• 제목/요약/키워드: Phase diagram

검색결과 527건 처리시간 0.027초

강유전체 고분자의 음의 압전 물성 및 상공존경계(MPB)에 대한 고찰 (Perspective on Ferroelectric Polymers Presenting Negative Longitudinal Piezoelectric Coefficient and Morphotropic Phase Boundary)

  • 임성빈;부상돈;정창규
    • 한국전기전자재료학회논문지
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    • 제35권6호
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    • pp.523-546
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    • 2022
  • Morphotropic phase boundary (MPB), which is a special boundary that separates two or multiple different phases in the phase diagram of some ferroelectric ceramics, is an important concept in identifying physics that includes piezoelectric responses. MPB, which had not been discovered in organic materials until recently, was discovered in poly(vinylidene fluoride-co-trifluoroethylene (P(VDF-TrFE)), resulting from a molecular approach. The piezoelectric coefficient of P(VDF-TrFE) in this MPB region was achieved up to -63.5 pC N-1, which is about two times as large as the conventional value of -30 pC N-1 of P(VDF-TrFE). An order-disorder arrangement greatly affects the rise of the piezoelectric effect and the ferroelectric, paraelectric and relaxor ferroelectric of P(VDF-TrFE), so the arrangement and shape of the polymer chain is important. In this review, we investigate the origin of negative longitudinal piezoelectric coefficients of piezoelectric polymers, which is definitely opposite to those of common piezoelectric ceramics. In addition to the mainly discussed issue about MPB behaviors of ferroelectric polymers, we also introduce the consideration about polymer chirality resulting in relaxor ferroelectric properties. When the physics of ferroelectric polymers is unveiled, we can improve the piezoelectric and pyroelectric properties of ferroelectric polymers and contribute to the development of next-generation sensor, energy, transducer and actuator applications.

Crystal pulling법에 의한 Bi-Sr-Ca-Cu-O계의 결정 성장과 특성 평가 (Growth and characterization of a Bi-Sr-Ca-Cu-O phase by crystal pulling method)

  • 윤대호;좌등혜유;길본칙지;길택정인
    • 한국결정성장학회지
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    • 제7권1호
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    • pp.1-5
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    • 1997
  • $Bi_2Sr_2Ca_{n-1}Cu_nOy$(BSCCO)계는 강한 이방성의 움직임을 갖는 초전도체로서 잘 알려져 있으며, 결정육성시 성장방향의 제어에 큰 어려움이 있다. 본 연구에서는 종자 결정과 도가니의 회전을 이용한 crystal pulling법을 이용하여 Bi-Sr-Ca-Cu-O계의 결정성장을 시도하였으며, 이로부터 $5{\times}5{\times}5{\textrm}{mm}^3$ 크기의 비교적 큰 결정을 성장하였. 또한 성장결정의 초전도 특성을 조사하였으며, $BiO_{1.5}$ -(Sr, Ca)O-CuO 3원 상태도에서의 결정화 가능 영역을 검토하였다.

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Design of DC Side Voltage and Compensation Analysis of THD for Shunt Power Quality Controller under System Load of Rectifier with R-L Load

  • Zhao, Guopeng;Han, Minxiao
    • Journal of Electrical Engineering and Technology
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    • 제10권1호
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    • pp.30-40
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    • 2015
  • For a shunt power quality controller (SPQC) the DC side voltage value which is closely related to the compensation performance is a significant parameter. Buy so far, very little discussion has been conducted on this in a quantitative manner by previous publications. In this paper, a method to design the DC side voltage of SPQC is presented according to the compensation performance in the single-phase system and the three-phase system respectively. First, for the reactive current and the harmonic current compensation, a required minimal value of the DC side voltage with a zero total harmonic distortion (THD) of the source current and a unit power factor is obtained for a typical load, through the equivalent circuit analysis and the Fourier Transform analytical expressions. Second, when the DC side voltage of SPQC is lower than the above-obtained minimal value, the quantitative relationship between the DC side voltage and the THD after compensation is also elaborated using the curve diagram. Hardware experimental results verify the design method.

