• 제목/요약/키워드: Phase transfer

검색결과 2,001건 처리시간 0.031초

고온의 기포접촉에 의한 에탄올 회수공정에 관한 연구 (Study on the Ethanol Recovery Process using Dircet Contact Heat Exchange)

  • 이원영;여상도;최용희
    • 한국식품과학회지
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    • 제27권2호
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    • pp.176-180
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    • 1995
  • 고온의 기포를 액상에 분산시켜 형성되는 기-액상간의 온도구배로 인한 열 및 물질전달 방법인 고온기포접촉법을 도입하여 수용액으로부터 에탄올의 분리능력을 검토하고 회수율을 살펴보았다. 기포의 높은 분산속도는 액상내에서 jet regime을 형성하였으며 온도와 유속에 따라 air-water stripping coefficient는 각각 $5{\sim}10,\;1{\sim}1.5$배 증가하였다. 액상과 기포의 온도차가 클수록 stripping coefficient의 값이 높았으며 유속보다는 온도가 분리능력에 더 큰 영향을 미치는 것으로 나타났다. 회수율은 고온일 때와 유속이 클수록 증가해 $150^{\circ}C$, 84.88m/min 일때 80%의 회수율을 나타내었다. 고온기포접촉법은 stripping coefficient가 에탄올의 초기농도에 큰 영향을 받지 않으므로, 알코올 발효공정에서 배양액의 농도가 5% 이상 높아지면 알코올 생성균주의 생장장해를 일으켜 알코올 생산 수율이 떨어지는 생산물 저해작용을 줄이고 알코올을 회수하는 공정으로 응용될 수 있다.

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Study on the Systematic Technology of Promoting Purification for the Livestock Wastewater and Reuse

  • Okada, Yoshiichi;Shim, Jae-Do;Mitarai, Masahumi;Kojima, Takayuki;Gejima, Yoshinori
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 1996년도 International Conference on Agricultural Machinery Engineering Proceedings
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    • pp.692-700
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    • 1996
  • The objective of this study is to develop a systematic purification plant using the metabolism of aerobic microorganisms. This system is subsequently aerated and continuously removes suspended solids and settling sludges caused by aerating pressure at the bottom of a lower pipe (i.e., Continuous Removal of Suspended solids and Settling sludges, CRSS). The CRSS plants are brought out by introducing fine air bubbles into the liquid phase of a lower pipe in the bio-reactor. These plant uses aeration pipe, with multiple inlets to sweep the floor of bio-reactor tank, instead of the conventional scraper mechanisms. The principal advantage of this system is that it can continuously remove very small or light particles that settles completely within a short time. Once the particles have been floated to the surface, they can be moved into the pipe and collected in the settling tank by sequently aerated pressure. The experimental results shows that about 99.0% of the biochemical oxygen demand(BOD), 99.3% of the suspended solid(SS), 92.3% of the total nitrogen(T-N), 99.0% of the turbidity(TU), 100% of the total coliform(TC)and ammonia was respectively removed during aerobic digestion for 9 days. These result indicates that the CRS S plants are very effective for reduction and deodorization of swine wastewater contaminants, and the efflux from CRS S can either be discharged in the river or used as nutrient solution of formulation for plant growth factories. The developed CRSS plant proved to be flexible and it can simply be adapted to any type of biological waste treatment problem.roblem.

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전산유체해석기법을 이용한 용존공기부상공정의 유동해석 (Simulation study of DAF flotation basin using CFD)

  • 박병성;우성우;박성원;민진희;이우녕;유수남;전갑진
    • 상하수도학회지
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    • 제27권2호
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    • pp.261-272
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    • 2013
  • Algae boom (Red tide) in south coastal area of Korea has been appeared several times during a decade. If algae boom appears in the desalination plant, media filter and UF filter are clogged quickly, and the plant should be shutdown. In general, Algae can be removed from water by flotation better than by sedimentation, because of the low density of algal cell. The purpose of this study conducts the CFD simulation of DAF flotation basin to apply the design of the dissolved air flotation with ball filter in the Test Bed for SWRO desalination plant. In this study, Eulerian-Eulerian multiphase model was applied to simulate the behavior of air bubbles and seawater. Density difference model and gravity were used. But de-sludge process and mass transfer between air bubbles and seawater were ignored. Main parameter is hydraulic loading rate which is varied from 20 m/hr to 27.5 m/hr. Geometry of flotation basin were changed to improve the DAF performance. According to the result of this study, the increase of hydraulic loading rate causes that the flow in the separation basin is widely affected and the concentration of air is increased. The flow pattern in the contact zone of flotation basin is greatly affected by the location of nozzle header. When the nozzle header was installed not the bottom of the contact zone but the above, the opportunity of contact between influent and recycle flow was increased.

