• Title/Summary/Keyword: Phase Inversion

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Behaviour of Nanoemulsions Containing Ceramide IIIB and Stratum Corneum Lipids (세라마이드 IIIB와 각질층 지질을 함유한 나노에멀젼의 거동)

  • Cho, Wan Goo;Kim, Kyung Ah;Jang, Seon Il;Cho, Byoung Ok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.1
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    • pp.31-37
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    • 2018
  • Oil/water (O/W) nanoemulsions are effective vehicles to change the permeability of the skin. In this study, we focused on the preparation and characterization of nanoemulsion which serve as colloidal carriers for the dermal application of ceramide IIIB (CIIIB) and stratum corneum (SC) lipids such as cholesterol, and palmitic acid. In order to optimize the nanoemulsions, emulsification process conditions were conducted with regard to droplet size, nanoemulsion stability, and solubility of CIIIB. A decrease in droplet size was observed through emulsification temperature of $80^{\circ}C$ and phase inversion composition (PIC) method. CIIIB has low solubility in oil and water. When the concentration of CIIIB was increased, the droplet size of nanoemulsion was increased. When Lipoid S75-3 was added to the oil phase, the solubility of CIIIB increased, indicating some interactions shown in DSC measurements. CIIIB and SC lipids could be successfully incorporated in nanoemulsions without crystallization or physical instability. In conclusion, a stable nanoemulsion containing the SC lipids could be effective as an efficient moisturizing system for skin.

Phase Behavior and Morphological Studies of Polysulfone Membranes; The Effect of Alcohols Used as a Non-solvent Coagulant (비용매 알코올 응고조를 이용한 폴리술폰 막의 상전이 거동 및 모폴로지 특성 연구)

  • Park Byung Gil;Kong Sung-Ho;Nam Sang Yong
    • Membrane Journal
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    • v.15 no.4
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    • pp.272-280
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    • 2005
  • In this study, asymmetric polysulfone membranes were prepared by the phase inversion method and the casting solutions were containing N-methyl-2-pyrrolidone (NMP) as a solvent. Deionized water and various alcohols(methanol, ethanol, and propanol) were used as a coagulation medium in preparing asymmetric polysulfone membranes. This study investigates the effect of alcohol coagulants having different solubility parameters as a pore-former on the construction of porous structures and their pure water permeation properties. Asymmetric polysulfone membranes immersed in the pure alcohol coagulation bath solution showed the typical sponge-like structures and the reduced water permeability as compared with those of polysulfone membranes precipitated in the pure water coagulation bath solution. In the water/alcohol mixtures, asymmetric polysulfone membranes showed the finger-like structures with the sponge-like structures. Therefore, the sponge-like structure of polysulfone membrane was formed under the delayed demixing systems while the porosity of membrane was decreased significantly. The water permeability of polysulfone membrane precipitated in the pure water coagulant showed 164 [$L/m^2hr$] at 14.7 psi. In case of polysulfone membranes prepared in the pure methanol and ethanol coagulant, they showed the water permeability of 56 and 30 [$L/m^2hr$], respectively.

Preparation and Characterization of Polysulfone Membranes Using PVP as an Additive (폴리비닐피롤리돈 첨가제를 이용한 폴리설폰막의 제조 및 특성 분석)

  • Lee, Jin Young;Lee, Kune Woo;Han, Myeong-Jin;Park, So-Jin
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.277-285
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    • 2011
  • Polysulfone (PSf) membranes were prepared via the phase inversion process. Polyvinylpyrrolidone (PVP) was added as a nonsolvent additive in the casting solution containing a mixture of PSf and n-methylpyrrolidone. The added PVP played a role of enhancing liquid-liquid phase separation of the casting solution, and significantly reduced the solution fluidity. When prepared via the diffusion-induced process using water as a precipitation nonsolvent, the solidified membranes revealed a typical asymmetric structure irrespective of the addition of PVP. With 5 wt% PVP content, the finger-like cavities were more developed in the membrane sublayer compared to that of the membranes prepared without PVP. In contrast, with more than 10 wt% of PVP, the formation of finger-like cavities was suppressed, and the thickness of polymer nodule layer was increased. The surface porosity was also increased with the PSf content in the casting solution. The water permeability curve as a function of PVP addition revealed the inflection point. The maximum water permeability for 12 wt% PSf membrane was obtained with 5 wt% PVP content, and that for 18 wt% PSf membrane with 15 wt% PVP.

