• Title/Summary/Keyword: Phenolic

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A Study on the Color Reproduction of Halftone Image by used Factor N and Process Ink Characteristics (Factor N와 잉크특성을 고려한 망점화상의 색재현예측에 관한 연구)

  • 김성근
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.13-27
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    • 1994
  • Litho printing ink vehicles based on rosin modified phenolic are faster drying, have better durability, are harder and glosser and have greater resistance to water than ones based on ester gums. Ink-Water balance and rheological properties are important in litho printing process. These physical properties is concerned with molecular weight of Resin to use vehicle. So this paper was studied about the effects of changing molecular weight of Rosin modified phenolic on surface tension, viscosity, pseudoplasticity and printablility of Litho Inks. The results were as follows. 1) The surface tension of model inks depended on the molecular weight of the resin : Dispersion componnent of ink increase but non dispersion component decrease as molecular weight of Resin increase. 2) Water pick-up of litho ink is more fast balance, using low molecular weight of Resin. 3) Viscosity, Yield value and Newtonian value of model inks increase as molecular weight of Resin increase. 4) The litho ink prepared with the modified phenolic of which molecular weight is about 20000 showed the highest printing density and gloss.

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The Effect of Changing Molecular Weight of Rosin Modified Phenol Resin on Physical Properties of Litho Printing Inks (Rosin변성 phenol수지의 분자량 변화에 따른 평판인쇄 잉크의 물성변화에 관한 연구)

  • SungBinKim
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.145-157
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    • 1994
  • Litho printing ink vehicles based on rosin modified phenolic are faster drying, have better durability, are harder and glosser and have greater resistance to water than ones based on ester gums. Ink-Water balance and rheological properties are important in litho printing process. These physical properties is concerned with molecular weight of Resin to use vehicle. So this paper was studied about the effects of changing molecular weight of Rosin modified phenolic on surface tension, viscosity, pseudoplasticity and printability of Litho Inks. The results were as follows. 1) The surface tension of model inks depended on the molecular \veight of the resin : Dispersion componnent of ink increase but non dispersion component decrease as molecular weight of Resin increase. 2) Water pick-up of litho ink is more fast balance, using low molecular weight of Resin. 3) Viscosity, Yield value and Newtonian value of model inks increase as molecular weight of Resin increase. 4) The litho ink prepared with the modified phenolic of which molecular weight is about 20000 showed the highest printing density and gloss.

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Synthesis of novolac resins by condensation of phenolic compounds with formaldehyde (폐놀계 화합물과 포름알데히드의 축합반응으로부터 노볼락 레진의 합성)

  • Lee, Jong-Dae;Lee, Tae-Jun;Lee, Chang-Hoon;Cho, Kyung-Tae
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.3
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    • pp.309-318
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    • 2007
  • Novolac is widely used as the primary solid component of most photoresists in semiconductor and microelectronic devices. In this study, novolac resins were prepared by condensation of 35% formaldehyde with phenolic compounds such as m-/p-cresol, 2,5-dimethylphenol and bisphenol A in the presence of oxalic acid as catalyst. The average molecular weight $(M_w)$ of these novolac resins has been varied on the changing of mixing ratio of m-/p-cresol/2,5-dimethylphenol/bisphenol A or formaldehyde/phenolic compound. Also, thermal properties of novolac were observed by TGA.

Isolation and Identification of Adenosine in Fresh Ginseng (수삼에서의 아데노신 분리 및 동정)

  • Lee, Mee-Kyoung;Lim, Sun-Uk;Park, Hoon
    • Journal of Ginseng Research
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    • v.14 no.3
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    • pp.437-441
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    • 1990
  • The investigation of UV absorbing compounds in saponin fraction of Pnm.1. Kiairnk root was carried out by thin layer chromatography, semipreparative HVLC. l3C, 1H-NMR, mass spectrometry and chemical characteristics in searching plant for growth regulatony substances such as phenolic glycoside. Drying of fresh ginseng at 15 $^{\circ}C$ decreased not only number but also size of UV absorbing sports on TLC. One of the relatively large spots in fresh ginseng was isolated and identified as adenosine, which is subjected for growth stimulatory activity Detection of phenolic glycosides failed in dried root bolt was highly probable in fresh ginseng even with the insufficient amount of sample.

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Friction and Wear Characteristics of Friction Material with the Content of Hexamethylenetetramine (Hexamethylenetetramine의 함량에 따른 마찰재의 마찰.마모 특성)

  • Kim, Dae-Kyeun;Jang, Ho;Yoon, Ho-Gyu
    • Tribology and Lubricants
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    • v.16 no.4
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    • pp.266-273
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    • 2000
  • The friction characteristics of phenolic resin and model friction materials were investigated with the content of hexamethylenetetamine (HEXA). At 10 wt.% of HEXA, the phenolic resin and model friction materials showed the most stable friction coeffcient in constant temperature test at various test conditions because of its good thermal stability and proper curing reaction. It was found from constant interval test in mild condition that the friction coeffcients of friction materials cured with 10 wt.% of HEXA was the highest and stable values in the whole range of braking operations. However, at the severe condition in constant interval test, the friction coefficient of friction materials cured with 10 wt.% to of HEXA was lowered and as the number of braking operation increased, the values became stable. In order to obtain the thormal stable friction materials, the content of HEXA from 5 to 10 wt.% could be recommended.