일회용 전기화학적 에탄올 센서 (Disposable Type Electrochemical Ethanol Sensor)

  • 김문환;유재현;오현준;차근식;남학현;박성우;김영만
    • 분석과학
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    • 제12권3호
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    • pp.218-223
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    • 1999
  • 스크린 프린팅 기술을 이용하여 일회용 에탄올 센서를 개발하고 전기화학적 방법으로 그 성능을 조사하였다. 일회용 에탄올 센서는 폴리에스테르 기질 위에 탄소와 은 반죽 그리고 절연체 잉크로 작업 및 기준전극의 감응부위와 전기적 접촉부위의 형상을 차례로 인쇄한 후 알코올탈수소효소(ADH) 또는 알코올산화효소(AOD)를 알려진 전자전달 매개체(mediator)와 함께 작업전극에 고정시켜 제작하였다. 일회용 센서의 제작 과정에서 감응도와 재현성을 높이기 위하여 프린팅한 탄소 작업전극을 전처리 하는 몇 가지 방법들을 적용하고 그 결과들을 비교하였다. 제작된 일회용 센서는 소량의 혈액시료로 음주측정을 하는데, 그리고 발효공정 제어 등에 유용하게 사용될 수 있다.

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습식 교반 및 방전 플라즈마 소결 공정에 의한 CNT 분산 Cu 복합재료 제조 (Fabrication of CNT dispersed Cu matrix composites by wet mixing and spark plasma sintering process)

  • 조승찬;조일국;이상복;이상관;최문희;박재홍;권한상;김양도
    • 한국분말재료학회지
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    • 제25권2호
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    • pp.158-164
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    • 2018
  • Multi-walled carbon nanotube (MWCNT)-copper (Cu) composites are successfully fabricated by a combination of a binder-free wet mixing and spark plasma sintering (SPS) process. The SPS is performed under various conditions to investigate optimized processing conditions for minimizing the structural defects of CNTs and densifying the MWCNT-Cu composites. The electrical conductivities of MWCNT-Cu composites are slightly increased for compositions containing up to 1 vol.% CNT and remain above the value for sintered Cu up to 2 vol.% CNT. Uniformly dispersed CNTs in the Cu matrix with clean interfaces between the treated MWCNT and Cu leading to effective electrical transfer from the treated MWCNT to the Cu is believed to be the origin of the improved electrical conductivity of the treated MWCNT-Cu composites. The results indicate the possibility of exploiting CNTs as a contributing reinforcement phase for improving the electrical conductivity and mechanical properties in the Cu matrix composites.

Pd/C촉매하 파라니트로아닐린 수소첨가에 의한 고순도 파라페닐렌디아민의 합성공정 (Synthesis of High Purity p-Phenylenediamine from p-Nitroaniline by Catalytic Hydrogenation)

  • 조철군;정광보
    • 공업화학
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    • 제10권8호
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    • pp.1210-1215
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    • 1999
  • Pd/C촉매가 부유되어 있는 3상 슬러리 반응기에서 원료 p-nitroaniline(PNA)를 수소 첨가시켜 고순도의 p-phenylenediamine(PPD)를 합성하는 최적 반응조건을 구하였다. 수소첨가 반응시 활성점에서 수소부족을 줄이고 불순물의 생성을 감소시킬 수 있도록, 기체-액체, 액체-촉매사이의 물질전달 저항을 최소화하고 표면반응속도가 율속할 수 있게 반응조건을 설정하였다. 이 반응조건은 온도 $60^{\circ}C$, 압력 60~70 psig, 촉매농도 1~2 g-cat/L일 때가 최적이었으며, 반응속도는 PNA 농도에 0차, 수소 반응압력에 1차를 각각 보여주었으며, 총괄반응속도식은 $R_A=6.44{\times}10^6{\cdot}H{\cdot}P{\cdot}m{\cdot}$exp(-4659/T)로 나타났다.

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메탄올-글리세린계를 작동유체로 하는 흡수열펌프에서 흡수기 연구 (A Study on Absorber in Absorption Heat Pump with Methanol-Glycerine System as a Working Fluid)

  • 민병훈
    • 공업화학
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    • 제17권1호
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    • pp.111-117
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    • 2006
  • 냉 난방 수요에서 일어나는 환경오염의 최소화와 화석연료 소비를 감소시키기 위해서 에너지보존을 개선시키는 것은 필수적이다. 이러한 점에서 흡수식 열펌프기술은 에너지 절약을 위해서 많은 가능성을 가지고 있다. 흡수식 열펌프는 에너지를 주입하지 않고 폐열의 이용을 높일 수 있는 방법이다. 흡수식 열펌프는 흡수기에서 흡수된 양의 증가가 매우 중요하기 때문에 흡수기 성능이 매우 중요하다. 본 연구에서는 흡수기의 성능을 개선시키기 위해서 메탄올과 글리세린을 작동유체로 하는 두 종류의 흡수기에 관한 연구를 수행하였다. 전자는 흡수기 내에 액상을 접선방향으로 공급하는 것이고 후자는 흡수기 내벽에 나선형 관을 설치하여 액상을 접선방향으로 공급하는 것이다. 실험 결과 후자가 흡수기에서 발생하는 열 및 물질전달이 향상되어 흡수성능이 증가되었음을 알 수 있었다.

