• 제목/요약/키워드: Phase transfer

검색결과 1,999건 처리시간 0.031초

초소형 촉매 이상 분해 반응기 해석 모델 개발 (Development of Analysis Model for Down Scaled Two Phase Catalytic Reactor)

  • 이대훈;권세진
    • 대한기계학회논문집B
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    • 제28권1호
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    • pp.24-30
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    • 2004
  • Analysis model for the two-phase catalytic reactor is presented. With the progress in development of micro thermofluidic devices, needs fur understanding of the phenomena in two phase reaction in cm scale has been arisen. To investigate thermal and reactive performance of down scaled two phase reactor simple analysis model that is a kind of lumped flow model is proposed. Analysis model presented is based on the experiment on mm scale model reactor. Target experiment is catalytic decomposition of 70wt% hydrogen peroxide with existence of perovskite L $a_{0.8}$S $r_{0.2}$Co $O_3$ catalyst. It is composed of balance equations of mass and energy. Each phase is considered to be a species fur the simplicity. Axial diffusion and transversal distribution of properties are neglected. Two phase catalytic reaction is modeled as successive gasification of liquid lump around catalyst and reaction in gas phase. Heat transfer is modeled by model function ofNu number. Modeled Nu is expressed as Nu=N $u_{0}$ (1+ $a_1$( $a_2$ $T^{-}$ $a_3$)exp( $a_4$ $T^{-1}$)exp( $a_{5}$ z). Transfer coefficients are determined by the comparison of experimental results. With the model, heat transfer characteristics are investigated. Also by the mass transfer coefficient, characteristics in mass transfer is investigated. With the result basic understanding on design and analysis of mm scale two-phase reactive device is obtained. Also it can be further applied to micro scale reactive device fabricated by micromachining.ing..

Relationships between Biodegradation and Sorption of Phenanthrene in Slurry Bioremediation

  • 우승한;박종문
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2000년도 추계학술대회
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    • pp.171-176
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    • 2000
  • Bioremediation of hazardous hydrophobic organic compounds, such as polycyclic aromatic hydrocarbons (PAHs), is a major environmental concern due to their toxic and carcinogenic properties. Due to their hydrophobicity, the hydrophobic organic compounds are mainly associated with the soil organic matter or nonaqueous-phase liquids. A major question concerns the relationships between biodegradation and sorption. This work develops and utilizes a non- steady state model for evaluating the interactions between sorption and biodegradation of phenanthrene, a 3-ring PAH compound, in soil-slurry systems. The model includes sorption/desorption of a target compound, its utilization by microorganisms as a primary substrate existing in the dissolved phase and/or the sorbed phase in biomass and soil, oxygen transfer, and oxygen utilization as an electron acceptor. Biodegradation tests with phenanthrene were conducted in liquid and soil-slurry systems. The soil-slurry tests were performed with very different mass transfer rate: fast mass transfer in a flask test at 150 rpm, and slow mass transfer in a roller-bottle test at 2 rpm. In the slurry tests, phenanthrene was degraded more rapidly than in liquid tests, but with a similar rate in both slurry systems. Modeling analyses with several hypotheses indicate that a model without biodegradation of compound sorbed to the soil was not able to account for the rapid degradation of phenanthrene, particularly in the roller bottle slurry test. Reduced mass-transfer resistance to bacteria attached to the soil is the most likely phenomenon accounting for rapid sorbed-phase biodegradation.

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Analysis of Optical Transfer Function and Phase Error of the Modified Triangular Interferometer

  • 김수길;염정덕
    • 조명전기설비학회논문지
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    • 제21권1호
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    • pp.10-18
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    • 2007
  • We synthesize and analyze the optical transfer function(OTF) of the modified triangular interferometer(MTI) using two-pupil synthesis method and we present the optimal MTI, which can obtain any bipolar function by combining a wave plate and a linear polarizer. Also, we analyze its potential phase error sources caused by polarization components.

Long Chain Dicationic Phase Transfer Catalysts in the Condensation Reactions of Aromatic Aldehydes in Water Under Ultrasonic Effect

  • Esen, Ilker;Yolacan, Cigdem;Aydogan, Feray
    • Bulletin of the Korean Chemical Society
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    • 제31권8호
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    • pp.2289-2292
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    • 2010
  • Long chain dicationic ammonium salts were used successfully as phase transfer catalyst in the condensation reactions of aromatic aldehydes in water under ultrasonic irradiation for the first time. The quaternary salt having longer distance between the cation centers was more effective than the mono- and dicationic ones having short chain.

혼종 모형을 이용한 간호 학습전이의 개념 분석 (A Concept Analysis on Learning Transfer in Nursing Using the Hybrid Model)

  • 손해경;김효진;김동희
    • 한국직업건강간호학회지
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    • 제29권4호
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    • pp.354-362
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    • 2020
  • Purpose: This study aimed to define and clarify learning transfer in nursing. Methods: This study used a hybrid model to analyze the concept of learning transfer in nursing through three phases. For the theoretical phase, learning transfer attributes were identified through a scoping literature review. In the fieldwork phase, in-depth focus group interviews were conducted to develop attributes. Purposive sampling was performed with ten participants(five nursing students, two nurses, three nursing faculty members). In the analysis phase, the attributes and final analysis of learning transfer in nursing were extracted and integrated from the previous two phases. Results: According to the analysis, learning transfer was represented in two dimensions with eight attributes. The development of competency dimension had three attributes: 1) theory acquisition, nursing skills, professional attitude, 2) integration, and 3) analysis competency. The competency change dimension had five attributes: 1) appropriateness in patient care, 2) proficiency in patient care, 3) satisfaction, 4) achievement, and 5) confidence. Conclusion: The concept analysis might provide a basic understanding of learning transfer, a development framework toward a measurement of nursing learning transfer and effective educational nursing strategies.