Inhibition of Aromatic L-Amino Acid Decarboxylase (AADC) by Some Phenolic Compounds from Medicinal Plants (천연 페놀성 화합물들의 방향족 아미노산 탈탄산효소 저해작용)

  • Ryu, Shi-Yong;Han, Yong-Nam;Han, Byung-Hoon
    • YAKHAK HOEJI
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    • v.38 no.6
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    • pp.791-794
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    • 1994
  • Sixteen kinds of naturally occurring phenolic compounds including 5 stilbenes, 7 flavonoids and 4 anthraquinones were examined in the inhibitory activity against rat liver AADC(aromatic L-amino acid decarboxylase) in vitro, using 5-hydroxytryptophan as a substrate. Three hydroxystilbenes, resveratrol 1, rhapontigenin 3 and piceatanol 5, which were known to be monoamine oxidase A inhibitors, exhibited a significant inhibition against AADC($IC_{50}$=20, 8 and $5\;{\mu}M$, respectively). By the comparison of the activity of each phenolic compound, it was suggested that the 3',4'-dihydroxyphenyl group of stilbenes or flavones was the best pharmacophore for the AADC inhibitory activity.

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Antioxidant Potential in the Fruits of Pyrus Species (Pear) in Korea

  • Park, Young-Ki;Kim, Sea-Hyun;Chung, Hun-Gwan
    • Korean Journal of Medicinal Crop Science
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    • v.15 no.5
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    • pp.335-338
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    • 2007
  • Five samples (Bakwoonbae, Chungsilbae, Sandolbae, Dolbae, and Chuwhangbae) of Pyrus species differing in their origin of production were analyzed for total phenolic content, vitamin C content, and antioxidant activities. Two antioxidant activities were measured by the free-radical scavenging activity and reducing power method. Total phenolic content of the Chungsilbae extract (20.35 mg/g) was higher than those of other pears. Vitamin C content in five Pyrus species ranged from $420.32\;{\mu}g/g$ in Sandolbae to $659.75\;{\mu}g/g$ in Bakwoonbae. Chungsilbae also had the highest free radical scavenging activity (76.56%) and reducing power (0.35).

Antioxidant capacity of crude extract and fractions from Woodfordia fruticosa flower

  • Bhatt, Lok Ranjan;Baek, Seung-Hwa
    • Advances in Traditional Medicine
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    • v.7 no.2
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    • pp.162-170
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    • 2007
  • Woodfordia fruticosa Kurz. (Lythraceae), commonly known as Dhayero, is used in the treatment of various ailments in Nepal. In this study, the antioxidant capacity of crude extract and different polarity fractions of Woodfordia fruticosa flowers were assayed for their scavenging abilities against 1,1-diphenyl-2-picrylhydrazyl (DPPH) and nitric oxide radicals, competitive ${\beta}$-carotene bleaching, reducing power, metal chelating ability and total phenolic content. Crude extract and polar fractions showed stronger antioxidant capacity and contained very high level of total phenolics. They exhibited strong DPPH radical scavenging, nitric oxide scavenging and reducing power, medium ${\beta}$-carotene bleaching and poor metal chelating capacity. Positive correlation obtained between total phenolic content and antioxidant capacity assays, indicated the contribution of phenolics toards antioxidant capacity.

Tyrosinase Inhibition and Mutagenicity of Phenolic Compounds from Mulberry Leaves - Research Note -

  • Kim, Young-Chan;Takaya, Yoshiaki;Chung, Shin-Kyo
    • Preventive Nutrition and Food Science
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    • v.12 no.2
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    • pp.119-121
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    • 2007
  • The tyrosinase inhibition activity and mutagenicity as assessed by the Ames test on phenolic antioxidants (5-Caffeoyl quinic acid, 3,4-Dihydroxy cinnamic acid, Quercetin 3-O-${\beta}$-D-glucopyranose, Kaempferol 3-O-${\beta}$- D-glucopyranose) and the ethyl acetate fraction isolated from mulberry leaves were examined. The ethyl acetate fraction and chlorogenic acid exhibited weaker tyrosinase inhibitory activities than kojic acid. In addition, the ethyl acetate fraction from mulberry leaves, containing phenolic antioxidants, showed no mutagenicity by the Ames test.

Preparation of Composite Adsorbents by Activation of Water Plant Sludge and Phenolic Resin Mixtures

  • Myung, Heung-Sik;Kim, Dong-Pyo
    • Carbon letters
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    • v.1 no.3_4
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    • pp.154-157
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    • 2001
  • Composite adsorbents were prepared by mixing water plant sludge with phenolic resin having the ratio of 1 : 1, 1 : 2, and 1 : 3 respectively, curing from $100^{\circ}C$ to $170^{\circ}C$ under $N_2$ atmosphere, and then activating with $N_2$ at $700^{\circ}C$. Thermal property, specific surface area and morphology of the composite adsorbents as well as their precursors were measured by TGA, BET and SEM respectively. Removal efficiency of the composite adsorbents to ${NH_4}^+$ and TOC was compared with those of commercial zeolite and activated carbon. The adsorbents presented very promising TOC removal efficiency of 98%, which was identical level to that of commercial activated carbon while they displayed removal efficiency, only 32%, of ${NH_4}^+$. Therefore, this composite adsorbent considered as the alternative material of commercial activated carbon, used as an expensive removal agent of organic substances and THM in water treatment plant and it also suggested a possibility of practical application in other processes.

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