• Title/Summary/Keyword: Phase I study

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A Study on the Transport Mechanism of Tidal Beach Sediments I. Deukryang Bay, South Coast of Korea (조간대성 해빈 퇴적물의 이동양상에 관한 연구 I. 한국 남해안의 득량만)

  • Ryu, Sang-Ock;Kim, Joo-Young;Chang, Jin-Ho;Cho, Yeong-Gil;Shin, Sang-Eun;Eun, Go-Yo-Na
    • Journal of the Korean earth science society
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    • v.27 no.2
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    • pp.221-235
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    • 2006
  • In order to understand the transport mechanism of tidal beach sediments in Deukryang Bay, south coast of Korea, beach profiles, surface sediments, sedimentation rates and hydrodynamic conditions have been investigated. The beach is composed of a steep beach face and gentle low-tide terrace, showing general morphologic characteristics of tide dominated beach. Central beach face of an indented coast becomes flattened in summer, but ridge and runnel system developed in other seasons makes the beach profile rather irregular. These seasonal variations of beach profiles and sedimentation rate indicate that beach sedimentation is mainly controlled by both tide and wave processes. Erosion is prevalent in winter when strong wind wave is dominant, while deposition is dominant in other seasons. However, central beach showed an apparent erosional phase in summer. This is caused by strong waves induced by southerly strong winds occurring ephemerally during the summer. On the other hand, sedimentation rates are -89.2 mm/yr on the central beach and 60.5 mm/yr and 38.2 mm/yr on the sides. This result suggests that sediments are eroded on the central beach and subsequently transported to the both sides. Therefore, the central part of Sumun beach, used as a beach bathing site, will be continuously eroded, if nearby dyke continues to prevent the sediment supply from sources.

Oxidation of Cu(II)-EDTA by TiO2 Photo-Catalysis(I) - The Effects of TiO2 Loading & Initial pH of Solution - (TiO2 광-촉매 반응에 의한 Cu(II)-EDTA의 산화(I) - TiO2 량과 pH의 영향 -)

  • Chung, Hung-Ho;Park, Eun-Hee;Rho, Jae-Seong;Sung, Ki-Woung;Cho, Young-Hyun
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.154-159
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    • 1999
  • EDTA (ethylenediaminetetraacetic acid), a chelating agent is most widely used in industrial applications, especially for cleaning of metals in water, frequently prohibits metal removal from water in conventional water treatment technologies. It could be easier to remove aqueous metal ions by the breakdown of DETA complexed bonds first. This study investigated the availability of $TiO_2$ photo-catalysis for the aqueous phase oxidation of Cu(II)-EDTA, under an aerobic condition at $20^{\circ}C$ with $TiO_2$ (Degussa P-25) and 1.79mM of Cu(II)-EDTA. When $TiO_2$ loading was 2.0 g/L, the photo-catalytic oxidation of Cu(II)-EDTA was maximal. The tendency of EDTA adsorption onto the catalyst surface was affected by $TiO_2$ surface charge, and the oxidation rate of Cu(II)-EDTA by photo-catalysis was shown to be dependent upon the tendency of EDTA adsorption before photo-irradiation.

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Study on Formation of FePd Nano-dot Using Agglomeration of Fe/Au Bilayer (Fe/Au 이중층의 응집현상을 이용한 FePd 나노 점 형성에 관한 연구)

  • Koo, J.K.;Kim, J.M.;Ryua, D.H.;Choi, B.J.;Kim, D.W.;Lee, D.H.;Kim, U.I.;Mitani, S.;J.G., M. Kamiko;Ha, J.G.
    • Journal of the Korean Vacuum Society
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    • v.20 no.1
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    • pp.7-13
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    • 2011
  • [ $L1_0$ ]phase FePd nano-dot structures were successfully fabricated on self-organized Fe/Au bilayers. With atomic force microscopy, it is determined that surface morphologies of initially flat Fe/Au bilayer films were agglomerated and transformed their shape into nano-dots structures with increasing annealing temperature. With this bilayer as a template, FePd multilayers were deposited at various temperatures, i.e. $300^{\circ}C$, $350^{\circ}C$, $400^{\circ}C$, and $450^{\circ}C$. Surface morphologies of FePd superlattice had a near resemblance to self-organized bilayer. According to X-ray diffraction results, it is confirmed that $L1_0$ superlattice structures of FePd were obtained from samples which were annealed above $350^{\circ}C$. Results of X-ray photoelectron spectroscopy depth-profile analysis showed that chemical composition is identical to deposition sequence. As a result, without additional etching processes, fabrication of chemically ordered FePd superlattice nano-dots was achieved.

