• Title/Summary/Keyword: Phase Transition

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Variation of Electrical Properties by E-field Induced Phase Transition in PZN-PT Crystals (전계유기 상전이에 의한 PZN-PT 단결정의 전기적 특성변화)

  • 백동수;김영호;조봉희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.11
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    • pp.892-897
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    • 2001
  • Variations of dielectric and piezoelectric properties and associated phase transformation of <001> -oriented rhombohedral 0.92Pb (Zn$\sub$1/3/Nb$\sub$2/3/)O$_3$-0.08PbTiO$_3$ single crystals were investigated. The longitudinal strain level was found to abruptly increase at 15 kV/cm, corresponding to that where an induced phase appears within a multidomain matrix. Drastic decreases in the dielectric constant, transverse coupling, and transverse piezoelectric coefficient associated with the E-field induced phase were the result of increased crystal anisotropy in PZN-PT crystals. By contrast, the thickness coupling increased from 53 % at 0 kV/cm to 64 % at 45 kV/cm, also associated with this phase transition under the E-field. The measured dielectric and piezflelectric properties found for the induced phase state were nearly identical to those of <001> poled tetragonal (1-x)PZN-xPT (x>0.1) crystals. Based on these results, it is evident that the symmetry of induced phase is tetragonal.

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Understanding of Growth Habits of $VO_2$ Film on Graphene and Their Effects on Metal to Insulator $Transition_2$

  • Yang, Jae-Hoon;Kim, Keun-Soo;Jang, A-Rang;Yang, Hyoung-Woo;Kang, Dae-Joon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.572-572
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    • 2012
  • Growth of metal oxides on graphene may lead to a better understanding of delicate effects of their growth habits on their underlying physics. The vanadium dioxide ($VO_2$) is well known for its metal-to-insulator transition accompanied by a reversible first order structural phase transition at 340 K. This transition makes $VO_2$ a potentially useful material for applications in electrical and optical devices. We report a successful growth of $VO_2$ nanostructures on a graphene substrate via a vapor-solid transport route. As-grown $VO_2$ nanostructures on graphene were systematically characterized by field emission scanning electron microscopy, x-ray diffraction, Raman spectroscopy, FT-IR spectroscopy and high resolution transmission electron microscopy. These results indicate that the strain between $VO_2$ and graphene layers may be easily controlled by the number of underlying graphene layer. We also found that the strain in-between $VO_2$ and graphene layer affected its metal-to-insulator transition characteristics. This study demonstrates a new way for synthesizing $VO_2$ in a desired phase on the transparent conducting graphene substrate and an easy pathway for controlling metal-to-insulator phase transition via strain.

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The Low Probability of Intercept RADAR Waveform Based on Random Phase and Code Rate Transition for Doppler Tolerance Improvement (도플러 특성 개선을 위한 랜덤 위상 및 부호율 천이 기반 저피탐 레이다 파형)

  • Lee, Ki-Woong;Lee, Woo-Kyung
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.26 no.11
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    • pp.999-1011
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    • 2015
  • In modern electronic warfare, RADAR is under constant threat of ECM(Electronic Counter Measures) signals from nearby jammers. The conventional linear frequency modulated(Linear-FM) waveform is easy to be intercepted to estimate its signal parameters due to its periodical phase transition. Recently, APCN(Advanced Pulse Compression Noise) waveform using random amplitude and phase transition was proposed for LPI(Low probability of Intercept). But random phase code signals such as APCN waveform tend to be sensitive to Doppler frequency shift and result in performance degradation during moving target detection. In this paper, random phase and code rate transition based radar waveform(RPCR) is proposed for Doppler tolerance improvement. Time frequency analysis is carried out through ambiguity analysis to validate the improved Doppler tolerance of RPCR waveform. As a means to measure the vulnerability of the proposed RPCR waveform against LPI, WHT(Wigner-Hough Transform) is adopted to analyze and estimate signal parameters for ECCM(Electronic Counter Counter Measures) application.

The Study on Phase Transition Pressure of Donor doped Pb(Zr0.52Ti0.48)O3 Ceramics with Diamond Anvil Cell (다이아몬드 엔빌 셀을 이용한 Donor doped Pb(Zr0.52Ti0.48)O3 세라믹스의 상전이 압력 연구)

  • Cho, Kyung-Ho;Ko, Young-Ho;Seo, Chang-Eui;Kim, Kwang-Joo
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.471-478
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    • 2011
  • Investigations of crystal structure and phase transition of $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics doped with A-site substitution impurity (La, Nd) or B-site substitution impurity (Sb, Nb) at 2 mol% concentration were carried out. X-ray diffraction patterns of impurities doped $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics have been measured at pressures up to ~5 GPa with diamond anvil cell and synchrotron radiation. The patterns were obtained at room temperature using methanol-ethanol mixture as pressure-transmitting media. In order to refine the crystal structure, Rietveld analysis has been performed. The structures of impurities doped $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics are tetragonal in space group P4mm at ambient pressure and are transformed into a cubic phase in space group Pm$\bar{3}$m as the pressure increases. In this study, when A-site substitution donor $La^{3+}$ or $Nd^{3+}$ ion was added to $Pb(Zr_{0.52}Ti_{0.48})O_3$ ceramics, the phase transition phenomena showed up at the pressure of 2.5~4.6 GPa, but when B-site substitution donor $Nb^{5+}$ or $Sb^{5+}$ ion was added to it, the phase transition appeared at relatively lower pressure of 1.7~2.6 GPa.

