• Journal of the Korean Electrochemical Society
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• v.5 no.3
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• pp.131-142
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• 2002

The Langmuir adsorption isotherms of the under-potentially deposited hydrogen (UPD H) and the over-potentially deposited hydrogen (OPD H) at the poly-Pt/0.5M $H_2SO_4$ and 0.5 M LiOH aqueous electrolyte interfaces have been studied using cyclic voltammetric and ac impedance techniques. The behavior of the phase shift $(0^{\circ}{\leq}{-\phi}{\leq}90^{\circ})$ for the optimum intermediate frequency corresponds well to that of the fractional surface coverage $(1{\geq}{\theta}{\geq}0)$ at the interfaces. The phase-shift method, i.e., the phase-shift profile $({-\phi}\;vs.\;E)$ for the optimum intermediate frequency, can be used as a new electrochemical method to determine the Langmuir adsorption isotherms $({\theta}\;vs.\;E)$ of the UPD H and the OPD H for the cathodic $H_2$ evolution reactions at the interfaces. At the poly-Pt/0.5M $H_2SO_4$ aqueous electrolyte interface, the equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the OPD H are $2.1\times10^{-4}$ and 21.0kJ/mol, respectively. At the poly-Pt/0.5M LiOH aqueous electrolyte interface, K transits from 2.7(UPD H) to $6.2\times10^{-6}$ (OPD H) depending on the cathode potential (E) and vice versa. Similarly, ${\Delta}G_{ads}$ transits from -2.5kJ/mol (UPD H) to 29.7kJ/mol (OPD H) depending on I and vice versa. The transition of K and ${\Delta}G_{ads}$ is attributed to the two distinct adsorption sites of the UPD H and the OPD H on the poly-Pt surface. The UPD H and the OPD H on the poly-Pt surface are the independent processes depending on the H adsorption sites themselves rather than the sequential processes for the cathodic $H_2$ evolution reactions. The criterion of the UPD H and the OPD H is the H adsorption sites and processes rather than the $H_2$ evolution reactions and potentials. The poly-Pt wire electrode is more efficient and useful than the Pt(100) disc electrode for the cathodic $H_2$ evolution reactions in the aqueous electrolytes. The phase-shift method is well complementary to the thermodynamic method rather than conflicting.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.27 no.10
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• pp.59-68
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• 2013

This paper proposes the boost type bidirectional DC/DC converter with high efficiency for electric vehicle using an interleave method. This interleave method can reduce the system size because it reduces the ripple of output voltage and input current with no add to extra filter. Proposed system is consist of two converters and applies to interleaved method through phase shift to each converter. And it implements the high boost through voltage double and series construction of output port. Also, it reduces the price and increases the efficiency as operating the ZCS by leakage inductance of transformer and capacitor of voltage double with not add special reactor. Proposed DC/DC converter using interleave method is proved the validity through the result of PSIM simulation and experiment of 5kW DC/DC converter.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 1998.03a
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• pp.239-244
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• 1998

ESP(Electronic Speckle Pattern Interferometry) is an optical technique to measure deforamtion of engineering components and materials in industrial areas. ESPI, a non-contact and non-destructive measuring method, is capable of providing full-field results with high spatial resolution and high speed. One of important application aspects using electronic speckle pattern interferometry is to generate contours of a diffuse object in order to provide data for 3-D shape analysis and topography measurement. The electronic speckle contouring is suitable for providing measurement range from millimeters to several centimeters. In this study, we introduce the contouring method by modified dual-beam speckle pattern interferometer and a shift of the two illumination beams through optical fiber in order to obtain the contour fringe patterns. Before the experiments, we performed the geometric analysis for dual-beam-shifted ESPI contouring. And by this geometric analysis, we performed the electronic speckle contouring experiment. We used 4-frame phase shifting method with PZT for quantitative analysis of contour fringes. Finally, we showed good agreements between the geometric analysis and experimental results.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.19 no.1
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• pp.34-39
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• 2005

We presented the method to obtain four speckle patterns with relative phase shift of ${\pi}/2$ by passive devices such as wave plate and polarizer, and calculate the phase at each point of the speckle pattern in shearography using Wollaston prism. And, we analyzed the phase error caused by wave plates used in the proposed method by Jones matrix.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.19 no.8
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• pp.1-7
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• 2005

We introduced the method to obtain four speckle patterns with relative phase shift of ${\pi}/2$ by the polarizing elements, and calculate the phase at each point of the speckle pattern in shearography using Wollaston prism and polarizing elements. Ant we analyzed the phase error caused by the azimuth angles of wave plates used in the proposed method by Jones matrix.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.10
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• pp.1011-1017
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• 2012

We report the development of an optical micro-nanolithography method by using a roll-type mask. It includes phase-shift lithography and photolithography for realizing various target dimensions. For sub-wavelength resolution, a structure is achieved using the near-field exposure of a photoresist through a cylindrical phase-mask, allowing high-throughput continuous patterning. By using a film-type metal mask, continuous photolithography was achieved, and this method could be used to control the period of resultant patterns in real time by changing the rotating speed of the cylinder mask. As an application, we present the fabrication of a transparent electrode in the form of a metallic mesh by using the developed roll-type photolithography process. As a result, a transparent conductor with good properties was achieved by using a recently built cylindrical phase-shift lithography prototype, which was designed for patterning on 100-mm2 substrates.

