• 동력기계공학회지
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• 제22권6호
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• pp.74-79
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• 2018

Compressed natural gas has a high octane number and low particulate emission characteristics as compared with petroleum-based fuels, so it can respond to exhaust gas regulations positively. A natural gas engine has been introduced to improve the quality of the atmosphere, a diversity of fuel, a stable supply, and it has widely been used in city buses and garbage trucks. Recently, the natural gas engine has received attention by overcoming the disadvantage of the theoretical air-fuel ratio method through the development of EGR cooler and engine parts with the development of LP-EGR technology. In this study, we try to develop the cogeneration system that can simultaneously generate electric power and heat by remodeling the gasoline engine to the mixer type CNG engine. As a result, it was able to reduce the NOx (approximately 77%) compared to the diesel engines with same displacement.

• 한국응용과학기술학회지
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• 제34권4호
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• pp.1112-1120
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• 2017

석유제품은 다양한 형태의 탄화수소화합물로 구성되어진 화합물로, 다른 종류의 액체류와 마찬가지로 온도변화에 따른 밀도와 부피의 변화가 발생한다. 액상에서 석유제품의 밀도를 측정하는 방법은 분별 증류된 각 석유제품에 대해 주로 얻어진 실험 데이터를 기반으로 한다. 본 연구에서는 등유와 자동차용 경유의 온도변화에 따른 밀도와 부피변화를 실제 측정하여 온도변화에 따른 변화추이를 분석하고, 국제규격인 ASTM에서 제시하는 밀도부피 환산표를 이용한 환산값을 계산하고 두 값을 비교분석하였다. 또한, 국내 계량 관련법에서 규정하고 있는 온도변화에 대한 기준과 실측값과의 상호 비교를 통해 차이점을 분석하였다.

• 동력기계공학회지
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• 제21권6호
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• pp.68-78
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• 2017

Major countries have tighten their NOx regulation of diesel passenger cars. In the case of the EU, the regulation has been toughen up to 6.25 times since 2000. Despite the regulation the NOx concentration of the ambient has not been reduced proportionally. Futhermore, some manufacturers were disclosed using a defeat device for meeting the regulation illegally. As these issues, to reduce NOx emission practically, Korea and the EU introduced the real-world driving emission(RDE) regulation and the test method that will be applied after 2017. Also, the US has used the test equipment(PEMS) to detect a defeat device. In this paper, for the regulation to make a soft landing in Korea, 4 diesel passenger cars which met Euro 6a~6b regulation and were equipped with LNT/SCR were tested at a chassis dynamometer with environmental chamber applying the off-cycles(FTP, US06, SC03, HWFET and CADC) and several ambient condition(-7 and $14^{\circ}C$) as well as certification mode(NEDC, WLTC@ $23^{\circ}C$). The result of the test showed that the ambient temp. and the engine load as a test mode impacted the NOx emission of the cars while the vehicles with SCR emitted NOx lower than with LNT. Additionally, to propose an effective RDE test method, the above result was compared with the results of the other papers which tested RDE using the same cars.

• 공업화학
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• 제19권6호
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• pp.617-623
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• 2008

일산화탄소(CO)와 수소($H_2$)로부터 Fischer-Tropsch반응을 통해 합성된 GTL (gas-to-liquid)연료는 친환경적인 연료로 기존의 석유디젤을 대체, 또는 혼합하여 사용될 수 있는 연료로 크게 관심을 받고 있다. 본 논문에서는 Shell사에서 생산된 GTL연료와 국내유통중인 석유디젤을 일정 비율로 혼합하여 농도 별 연료특성을 분석하였다. 가스크로마토그래피를 이용해 GTL이 일반디젤보다 긴 파라핀계 화합물로 구성되어져 있음을 확인하였으며, 높은 인화점, 증류성상, 동점도, 유도세탄가와 함께, 낮은 황분으로 인한 윤활성감소를 보여주었다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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• pp.207-210
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• 2004