Surface Segregation and Order of FeCo Alloy (FeCo 합금의 표면 편석과 질서도)

  • Han, Wone-Keun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.3
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    • pp.240-244
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    • 2010
  • The surface segregation and surface order near the order-disorder phase transition of FeCo alloy was studied through Monte Carlo simulation of an Ising type model Hamiltonian. The results showed that the proper choice of Hamiltonian parameters could reproduce the recent observation of surface order above the transition temperature and that the field term played dominant role.

Phase Transition and Improvement of Output Efficiency of the PZT/PVDF Piezoelectric Device by Adding Carbon Nanotubes (Carbon Nanotube의 첨가에 의한 PZT/PVDF 압전소자의 상전이와 출력 효율 개선)

  • Lim, Youngtaek;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.2
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    • pp.94-97
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    • 2018
  • Lead zirconate titanate/poly-vinylidene fluoride (PZT/PVDF) piezoelectric devices were fabricated by incorporating carbon nanotubes (CNTs), for use as flexible energy harvesting devices. CNTs were added to maximize the formation of the ${\beta}$ phase of PVDF to enhance the piezoelectricity of the devices. The phase transition of PVDF induced by the addition of CNTs was confirmed by analyzing the X-ray diffraction patterns, scanning electron microscopy images, and atomic force microscopy images. The enhanced output efficiency of the PZT/PVDF piezoelectric devices was confirmed by measuring the output current and voltage of the fabricated devices. The maximum output current and voltage of the PZT/PVDF piezoelectric devices was 200 nA and 350 mV, respectively, upon incorporation of 0.06 wt% CNTs.

Crystal Growth and Phase Transition of Piezoelectric $KAlSiO_4$ (압전성 $KAlSiO_4$ 단결정 육성 및 상변화)

  • 오광석;박봉모;정수진;이태근;박병규;김호성
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.362-370
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    • 1996
  • Kalsilite (KAlSiO4) system undergoes a displacive phase transition from hexagonal phase with p63 space group to the phase with P63mc at 886$^{\circ}C$. The flux composition having kalsilite :K2O:B2O3=1:2:2 has enabled the growth of hexagonal kalsilite with the size of 0.5~1 mm at a slow cooling rate (0.3$^{\circ}C$/hr). On decreasing the cooling rate the size has increased and pyramidal (1011) faces are newly developed with the shape of (0001) and (1010) faces. Upon stirring (1011) faces are degraded. The space group of O1 and O2 are P21221 and C2221 respectively. Their orthorombic modification O1 and O2 are synthesized at relatively low and high temperature respectively.

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Effect of Triterpenoidal Glycosides of Dammarane Series and Their Aglycones on Phase Transitions of Dipalmitoylphosphatidylcholine (DPPC의 상전이에 미치는 Dammarane Series의 Triterpenoidal Glycoside와 그 Aglycone의 영향)

  • Kim, Yu.A.;Park, Kyeong-Mee;Park, Hwa-Jin
    • Journal of Ginseng Research
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    • v.20 no.1
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    • pp.23-29
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    • 1996
  • The effect of ginseng glycosides and their aglycones on the thermodynamic characteristics of membranes from dipalmitoylphosphatidylcholine (DPPC) was investigated. Total saponins (TS) from Korean red ginseng, Panax ginseng C.A. Meyer, interacted with the Eel Phase of lipid in the Polar region and did not penetrate the deeper glycerol backbone of lipid molecule. From the all investigated components of TS (aglycons and ginsenosides), only 20-(S)-panaxadiol (PD) had an effect similar to TS. High concentration of TS penetrated in hydrophobic Cl-C8 region. The presence of cholesterol did not influence the interaction of TS with DPPC. An elimination of transition, however, took place at 10~100 $\mu\textrm{g}$/ml of TS. DPPC had a low ability to interact with cholesterol (CHL) as compared with other lecithins except ethanolamine. From our results, only TS and PD, at high concentrations (100 mol%), influenced the phase transition of mixture of DPPC:CHL.

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Evaluation of Mechanical Properties of RPV Clad by Small Punch Tests

  • Lee, Joo-Suk;Kim, In-Sup
    • Nuclear Engineering and Technology
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    • v.34 no.6
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    • pp.574-585
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    • 2002
  • The microstructural characteristics and its related mechanical properties of RPV cladding have been investigated using small punch (SP) tests. SA508 Cl.3 RPV steel plates were overlay cladded with the type ER309L welding consumables by submerged arc welding process. Although the RPV clad material had a small portion of 5 ferrite phase, it still showed the ductile to brittle transition behavior The transition temperature was determined by the SP test and it depended on the content of $\sigma$ phase, specimen size, and determination methods. The fracture appearance of SP specimen was changed from circumferential to radial cracking as test temperature became low, and below the transition temperature region, ER309L cladding usually fractured along the 6 ferrite by the low temperature failure of ferrite phase.