Electrokinetic Studies on Nylon and Wool/Acid Dye System (나일론과 양모/산성염료계에 대한 계면동전위적 연구)

  • 박병기;김진우;김찬영
    • Textile Coloration and Finishing
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    • v.1 no.1
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    • pp.19-25
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    • 1989
  • In past, dye diffusion and dyeing rate in fibers have been emphasized in dyeing phenomena. However, in the light of the properties of colloids in the surface of disperse phase and dispersion, there exist specific characters such as adsorption or electric double layer, which seems to play important roles in determining the physiochemical properties in the dyeing system. Electrostatic bonding, hydrogen bonding and Van der Waals adsorption are common in dyeing as well as covalent bonding. Particularly, electrostatic bonding is premised on the existance of ionic radicals in fibers. The present study was aimed to clarify the electrokinetic phenomena of dyeing through the role of electric double layer by ion in amphoteric fibers with different ionic effects under different pH. Spectrophotometric analysis method was used to compare dyeing condition of surface, which can be detected by electrokinetic phenomena and the inner of fibers after deceleration of dyed fibers. Nylon and wool, the typical amphoteric fibers were dyed with monoazo acid dyes such as C.I. Acid Orange 20, and C.I. Acid Orange 10. Various combinations were prepared by combining pH, temperature and dye concentration, in order to generate streaming electric potential which were measured by microvolt meter and specific conductivity meter. The results were transformed to zeta potential by Helmholtz-Smoluchowski formular and to surface electric charge density by Suzawa formular, surface dye amount, and effective surface area of fibers. The amount of dyes of inner fibers were also measured by the Lambert-Beer’s law. The main results obtained are as follows. 1. By measuring zeta pontential, it was possible to detect the dyeing mechanism, surface charge density, surface dye amount and effective surface area concerning dye adsorption of the amphoteric fibers. 2. Zeta pontential increases in negative at low pH and high dye concentration in the process of dyeing. This implied that there existed ionic bond formation in the dyeing mechanism between acid dyes and amphoteric fibers. 3. Dibasic acid dye had little changing rate in zeta potential due to the difference in solubility of dye and in number of dissociated ions per dye molecule to bond with amino radicals of amphoteric fibers. The dye adsorption of mono basic acid dye was higher than that of dibasic acid dye. 4. The effective surface areas concerning dyeing were $6.3E+05\;cm^2/g$ in nylon, $1.6E+07\;cm^2/g$ in wool fiber being higher order of wool then nylon.

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Early gonadotropin-releasing hormone antagonist start improves follicular synchronization and pregnancy outcome as compared to the conventional antagonist protocol

  • Park, Chan Woo;Hwang, Yu Im;Koo, Hwa Seon;Kang, Inn Soo;Yang, Kwang Moon;Song, In Ok
    • Clinical and Experimental Reproductive Medicine
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    • v.41 no.4
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    • pp.158-164
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    • 2014
  • Objective: To assess whether an early GnRH antagonist start leads to better follicular synchronization and an improved clinical pregnancy rate (CPR). Methods: A retrospective cohort study. A total of 218 infertile women who underwent IVF between January 2011 and February 2013. The initial cohort (Cohort I) that underwent IVF between January 2011 and March 2012 included a total of 68 attempted IVF cycles. Thirty-four cycles were treated with the conventional GnRH antagonist protocol, and 34 cycles with an early GnRH antagonist start protocol. The second cohort (Cohort II) that underwent IVF between June 2012 and February 2013 included a total of 150 embryo-transfer (ET) cycles. Forty-three cycles were treated with the conventional GnRH antagonist protocol, 34 cycles with the modified early GnRH antagonist start protocol using highly purified human menopause gonadotropin and an addition of GnRH agonist to the luteal phase support, and 73 cycles with the GnRH agonist long protocol. Results: The analysis of Cohort I showed that the number of mature oocytes retrieved was significantly higher in the early GnRH antagonist start cycles than in the conventional antagonist cycles (11.9 vs. 8.2, p=0.04). The analysis of Cohort II revealed higher but non-significant CPR/ET in the modified early GnRH antagonist start cycles (41.2%) than in the conventional antagonist cycles (30.2%), which was comparable to that of the GnRH agonist long protocol cycles (39.7%). Conclusion: The modified early antagonist start protocol may improve the mature oocyte yield, possibly via enhanced follicular synchronization, while resulting in superior CPR as compared to the conventional antagonist protocol, which needs to be studied further in prospective randomized controlled trials.

