• 제목/요약/키워드: Phase cycling

검색결과 158건 처리시간 0.023초

리튬 이온 이차전지용 $LiCr_xMn_{1-x}O_2$ 정극활물질의 전기 화학적 특성 (Electrochemical properties of $LiCr_xMn_{1-x}O_2$ cathode materials for lithium ion battery)

  • 김은미;전연수;백형렬;구할본;손명모
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.418-419
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    • 2005
  • $\o-LiMnO_2$ is known to have poor cycle performance causing the irreversible phase transformation on cycling. In this paper, the effect of chemical substitution on improving cycle performance of $o-LiMnO_2$ was studied at the compositions of $LiCr_xMn_{1-x}O_2$(x=0, 0.1, 0.2, 0.4). XRD is showed that structure of $LiCr_xMn_{1-x}O_2$ transformed from orthorhombic to spinel according to the increase of substitute degree. For lithium ion battery applications, $LiCr_xMn_{1-x}O_2$/Li cell were characterized electrochemically by charge/discharge cycling.

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근피로를 고려한 FES 싸이클링의 제어 (Control of FES Cycling Considering Muscle Fatigue)

  • 김철승;하세 카즈노리;강곤;엄광문
    • 한국정밀공학회지
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    • 제22권6호
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    • pp.207-212
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    • 2005
  • The purpose of this work is to develop the FES controller that can cope with the muscle fatigue which is one of the most important problems of current FES (Functional Electrical Stimulation). The feasibility of the proposed FES controller was evaluated by simulation. We used a fitness function to describe the effect of muscle fatigue and recovery process. The FES control system was developed based on the biological neuronal system. Specifically, we used PD (Proportional and Derivative) and GC (Gravity Compensation) control, which was described by the neuronal feedback structure. It was possible to control of multiple joints and muscles by using the phase-based PD and GC control method and the static optimization. As a result, the proposed FES control system could maintain the cycling motion in spite of the muscle fatigue. It is expected that the proposed FES controller will play an important role in the rehabilitation of SCI patient.

$LiMn_{2-y}M_{y}O_{4}$(M=Mg, Zn) 정극의 충방전 용량 및 AC 임피던스 특성 (Charge-discharge capacity and AC impedance of $LiMn_{2-y}M_{y}O_{4}$(M=Mg, Zn) cathode)

  • 정인성;위성동;이승우;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.455-458
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    • 2001
  • Spinel $LiMn_{2-y}$$M_{y}$ $O_4$powder was prepared solid-state method by calcining the mixture of LiOH - $H_2O$, Mn $O_2$, ZnO and MgO at 80$0^{\circ}C$ for 36h. To investigate the effect of substitution with Mg, Zn cation, charge-discharge experiments and initial impedance spectroscopy performed. The structure of $LiMn_{2-y}$$M_{y}$ $O_4$crystallites was analyzed from powder X-ray diffraction data as a cubic spinel, space group Fd3m. all cathode material showed spinel phase based on cubic phase in X-ray diffraction. Ununiform which calculated by (111) face and (222) face was constant in spite of the change of y value, except PUf\ulcorner LiM $n_2$ $O_4$. The discharge capacities of the cathode for the cation subbstitUtes $LiMn_{2-y}$$M_{y}$ $O_4$/Li cell at the 1st cycle and at the 40th cycle were about 120~124 and 108~112mAh/g except LiM $n_{1.9}$Z $n_{0.1}$ $O_4$/Li cell, respectively. This cell capacity is retained by 93% after 40th cycle. AC impedance of $LiMn_{2-y}$$M_{y}$ $O_4$/Li cells revealed the similar resistance of about 65~110$\Omega$ before cycling. before cycling.g.g.

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$LiMn_{2-y}M_{y}O_4$ 정극 활물질의 전기화학적 특성 - I. $LiMn_{2-y}Mg_{y}O_4$의 결정 구조 및 AC Impedance 특성 (The Electrochemical Characterization of $LiMn_{2-y}M_{y}O_4$ Cathode Material - I. Crystal Structure and AC Impedance Properties of $LiMn_{2-y}Mg_{y}O_4$)

