• Title/Summary/Keyword: Phase and size control

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Atomic layer deposition of In-Sb-Te Thin Films for PRAM Application

  • Lee, Eui-Bok;Ju, Byeong-Kwon;Kim, Yong-Tae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.132-132
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    • 2011
  • For the programming volume of PRAM, Ge2Sb2Te5(GST) thin films have been dominantly used and prepared by physical vapor deposition (PVD), chemical vapor deposition (CVD), atomic layer deposition (ALD). Among these methods, ALD is particularly considered as the most promising technique for the integration of PRAM because the ALD offers a superior conformality to PVD and CVD methods and a digital thickness control precisely to the atomic level since the film is deposited one atomic layer at a time. Meanwhile, although the IST has been already known as an optical data storage material, recently, it is known that the IST benefits multistate switching behavior, meaning that the IST-PRAM can be used for mutli-level coding, which is quite different and unique performance compared with the GST-PRAM. Therefore, it is necessary to investigate a possibility of the IST materials for the application of PRAM. So far there are many attempts to deposit the IST with MOCVD and PVD. However, it has not been reported that the IST can be deposited with the ALD method since the ALD reaction mechanism of metal organic precursors and the deposition parameters related with the ALD window are rarely known. Therefore, the main aim of this work is to demonstrate the ALD process for IST films with various precursors and the conformal filling of a nano size programming volume structure with the ALD?IST film for the integration. InSbTe (IST) thin films were deposited by ALD method with different precursors and deposition parameters and demonstrated conformal filling of the nano size programmable volume of cell structure for the integration of phase change random access memory (PRAM). The deposition rate and incubation time are 1.98 A/cycle and 25 cycle, respectively. The complete filling of nano size volume will be useful to fabricate the bottom contact type PRAM.

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A study on the heat treatment effect upon luminous properties of oxy-fluoride glass doped with TiO2 (TiO2가 첨가된 oxy-fluoride 계 유리의 발광특성에 미치는 열처리 효과 연구)

  • Woo, Heesu;Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.6
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    • pp.232-236
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    • 2020
  • In this study, the optical properties of CaF2-Al2O3-B2O3-TiO2 (CABT) system glass doped with rare earth ion, that is used in various light devices due to its excellent luminous properties, were analyzed as a function of kind of crystal phases formed and size of crystals generated in the glass matrix. TiO2 was added to control nucleation and crystallization, and Eu2O3 was added to enhance the luminescence characteristics. DTA analysis was performed to confirm the heat treatment condition of crystal generation, and XRD and SEM anal ysis were carried out for the crystal phase change of nanometer size. As a result of the analysis, the luminous properties of oxy-fluoride-based glass were improved duo to crystallization of nanometer size, but was rather degraded when excessively large crystals were generated.

Study on Optimization and Skin Permeation of PIT Nanoemulsion Containing α-Bisabolol (α-Bisabolol을 함유한 PIT Nanoemulsion의 최적화 및 피부흡수연구)

  • Kim, HuiJu;Yoon, Kyung-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.6
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    • pp.1738-1751
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    • 2020
  • The skin is divided into three parts: the epidermis, the dermis, and the subcutaneous fat, and the stratum corneum, which is located at the top of the epidermis, acts as a barrier that prevents drug delivery. Nanoemulsions are known to be effective in transdermal delivery of drugs through intercellular lipids because of their unique small particle size. In this study, phase inversion temperature (PIT) nanoemulsion containing α-bisabolol was optimized using response surface methodology (RSM) for effective skin absorption of α-bisabolol. As a preliminary experiment, the 25-2 fractional factorial design method and the 23 full factorial design method were performed. Box-Behnken design was performed based on the results of the factorial design method. The content of surfactant (6.3~12.6%), co-surfactant (5.2~7.8%) and α-bisabolol (0.5~5.0%) were used as factors, and the dependent variable was the particle size of the nanoemulsion. PIT nanoemulsion optimization was performed according to the RSM results, and as a result, the optimal nanoemulsion formulation conditions were predicted to be 10.4% surfactant content, 6.3% co-surfactant content, and 5.0% α-bisabolol content. As a result of the skin absorption test, the final skin absorption rate of the PIT nanoemulsion was 35.11±1.01%, and the final skin absorption rate of the general emulsion as a control was 28.25±1.69%, confirming that the skin absorption rate of the PIT nanoemulsion was better.

