• 한국표면공학회:학술대회논문집
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• 한국표면공학회 1998년도 춘계학술발표회 초록집
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• pp.3-3
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• 1998

The atmospheric corrosIOn properties of Zinc (Zn) under wet/dry transition of $H_20$ film were investigated in this study. The atmospheric corrosion of metal is usually occurred as a result of repetitious thickness transition (so called wet/dry transition) of liquid phase which is covering the metal surface. Corrosion potential and the polarization behaviour of Zn during liquid film thickness transition were measured by Kelvin probe method which IS using vibrating reference electrode without touching the liquid film. The oxidized states of Zn as a result of successive wet/dry transition were also investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results show that the corrosion potential and the corrosIOn rate of Zn both are increasing during drying. However, the corrOSIon rate is decreasing again when the Zn surface is completely dried while the corrosion potential still remains high. This behaviour can be explained by the polarization behaviour change of Zn according to the $H_20$ film thickness change. The completely dried surface is consisted mostly with Zn and ZnO phases. After a number of cycles of wet/dry transition, however, the oxidized Zn phase of ${\varepsilon}-Zn(OH)_2$, which has rather voluminous and defected structure, were found.

• Macromolecular Research
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• 제17권6호
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• pp.365-377
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• 2009

In this feature article, we briefly review the new methods we have utilized recently in the investigation of morphology and phase behavior of block copolymers. We first describe the chromatographic fractionation method to purify block copolymers from their side products of mainly homopolymers or block copolymer precursors inadvertently terminated upon addition of the next monomer in the sequential anionic polymerization. The chromatographic method is extended to the fractionation of the individual block of diblock copolymers which can yield the diblock copolymer fractions of different composition and molecular weight, which also have narrower distributions in both molecular weight and composition. A more detailed phase diagram could be constructed from the set of block copolymer fractions without the need of acquiring many block copolymers each prepared by anionic polymerization. The fractions with narrow distribution in both molecular weight and composition exhibit better long-range ordering and sharper phase transition. Next, epitaxial relationships between two ordered structures in block copolymer thin film is discussed. We employed the direct visualization method, transmission electron microtomography(TEMT) to scrutinize the grain boundary structure.

• 대한화학회지
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• 제36권3호
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• pp.360-365
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• 1992

고체 시료의 상전이 현상을 연구하기 위하여 온도 가변용 광음향 cell과 dewar를 제작하였고, 이 장치를 이용하여 wood's metal의 상전이 온도를 측정하였다. 실험 결과는 융점으로 알려진 343 K와 잘 일치하고, 잠열(latent heat)이 존재하는 1차 상전이임을 나타냈으며 supercooling 현상이 존재한다는 것을 알았다. 고체-액체 상전이와 같은 1차 상전이의 경우 잠열이 존재하며 이러한 잠열은 시료의 온도를 올리며 측정할 경우 상전이 온도 부근에서 광음향 신호의 급작스런 감소를 발생시킨다. 그러나 온도를 내릴 경우 광음향 신호에는 아무런 영향을 미치지 못하므로 광음향 측정은 상전이의 차수를 결정할 수도 있음을 물론, 고체의 상전이 현상 연구에 유용한 방법임을 입증하였다.

• 한국세라믹학회지
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• 제35권1호
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• pp.11-16
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• 1998

$VO_2$ thin films have been prepared on borosilicate glass substrate using alkoxide method to characterize the effects of fabricating factors on thermochromic performance. The gel films formed by spin coating were converted to $V_2O_5$ phase during oxidizing heat-tratment and the $VO_2$ phase were formed by reducing heat-treatement. The thermochromic switching properties of $VO_2$ thin films are strongly affected by the crystal phase and microstructure and those could be controlled by reducing heat-treatment conditions. The ther-mochromic switching characteristics of $VO_2$ thin films synthesized were measured at IR (2.5$\mu\textrm{m}$) as the transition temperature of $63^{\circ}C$ the transition width of $3.6^{\circ}C$and the maximum and minimum transmittance of 84% and 14% respectively.

• 대기
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• 제18권3호
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• pp.159-169
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• 2008

The characteristics of the typhoon's extratropical transition (ET) over the western North Pacific area were investigated using the cyclone phase space (CPS) diagram method suggested by Hart (2003). The data used in this study were the global data assimilation prediction system (GDAPS) and NCEP data set. The number of typhoons selected were 75 cases during 2002 to 2007, and the three parameters were analyzed : the motion relative thickness asymmetry of the storm (B), the upper thermal wind shear and the lower thermal wind shear. Comparing the best-track data provided by the Regional Specialized Meteorological Center /Tokyo, the time of the ET based on CPS was 2~6 hours earlier than the best-track data. And it was shown that the 400- km and 30 kt wind radius of storm for the CPS method were better agreement than the previous suggested radius 500- km.