• Journal of IKEEE
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• v.22 no.3
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• pp.539-547
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• 2018

Grid-connected inverter is required to cut off the power supplied to the grid at the islanding condition, immediately. For this reason, an islanding detection is an indispensable function for grid-connected distributed generation system. Slip-Mode frequency Shift (SMS) islanding detection method is very popular method to determine the grid state. SMS method supplies the reactive power to the load according to the grid frequency. In the islanding condition of grid, this injected reactive power pulls out the grid frequency from the allowable range, then the inverter system can detect the islanding condition of the grid. The SMS method can detect the islanding state well and does not generate any harmonics of the grid current. However, the reactive power would be generated and the power quality is reduced even though the grid is not islanding condition, but normal condition. In this paper, a modified SMS method is proposed to remove the reactive power in the normal condition. The performance of the proposed method is evaluated by 600W single phase inverter experimental results.

• Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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• v.8 no.11
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• pp.523-530
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• 2018

It has been studied over the long time for the high efficiency and high power density of the power converter. It is possible to obtain higher power conversion efficiency and small volume by increasing switching frequency, however, the switching loss is also increased. The soft switching technique can overcome of the above deficiency. The design and analysis method for ZVS(Zero Voltage Switching) Phase Shifte Full bridge converter is presented in this paper. The power transfer depends on the phase difference between two legs of the power stage and the maximum power conversion efficiency is achieved by the optimum leakage inductance value. The waveform of the current and voltage of the operational mode is analysed and the corresponding switch status is plotted as on/off status. A ZVS full bridge converter for a communication rectifier with 2kW output power is implemented and its performance are verified through PSIM software simulation and experimental results.

• Proceedings of the IEEK Conference
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• 2002.07a
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• pp.519-522
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• 2002

An active phased array antenna consists of many channels. Each channel has a different initial phase shift and gain because of the inequality in the active circuits themselves, interface between radiators and active circuits, and beam-forming circuits and other antenna system configurations. This raises an inherent problem in active phased array antennas. To compensate for this problem the initial phase and gain of each channel should be calibrated. This paper presents an efficient calibration method for an initial phase variation of each channel in active phased array antennas. We tested our method in an active phased array antenna, and obtained good results in the radiation pattern and beam direction of antenna.

• Journal of the Korean Electrochemical Society
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• v.10 no.2
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• pp.132-140
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• 2007

The phase-shift method and correlation constants for studying a linear relationship between the behavior ($-{\varphi}\;vs.\;E$) of the phase shift ($0^{\circ}{\leq}-{\varphi}{\leq}90^{\circ}$) for the optimum intermediate frequency and that (${\theta}\;vs.\;E$) of the fractional surface coverage ($1{\geq}\theta{\geq}0$) have been proposed and verified to determine the Langmuir, Frumkin, and Temkin adsorption isotherms (${\theta}\;vs.\;E$) at noble metal/aqueous electrolyte interfaces. At an Ir/0.1 M KOH aqueous electrolyte interface, the Langmuir and Temkin adsorption isotherms (${\theta}\;vs.\;E$), equilibrium constants ($K=3.3{\times}10^{-4}\;mol^{-1}$ for the Langmuir and $K=3.3{\times}10^{-3}{\exp}(-4.6{\theta})\;mol^{-1}$ for the Temkin adsorption isotherm), interaction parameter (g = 4.6 for the Temkin adsorption isotherm), and standard free energies (${\Delta}G_{ads}^0=19.9kJ\;mol^{-1}\;for\;K=3.3{\times}10^{-4}\;mol^{-1}$ and $16.5<{\Delta}G_{\theta}^0<23.3\;kJ\;mol^{-1}\;for\;K=3.3{\times}10^{-3}{\exp}(-4.6{\theta})\;mol^{-1}\;and\;0.2<\theta<0.8$) of H for the cathodic $H_2$ evolution reaction are determined using the phase-shift method and correlation constants. The inhomogeneous and lateral interaction effects on the adsorption of H are negligible. At the intermediate values of ${\theta},\;i.e,\;0.2<{\theta}<0.8$, the Temkin adsorption isotherm (${\theta}\;vs.\;E$) correlating with the Langmuir or the Frumkin adsorption isotherm (${\theta}\;vs.\;E$), and vice versa, is readily determined using the correlation constants. The phase-shift method and correlation constants are accurate and reliable techniques to determine the adsorption isotherms (${\theta}\;vs.\;E$) and related electrode kinetic and thermodynamic parameters(K, g, ${\Delta}G_{ads}^0, {\Delta}G_{\theta}^0$).