• Title/Summary/Keyword: Phase stability

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Influence of CuO Dopants on the Sintering Ability and Phase Stability of Yttria-Stabilized Tetragonal Zirconia Polycrystals (Y-TZP의 燒結性 및 相 安定性에 대한 CuO添加의 影響)

  • Pee, Jae-Hwan;Kim, Yun-Hae;Motozo Hayakawa
    • Journal of Ocean Engineering and Technology
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    • v.13 no.2 s.32
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    • pp.35-40
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    • 1999
  • Effects of CuO addition on the sintering ability and the phase stability of Y-TZP. (Yttria doped Tetragonal Zirconia Polycrystals) were studied. The CuO dopants were found to be quite effective in reducing the sintering temperature to obtain full density and refining the grain size. The maximum allowable concentration of the dopants was limited to 0.3%mol% for CuO to maintain fully tetragonal phase. With the addition of these dopants, the flexual strength decreased by 20% in comparison with the undoped specimen but the fracture toughness increased by 15%.

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Phase stability and Morphology of high-k gate stack of $Si/SiO_2/HfO_2$ and $Si/SiO_2/ZrO_2$

  • Lee, Seung-Hwan;Bobade, Santosh M.;Yoo, W.J.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.118-119
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    • 2007
  • Phase stability and morphological investigation on the $Si/SiO_2/HfO_2$ and $Si/SiO_2/ZrO_2$ stack are presented. Thermal stability of $HfO_2$ and $ZrO_2$ determines the quality of interface and subsequently the performance of device. The stacks have been fabricated and annealed at $1000^{\circ}C$ for various time. In evolution of crystalline phase and morphology (electrical and geometrical) of high-k materials, annealing time and process are observed to be crucial factors. The crystallization of some phase has been observed in the case of $Si/SiO_2/HfO_2$. The chemical environment around Zr and Hf in respective samples is observed to be different.

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Effect of Annealing Temperature on Phase-change Characteristics of GeSbTe-based Bilayers (GeSbTe계 이중층의 상변화 특성에 미치는 열처리 온도 효과)

  • Yoon, Hoi Jin;Bang, Ki Su;Lee, Seung-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.2
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    • pp.86-90
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    • 2017
  • This work reports the phase-change behavior and thermal stability of doped GeSbTe/GeSbTe bilayers. We prepared the bilayers using RF sputtering, and annealed them at annealing temperature ranging from $100^{\circ}C$ to $400^{\circ}C$. The sheet resistance of the bilayer decreased and saturated with increasing annealing temperature, and the saturated value was close to that of pure GeSbTe film. The surface of the bilayer roughened at $400^{\circ}C$, which corresponds to the surface roughening of doped GeSbTe film. Mixed phases of face-centered cubic and hexagonal close-packed crystalline structures were identified in the bilayers annealed at elevated temperature. These results indicate that the phase-change behavior of the bilayer depends on the concurrent phase-transitions of the two GeSbTe-based films. The dopants in the doped GeSbTe film were diffused out at annealing temperatures of $300^{\circ}C$ or higher, which implies that the thermal stability of the bilayer should be considered for its application in phase-change electronic devices.

Phase Inversion Emulsification and Enhancement of Physical Properties for Cationic Emulsified Asphalt

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.265-273
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    • 2015
  • In this work, the emulsified asphalt with high phase stability and storage stability was prepared by using phase inversion emulsification and the surfactant mixed with cationic and nonionic surfactants. It was found that the asphalt together with Span 20, nonionic surfactant and DDA (Dimethyl Dodecyl Amine), cationic surfactant showed the most stable phase. The phase stability of the emulsified asphalt, therefore, was investigated through the particle size with mixed surfactant content, rheology behavior and Zeta potential value; the particle size decreased with the increase of the mixed surfactant content but the viscosity increased. The shear thinning behaviors and the Zeta potential value with 50 mV~60 mV were shown, which was found to be considered stable. In addition, SBR latex(Styrene-butadiene-rubber) and water dispersed Epoxy (EPD) were used to enhance the physical properties of the emulsified asphalt. The swelling and adhesion features of the emulsified asphalt were also studied with $CaCO_3$, Silica, and Montmorillonite (MMT). It was shown that the addition of SBR latex and MMT can be another way to improve the physical properties of the emulsified asphalt in that the lowest swelling feature was found.

