• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.11a
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• pp.7-7
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• 1998

• Journal of Surface Science and Engineering
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• v.52 no.4
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• pp.233-238
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• 2019

The formation behavior of zinc phosphate conversion coating (ZPCC) on SCM430 alloy was investigated in 25 vol.% of 1M ZnO + 170 ml/L solution containing various $Fe(NO_3)_2$ concentrations, using open-circuit potential(OCP), electrochemical impedance spectroscopy(EIS), cyclic polarization(CP) curve and tape peel test. OCP of SCM430 alloy and corrosion current density increased with increasing $Fe(NO_3)_3$ concentration. Resistance of films formed on SCM430 alloy by chemical conversion treatment decreased with increasing $Fe(NO_3)_3$ concentration. Color and adhesion of chemical conversion coatings became darker and worse, respectively, with increasing $Fe(NO_3)_3$ concentration. It is concluded that addition of $Fe(NO_3)_3$ into a zinc phosphating bath leads to faster reaction to form porous surface coatings with poor adhesion and corrosion resistance.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.41-42
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• 2014

현대 산업에서 철은 매우 중요한 재료이다. 다양한 산업적 요구에 맞게 제철산업에서도 다양한 성질의 강을 개발하고 생산하고 있다. 강의 주요 물성으로는 인장강도, 항복강도, 연신율 등이 있으며 이러한 물성들을 향상시키거나 변경하는데 다양한 첨가원소와 제조 공법들이 적용되어진다. 본 연구에서는 그 중 합금 원소를 첨가하여 강도를 높이는 초고강 강에 대해서 화성처리 특성을 연구하고 그에 영향을 미치는 인자에 대해서 분석하였다. 그리고 화성처리 공정을 개발하여 초고강도강의 인산염특성을 향상 시켰다.

• Journal of Surface Science and Engineering
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• v.28 no.5
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• pp.289-299
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• 1995

The effects of phosphate coating have been studied on physical properties and corrosion resistance of painted aluminum alloy sheet for automobile body. The physical properties (surface roughness, paint adhesion, impact resistance and pencil hardness) and corrosion resistance(cyclic corrosion and filiform corrosion) were investigated. Phosphate coatings enhanced the physical properties of painted Al alloy sheet, especially paint adhesion after the 240hours water immersion test. Phosphate coating also markedly improved the resistance for cyclic corrosion and filiform corrosion of painted cold rolled steel and Zn-Ni plated steel sheet as well as painted Al alloy sheet. The corrosion resistance of painted Al sheets was varied with the concentration of free fluoride ion and metal additives like Ni and Mn in the phosphating bath. A maximum corrosion resistance was obtained at about 300ppm of fluoride ion and additives of Ni and Mn obviously increased the corrosion resistance of painted specimens.

• Tribology and Lubricants
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• v.12 no.1
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• pp.15-21
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• 1996

Friction and wear properties of MoS$_2$ bonded films were studied using the Falex testing machine, and their properties were evaluated in terms of the life and the load carrying capacity of the films. MoS$_2$ bonded films were formulated from the mixtures of MoS$_2$ solid particles and epoxyphenol resin, and they were applied onto AISI 4130 steel surface by dipping method to form lubricating bonded films. The results of the life and the load carrying capacity of the films showed that films were mainly affected by the surface temperature arisen from the frictional heat at the contact surface. To obtain enhanced tribological properties of the films, various combinations of solid lubricants and additives with a basic polymer resin were attempted and evaluated. The effects of surface pretreatment, such as sand blast or Zn-phosphating, were also investigated.

• Journal of Surface Science and Engineering
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• v.36 no.2
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• pp.176-184
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• 2003

New lubricant film of organic and inorganic composite resin was developed to improve the press formability of galvannealed steel sheets (GA) for automotive body panels. The frictional coefficient of lubricant GA steel sheets is about 20% superior to that of uncoated GA. The current range of spot welding of lubricant GA is similar to that of the uncoated GA, but the burning trace of spot welding is inferior to that of the uncoated GA in the oiling condition. The alkaline degreasability of lubricant GA shows 100% in alkaline degreasing condition of automotive company. The size and shape of the phosphated coating layer are similar to those of the uncoated GA sheet. The powdering property of the lubricant GA gives rise to 20∼50% improved property compared with the uncoated GA sheet.

• Journal of Surface Science and Engineering
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• v.36 no.2
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• pp.184-193
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• 2003

Cyclic sweep voltametry was performed to investigate the electrochemical behavior of heavy metal ions and the organic additives in surface finishing process. And electrolysis using parallel plate electrode electrolyzer was carried out to simulate the treatment of real waste water. Results showed that more than 99 percent of Cu was recovered and selective recovery of Cu in mixed waste water was possible, but the possibility of economical recovery of Ni and Cr were very low due to the evolution of hydrogen gas. Electrochemical oxidation of cyanide and organic additives on anode showed very excellent removal rate. The complete removal of several hundred ppm of cynide was possible within several tens minutes and organics within 2 or 3 hours. Even in case of concentrate waste water, the complete removal of COD by using NaCl and air stirring seemed to be possible.

• Journal of Surface Science and Engineering
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• v.30 no.5
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• pp.310-319
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• 1997

The purpose of this study is to investigate the effect of the specific alloying elements in steel such as Cr, Ni and Cu, and surface roughness of substrate with two different FCS temperature zones in the CAL process on the phosphatability of the cold-rolled sheet used for the drum in order to improve the zinec phosphating property. Phosphatability is dependent of the surface oxide and roughness on the substrate and can be indirectly improved by increasing surface roughness of the steel sheet. Basically, in order to obtain the good phosphatability, the low concentration of the retained elements such as Cr, Ni and Cu among the steel alloy elements should be required. Phosphatability of substrate with high concentration instead of the retained elements and surface roughness, however, can be effectively improved instead of low FSC temperature.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.05a
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• pp.264-264
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• 2012

Zn-Mg 합금도금의 인산염 처리시 산성의 인산염 용액에 의해 도금층으로부터 용출된 마그네슘이온은 인산염 결정 형성에 참여하고, 이로인해 미세하고 치밀한 인산염 피막이 형성되었다. 마그네슘을 포함함 치밀한 인산염 피막은 우수한 내식성을 보였다. 마그네슘이온의 영향성 파악을 위해 인산염 용액내 추가적으로 마그네슘 이온을 투입하였으며, 마그네슘 함량증가에 따라 인산염 피막의 내식성이 향상됨을 확인하였다.

• Journal of Surface Science and Engineering
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• v.48 no.2
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• pp.56-61
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• 2015

In this study, the wear performance of manganese phosphate coating on SM45C with addition agent of Tartaric acid and Citric acid were investigated. The Surface morphology of manganese phosphate coating was examined by Scanning Electron Microscope (SEM) and Energy Dispersive X-ray spectroscopy (EDS). It is found that Mn, P, Fe, O and C. The crystal structure and thee composition was analysis and determined by using XRD. The XRD results indicated that manganese phosphate coatings are mainly composed of $(Mn,Fe)_5H_2(PO_4)_44H_2O$ and consists of a lot of close packed lump crystalline. Based on the time dependence of morphology and the weight of manganese phosphate coating, it shows that the phosphating process mainly includes three stages: corrosion of the substrate, creation and growth of phosphate crystal nucleus and thickening of manganese phosphate coating. The wear tests were performed in a ball on disc apparatus as per ASTM G-99 Standard. It was showed that the initial wear was quite high followed by low sludge.