• Title/Summary/Keyword: Phase boundary

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Effects of Nitrogen on Deformation Behavior of Duplex Stainless Steel (이상 스테인레스강의 변형거동에 미치는 질소의 영향)

  • 이형직;장영원
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.49-52
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    • 2003
  • The effects of nitrogen on the deformation behavior of duplex stainless steel have been studied The variation of strength was correlated with the characteristic microstructures. Analysis based on Hall-Petch relation confirmed that nitrogen enhances phase-boundary strengthening effect. The evolution of dislocation structure, slip traces, and misorientation distribution during deformation were also characterized to elucidate the effect of nitrogen on inelastic deformation mechanism.

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Thermal Aging Embrittlement in LWR Primary Pressure Boundary Components

  • Kim, Sunki;Kim, Yongsoo;Wonmok Jae
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.635-640
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    • 1995
  • Two techniques for the verification of the phase separation in ferrite phase of primary pressure bounary component materials, the primary cause of thermal aging embrittlement, are presented. Data base of room-temperature Charpy V-notch impact energy during reactor service was estimated as a measure of the degree of embrittlement. The serviceable period of CF-3 and CF-8 alloys as the primary pressure boundary components may be acceptably extended for 60 years of lifetime. However, the integrity of CF-8M alloys can be degraded seriously after several years of service in the nuclear reactor.

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Phase Transition Behavior and Dielectric Properties of Morphotropic Phase Boundary in (1-x)Pb(Yb1/2Nb1/2)O3-xPbTiO3 (0.40 ≤ x ≤ 0.60) Solid Solutions ((1-x)Pb(Yb1/2Nb1/2)O3-xPbTiO3 (0.40 ≤ x ≤ 0.60) 고용계에서의 PbTiO3 치환에 따른 상전이 영역의 상전이 거동과 유전특성)

  • Kim, Jung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.49 no.3
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    • pp.253-259
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    • 2012
  • In this study, crystal structural changes and dielectric properties of $(1-x)Pb(Yb_{1/2}Nb_{1/2})O_3-xPbTiO_3$ ((1-x)PYN-xPT) solid solutions were measured and analyzed with respect to the $PbTiO_3$ (PT) contents ($0.40{\leq}x{\leq}0.60$). From X-ray diffraction (XRD) measurements, (1-x)PYN-xPT solid solutions showed changes of the crystal structure from pseudocubic ($0.40{\leq}x{\leq}0.44$) to tetragonal ($0.52{\leq}x{\leq}0.60$) on increasing PT contents and exhibited the coexistence of pseudocubic and tetragonal phase near the morphotropic phase boundary (MPB) composition ($0.46{\leq}x{\leq}0.50$). The dielectric constant showed a maximum value at x = 0.46 and the maximum values in (1-x)PYN-xPT decreased with higher PT contents. The phase transition temperatures of (1-x)PYN-xPT solid solutions increased over the whole composition ranges tested ($0.40{\leq}x{\leq}0.60$).

The Apparent Mass Capacity Method for Transient Diffusion Problems with Change of Phase

  • Kim, Yongsoo;Wonmok Jae;D. R. Olander
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.643-650
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    • 1995
  • A numerical method for treating transient diffusion Involving change of phase is presented. In other methods of dealing with this class of problems, the mass flux balance at the moving phase boundary requires explicit treatment of two distinct phases. The technique, originating from the apparent heat capacity method in transient heat conduction with the phase change, avoids the difficulty by transferring the concentration discontinuity at the boundary to smoothed physical property variations near the moving front. This technique accomodates the nonlinearities which preclude use of analytical solutions. It was tested against known analytical solutions for simple cases and turned out to be quite accurate.

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Perspective on Ferroelectric Polymers Presenting Negative Longitudinal Piezoelectric Coefficient and Morphotropic Phase Boundary (강유전체 고분자의 음의 압전 물성 및 상공존경계(MPB)에 대한 고찰)

  • Im, Sungbin;Bu, Sang Don;Jeong, Chang Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.6
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    • pp.523-546
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    • 2022
  • Morphotropic phase boundary (MPB), which is a special boundary that separates two or multiple different phases in the phase diagram of some ferroelectric ceramics, is an important concept in identifying physics that includes piezoelectric responses. MPB, which had not been discovered in organic materials until recently, was discovered in poly(vinylidene fluoride-co-trifluoroethylene (P(VDF-TrFE)), resulting from a molecular approach. The piezoelectric coefficient of P(VDF-TrFE) in this MPB region was achieved up to -63.5 pC N-1, which is about two times as large as the conventional value of -30 pC N-1 of P(VDF-TrFE). An order-disorder arrangement greatly affects the rise of the piezoelectric effect and the ferroelectric, paraelectric and relaxor ferroelectric of P(VDF-TrFE), so the arrangement and shape of the polymer chain is important. In this review, we investigate the origin of negative longitudinal piezoelectric coefficients of piezoelectric polymers, which is definitely opposite to those of common piezoelectric ceramics. In addition to the mainly discussed issue about MPB behaviors of ferroelectric polymers, we also introduce the consideration about polymer chirality resulting in relaxor ferroelectric properties. When the physics of ferroelectric polymers is unveiled, we can improve the piezoelectric and pyroelectric properties of ferroelectric polymers and contribute to the development of next-generation sensor, energy, transducer and actuator applications.