Improvement of Synchronous Motor Transient Stability by Phase Slipping (상변위에 의한 동기전동기의 과도안정도 개선)

  • Song Yop Hahn
    • 전기의세계
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    • v.21 no.2
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    • pp.20-24
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    • 1972
  • The transient stability of the synchronous motor is generally improved by damper winding or flywheel. However the synchronous motor at full load will be pulled out from normal operation state when the period of power failure exceeds approximately ten cycle per second. This paper studies the method of improving the stability of synchronous motor by equipping the phase slipping switch between the motor and power source. This paper shows the motor does not pull out, which results from the decrease of power angle to about 30 electrical degrees by means of the switch even when the relatively long period of power failure brings the power angle to some 150 electrical degrees.

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Variation of Dielectric Properties and Phase Stabilities with Substitution of A-Site in $Pb(Zn_{0.6}Mg_{0.4})_{1/3}Nb_{2/3}O_3$[PZMN] System ($Pb(Zn_{0.6}Mg_{0.4})_{1/3}Nb_{2/3}O_3$ [PZMN] 계에서 A-자리 치환에 따른 상안정화 및 유전 특성 변화)

  • 김봉철;김정주;김남경;조상희
    • Journal of the Korean Ceramic Society
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    • v.33 no.10
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    • pp.1131-1137
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    • 1996
  • The dielectric properties and phase stabilities of Pb(Zn0.6Mg0.4)1/3Nb2/3O3 [PZMN]system were investigated into substitution of A-site with Ba, Sr and Ca ions. The A-site substitutions led to the complexity of components of perovskite phase and then DPT coefficient increased. The A-site substitutions of Ba or Sr ion perovskite single phase could be easily formed by columbite process due to increase of perovskite phase stability. The variation of lattice parameters in specimen obeyed Vegard's law and curie temperature and dielectric constant of specimen decreased linearly. But Ca substitution led to perovskite phae instability. The lattice parameter dielectric constant and curie temperature of specimens drasticaly decreased with formation of pyrochlore phase.

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Factor Analysis of the Somatosensory for Foot according to the Instability Level of Snatch Lifting (역도 인상동작 불안정성 수준에 따른 발바닥 체성감각요인 분석)

  • Moon, Young Jin
    • Korean Journal of Applied Biomechanics
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    • v.30 no.1
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    • pp.7-16
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    • 2020
  • Objective: It is to find factors related to stability through analysis of plantar pressure factors according to the level of instability when performing Snatch. Method: Foot pressure analysis was performed while 10 weightlifters performed 80% of the highest level of Snatch, and motion was classified and analyzed in 3 grades according to the level of instability. Results: First, in Bad Motion, the movement distance of the pressure center in the direction of ML and AP was larger significantly in Phase 2. Second, in Phase 2, the number of zero-crossing in the AP direction was larger statistically significantly in Good Motion. Third, in the bad motion in Phase 3, the number of zero-crossing in the ML direction showed a significantly larger value. Fourth, in Phase 4, it was found that the more stable the lock out motion, the greater the activity of foot controlling in the left and right directions. Fifth, Phase 3, the greater the Maximum/Mean foot pressure value, the more stable the pulling action. Sixth, in Phase 2, the foot pressure was concentrated with a wide distribution in the midfoot and rearfoot. Seventh, the triggering number of the forefoot region was small in the last pull phase. Eighth, the number of triggers in the toe area was significantly higher during Good Motion in Phase 4. Conclusion: Summarizing the factors of instability in Snatch, there was no significant difference in Phase 1 for each condition. In order to enhance the stability in Phase 2, the sensory control ability in the AP direction is required, and focusing the foot pressing motion with a wide distribution in the middle and rear parts increases the instability. In Phase 3, it was found that the more unstable, the more sensory control activity was performed in the ML direction, the stronger the forefoot pressing action should be performed for a stable Snatch. In Phase 4, It is important that the feet sensory control activity in ML directions and the control ability of the toes in order to have stable Lock out motion.