Transport and Fate of Benzene in a Sandy Soil (사질토양에서의 Benzene의 이동성에 관한 연구)

  • 백두성;김동주
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.2
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    • pp.95-100
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    • 1999
  • Hydrocarbon compounds in vadose zone soils caused by adsorption onto the surfaces of solid particles are generally considered to show retardation effect. In this study, we investigated the retardation effect on the transport of Benzene in a sandy soil by conducting batch and column tests. The batch test was conducted by equilibrating dry soil mass with Benzene solutions of various initial concentrations. and by analyzing the concentrations of Benzene in initial and equilibrated solutions using HPLC. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used KCl and Benzene solutions with the concentration of 10 g/L and 0.88 g/L as a tracer, and injected them into the inlet boundary of the soil sample as a square pulse type respectively, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and HPLC. From the batch test, we obtained a distribution coefficient assuming that a linear adsorption isotherm exists and calculated the retardation factor based on the bulk density and porosity of the column sample. We also predicted the column BTC curve using the retardation factor obtained from the distribution coefficient and compared with the measured BTC of Benzene. The results of the column test showed that i) the peak concentration of Benzene was much smaller than that of KCl and ⅱ) the travel times of peak concentrations for the two tracers were more or less identical. These results indicate that adsorption of Benzene onto the sand panicles occurred during the pulse propagation but the retardation of Benzene caused by adsorption was not present in the studied soil. Comparison of the predicted with the measured BTC of Benzene resulted in a poor agreement due to the absence of the retardation phenomenon. The only way to describe the absolute decrease of Benzene concentration in the column leaching experiment was to introduce a decay or sink coefficient in the convection-dispersion equation (CDE) model to account for an irreversible sorption of Benzene in the aqueous phase.

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A Study of Noncontact Heartbeat and Respiration Detection Using the Doppler Radar (도플러 레이더를 이용한 비접촉 방식의 심박 및 호흡 검출에 관한 연구)

  • Shin, Jae-Yeon;Cho, Sung-Pil;Jang, Byung-Jun;Park, Ho-Dong;Lee, Yun-Soo;Lee, Kyoung-Joung
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.46 no.1
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    • pp.1-9
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    • 2009
  • In this paper, a 2.4 GHz doppler radar system consisting of a doppler radar sensor and a baseband module were designed to detect heart beat and respiration signal without direct skin contact. The doppler radar system emits RF signal of 2.4 GHz toward human chest, and then detects phase modulation of the reflected signal so as to investigate cardiopulmonary activities. The heartbeat and respiration signals acquired from I/Q channels of the doppler radar system are applied to the pre-processing circuit, the amplification circuit, and the offset circuit of the baseband module. The designed system was tested on mouse, rabbit and mankind, which have different range of heart rates and respiration signals, to evaluate detection accuracy of the system. ECG acquisition system and respiration transducer were used to generate the reference signal. In our experiments, a performance of detection were found to be high in the case that the subject stays still. In this paper, we confirmed that non-contact heart beat and respiration detection using the doppler radar has the possibility and limitation according to distance, cardiopulmonary activities, range of heart rates and respiration.

Risk-based Safety Impact Assessment for Construction Projects (위험도 접근방법에 의한 건설사업 안전영향평가방안에 관한 연구)

  • Choi Hyun-Ho;Jung Pyung-Ki;Seo Jong-Won;Choi Ook
    • Proceedings of the Korean Institute Of Construction Engineering and Management
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    • 2004.11a
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    • pp.504-509
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    • 2004
  • Safety assessment of construction projects may be affected by various factors such as types and scale of projects, construction methods, procedure, climactic, and site conditions etc. Presently, in planning and design phases, designers are still often uncertain of their responsibilities, l3i]I information and training of safety. Therefore, designers are still failing to exploit the potential that have to eliminate and reduce risks on site. In this study, the concepts of safety impact assessment is introduced in order to derive the performing design for safety in design phase. For this purpose, a framework for safety impact assessment model using risk-based approach for construction projects is suggested. The suggested model includes of information survey and scenarios, classification of safety impact factors occurred by design and construction, and quantitative estimation of magnitude and frequency. Moreover, the checklist which is enable to identify relationship between safety impact factors and design factors is developed and the methodology of safety impact assessment model using risk-based approach is also proposed.

