fine root decomposition and nutrient release patterns were examined using in situ buried fine root (< 2mm in diameter) bags inserted vertically into the mineral soil to a depth of the top 15 cm in a sawtooth oak (Quercus acutissima) and a Korean pine (Pinus korainesis) stands in the Jungbu Forest Experiment Station, Kyonggi-do, Korea. The pine roots compared with the oak roots showed rapid mass loss in early stages of decomposition, but decomposed similarly after 12 months of incubation. Decomposition rates of fine roots were about 33%/yr for the oak roots and 37$\%$/yr for the pine roots. Nutrients except for calcium and phosphorus showed similar concentrations between the oak and the pine roots during the study period. However, calcium concentration was significantly higher in the oak than in the pine roots. Nutrient concentrations in both stands except for nitrogen decreased during the study period. In addition, potassium compared with other nutrients was the most mobile ion and about 70$\%$ of initial amount was released during the first 3 months of incubation. The results indicate that tree species influence mass loss and nutrient dynamics of fine roots on similar site conditions.

Application of Dissolved Air Flotation Technique to Improve Eutrophic Reservoir Water Quality (가압부상법을 이용한 부영양저수지의 수질개선)

  • Kim, Ho-Sub;Jung, Dong-Il;Lee, Il-Kuk;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.38 no.3 s.113
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    • pp.372-381
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    • 2005
  • This study was conducted to test the efficiency of water quality improvement using the dissolved air flotation (DAF) technique in a shallow eutrophic reservoir. The application of DAF was followed by the addition of a chemical coagulant (poly aluminum chloride; PAC). The experiment was conducted in the mesocosm scale (wide ${\times}$ length ${\times}$ depth: 6 m ${\times}$ 6 m ${\times}$ 3 m). Suspended solids (SS) and volatile SS (VSS) concentration decreased by 54 ${\sim}$ 71% and 57 ${\sim}$ 79% of the initial concentrations, respectively. Total phosphorus and Chl- a concentration also decreased by 74 ${\sim}$ 92% and 54 ${\sim}$ 98%, respectively. BOD decreased by>86% while COD decrease ranged 29 ${\sim}$ 63%. Dissolved inorganic P (DIP) and dissolved total P (DTP) concentration decreased by 34 ${\sim}$ 88% and 62 ${\sim}$ 88%, respectively. After DAF application further onto the sediment, DIP-release rates from the sediment decreased by 17% (0.82 ${\to}$ 0.68 mg $m^{-2}$$day^{-1}$ in the oxic condition and 23% (2.27 ${\to}$ 1.76 mg $m^{-2}$$day^{-1}$) in the anoxic condition, compared to the release rate from the untreated sediment. DTP-release rate from both the oxic and anoxic sediments also decreased by 33% (5.62 ${\to}$ 3.78 mg $m^{-2}$$day^{-1}$) and 20% (6.23 ${\to}$ 4.99 mg $m^{-2}$$day^{-1}$), respectively. These results suggest that the DAF application both to the water column and onto the sediment be effective to improve water quality by removing particulate matters in the water column as well as reducing P-release from the sediment.

Effect of Flame Retardants on Flame Retardancy of Flexible Polyurethane Foam (난연제 종류에 따른 연질 폴리우레탄 폼의 난연 특성에 대한 연구)

  • Kwon, Ohdeok;Lee, Ju-Chan;Seo, Ki-Seog;Seo, Chung-Seok;Kim, Sang Bum
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.208-213
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    • 2013
  • In this study, the effect of phosphorus flame retardants on the flame retardancy of the flexible polyurethane foam (PUF) was investigated. Tetramethylene bis(orthophosphorylurea) [TBPU] and phosphinyl alkylphosphate ester [CR-530], resorcinol bis diphenylphosphate [RDP], triethyl phosphate [TEP] were used as flame retardants. The results of thermogravimetric analysis (TGA) indicate that TBPU added PUF produces more charred residues than the other flame retardant added PUF. It was found that TBPU added PUF exhibits low mean heat release rate (HRR), peak HRR, effective heat of combusion (EHC), mass loss rate (MLR), CO yield and $CO_2$ compared to those other flame retardants.