Solid-liquid phase equilibria on the GdBa2Cu3O7-δ stability phase diagram in low oxygen pressures (1 - 100 mTorr)

  • Lee, J.W.;Lee, J.H.;Moon, S.H.;Yoo, S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.4
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    • pp.28-31
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    • 2012
  • We report the solid-liquid phase equilibria on the $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) stability phase diagram in low oxygen pressures ($PO_2$) ranging from 1 to 100 mTorr. On the basis of the GdBCO stability phase diagram experimentally determined in low oxygen pressures, the isothermal sections of three different phase fields on log $PO_2$ vs. 1/T diagram were schematically constructed within the $Gd_2O_3-Ba_2CuO_y-Cu_2O$ ternary system, and the solid-liquid phase equilibria in each phase field were described. The invariant points on the phase boundaries include the following three reactions; a pseudobinary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3$ + liquid ($L_1$), a ternary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3+GdBa_6Cu_3O_y$ + liquid ($L_2$), and a monotectic reaction of $L_1{\leftrightarrow}GdBa_6Cu_3O_y+L_2$. A conspicuous feature of the solid-liquid phase equilibria in low $PO_2$ regime (1 - 100 mTorr) is that the GdBCO phase is decomposed into $Gd_2O_3+L_1$ or $Gd_2O_3+GdBa_6Cu_3O_y+L_2$ rather than $Gd_2BaCuO_5+L$ well-known in high $PO_2$ like air.

The Effect of Pelvic Stability Exercise Program on Pain and Hip Joint of Patients with Chronic Low Back Pain involving Sacroiliac Joint Pain (골반안정화 운동프로그램이 엉치엉덩관절 통증을 동반한 만성요통환자의 통증과 엉덩관절에 미치는 영향)

  • Kang, Jeong-Il;Choi, Hyun
    • Journal of Digital Convergence
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    • v.11 no.4
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    • pp.331-338
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    • 2013
  • For this research, 27 out of 52 patients with chronic low back pain involving sacroiliac joint pain were classified into the experimental group to conduct pelvic exercise program and traditional physical therapies in parallel, and the remaining 25 ones were classified into the control group to only apply traditional physical therapies for 6 weeks. After that, their clinical samples were randomly extracted. Before the experiment, both of the experimental group and the control group had the Oswestry disability index test to see how big their pain was and their hip joint angles were analyzed during walking. After the post-test, finally, the results of the Oswestry disability index test and hip joint angles while walking before and after the experiment were compared between two groups to know the effect of pelvic stability exercise program. Within-group results and between-group results both displayed significantly reduced low back pain, and when comparing hip joint angles of the experimental group, there were differences between mid stance phase, terminal stance phase, pre swing phase and early swing phase of the right hip joint, and mid stance phase, terminal stance phase, pre swing phase and early swing phase of the left hip joint. In the control group, there were significant differences between mid stance phase, terminal stance phase and early swing phase of the right hip joint, and loading response phase, mid stance phase, terminal stance phase and pre swing phase of the left hip joint. as a result, pelvic stability exercise program is helpful to gait rhythm on stance phase and swing phase although effective to decrease Oswestry disability index including pain.

A Study on the Storage Stability of Waste Vinyl-Modified Asphalt (폐비닐로 개질된 아스팔트의 저장안정성에 관한 연구)

  • Kim, Kang-San;Hong, Young-Keun
    • Elastomers and Composites
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    • v.43 no.3
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    • pp.191-198
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    • 2008
  • It is said that polymer modified asphalt using polyethylene as modifier would show phase separation due to density difference and incompatibility between asphalt and polyethylene. In this study, to prevent coalescence of polyethylene in asphalt, we employed peroxides as phase separation inhibitor. On microscope, peroxides (dicumyl peroxide, lauroyl peroxide) with waste vinyl (comprising low density polyethylene) did not show phase separation, however, rheometer test showed phase separation at molecular level, i.e., polyethylene and asphalt are immiscible ultimately. Mechanical properties (tensile strength, Marshall stability, dynamic stability) showed waste vinyl-modified asphalts are highly resistant to plastic deformation and these properties are even better than those of Superphalt.