Evaluation of Microstructure and Electrical Properties in (Na,K)NbO3-Based Pb-free Piezoelectrics Doped with Various Cu2O Concentration ((Na,K)NbO3계 무연 압전체에서 Cu2O 첨가물의 농도 변화에 따른 미세구조 및 전기적 특성 평가)

  • Lee, Youn-Ki;Ryu, Sung-Lim;Kweon, Soon-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.11
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    • pp.870-875
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    • 2011
  • The $(Na_{0.52}K_{0.44})(Nb_{0.9}Sb_{0.06})O_3-0.04dLiTaO_3$ (NKNS-LT) ceramics with various $Cu_2O$ concentration were prepared by the conventional solid state reaction method. The $Cu_2O$ content was varied in the range of 0.1~0.4 wt%. The effects of Cu on microstructure, crystallographic phase transition, and piezoelectric properties were investigated. The material with perovskite structure had a tetragonal phase (T1) when $Cu_2O$ concentration was less than 0.3 wt% and it transformed to another tetragonal phase (T2) when the $Cu_2O$ amount was greater than 0.3 wt%. The phase boundary between T1 and T2 phases appeared at around 0.3 wt% of $Cu_2O$ concentration. The piezoelectric properties were shown the maximum values at the composition of the phase boundary. The electro-mechanical coupling factor ($k_p$) was 0.42 and the piezoelectric charge constant ($d_{33}$) was 245 pC/N at the 0.3 wt% of $Cu_2O$ concentration.

Analysis of Pulsating Flow in Elastic Parallel Plates and an Elastic Pipe Model Using Moving Boundary Algorithm (이동경계 수치해법을 이용한 탄성평판 및 탄성관 모델내의 맥동유동 해석)

  • Park Hyung Gyu;Kim Charn-Jung;Lee Chong-Sun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.4 s.235
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    • pp.425-434
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    • 2005
  • In order to analyze pulsating flows in elastic blood vessels, a method based on the ALE concept and finite volume method was reformed and modulated to include wall motion of elastic vessels and impedance phase angle(phase difference between wall motion and blood flow). Our study indicated wall shear rates(WSR) were significantly influenced by the wall motion and the impedance phase angle. For larger wall motion more than $5{\%},$ the computed WSR started to deviate from the results of the perturbation theory that assumed smaller wall motion. The study showed that oscillatory shear index increased as the impedance phase angle became more negative like $-70{\circ}\;or\;-80{\circ}$ due to reduced mean WSR and increased amplitude of WSR. This result indicated that hypertensive patients are more vulnerable to atherosclerosis than normal persons because of the role of more negative impedance phase angles usually observed in these patients.

Chemically Induced Zigzag Migration in Alumina Bicrystals (알루미나 쌍결정에서 조성변화에 의한 Zigzag Migration)

  • 백용균;강석중
    • Journal of the Korean Ceramic Society
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    • v.32 no.10
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    • pp.1117-1122
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    • 1995
  • The effect of grain boundary structure on zigzag migrtion has been studied. Five kinds of a(2110)-m(1010) diffusion couples with different twist angles by 30$^{\circ}$from a [0001] common direction of each plane were prepared. When chromia (Cr2O3) was added to the diffusion couples by a vapor phase, zigzag migration of the grain boundary occurred. The fraction of zigzag migration did not essentially vary with the twist angle, but the magnitude and migration distance of individual migrating segment varied. The variation of CIGM morphology thus appears to result from the change in grain boundary mobility due to microscopic deviation of grain boundary structure out of a macroscopic grain boundary orientation.

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Laminar Convective Heat Transfer from a Horizontal Flat Plate of Phase Change Material Slurry Flow

  • Kim Myoung-Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.7
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    • pp.779-784
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    • 2005
  • This paper presents the theory of similarity transformations applied to the momentum and energy equations for laminar, forced, external boundary layer flow over a horizontal flat plate which leads to a set of non-linear, ordinary differential equations of phase change material slurry(PCM Slurry). The momentum and energy equation set numerically to obtain the non-dimensional velocity and temperature profiles in a laminar boundary layer are solved. The heat transfer characteristics of PCM slurry was numerically investigated with similar method. It is clarified that the similar solution method of Newtonian fluid can be used reasonably this type of PCM slurry which has low concentration. The data of local wall heat flux and convective heat transfer coefficient of PCM slurry are higher than those of water more than 150$\~$200$\%$, approximately.

An Eeffective Mesh Generation Algorithm Using Singular Shape Functions

  • Yoo, Hyeong Seon;Jang, Jun Hwan;Pyun, Soo Bum
    • Transactions on Control, Automation and Systems Engineering
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    • v.3 no.4
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    • pp.268-271
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    • 2001
  • In this paper, we propose a simplified pollution adaptive mesh generation algorithm using singular elements. The algorithm based on the element pollution error indicator concentrate on boundary nodes. The automatic mesh generation method is followed by either a node-relocation or a node-insertion method. The boundary node relocation phase is introduced to reduce pollution error estimates without increasing the boundary nodes. The node insertion phase greatly improves the error and the factor with the cost of increasing the node numbers. It is shown that the suggested r-h version algorithm combined with singular elements converges more quickly than the conventional one.

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