Browse > Article
http://dx.doi.org/10.5695/JKISE.2015.48.2.56

Characterization of Tribology for Automobile Part of Manganese Phosphate Solution with Addition agent  

Byoun, Young-Min (Dept. of Metallurgical Engineering, College of Engineering, Inha University)
Park, Jong-Kyu (Dept. of Metallurgical Engineering, College of Engineering, Inha University)
Seo, Sun-Kyo (Sam Young Chemical)
Lee, Chi-Hwan (Dept. of Metallurgical Engineering, College of Engineering, Inha University)
Publication Information
Journal of the Korean institute of surface engineering / v.48, no.2, 2015 , pp. 56-61 More about this Journal
Abstract
In this study, the wear performance of manganese phosphate coating on SM45C with addition agent of Tartaric acid and Citric acid were investigated. The Surface morphology of manganese phosphate coating was examined by Scanning Electron Microscope (SEM) and Energy Dispersive X-ray spectroscopy (EDS). It is found that Mn, P, Fe, O and C. The crystal structure and thee composition was analysis and determined by using XRD. The XRD results indicated that manganese phosphate coatings are mainly composed of $(Mn,Fe)_5H_2(PO_4)_44H_2O$ and consists of a lot of close packed lump crystalline. Based on the time dependence of morphology and the weight of manganese phosphate coating, it shows that the phosphating process mainly includes three stages: corrosion of the substrate, creation and growth of phosphate crystal nucleus and thickening of manganese phosphate coating. The wear tests were performed in a ball on disc apparatus as per ASTM G-99 Standard. It was showed that the initial wear was quite high followed by low sludge.
Keywords
SM45C; Conversion coating; Addition agent; Tribology;
Citations & Related Records
연도 인용수 순위
  • Reference
1 T. S. N. S. Narayanan, Rev. Adv. Mater. Sci., 9 (2005) 130.
2 A. W. Czanderna, C. J. Powell, Specimen handling, Preparation, and Treatments in Surface Characterization, Springer science Business media,llc., (1998)
3 W. Rausch, The Phosphating of Metal, ASM international, (1988) 149.
4 L. Fang, L. Xie, J. Hu and W.T. Zhang, Phys Procedia., 18 (2011) 227.   DOI
5 B. Moon, J. Kor. Inst. Surf. Eng., 37 (2004) 137.
6 E. P. Banczek, P.R.P. Rodrigues, I. Costa, Surf. Coat. Technol., 201 (2006) 3701.   DOI
7 V. Burokas, A. Martusiene, O. Girciene, Surf. Coat. Technol., 202 (2007) 239.   DOI
8 S. M. Tamborim Takeuchi, D. S. Azambuja, A.M. Saliba-Silva, I. Costa, Surf. Coat.Technol., 200 (2006) 6826.   DOI
9 A.S. Akhtar, K.C. Wong, K.A.R. Mitchell, Appl. Surf. Sci., 253 (2006) 493.   DOI
10 P.K. Sinha, R. Feser, Surf. Coat. Technol., 16 (2002) 158.
11 S. Jegannathan, T.S.N. Sankara Narayanan, K. Ravichandran, Surf.Coat. Technol., 200 (2006) 4117.   DOI
12 Minqi Sheng, Yinyin Wei, Qindong Zhong, J. Coat. Technol. Res., 6 (2009) 543.   DOI
13 Xiuzhi Zhang, Fuhui Wang, Du. Yuanlong, Surf. Coat. Technol., 201 (2007) 7241.   DOI
14 Alka Phanasgaonkar, V.S. Raja, Surf. Coat. Technol., 203 (2009) 2260.   DOI
15 A.N. Khramov, V.N. Balbyshev, N.N. Voevodin, M.S.Donley, Prog.Org. Coat., 47 (2003) 207.   DOI
16 J.R. Van Wazer, Phosphorous and Its Compounds, vol. IIInterscience Publishers Inc.,New York, 1966.
17 M. Sheng, Y. Wang, H. Wu, Q. Zhou, Surf Coat Technol., 205 (2011) 3455.   DOI
18 D. M. ahuang, Y.R Liu, J.J. Liu, X.D Fang, M.X. Guang, Wear., 799 (1999) 225.
19 S. Ilaiyabel, A.Venkatesan, Phys Procedia., 38 (2012) 1916.
20 J.H. Hong, S.H. Lee, J.G. Kim, J.B. Yoon, Corros. Sci., 54 (2012) 174.   DOI
21 F. Rosalbino, G. Scavino, G. Mortarino, E. Angelini, J Solid State Electrochem., 1 (2010) 23.