Browse > Article

Electrochemical Properties of $LiNi_{1-y}In_yO_2$ Synthesized by Milling and Solid-/state Reaction Method  

Kim, Hun-Uk (Division of Advanced Materials Engineering, Automobile Hi-Technology Research Center, Engineering Research Institute, Chonbuk National University)
Youn, Sun-Do (Division of Applied Chemical Engineering, Chonnam National University)
Lee, Jae-Cheon (Division of Applied Chemical Engineering, Chonnam National University)
Park, Hye-Ryoung (Division of Applied Chemical Engineering, Chonnam National University)
Park, Chan-Gi (Division of Advanced Materials Engineering, Automobile Hi-Technology Research Center, Engineering Research Institute, Chonbuk National University)
Song, Myoung-Youp (Division of Advanced Materials Engineering, Automobile Hi-Technology Research Center, Engineering Research Institute, Chonbuk National University)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.17, no.1, 2006 , pp. 117-124 More about this Journal
Abstract
By calcining at $750^{\circ}C$ for 30 h in $O_2$ stream after milling, $LiNi_{1-y}In_yO_2$(y = 0.005, 0.01, 0.025, 0.05, and 0.1) were synthesized and their electrochemical properties were investigated. All the samples had the $R{\bar{3}}m$ structure. In addition, they contained $LiInO_2$ phase and the intensities of the peaks for the $LiInO_2$ phase increased as the value of y increased. The sample with y = 0.01 had the largest first discharge capacity (140.2 mAh/g), but the sample with y = 0.005 had a better cycling performance. The samples with y $\geq$ 0.025 had a bad cycling performance irrespective of the first discharge capacity. The sample with y = 0.005 had the largest value of $I_{003}/I_{104}$ and the smallest value of R-factor. Among all the samples, $LiNi0_{0.995}In_{0.005}O_2$ had the best electrochemical properties. This sample had a smaller first discharge capacity than $LiNiO_2$, but it showed a better cycling performance than $LiNiO_2$.
Keywords
Milling; Solid-state reaction method$LiNi_{1-y}In_yO_2$; Electrochemical properties$I_{003}/I_{104}$; R-factor;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 R. V. Moshtev, P. Zlatilova, V. Manev and A. Sato, 'The $LiNiO_2$ Solid Solution as a Cathode Material for Rechargeable Lithium Batteries,' J. Power Sources, vol. 54, No. 3-4, 1995, pp. 329-33   DOI   ScienceOn
2 T. Ohzuku and A. Veda, 'Why Transition Metal (di) Oxides are the Most Attractive Materials for Batteries', Solid State Ion., vol. 69, No. 3-4, 1994, pp. 201-211   DOI   ScienceOn
3 C. Julien, S. S. Michael, S. Ziolkiewicz, 'Structural and Electrochemical Properties of $LiNi_{0.3}Co_{0.7}O_2$ Synthesized by Different LowTemperature Techniques' Int. J. Inorg. Matt., vol. 1, NO. 1, 1999, pp. 29-37   DOI   ScienceOn
4 H. U. Kim, S. D. Youn, H. R. Park, M. Y. Song, 'Electrochemical Properties of $LiNi_1-yMyO_2$ (M = $Zn^{2+}$, $Al^{3+}$ and $Ti^{4+}$ Synthesized by Milling and Solide-State Reaction Method' J. Kor. Ceram. Soc, vol. 42, No. 5, 2005, pp. 352-358   과학기술학회마을   DOI