Enhancing the Intrinsic Bioremediation of PAH-Contaminated Anoxic Estuarine Sediments with Biostimulating Agents

  • Bach Quang-Dung;Kim Sang-Jin;Choi Sung-Chan;Oh Young-Sook
    • Journal of Microbiology
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    • v.43 no.4
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    • pp.319-324
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    • 2005
  • Estuarine sediments are frequently polluted with hydrocarbons from fuel spills and industrial wastes. Polycyclic aromatic hydrocarbons (PAHs) are components of these contaminants that tend to accumulate in the sediment due to their low aqueous solubility, low volatility, and high affinity for particulate matter. The toxic, recalcitrant, mutagenic, and carcinogenic nature of these compounds may require aggressive treatment to remediate polluted sites effectively. In petroleum-contaminated sediments near a petrochemical industry in Gwangyang Bay, Korea, in situ PAH concentrations ranged from 10 to 2,900 ${\mu}g/kg$ dry sediment. To enhance the biodegradation rate of PAHs under anaerobic conditions, sediment samples were amended with biostimulating agents alone or in combination: nitrogen and phosphorus in the form of slow-release fertilizer (SRF), lactate, yeast extract (YE), and Tween 80. When added to the sediment individually, all tested agents enhanced the degradation of PAHs, including naphthalene, acenaphthene, anthracene, fluorene, phenanthrene, fluoranthene, pyrene, chrysene, and benzo [a] pyrene. Moreover, the combination of SRF, Tween 80, and lactate increased the PAH degradation rate 1.2-8.2 times above that of untreated sediment (0.01-10 ${\mu}g$ PAH/ kg dry sediment/day). Our results indicated that in situ contaminant PAHs in anoxic sediment, including high molecular weight PAHs, were degraded biologically and that the addition of stimulators increased the biodegradation potential of the intrinsic microbial populations. Our results will contribute to the development of new strategies for in situ treatment of PAH-contaminated anoxic sediments.

Survey on the Contaminated Sediments on Lake Paldang (팔당호 퇴적물 오염 현황 조사)

  • Jung, Yong-Jun
    • Journal of Wetlands Research
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    • v.8 no.4
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    • pp.49-58
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    • 2006
  • The extent and degree of contaminated sediments on lake Paldang were analyzed at 40 sites for organic matters, nutrients and heavy metals. COD, T-N and T-P were fairly correlated with the grain size of sediments, and the sites which were most distributed with sand were less contaminated with the sites covered with silt and clay. Phosphorus species were in the range of 7-58 for adsorbed-P, $13{\sim}411{\mu}g/g$ for NAI-P, $52{\sim}482{\mu}g/g$ for Apatite-P and $75{\sim}894{\mu}g/g$ for residual-P, respectively. Although heavy metals of sediments were detected at the range of $0.2-4.2{\mu}g/g$(Cr), $1.6{\sim}20.7{\mu}g/g$(Cu), 1.4~78.0ng/g(Hg), $2.1{\sim}18.9{\mu}g/g$(Pb), $1.8{\sim}99.5{\mu}g/g$(Zn), further survey over the long period were required for more monitoring data. The release rate of nutrients were found no relationship in this study.

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Assessment of Pollution Characteristics of Surface Sediments from Lake Andong(II): Studies on the Nutrient and Heavy Metal Release Characteristics from Sediments in Andong Dam (안동댐 퇴적물의 오염도 평가(II): 안동댐 퇴적물에 대한 영양염류 및 중금속 용출 특성 연구)

  • Kim, Young Hun;Park, Jae Chung;Shin, Tae Cheon;Kim, Jeong Jin
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.4
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    • pp.391-405
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    • 2020
  • Leaching chracteristics of Andong-dam sediment was conducted for heavy metal and nutrients. Five mixed sediment samples were prepared and leaching was conducted under aerobic and anaerobic condition for 60 days. Cd, Cu, Pb, Cr, Zn, Hg, As, Fe, Mn, phosphorus, and nitrogen were analyzed at each sampling time. The leaching rate of phosphorus was higher in anaerobic condition comparing with that of under aerobic condition. Some samples showed higher than the water-quality level IV. In case of As and Cd which showed highest contamination level in the sediment, leached concentration were 0.028 mg/L and 0.003 mg/L in maximum, respectively. The leached concentration is below than the lake water quality standard of Korea. Other heavy metals including Cu, Pb, and Cr also showed similar trend. Five step sequential extraction showed that easily extractable 1-2 step portion such as ion-exchangeable and adsorbed one was less than 10% and the most of the portion was residual. For As and Cd, the residual portion were 80% and 95% respectively indicating the risk by the heavy metal leaching into the lake for a short period was not high in comparing with the contamination levels.

The application of ecosystem model for the eutrophication control in Masan Bay in summer (하계 마산만의 부영양화 제어를 위한 생태계모델의 적용)