A Study on the Preparation of Hollow Microspheres Using Waste Polystyrene (폐 Polystyrene을 이용한 중공 미세구 제조에 관한 연구)

  • Kwon, Soon Young;Woo, Je-Wan
    • Clean Technology
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    • v.12 no.4
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    • pp.205-210
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    • 2006
  • In this study, polystyrene hollow microspheres were prepared via optimized purifying steps for the reuse of waste polystyrene. PS/PVA double layered hollow microspheres were prepared using the multiple emulsion ($W_1/O/W_2$) method with recycled polystyrene. The sonication treatment at the first stage of $W_1/O$ emulsion formation was very important factor of control of particle size and its distribution. When sonication was treated for 20 seconds, the average particle size and distribution were $1.35{\mu}m$ and $0.8{\mu}m{\sim}2.8{\mu}m$, respectively. The double layered hollow microspheres that have smaller and uniformed particle size distribution were manufactured when gelatin or Tween 80 was used as surfactants in the $W_2$ phase.

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Distribution and Migration Characteristics of Explosive Compounds in Soil at Military Shooting Ranges in Gyeonggi Province (경기도 북부지역 군용 사격장 토양에 존재하는 화약물질 분포 및 이동 특성 조사)

  • Bae, Bumhan;Park, Jieun
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.6
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    • pp.17-29
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    • 2014
  • A remedial investigation was conducted at five military training ranges in northern Gyeonggi province to collect information necessary for the design of on-site treatment facilities for the abatement of explosive compounds release to the environment. These information includes (i) identification of dominant explosive compounds in each range, (ii) discharge/migration routes, and (iii) contaminant distribution in particle size fraction and settling velocity of the soils. The results of investigation showed that TNT and RDX are the major contaminants but the extent of contamination varied depending on the types of military training practices and topography of the site. RDX was also detected in the subsurface soil and in the nearby stream within the training ranges, suggesting release of contaminants to streams. The median concentrations of explosives in the surface soil were less than 20 mg/kg despite several 'hot spots' in which explosives concentrations often exceeds several hundred mg/kg. The average clay contents in the soil of target area was less than 5 % compared to 12 % in the control, indicating loss of smaller particles by surface runoff during rainfall due to lack of vegetative land cover. Analysis of explosive compounds and particle size distribution showed that the amount of explosive compounds in soil particles smaller than 0.075 mm was less than 10 % of the total. Settling column tests also revealed that the quantity of explosive compounds in the liquid phase of the effluent was greater than that in the solid phase. Therefore, pre-treatment of particulate matter in surface runoff of shooting range with a simple settling basin and subsequent effluent treatment with planted constructed wetlands as polishing stage for explosives in the aqueous phase would provide the shooting ranges with a self-standing, sustainable, green solution.

The Processing control of NiCuZn Ferrite (I) - Mixing and Size Reduction of Raw Materials by Wet Ball Milling. (NiCuZn Ferrite의 제조공정 제어 (제1보) - 습식 볼밀링에 의한 다성분 원료의 혼합 및 분쇄 공정의 고찰)

  • 류병환;김선희;최경숙;고재천
    • Journal of the Korean Magnetics Society
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    • v.5 no.6
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    • pp.928-936
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    • 1995
  • In this research, the processing control of NiCuZn Ferrite has been developed. The mixing and the size reduction of raw materials have been proceeded. In order to produce NiCuZn Ferrite, highly concentrated slurry with fixed ratio and wet ball milling were used. First, the dispersion behavior of raw mixture at the region of pH4~pH11 has been studied. Using wet ball milling operation, the best conditions of mixing and size reduction have been determined. Further more, the most suitable conditions, such as, dispersant kind, dispersant amount, milling time, and slurry concentration have been studied. The poly acrylic ammonium salt (PAN) was chosen as a suitable dispersant to have effective dispersion in basic region. The slurry of raw mixture without dispersant, showed high viscosity and poor grindability. As 0.7 wt% of PAN was added, the concentrated slurry (up to 55 vol%) was possible, and showed well grindability. After 18 h ball milling of 30 vol% of mixture slurry with 0.7 wt% of PAN, the average particle size and specific surface area of raw mixture were $0.54\mu\textrm{m}$ and $12.92m^{2}/cc$, respectively. The ball milled raw mixture, calcined at $700^{\circ}C$ for 3h, was totally changed into NiCuZn Ferrite with spinel phase.

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Gait Type Change for Decrease of Leg's Fatness (다리의 지방감소를 위한 보행형태 변화에 관한 연구)

  • Bae, Sung-Soo;Lee, Hea-Deok;Oun, Jung-Young;Yoon, Chang-Goo;Choi, Houng-Sik
    • Journal of Korean Physical Therapy Science
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    • v.4 no.1
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    • pp.303-313
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    • 1997
  • We developed the shoes which is specially designed to decrease the leg's fatness during walking and to improve the body figure. The analysis of the gait cycle and the shoes gave changes at the swing phase. We examined the results to 30 girl students of Yeong Dong Junior College for 5 weeks from 27, October to 29, Nobember in 1996, and the results were also obtained in decrease of their thigh's size in circumference. The results of the analysis are as followings; 1) After experiment circumference of the right thigh was decreased 0.04cm in noncontrol group and significantly decreased 1.04 cm in control group(p<0.01). 2) After experiment circumference of the left thigh was decreased 0.27 cm in noncontrol group and significantly decreased 1.17cm in control group(p<0.01). 3) After experiment circumference of the right calf of the leg decreased 0.09 cm in noncontrol group and significantly decreased 0.54 cm in control group(p<0.01). 4) After experiment circumference of the left calf of the leg decreased 0.21 cm in noncontrol group and significantly decreased 0.47 cm in control group. 5) After experiment body weight were not changed significantly in both group. In these results, if the people want to exercise the analysis of fat in the thigh, put on the shoes which improves the body figure and do daily work, and it will be naturally decreased the fat in thigh and they will maintain the beauty lines of the legs. There weren't any changes in the body weight while the fat of thigh in circumsference was analysed and decreased. It means that because the weight of the fat is very light, there weren't any changes in body weight.