5 Z. S. Peng, C. R. Wan and C. Y. Jiang, 'Synthesis by Sol-Gel Process and Characterization of $LiCoO_2$ Cathode Materials' , J. Power Sources, vol. 72, No. 2, 1998, pp. 215-220   DOI   ScienceOn
6 Y. Gao, M. V. Yakov1eva and W. B. Ebner, 'Novel $LiNi_1-xTix$/2Mgx/$2O_2$ Compounds as Cathode Materials for Safer Lithium-Ion Batteries,' Electrochem. Solid State Lett., vol. 1, No. 3, 1998, pp. 117-119   DOI
7 M. Y. Song and D. S. Ahn, 'Improvement in the Cycling Performance of $LiMn_2O_4$ QY the Substitution of Fe for Mn', Solid State Ion., vol. 112, No. 3-4, 1998, pp. 245-248   DOI   ScienceOn
8 J. Kim and K. Amine, 'A Comparative Study on the Substitution of Divalent, Trivalent and Tetravalent Metal Ions in $LiNi_1-xMxO_2$ (M = $Cu^{2+}$, $Al^{3+}$ and $Ti^{4+}$,' J. Power Sources, vol. 104, No. 1, 2002, pp.33-39   DOI   ScienceOn
9 C. C. Chang and P. N. Kumta, 'Particulate Sol-Gel Synthesis and Electrochemical Characterization of $LiMO_2$ (M = Ni, $Ni_{0.75}$ $Co_{0.25}$) Powders', J. Power Sources, vol. 75, NO. 2, 1998, pp. 44-55   DOI   ScienceOn
10 M. Y. Song, H. Rim, E. Y. Bang, S. G. Kang and S. H. Chang, 'Synthesis of Cathode Materials $LiNi_1-yCoyO_2$ from Various Starting Materials and their Electrochemical Properties' , J. Kor. Ceram. Soc., vol. 40, No. 6, 2003, pp. 507-12   DOI
11 T. Ohzuku, A. Veda, M. Nagayarna, 'Electrochemistry and Structural Chemistry of $LiNiO_2$ for 4Volt Secondary Lithium Cells' J. Electrochem. Soc., vol. 140, No. 7, 1993, pp. 1862-1870   DOI
12 M. Y. Song, I. H. Kwon and M. S. Shon, 'Electrochemical Properties of $LiNiyMn_2-yO_4$ Prepared by the Solid-State Reaction', J. Kor. Ceram. Soc., vol. 40, No. 5, 2003, pp. 401-4   DOI
13 K. Ozawa, 'Lithium-Ion Rechargeable Batteries with $LiCoO_2$ and Carbon Electrodes: the $LiCoO_2$/C System,' Solid State Ion., vol. 69, No. 3-4, 1994, pp. 212-221   DOI   ScienceOn
14 J. R. Dahn, U. von Sacken and C. A. Michal, 'Structure and Electrochemistry of $Li_1$ $\pm$ $yNiO_2$ and a New $Li_2NiO_2$ Phase with the $Ni(OH)_2$ Structure,' Solid State Ion., vol. 44, No. 1-2, 1990, pp. 87-97   DOI   ScienceOn
15 W. Li, J. N. Reimers and J. R. Dahn, 'In Situ X-ray Diffraction and Electrochemical Studies of $Li_1-xNiO_2$', Solid State Ion., vol. 67, No. 1-2, 1993, pp. 123-30   DOI   ScienceOn
16 M. Guilmard, A. Rougier, M. Grone, L. Croguennec, C. Delmas, 'Effects of Aluminum on the Structural and Electrochemical Properties of $LiNiO_2$,' J. Power Sources, vol. 115, No. 2, 2003, pp. 305-314   DOI   ScienceOn
17 H. Arai, S. Okada, H. Ohtsuka, M. Ichimura, J. Yamaki, 'Characterzation and Cathode Performance of $Li_{1-x}Ni_{1+x}O_2$ Prepared with the Excess Lithium Method' Solid State Ion., vol. 80, No. 3-4, 1995, pp. 261-269   DOI   ScienceOn
18 H. U. Kim, S. D. Youn, J. C. Lee, H. R. Park and M. Y. Song, 'Study on the Sunthesis by Milling and Solid-State Reaction Method and Electrochemical Properties of $LiNiO_2$,' J. Kor. Ceram. Soc., (submitted)