  • Kim, Jong-Gu;Park, Cheong-Gil;Kim, Gwang-Su
    • Journal of Environmental Science International
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    • v.3 no.3
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    • pp.185-195
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    • 1994
  • Masan bay is one of the polluted enclosed bays, which has red tides problem and the formation of oxygen deficient water in the bottom layer. Most important factors that cause eutrophication and red tide is nutrient materials containing nitrogen and phosphorus which stem from terrestrial sources and nutrients released from sediment. Therefore, to improve of water quality, reduction of these nutrient loads should be indispensible. At this study, the three-dimensional numerical hydrodynamic and eutrophication model, which were developed by Institute for Resources and Environment of Japan, were applied to analyze the processes affecting the phytoplankton production and also to evaluate the effect of water quality improvement plans on phytoplankton production. In field sorvey, the range of concentrations of chlorophyll-a at surface area was found to be 29.17 - 212.5mg/m3, which were exceeding eutrophication criteria. The constant currents defined by integrating the simulated tidal currents over 1 tidal cycle showed the counterclockwise eddies in the southern part of Budo. The general directions of constant currents were found to be southward at surface and northward at bottom over all the bay. The eutrophication model was calibrated with the data surveyed in the field area in June, 1993. The calculated results are in fairly good agreement with values within relative error of 30%. The pollutant load from the sources such as the input from terrestrial release from the sediment was reduced by the rate of 50, 70, 90, 98% to effect of phytoplankton production. Phytoplankton production was reduced to of the 90% reduction of the input loads from terrestrial sources and 8% in 90% reduction of the load from sediment.

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Decomposition and, Nitrogen, Phosphorus and Potassium Dynamics of Pinus thundbergii Needle Litter (해송엽(海松葉) Litter의 분해(分解)와 N, P 및 K의 동태(動態))

  • Yi, Myong-Jong
    • Journal of Korean Society of Forest Science
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    • v.80 no.3
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    • pp.303-310
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    • 1991
  • Seasonal patterns of decomposition and nutrient release from the needle litter were examined using litter-bags in coastal Pinus thunbergii forests in nothern Kyushu, Japan. Dry matter losses from decomposing needle litter were smillar in all standsover a experimental period. Mass loss in dry weight is lost rapidly during the first year, and thereafter the rate of loss slows. Litter lost approximately 40% of initial mass in 1 yr. The predicted decay constant, k values ranged from 0.5 to 0.6 Decomposition half-times($t_{0.50}$) ranged from 1.1 to 1.4 year. In the decomposing needle litter, the concentrations of N and P generally increased with time while the concentration of K decreased. A decrease in absolute amount was noted for K during decomposition while in an increase was found for N. The order of mobility of elements was K>P>N. Mineralization phase of N had not appeared during the experiment.

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Effect of Air-flow on Enhanced Nutrient Removal and Simultaneous Nitrification/Denitrification in DMR Biofilm Process (DMR 생물막 공정에서 포기량에 따른 질산화 동시 탈질화 및 영양염류 제거특성)

  • Kim, Il-Kyu;Lee, Sang-Min;Lim, Kyeong-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.992-998
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    • 2008
  • Recently, a new concept for nitrogen removal that is simultaneous nitrification and denitrification(SND) has been studied for wastewater treatment process. The DMR(Daiho Microbic Revolution) process that used in this study consists of two suspended anoxic, anaerobic reactors and an aerobic biofilm reactor. The function of aerobic environment and the intensity of air flow rate(2.0, 1.0, 0.5, 0.4, 0.2 L/min) were studied in the biofilm reactor; also SND and nutrient removal efficiencies were investigated. Experimental results indicated that the change in air flow did not affect COD$_{Cr}$ removal significantly. Thus sustained at 93%. The lower the air flow rate, the higher T-N removal efficiency was attained(i.e.80% at 0.2 L/min). SND efficiency was 62, 65, 72 and 78% corresponding to each air flow rate. T-P removal was sensitive to aeration intensity and removal enhanced from 75% to 96% when the air flow rate was changed from 2.0 to 0.5 L/m; however second release occured in the clarifier at 0.2 L/min. Phosphorus content of activated sludge was 5.0%, as P releases and acetate uptake a ratio of 0.75 mg P/ mg HAc.

A Study on the Filtration of BNR Process Effluent (BNR공정 처리수의 여과에 관한 연구)

  • Kim, Seong-Young;Bum, Bong-Su;Cho, Kwang-Myeung
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.895-905
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    • 2000
  • This study was performed to investigate the removal efficiencies of pollutants at various filtration rates and the quality of the filtered water along the depth of filter media during treatment of a BNR process effluent by a dual-media gravitational rapid filtration. The results of the experiments at filtration rates of 200, 300 and 400 m/day using the effluent of a pilot scale 4-stage BNR plant showed that turbidity of the filtered water was below 2.6 NTU, satisfying the Korean standard for water for reuse. Even though the SS removal efficiency deteriorated as the filtration rate increased, the average SS concentration of the filtered water was 1.3 mg/L at all filtration rates. Simultaneous biological nitrification and denitrification was observed with nitrification efficiencies of 17.4, 18.8 and 14.3%, and denitrification efficiencies of 32.3, 27.7 and 21.4% respectively at filtration rates of 200, 300 and 400 m/day. At the latter period of each filtration cycle, the effluent T-P concentration was higher than influent T-P concentration by 6.1 to 21.4% due to phosphorous release under DO-deficient condition.

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