체외수정시술을 위한 성선자극호르몬 과배란유도에 Poor Response를 나타낸 환자에서 GnRH Analogue의 사용 (GnRH Analogue in Controlled Ovarian Hyperstimulation for Gonadotropin Poor Responder)

  • 김선행;이희경;구병삼
    • Clinical and Experimental Reproductive Medicine
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    • 제20권1호
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    • pp.37-43
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    • 1993
  • In 27 patients with the past history of poor response to the gonadotropin superovulation induction due to poor follicular growth or permature surge of endogenous luteinizing hormone, the effectiveness of pituitary supperssion with the gonadotropin releasing hormone agonist(GnRH-a) in in vitro fertilization(IVF) program was evaluated in 43 cycles using a combination regimen of D-Trp-6 LHRH(Decapeptyl, Ferring)and FSH/hMG from June, 1989 to August, 1990 at Korea University Hospital IVF Clinic. At midluteal phase of menstrual cycle, Decapeptyl-CR was administered by long-term protocol to minimize initial agonistic effect of endogenous gonadotropins. After the confirmation of pituitary suppression, about 2-3 weeks after GNRH-a administration, ovarian follicle growth was stimulated with FSH/hMG and followed by transvaginal ultrasonic measurement of follicle size and by monitoring of serm E2 and LH if necessary. When compared with the control group stimulated with gonadotropin regimen only, the cancellation rate and occurrence rate of premature LH surge during gonadotropin treatment were significantly lower in study group(11.6% and 2.4%, respectively). There is no significant differences in the mean number of aspirated oocytes, fertilization/cleavage rate, embryo transfer(ET) rate, and mean number of embryos transferred between the two groups. The pregnancy rate per treatment cycle, 16.3%, and per ET cycle, 23.3%, were significantly higher in the study group compared with those of control group. These data suggest that GnRH-a therapy is effective for previous poor responder In gonadotropin superovulation induction for IVF.

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Instrumentation and system identification of a typical school building in Istanbul

  • Bakir, Pelin Gundes
    • Structural Engineering and Mechanics
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    • 제43권2호
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    • pp.179-197
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    • 2012
  • This study presents the findings of the structural health monitoring and the real time system identification of one of the first large scale building instrumentations in Turkey for earthquake safety. Within this context, a thorough review of steps in the instrumentation, monitoring is presented and seismic performance evaluation of structures using both nonlinear pushover and nonlinear dynamic time history analysis is carried out. The sensor locations are determined using the optimal sensor placement techniques used in NASA for on orbit modal identification of large space structures. System identification is carried out via the stochastic subspace technique. The results of the study show that under ambient vibrations, stocky buildings can be substantially stiffer than what is predicted by the finite element models due to the presence of a large number of partitioning walls. However, in a severe earthquake, it will not be safe to rely on this resistance due to the fact that once the partitioning walls crack, the bare frame contributes to the lateral stiffness of the building alone. Consequently, the periods obtained from system identification will be closer to those obtained from the FE analysis. A technique to control the validity of the proportional damping assumption is employed that checks the presence of phase difference in displacements of different stories obtained from band pass filtered records and it is confirmed that the "proportional damping assumption" is valid for this structure. Two different techniques are implemented for identifying the influence of the soil structure interaction. The first technique uses the transfer function between the roof and the basement in both directions. The second technique uses a pre-whitening filter on the data obtained from both the basement and the roof. Subsequently the impulse response function is computed from the scaled cross correlation between the input and the output. The overall results showed that the structure will satisfy the life safety performance level in a future earthquake but some soil structure interaction effects should be expected in the North South direction.

핵 연료봉 지지격자에 의한 Droplet Breakup Model의 RELAP5 / MOD2 삽입 (Incorporation of Droplet Breakup Model at Spacer Grid into RELAP5/ MOD2)

  • Park, Jong-Ho;Lee, Sang-Yong;Kim, Si-Hwan;Chang, Soon-Heung
    • Nuclear Engineering and Technology
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    • 제22권4호
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    • pp.326-336
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    • 1990
  • 최근 수행된 일련의 실험들을 통하여 핵연료 집합체 지지격자(Spacer Grid)의 존재가 냉각재상실사고시에 핵연료봉으로부터의 열제거에 긍정적인 효과를 미치고 있음이 밟혀졌다. 그 이유는 열원이 없는 지지격자가 연료봉보다 먼저 ?칭이 일어나며 물방울이 지지격자에 부딪쳐서 잘게 부수어져 증발이 쉽게 일어나게 되고 또한 난류효과를 증대시키는 요인이 되기 때문이다. 따라서 냉각재상실사고의 진행 과정에서 첨두피복관온도가 발생하는 재관수 구간의 수면 위쪽에서 유지되는 DFFB에서의 정확한 열전달을 계산하기 위해서는 이들의 고려가 필요하다. 본 논문에서는 DFFB에서 지지격자의 존재로 인해 물방울이 잘게 부수어져 증발이 쉽게 이루어지도록 하는 Droplet Breakup Model을 냉각재상실사고 최적해석 코드인 RELAP5/MOD2에 삽입하였다. 재관수 구간에서 지지격자의 영향을 체계적으로 조사한 FEBA실험에 대해서 검증계산을 수행하여 실험자료와 비교하였다.

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