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Study on Principle of the Theory of Eight Constitutional Medicine (팔체질의학론의 원리에 대한 고찰)

  • Lee, Bong-Hee;Kwon, Kang-Beom;Park, Cheol;Jo, Chang-Rae;Ryu, Do-Gon
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.23 no.4
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    • pp.789-798
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    • 2009
  • In Sasang constitutional medicine, I have researched the process of visceral structure in the Eight Constitutionals under circulation of the five elements and the formation of primary source of illness. From this research, I could draw following conclusions through combination of the auxiliary psycho-formulas by applying the constitutional acupuncture therapy on the five elements diagnostic calculation. Since the arrangement for the five dimensions of organs in the eight constitutions has been formulated by circulation of the five elements in Sasang constitutions, if the five elements begin circulating count-clockwise from the reference point at the organs in Sasang constitutional medicine, the positive constitutional arrangement of organs is built up such as, the positive constitution of metal, earth, wood and water, while begin circulating clockwise, the negative constitutional arrangement of organs is formulated, such as the negative constitutions of metal, earth, wood and water. The source of illness results from imbalance of the organic force being generated by transfer of the five elements from compatibility to incompatibility when the five elements circulate. Hence, it has been acknowledged that if the source of illness comes from the strongest organ, it is the time when circulation of the five elements progresses from the second organ (the second strongest) in incompatibility, and if the source of illness comes from the weakest organ, it is the time when circulation of the five elements progresses from the third organ (the middle) in incompatibility. It is considered proper to diagnose meridians of the pericardium and the Triple Burners rather than to diagnose meridians of the heart and the small intestine which forms the visceral arrangement of the eight constitutions. For instance, the auxiliary psycho-formula obtains its prescription by attenuating the first organ (the strongest) while augmenting the fourth organ (the second weakest) when the axis of incompatibility in the five elements circulation crosses the second and the third organs, and it gets its prescription by attenuating the second organ(the second strongest) while augmenting the fifth organ(the weakest) when the axis of incompatibility in the five elements circulation crosses the third and the fourth organs. In addition, when medicating, the $4{\sim}5$ times of repeated performance can be assumed to represent the amount of an energy that each organ bears depending on the phase in the arrangement of the eight constitutional organs.

Retardation Effect and Mobility of a Heavy Metal in a Sandy Soil (사질토양에서의 중금속의 지연효과와 이동성)

  • Kim, Dong-Ju;Baek, Doo-Sung
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.3
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    • pp.155-161
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    • 1998
  • Retardation effect of heavy metals in soils caused by adsorption onto the surfaces of solids particles is well known phenomenon. In this study, we investigated the retardation effect on the mobility of a Zn in a sandy soil by conducting batch and column tests. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used NaCl and ZnCl$_2$ solutions with the concentration of 10 g/L as a tracer, and injected them respectively into the inlet boundary of the soil sample as a square pulse type, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and ICP-AES. The batch test was conducted based on the standard procedure of equilibrating fine fractions collected from the soil with various initial ZnCl$_2$ concentrations, and analysis of Zn ions in the equilibrated solutions using ICP-AES. The results of column test showed that i) the peak concentration of ZnCl$_2$analyzed by ICP was far less than that of either NaCl or bulk electrical conductivity and ⅱ) travel times of peak concentrations for two tracers were more less identical. The relatively low concentration of Zn can be explained by ion exchange between Zn and other cations, and possible precipitation of Zn in the form of Zn(OH)$_2$due to high pH range (7.0∼7.9) of the effluent. The identical result of travel times of peak concentrations indicates that the retardation effect is not present in the soil. The only way to describe the prominent decrease of Zn ion was to introduce decay or sink coefficient in the CDE model to account for irreversible decrease of Zn ions in the aqueous phase.

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