두 종류의 특정상호작용을 갖는 이성분 용액의 부분 혼합도 (Partial Miscibilities in Binary Solutions with Two Kinds of Specific Interactions)

  • 정해영
    • 대한화학회지
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    • 제60권2호
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    • pp.111-117
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    • 2016
  • 본 연구에서는 이성분 격자 용액에서 용매-용질, 용질-용질 분자 사이에 특정상호작용이 존재하는 경우에 대한 새로운 혼합자유에너지식을 유도하였다. 특정상호작용이 일어날 확률은 이항분포를 만족한다고 가정하였다. 이 혼합자유에너지식을 이용하여 나타낼 수 있는 부분혼합도에 대한 유형을 조사하였고 Ω-모양의 온도-조성 상도가 존재할 수 있음을 보여 주었다. 그리고 물-2-부탄올에 대한 Ω-모양의 온도-조성 상도를 계산하여 Hino등 5의 방법에 의한 계산값, 실험값과 비교하여 보았다.

CVD법을 이용한 SiC/C경사기능재료 증착공정의 열역학적 해석 (Thermodynamic analysis of the deposition process of SiC/C functionally gradient materials by CVD technique)

  • 박진호;이준호;신희섭;김유택
    • 한국결정성장학회지
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    • 제12권2호
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    • pp.101-109
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    • 2002
  • Hot-wall CVD법으로 SiC/C 경사기능재료를 증착시키는 공정을 열역학적으로 해석하였다. Si-C-H-Cl계에 대한 열역학적 계산을 통해 공정변수(증착온도, 반응기 압력 원료 기체의 C/[Si+C]비와 H/[Si+C]비)가 증착층의 조성과 증착 수율에 미치는 영향을 조사하였고, 이를 통해 SiC/C 경사기능재료 증착에 있어서의 CVD 상평형도와 최적 공정 조건의 범위를 예측할 수 있었다.

Dynamic Analysis of Topside Module in Lifting Installation Phase

  • Lee, Jong-Hyun
    • 한국해양공학회지
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    • 제25권4호
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    • pp.7-11
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    • 2011
  • The installation phase for a topside module suggested can be divided into 9 stages, which include start, pre-lifting, lifting, lifted, rotating, positioning, lowering, mating, and end of installation. The transfer of the topside module from a transport barge to a crane vessel takes place in the first three stages, from start to lifting, while the transfer of the module onto a floating spar hull occurs in the last three stages, from lowering to the end. The coupled multi-body motions are calculated in both calm water and in irregular waves with significant wave height (1.52m), with suggested force equilibrium diagrams. The effects of the hydrodynamic interactions between the crane vessel and barge during the lifting stage have been considered. The internal forces caused by the load transfer and ballasting are derived for the lifting phases. The results of these internal forces for the calm water condition are compared with those in the irregular sea condition. Although the effect of pitch motion on the relative vertical motion between the deck of the floating structure and the topside module is significant in the lifting phases, the internal force induced pitch motion is too small to show its influence. However, the effect of the internal force on the wave-induced heave responses in the lifting phases is noticeable in the irregular sea condition because the transfer mass-induced draught changes in the floating structure are observed to have higher amplitudes than the external force induced responses.

rf-sputtering을 이용한 $MgB_2$ 박막 제작 (Fabrication of $MgB_2$ Thin Films by rf-sputtering)

  • 안종록;황윤석;이순걸
    • Progress in Superconductivity
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    • 제4권2호
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    • pp.153-156
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    • 2003
  • We have studied fabrication of $MgB_2$ thin film on $SrTiO_3$ (001) and r-cut $A1_2$$O_3$ substrates by rf magnetron sputtering method using and $ MgB_2$ single target and two targets of Mg and B, respectively. Based on P -T phase diagram of $MgB_2$ and vapor pressure curves of Mg and B, a three-step process was employed. B layer was deposited at the bottom to enhance the film adhesion to the substrate. Secondly, co-sputtering of Mg and B was done. Finally, Mg was sputtered on top to compensate fur the loss of Mg during annealing. Subsequently, $MgB_2$ films were in-situ annealed in various conditions. The sample fabricated using the three-step process showed $T_{c}$ of 24 K and formation of superconducting $MgB_2$ phase was confirmed by XRD spectra. In case of co-sputtering deposition, $T_{c}$ depended on annealing time and argon pressure. However, those made by single-target sputtering showed non-superconducting behavior or low transition temperature, at best.est.