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Development of Regenerative Inverter for Electric Railway Using Space Vector PWM (SVPWM을 이용한 전기철도용 회생 인버터 개발)

  • 백병산;정문구;김태완
    • The Transactions of the Korean Institute of Power Electronics
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    • v.9 no.2
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    • pp.97-104
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    • 2004
  • As a device that returns surplus energy, regenerated from trains to d.c. source, to a.c. system and reuses it, the thyristor Inverter has been widely used. Because the conventional thyristor inverter is a unidirectional phase-controlled device, it Is Impossible to control the power factor of its output. Moreover, harmonics emission is high and it needs to take a additional filter. In this paper, to solve the problems stated above, the inverter, which can control real and reactive power by adopting IGBT modules as switching elements and being controlled by means of space vector PWM, is developed. Considering high economical efficiency and reliability in order to apply to the system for commercial use, the developed inverter is equipped with fully digital control system and low pass filter, and reduces harmonics and has compact size. The detail description about the developed inverter is stated in various respects: design criteria, technical description, power circuits, control techniques, the developed system, test results, etc.

Output characteristics of ac excited $CO_2$ laser as a adjusting a phase angle and frequency (위상각와 주파수 제어에 따른 상용주파 AC 여기 방식의 펄스형 $CO_2$ 레이저 전원장치 개발에 관한 연구)

  • Chung, Hyun-Ju;Kim, Do-Wan;Lee, Dong-Hoon;Kim, Joong-Mann;Kim, Mee-Je;Cho, Jung-Soo
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2098-2100
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    • 2000
  • We propose pulsed $CO_2$ laser below 30W by the AC(60Hz) switching control of leakage transformer primary which has some advantage of cost and size compared to a typical pulsed power supply. Pulse repetition rate is adjusted from 5Hz to 60Hz to control laser output. In this laser, a low voltage open loop control for high voltage discharge circuit is employed to avoid the HV sampling or switching and high voltage leakage transformer is used to convert rectified low voltage pulse to high voltage one. A ZCS(Zero Cross Switch) circuit and a PIC one-chip microprocessor are used to control gate signal of SCR precisely. The pulse repetition rate is limited by 60Hz due to the frequency of AC line and a high leakage inductance. The maximum laser output was obtained about 23W at pulse repetition rate of 60Hz, total gas mixture of $CO_{2}/N_{2}$/He = 1/9/15, SCR gate trigger angle 90$^{\circ}$, and total pressure of 18Torr.

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THE INVESTIGATION OF MICROVASCULATURE CHANGES IN OSSEOUS REGENERATION BY GUIDED TISSUE REGENERATION PROCEDURE (골재생유도술에 의한 골재생시 미세혈관 구축 양상)

  • Choi, Du-Hee;Ryoo, Hyun-Mo;Shin, Hong-In
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.21 no.3
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    • pp.257-265
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    • 1999
  • To investigate the sequential changes in microvascular architecture and osseous regeneration during the bony healing after an application of the guided tissue regeneration method, we made artificial defects measuring $0.7cm{\times}0.3cm$ in size on femoral bones of rats measuring about 200gm and applied non-absorbable TEFE membrane at experimental sites but not at control sites. Then we observed the sequential changes and correlations between new vacuolation and bony regeneration using microvascular corrosion cast method and routine light microscopic observation at 1, 2 and 3 weeks after operation, respectively. The results showed that there were close relationships between regeneration of microvasculature and bone. In early phase, the invasion of granulation tissue at control sites delayed bony regeneration, however, in later phase, there was no remarkable differences in bony regeneration between control and experimental sites. The placement of barrier also affected in revascularization of regenerating bony defects. This is, the experimental sites showed parallel arranged nutritional vessels along long axis with well developed retiform plexus whereas the control revealed vertical invasion of microvasculature from outside of marrow space through bony defects which was also rearrange with time into parallel pattern with a vertical plexus but lesser organized than that of experimental sites. These findings suggest that the reconstruction of regenerating vasculature within the marrow cavity only may be sufficient and/or more be efficient in regeneration of bony defects.

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