• 한국결정학회지
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• 제13권1호
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• pp.36-40
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• 2002

중성자회절법을 이용하여 여러 다른 조건으로 열처리한 (Fe/sub 0.61/Ni/sub 0.39/)₃V 합금 분말시료의 장거리 규칙도를 측정하여 규칙-불규칙 상전이의 정도를 조사하였다. 조사 결과 680℃-94 h 열처리 시료는 완전 불규칙 상태로 상전이가 발생하지 않았으며 면심입방구조를 보였다. T < 640℃의 조건에서 열처리한 시료들은 모두 장거리 규칙도 0 < S < 1으로 면심입방구조의 일부가 단순입방구조로 상전이 함을 보여주었다. 또한 Cowley의 S-T/T/sub c/ 관계식으로부터 465℃-144 h 으로 열처리한 시료가 열평형상태에 가장 근접하였음을 확인하였다

• 한국음향학회지
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• 제9권2호
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• pp.61-69
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• 1990

디지틀 통신에서 매우 중요한 문제인 비트 동기화(bit synchronization)를 기저대역(baseband)의 PAM 신호에 대하여 weighted least square 추정 기법과 등가인 Gauss-Markov 추정 기법을 연구하였다. 백색 가우시안 확류분포를 갖는 잡음하에서, 천이 위상(Transition phase)과 데이터 레벨의 추정을 2차원적으로 동시에 수행하여 수신단에서 완전한 신호를 복원하는, 검파기 포함형의 비트 동기화기(synchronizer) 실현에 관한 연구를 수행하였다. 컴퓨터 시물레이션으로 실현성을 확인하였으며, 기존의 대표적 비트 동기화 방식인 maximum likelihood 추정 이론에 근거한 DTTL(digital data transition tracking loop)와 그리고 minimum likelihood 추정 기법에 근거한 방식과의 추정 오차성능을 비교 평가하였다.

• 한국추진공학회지
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• 제24권4호
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• pp.1-11
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• 2020

본 연구에서는 추진제 연소면적을 조절하여 이중추력 프로파일을 구현하는 단일연소관 이중추력 로켓모터의 내탄도성능 분석 방법을 제시한다. 천이 구간에서의 연소속도 보정계수 및 비추력의 점진적 변화를 고려하며 성능 예측에 필요한 변수를 획득할 수 있는 분석법을 제시하고, 해당 분석법을 적용한 결과와 천이 구간 내 변화를 고려하지 않는, 기존 연구의 분석법을 적용한 결과를 비교함으로써 새로 제시하는 분석법에서 개선된 부분을 확인한다. 추진제 초기 온도 또는 배치 조건이 다른 네 가지의 시험 조건에 대하여 제시하는 분석법을 이용해 내탄도 변수를 획득하고, 이를 이용하여 각 시험 조건별로 성능 예측을 수행한다. 해당 예측 결과는 실제 연소시험 결과와 잘 일치하며, 따라서 본 연구의 분석법을 기반으로 설계 형상이 동일한 이중추력 모터의 성능 예측이 가능함을 확인할 수 있다.

• 대한전기학회논문지:전기기기및에너지변환시스템부문B
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• 제54권10호
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• pp.470-476
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• 2005

In this paper PU control scheme is presented. The proposed scheme has following features. The one is oft-starting method which is used for preventing to flow large current in motor phase winding when motor starts. The ther is the selection of the level of the over current. The first feature is implemented by increasing the PWM duty lowly, the second feature is implemented by limiting the magnitude of the phase current level by which the over heat f motor by copper losses and magnetic saturation decreases. By the analysis using FEM considering load condition, the peed of mode transition from PW to single pulse control is selected and confirmed by simulation that there is no ver current occurs during the mode transition. For the verification of proposed scheme, the simulation using MATLAB Simulink with considering non-linearity of inductance profile from FEM analysis is performed and the experiment with SRM drive system which has the DSP controller and single Phase SRM are peformed.

• 암석학회지
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• 제3권1호
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• pp.34-40
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• 1994

High pressure X-ray diffraction study was carried out on a graphite to investigate its compressibility as well as any possible phase transition to the hexagonal diamond structure at room temperature. Energy dispersive X-ray diffraction method was introduced using a Mao-Bell type diamond anvil cell with Synchrotron Radiation. Polycrystalline sodium chloride was compressed together with graphite for the high pressure determinations. Because of the poor resolution of the X-ray diffraction pattern of graphite, its compressibility was estimated to be almost same as that of NaCl by graphite (002) X-ray diffraction peak only. An observation of any new peak from a possible hexagonal diamond phase seems very unplausible for its definite identification based on the present data. Alternative approaches such as an Wiggler Radiation source as well as a Large Volume high pressure apparatus will be necessary for the detailed studies on a graphite in future.