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대향분출화염의 분산화학반응 화염구조와 NOx 저감기구 (Flame Structure of Moderately Turbulent Combustion in the Opposed Impinging Jet Combustor)

  • 손민호;조용진;윤영빈;이창진
    • 대한기계학회논문집B
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    • 제26권10호
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    • pp.1387-1393
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    • 2002
  • The measurement of velocity and stain rate field has been conducted in opposed impinging jet combustion. When a smaller diameter (5mm) orifice of pre-chamber was used, previous studies had reported that the combustion phase showed a shift from weak turbulent combustion to moderate turbulent combustion in the modified Borghi Diagram. In the case with smaller orifice diameter (5mm), NOx emission was substantially reduced by a factor 1/2 while the combustion pressure remains at the same as that in the conventional combustion. Hence, in this study, the experiment setup using PIV technique was designed to identify the relation of the strain rate distribution and NOx reduction associated with moderate turbulent combustion. As a result, it was found that the highly strained pockets are widely distributed during the combustion in the middle of chamber when the orifice diameter is 5mm. And the corresponding PDF distribution of strain rates she was the smoothly distributed strain .ate within the range of |$\pm$1000| (1/sec) rather than a spike shape about zero point. This is the unique feature observed in the combustion with 5mm orifice diameter. Therefore, it can be concluded that the substantial NOx reduction in opposed impinging combustor is mainly attributed to the strain rate distribution within the range of |$\pm$1000|resulting in the combustion phase shift to moderate turbulent combustion.

엔진 가진력의 감도해석을 이용한 차실 소음 저감에 관한 연구 (A Study on the Noise Reduction of Compartment of Vehicle Using Sensitivity Analysis of Engine Exciting Force)

  • 오재응;김태욱;송재은;이해승
    • 한국자동차공학회논문집
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    • 제5권4호
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    • pp.171-178
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    • 1997
  • Vehicle interior noise has become increasingly important in this recent years. The noise of a vehicle is one of the important problems in a vehicle design. The interior noise is caused by various vibration sources of vehicle compartment. The booming noise of a vehicle can be significantly affected by vibrations transmitted from engine excitation forces to the vehicle body. Specially, we are interested in the state of transmission paths such as engine mounts to reduce noise in a vehicle compartment. In this paper, we have been calculated the contribution of each transmission path such as engine mounts to interior noise. To identify contribution of each input sources and transmission paths to output, the effectiveness of each input component to output is calculated. Sensitivity analysis is carried out for investigation of contribution to output due to input variations. With the simulation of magnitude and phase change of inputs using vector synthesis diagram, the trends of synthesized output vector are obtained. As a result, we suggested sensitivity analysis of vector synthesis as a technique of prediction and control for noise in a vehicle compartment.

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Fabrication of FeCuNi alloy by mechanical alloying followed by consolidation using high-pressure torsion

  • Asghari-Rad, Peyman;Kim, Yongju;Nguyen, Nhung Thi-Cam;Kim, Hyoung Seop
    • 한국분말재료학회지
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    • 제27권1호
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    • pp.1-7
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    • 2020
  • In this research, a new medium-entropy alloy with an equiatomic composition of FeCuNi was designed using a phase diagram (CALPHAD) technique. The FeCuNi MEA was produced from pure iron, copper, and nickel powders through mechanical alloying. The alloy powders were consolidated via a high-pressure torsion process to obtain a rigid bulk specimen. Subsequently, annealing treatment at different conditions was conducted on the four turn HPT-processed specimen. The microstructural analysis indicates that an ultrafine-grained microstructure is achieved after post-HPT annealing, and microstructural evolutions at various stages of processing were consistent with the thermodynamic calculations. The results indicate that the post-HPT-annealed microstructure consists of a dual-phase structure with two FCC phases: one rich in Cu and the other rich in Fe and Ni. The kernel average misorientation value decreases with the increase in the annealing time and temperature, indicating the recovery of HPT-induced dislocations.