Time-Lapse Crosswell Seismic Study to Evaluate the Underground Cavity Filling (지하공동 충전효과 평가를 위한 시차 공대공 탄성파 토모그래피 연구)

  • Lee, Doo-Sung
    • Geophysics and Geophysical Exploration
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    • v.1 no.1
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    • pp.25-30
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    • 1998
  • Time-lapse crosswell seismic data, recorded before and after the cavity filling, showed that the filling increased the velocity at a known cavity zone in an old mine site in Inchon area. The seismic response depicted on the tomogram and in conjunction with the geologic data from drillings imply that the size of the cavity may be either small or filled by debris. In this study, I attempted to evaluate the filling effect by analyzing velocity measured from the time-lapse tomograms. The data acquired by a downhole airgun and 24-channel hydrophone system revealed that there exists measurable amounts of source statics. I presented a methodology to estimate the source statics. The procedure for this method is: 1) examine the source firing-time for each source, and remove the effect of irregular firing time, and 2) estimate the residual statics caused by inaccurate source positioning. This proposed multi-step inversion may reduce high frequency numerical noise and enhance the resolution at the zone of interest. The multi-step inversion with different starting models successfully shows the subtle velocity changes at the small cavity zone. The inversion procedure is: 1) conduct an inversion using regular sized cells, and generate an image of gross velocity structure by applying a 2-D median filter on the resulting tomogram, and 2) construct the starting velocity model by modifying the final velocity model from the first phase. The model was modified so that the zone of interest consists of small-sized grids. The final velocity model developed from the baseline survey was as a starting velocity model on the monitor inversion. Since we expected a velocity change only in the cavity zone, in the monitor inversion, we can significantly reduce the number of model parameters by fixing the model out-side the cavity zone equal to the baseline model.

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An Experimental Study on Dryout Pattern of Two-Phase Flow in Helically Coiled Tubes

  • Chung, Won-Seok;Sa, Young-Cheol;Lee, Joon-Sik
    • Journal of Mechanical Science and Technology
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    • v.16 no.11
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    • pp.1540-1549
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    • 2002
  • Experimental results are presented for the effects of coil diameter, system pressure and mass flux on dryout pattern of two-phase flow in helically coiled tubes. Two tubes with coil diameters of 215 and 485 mm are used in the present study, Inlet system pressures range from 0.3 to 0.7 MPa, mass flux from 300 to 500 kg/㎡s, and heat flux from 36 to 80 kw/㎡. A partial dryout region exists because of the geometrical characteristics of the helically coiled tube. The length of the partial dryout region increases with coil diameter and system pressure. On the other hand, it decreases with increasing mass flux. The critical quality at the tube top side increases with mass flux, but decreases with increasing system pressure. This tendency is more notable when the coil diameter is larger. When the centrifugal force effect becomes stronger, dryout starts at the top and bottom sides of the tube. However, when the gravity effect becomes stronger, dryout is delayed at the tube bottom side. In some cases when the mass flux is low, dryout occurs earlier at the outer side than at the inner side of the tube because of film inversion.

Quasi Phase-Matched Second Harmonic-Wave Generation based on Nonlinear-Optic Effect Utilizing Ti:PPLN Optical Waveguides (Ti:PPLN 광도파로를 이용한 비선형광학 기반의 의사 위상정합 2차 조화파 발생)

  • Jung, Hong-Sik;Jung, Young-Sik
    • Korean Journal of Optics and Photonics
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    • v.19 no.6
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    • pp.408-415
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    • 2008
  • The characteristics of a ferroelectric-domain inverted grating fabricated by applying a high-voltage pulse at room temperature in Ti-diffused channel waveguides in z-cut $LiNbO_3$ (Ti:PPLN) were examined for channel waveguide quasi phase-matched secondharmonic generation devices. The fabrication conditions of uniform periodic domain-inversion were examined. Ti:PPLN with period ${\Lambda}=16.6{\mu}m$ for SHG were fabricated and the performances were measured. A normalized SHG efficiency as high as 473 (%/W) was obtained with 49 mm interaction length.

Experimental Investigation on Flame Structure and Emission Characteristics in a Lean Premixed Model Gas Turbine Combustor (희박 예혼합 모형 가스터빈 연소기의 화염구조와 배기특성에 관한 실험적 연구)