  • 정인성;김종욱;구할본;김형곤;손명모
    • 한국전기전자재료학회논문지
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    • 제14권4호
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    • pp.309-315
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    • 2001
  • Crystallized $LiMn_{2-y}Mg_{y}O_4$ powder was prepared by calcing the mixture of LiOH.$H_2O$, $MnO_2$ and MgO at $800^{\circ}C$ for 36h in an air atmosphere. The structure of $LiMn_{2-y}Mg_{y}O_4$ crystallites was analyzed from powder X-ray diffraction data as a cubic spinel, space group Fd3m. Though all cathode material showed spinel phase based on cubic phase in X-ray diffraction, other peaks gradually exhibited and became intense with increasing y value in $LiMn_{2-y}Mg_{y}O_4$. However, ununiform which calculated by (111) face and (222) face was constant in spite of the increase of y value, except pure $LiMn_2O_4$. AC impedance of Li/$LiMn_{2-y}Mg_{y}O_4$ cells revealed the similar resistance of about $70\Omega$ before cycling. In addition, The impedance of Li/$LiMn_{1.9}Mg_{0.1}O_4$ cell changed during charge and discharge or after cycling.

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전기저항 측정법을 이용한 Pd박막의 수소화 특성 측정 (Measurement of Hydrogenation Characteristics of Pd Film by Using Electrical Resistivity Measurement Technique)

  • 조영신;이호재;이종숙
    • 한국수소및신에너지학회논문집
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    • 제7권2호
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    • pp.173-180
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    • 1996
  • 4-probe resistivity measurement technique was used to study kinetics of hydrogen absorption-desorption on Pd film($520{\AA}$ thick) at room temperature upto 1 bar. Kinetics data are fitted well to 1st order kinetics equation in ${\alpha}$ and ${\alpha}^{\prime}$ phases. In ${\alpha}+{\alpha}^{\prime}$ phase, absorption kinetics was very complicated, but it could be explained partially with nucleation and growth process. Ln(dR/dt) vs. time plot gives rate constant k value(R is resistance of sample, t is time). k value for absorption is $4^{-6}{\times}10^{-4}/sec$ in ${\alpha}$ phase. k is increasing upto $4^{\times}10^{-2}/sec$ as hydrogen pressure increasing in ${\alpha}^{\prime}$ phase. k is proportional to ln(Pop/Peq), where Peq is equilibrium plateau pressure and Pop is the opposing pressure. In contrast to bulk sample k value was decreasing with increasing number of A-D cycling in ${\alpha}^{\prime}$ phase absorption.

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POD용 환경조절장치를 위한 상변화열교환기 개념연구 (A Design Study on a Phase Change Heat Exchanger of an Environmental Control System for a POD)

  • 유영준;민성기
    • 한국추진공학회지
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    • 제16권1호
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    • pp.64-71
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    • 2012
  • 환경조절장치는 일반적으로 냉각기계와 열교환기를 주요 구성품으로 한다. 그런데, 본 연구에서는 환경조절장치의 천이성능 향상을 위하여 상변화 열교환기를 추가하는 새로운 개념을 제시하였다. 그 효과는 상변화 열교환기를 포함하는 환경조절장치의 모델링 프로그램을 개발하여 이륙, 기동, 순항, 착육 등과 같은 다양한 비행조건에 대하여 평가되었다. 다양한 조건에서의 시뮬레이션 결과, 회수되는 공기의 온도가 $80^{\circ}C$ 이내를 유지하는 것이 확인되어, 상변화 열교환기를 포함하는 새로운 환경조절장치의 개념이 성공적으로 검증되었다.

가스터빈 블레이드용 IN738LC의 열기계피로수명에 관한 연구 (Thermo-Mechancal Fatigue of the Nickel Base Superalloy IN738LC for Gas Turbine Blades)

  • 에릭 플러리;하정수;현중섭;장석원;정훈
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 춘계학술대회논문집A
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    • pp.188-193
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    • 2000
  • A more accurate life prediction for gas turbine blade takes into account the material behavior under the complex thermo-mechanical fatigue(TMF) cycles normally encountered in turbine operation. An experimental program has been carried out to address the thermo-mechanical fatigue life of the IN738LC nickel-base superalloy. In the first phase of the study, out-of-phase and in-phase TMF experiments have been performed on uncoated and coated materials. In the temperature range investigated. the deposition of NiCrAlY air plasma sprayed coating did not affect the fatigue resistance. In the second phase of the study, a physically-base life prediction model that takes into account of the contribution of different damage mechanisms has been applied. This model was able to reflect the temperature and strain rate dependences of isothermal cycling fatigue lives, and the strain-temperature history effect on the thermo-mechanical fatigue lives.