루우프형 2상 유동 열사이폰의 비등열전달 특성에 관한 연구 (A Study on the Characteristics of Boiling Heat Transfer of Two-Phase Loop Thermosyphons)

  • 조동현
    • 수산해양교육연구
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    • 제26권3호
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    • pp.639-646
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    • 2014
  • A heat exchanger using two-phase loop thermosyphons was developed as a waste heat recovery system. An experimental study was carried out on the heat transfer characteristics of two-phase loop thermosyphons heat exchanger and the results from the experiments were used to see the possibility which the two-phase loop thermosyphons could be an alternate solution for waste heat recovery system. In the present work, R134a has been used as the working fluid and the filling rate do working fluid and heat flux have been used as the experimental parameters. The results show that the filling rate of working fluid and heat flux are very important factors for the operation of two-phase loop thermosyphons. The experimental results showed the provisional results as a waste heat recovery system.

세관 내 액단상 열전달 및 압력강하 특성에 관한 연구 (Study on the Single-Phase Heat Transfer and Pressure Drop Characteristics of R-718 in Small Diameter Tubes)

  • 홍진우;정재천;김종렬;노건상;구학근;오후규
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.425-432
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    • 2001
  • Single-phase heat transfer coefficients and pressure drops of R-22 were measured in smooth, horizontal copper tubes with inner diameters of 3.36 mm, 5.35 mm, 6.54 mm and 8.12 mm, respectively. The experiments were conducted in the closed loop, which was driven by a magnetic gear pump. Data are presented for the following range of variables: Reynolds from 1000 to 20000. Single-phase heat transfer coefficients increased by $10{\sim}30%$ as the inner diameter of tube was reduced and it was found that a well-known previous correlation, Gnielinski's correlation, was not suitable for the small diameter tubes. But the pressure drop in the small diameter tubes have been shown slightly deviations with Blauius' correlation. Based on an analogy between heat and mass transfer, the new heat transfer correlation is proposed to predict the experimental data successfully.

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파라핀 슬러리의 생성 및 관내 대류열전달에 관한 연구 (Formation of a paraffin slurry and its convective heat transfer in a circular pipe)

  • 최은수
    • 대한기계학회논문집B
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    • 제22권1호
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    • pp.50-60
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    • 1998
  • As a method to develop an enhanced heat transfer fluid, the fine particles of a phase-change material were mixed with a conventional heat transfer fluid. Paraffin, which can be obtained easily in domestic market, was used for the phase-change material and water was used as a carrier fluid. Fine liquid particles of paraffin were formed in water as an emulsion by using an emulsifier, and they were cooled rapidly to become solid particle, resulting in paraffin slurry. The average diameter of produced solid particles was inversely proportional to the amount of the added emulsifier, which was theoretically proved. The produced paraffin slurry was tested thermally in heat transfer test section having a constant-heat-flux boundary condition. The test section was made of a circular stainless-steel pipe, which was directly heated by the power supply having a maximum of 50 Volts-500 Amperes. DSC(Differential scanning calorimeter) tests showed that two kinds of phase change were involved in the melting of paraffin, and it was explained in two different ways. A five- region-melting model was developed by extending the conventional three-region-melting model, and was used to obtain the local bulk mean temperatures of paraffin slurry in the heating test section. The local heat transfer coefficient showed a maximum where the bulk mean temperature of the paraffin slurry reached at the melting temperature of paraffin.

A Study on the Boiling Heat Transfer Characteristics Using Loop Type Thermosyphon

  • HAN, Kyu-il;CHO, Dong-Hyun
    • 수산해양기술연구
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    • 제52권3호
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    • pp.257-262
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    • 2016
  • Flexible two-phase thermosyphons are devices that can transfer large amounts of heat flux with boiling and condensation of working fluid resulting from small temperature differences. A flexible two-phase thermosyphon consists of a evaporator, an insulation unit, and a condenser. The working fluid inside the evaporator is evaporated by heating the evaporator in the lower part of the flexible two-phase thermosyphon and the evaporated steam rises to the condenser in the upper part to transfer heat in response to the cooling fluid outside the tube. The resultant condensed working fluid flows downward along the inside surface of the tube due to gravity. These processes form a cycle. Using R134a refrigerant as the working fluid of a loop type flexible two-phase thermosyphon heat exchanger, an experiment was conducted to analyse changes in boiling heat transfer performances according to differences in the temperature of the oil for heating of the evaporator, the temperature variations of the refrigerant, and the mass flows. According to the results of the present study, the circulation rate of the refrigerant increased and the pressure in the evaporator also increased proportionally as the temperature of the oil in the evaporator increased. In addition, the heat transfer rate of the boiler increased as the temperature of the oil in the evaporator increased.

헬리컬 증기발생기 코일에서 강제대류 비등 열전달 및 유동의 수치 적 예측 (Numerical Prediction of Forced Convective Boiling Heat Transfer and Flow in Steam Generator Helical Coils)

  • 조종철;김효정;김웅식;유선오
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2004년도 추계 학술대회논문집
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    • pp.127-130
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    • 2004
  • In this study, three-dimensional numerical calculations are peformed to simulate the flow and heat transfer in helically coiled tube steam generator employing a commercial CFD (Computational Fluid Dynamics) code. The problem considered herein includes the boiling phase change flow of tube side fluid and the single-phase counter-current flow of shell side hot fluid transferring heat to the tube side flow thru the tube wall. Detailed investigations are performed for both shell-side and tube-side flow fields in terms of density and volume fractions of each phase of fluids as well as for the tube wall heat transfer field in terms of heat transfer coefficients.

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