  • Lee, Jong-Ho;Kim, Dae-Hyun;Jeon, Hung-Hwan;Chang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.4
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    • pp.425-432
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    • 2004
  • The objective of this study is a qualitative comparison between line-integrated OH chemiluminescence(OH$\^$*/) image and its Abel inverted image to investigate the flame structure at different phase of the oscillating pressure field. PIV(Particle Image Velocimetry) measurements were conducted under non-reacting conditions to see the global flow structure and NOx emission was measured to investigate the effect of fuel-air premixing on combustion instability and emission characteristics. Experiments were carried out in an atmospheric pressure, laboratory-scale dump combustor operating on natural gas. Combustion instabilities in present study exhibited a longitudinal mode with a dominant frequency of ∼341.8㎐, which corresponded to a quarter wave mode of combustor. Heat release and pressure waves were in-phase when instability occurred. Results gave an insight about the location where the strong coherence of pressure and heat release existed. Also an additional information on active control to suppress the combustion instabilities was obtained. For lean premixed combustion, strong correlation between OH$\^$*/ and NOx emissions was expected largely due to the exponential dependence of thermal NOx mechanism on flame temperature.

Improvement of Bit Error Rate of 16×40 Gbps NRZ-formated WDM Signals over 1,000km NZ-DSF using MSSI with Optimal Parameters (1,000km의 비 영 분산 천이 광섬유로 구성된 WDM 시스템에서 최적 파라미터를 갖는 MSSI를 이용한 NRZ 형식의 16×40 Gbps WDM 신호의 비트 에러율 개선)

  • Lee, Young Kyo
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.6 no.3
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    • pp.111-119
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    • 2010
  • In this paper the numerical methods of finding out the optimal position of optical phase conjugator (OPC) and the optimal fiber dispersion are proposed, which are able to effectively compensate overall channels in $16{\times}40$ Gbps WDM system. And the compensation characteristics in the system with two induced optimal parameters are compared with those in the system with the currently used mid-span spectral inversion (MSSI) in order to confirm the availability of the proposed methods. It is confirmed that the reception performances are largely improved in the system with the induced optimal parameters than in the system with MSSI through the analyzing the eye opening penalty (EOP) and bit error rate (BER) characteristics. It is also confirmed that two optimal parameters depend on each other, but are less related with the procedural problem about the first optimal value among these parameters.

Morphology and Rheology on the Blends of PLA/CMPS

  • Shin, Boo-Young;Jo, Gyu-Soon;Kang, Kyoung-Su;Lee, Tae-Jin;Kim, Bong-Shik;Lee, Sang-Il;Song, Jeong-Sup
    • Macromolecular Research
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    • v.15 no.4
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    • pp.291-301
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    • 2007
  • The rheological behaviors and morphologies of polylactide (PLA) and chemically modified plasticized starch (CMPS) blends were investigated. For this study, oscillatory shear flow measurements of the PLA, CMPS and their blends were performed. A scanning electron microscope (SEM) study was also conducted on the extracted extrudates of the blends. The morphology of the blend changed in relation to the composition: sphere-shaped CMPS disperse/continuous PLA, rod-like deformed CMPS phase/continuous PLA, a co-continuous structure with bridged CMPS long rods and PLA dispersed/continuous CMPS. The composition of the phase inversion could be estimated and closely coincided from the observed morphology experimental results. The rheological behavior of the blends, from oscillatory measurements, was found to vary in relation to the composition, and reflected the morphologies of the blends. PLA showed Newtonian flow behavior, while CMPS showed strong shear thinning behavior. The relationships between the morphology and rheological properties were observed in detail.

Rheology and morphology of concentrated immiscible polymer blends

  • Mewis, Jan;Jansseune, Thomas;Moldenaers, Paula
    • Korea-Australia Rheology Journal
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    • v.13 no.4
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    • pp.189-196
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    • 2001
  • The phase morphology is an important factor in the rheology of immiscible polymer blends. Through its size and shape, the interface between the two phases determines how the components and the interface itself will contribute to the global stresses. Rheological measurements have been used successfully in the past to probe the morphological changes in model blends, particularly for dilute systems. For more concentrated blends only a limited amount of systematic rheological data is available. Here, viscosities and first normal stress differences are presented for a system with nearly Newtonian components, the whole concentration range is covered. The constituent polymers are PDMS and PIB, their viscosity ratio can be changed by varying the temperature. The data reported here have been obtained at 287 K where the viscosities of the two components are identical. By means of relaxation experiments the measured stresses are decomposed into component and interfacial contributions. The concentration dependence is quite different for the two types of contribution. Except for the component contributions to the shear stresses there is no clear indication of the phase inversion. Plotting either the interfacial shear or normal stresses as a function of composition produces in some cases two maxima. The relaxation times of these stresses display a similar concentration dependence. Although the components have the same viscosity, the stress-component curves are not symmetrical with respect to the 50/50 blend. A slight elasticity of one of the components seems to be the cause of this effect. The data for the more concentrated blends at higher shear rates are associated with a fibrillar morphology.

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