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무선 센서 네트워크에서 에너지 효율성과 지연 감소를 위한 다중 채널 파리프라인 기법 (Multi-Channel Pipelining for Energy Efficiency and Delay Reduction in Wireless Sensor Network)

  • 이요한;김대영
    • 전자공학회논문지
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    • 제51권11호
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    • pp.11-18
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    • 2014
  • 무선 센서 네트워크에서 다중 흐름들 (multiple flows) 이 동시에 발생하여 sink 노드로 전달되는 과정에서 기존의 duty cycling 기반의 단일 채널 센서 네트워크 MAC 프로토콜들은 경쟁 (contention) 과 충돌 (collision) 로 인한 심각한 성능 저하를 보인다. 본 논문에서는 이러한 문제점을 해결하기 위해서 다중 채널을 활용하는 Multi-Channel Pipelining (MCP) 기법을 제안한다. 본 논문은 종단 간 지연시간 (end-to-end latency) 을 최소화하기 위해서 다중 홉 상에 노드들의 wake-up 스케줄에 시차를 두는 SDPS (Staggered Dynamic Phase Shift) 알고리즘과 에너지 효율성을 최적화하기 위한 PLI (Phase-Locking Identification) 알고리즘을 제안한다. 이러한 방법을 바탕으로 다중 흐름들은 다중 채널에서 동적으로 파이프라인 (pipeline) 되어 처리됨으로써 성능이 향상된다. Qualnet 시뮬레이션을 통해 본 논문에서 제안하는 MCP 기법이 기존의 센서 네트워크 MAC 프로토콜들 보다 듀티 사이클 (duty cycle), 종단 간 지연시간, 패킷 전달율 (packet delivery ratio), 통합 처리량(aggregate throughput) 관점에서 성능을 향상시킴을 보였다. 또한, MCP 의 듀티 사이클과 종단 간 지연시간을 위한 분석 모델을 제안하고 시뮬레이션을 통해 검증하였다.

Celecoxib, a COX-2 Selective Inhibitor, Induces Cell Cycle Arrest at the G2/M Phase in HeLa Cervical Cancer Cells

  • Setiawati, Agustina
    • Asian Pacific Journal of Cancer Prevention
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    • 제17권4호
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    • pp.1655-1659
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    • 2016
  • Celecoxib, a selective inhibitor of COX-2, showed cytotoxic effects in many cancer cell lines including cervical cancer cells. This study investigated the effect of celecoxib on cell cycle arrest in HeLa cervical cancer cells through p53 expression. In vitro anticancer activity was determined with the 3-[4,5-dimethylthiazol-2-yl]-2,5 diphenyl tetrazolium bromide (MTT) method. A double staining method was applied to investigate the mechanism of cell death, cell cycling was analyzed by flow cytometryand immunocytochemistry was employed to stain p53 expression in cells. Celecoxib showed strong cytotoxic effects and induced apoptosis with an $IC_{50}$ value of $40{\mu}M$. It induced cell cycle arrest at G2/M phase by increasing level of p53 expression on HeLa cells.

기계적 혼합과 고상법에 의해 합성한 $LiNi_{1-y}In_yO_2$ 전기화학적 특성 (Electrochemical Properties of $LiNi_{1-y}In_yO_2$ Synthesized by Milling and Solid-/state Reaction Method)

  • 김훈욱;윤순도;이재천;박혜령;박찬기;송명엽
    • 한국수소및신에너지학회논문집
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    • 제17권1호
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    • pp.117-124
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    • 2006
  • By calcining at $750^{\circ}C$ for 30 h in $O_2$ stream after milling, $LiNi_{1-y}In_yO_2$(y = 0.005, 0.01, 0.025, 0.05, and 0.1) were synthesized and their electrochemical properties were investigated. All the samples had the $R{\bar{3}}m$ structure. In addition, they contained $LiInO_2$ phase and the intensities of the peaks for the $LiInO_2$ phase increased as the value of y increased. The sample with y = 0.01 had the largest first discharge capacity (140.2 mAh/g), but the sample with y = 0.005 had a better cycling performance. The samples with y $\geq$ 0.025 had a bad cycling performance irrespective of the first discharge capacity. The sample with y = 0.005 had the largest value of $I_{003}/I_{104}$ and the smallest value of R-factor. Among all the samples, $LiNi0_{0.995}In_{0.005}O_2$ had the best electrochemical properties. This sample had a smaller first discharge capacity than $LiNiO_2$, but it showed a better cycling performance than $LiNiO_2$.