Effect of electron accepters on anaerobic degradation of petroleum hydrocarbons by an anaerobic sludge taken from a sludge digestion tank in a soil artificially contaminated with 10,000 mg/kg soil of diesel fuel was tested. Treatments of soil with 30 mL of the digestion sludge (2,000 mg/L of vss (volatile suspended solids)) were incubated under several anaerobic conditions including nitrate reducing, sulfate reducing, methanogenic, and mixed electron accepters conditions for 120 days. Treatments with the digested sludge showed significant degradation of diesel fuel under all anaerobic conditions compare to control treatments with an autoclaved sludge and without the sludge. The amount of TPH degradation after 120days incubation was the largest in the treatment with the sludge and mixed electron accepters (75% removal of TPH) followed in order by sulfate reducing, nitrate reducing, methanegenic condition as 67%, 53％, 43%, respectively. However, the rate of TPH degradation in the nitrate- and sulfate reducing condition within 105 days were comparable with that of the mixed electron accepters condition. Microorganisms in each electron acceptor condition were plated on solid mediums containing nitrate or sulfate as sole electron acceptor and several nitrate- and sulfate reducing bacteria showed effective degradation of diesel fuel within 30 days incubations. These results suggest that anaerobic degradation of diesel fuel in soil with digested sludge is effective for practical remediation of soil contaminated with petroleum hydrocarbons.

• 한국응용과학기술학회지
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• 제31권2호
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• pp.320-328
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• 2014

국내 자동차용 경유에 혼합하여 유통 중인 바이오디젤은 물리적인 관점에서 기존 석유계 경유와 동점도, 밀도 등의 물성값이 유사하고 세탄가가 높은 장점이 있다. 또한 환경적인 측면에서는 기존의 석유유통 인프라 개조 및 변경없이 사용가능하다는 점과 함산소 연료로서 디젤기관에서의 연소성이 좋고 유해 배출가스 저감효과가 있으며 생분해성도 높아 환경오염이 적어 자동차용 경유 대체연료로 각광받고 있다. 그러나, 기존 식용계 작물을 원료로 하고 있다는 점에서 단점으로 지적되는 바이오디젤 대신 단위면적당 $CO_2$ 흡수율이 높고 빠른 성장 속도가 장점으로 거론되는 미세조류의 활용에 대한 연구가 대두되고 있다. 본 연구에서는 미세조류 중 Dunaliella tertiolecta 종을 이용하여 생산한 바이오디젤의 전환율을 연구하기위해 기존에 사용되고 있는 GC-FID분석방법의 문제점에 대해 조사하고 TOF-MS 장비를 통한 개별 지방산 메틸에스테르의 성분을 검토하였다.

• 한국화재소방학회논문지
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• 제21권3호
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• pp.78-83
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• 2007

석유류 중에서도 차량, 선박, 보일러 등에 많이 사용되고 있는 디젤유는 휘발유나 등유보다도 연소시에 발열량이 높기 때문에, 화재 발생시에 큰 피해를 초래한다. 따라서 본 연구는 시중에 판매중인 디젤유을 이용하여 액면화재 실험을 하였으며, 연소시에 화염의 내부온도와 화염으로부터 발생되는 복사열에 대해서 측정하였다. 디젤유의 순간 최대화염온도는 $900^{\circ}C$ 이상되는 것으로 나타났으며, 평균 최대화염온도는 $800^{\circ}C$ 이상으로 나타났다. 또한 최대화염온도는 가연성 액체의 표면으로부터 5 H/D에서 나타났으며, 이 거리 보다 멀어질 수로 화염의 온도는 낮아졌다. 복사열의 경우 저장용기의 크기와 시료의 량에 따라서 크게 달라지는 것을 알 수 있었으며, 실험 용기의 크기가 0.5 m이고, 시료량이 13 mm와 20 mm에서는 각각 92.29 kW와 117.43 kW로 나타났으며, 크기가 1.0 m의 용기에서는 각각 364.35 kW와 405.88 kW로 나타났다.

• 대한기계학회논문집B
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• 제28권10호
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• pp.1178-1183
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• 2004

The purpose of this study was to investigate the influence of compression ratio on engine performance in a LPG(Liquefied Petroleum Gas) engine converted from a diesel engine. In ordor to determine the ideal compression ratio, a variable compression ratio 4-cylinder engine was developed. Retrofitting a diesel engine into a LPG engine is technically very complicated compared to a gasoline to LPG conversion. The cylinder head and the piston crown were modified to bum LPG in the engine. Compression ratios were increased from 8 to 10 in an increment of 0.5, the ignition timing was controlled to be at MBT(Minimum Spark Advance for Best Torque) for each case.

• Tribology and Lubricants
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• 제29권2호
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• pp.117-123
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• 2013

Dimethyl ether (DME) has a high cetane number that is suitable for diesel fuel. DME does not contain sulfur or nitrogen, and is an oxygenated fuel so it produces no particulate matter when combusted and is environmentally friendly. DME fuel for diesel engines show excellent material properties such as a lower volumetric heating value, lower boiling point, lower lubricity, and stronger solvent effect than light oil. This study experimentally examined a lubricity improver (LI) for dimethyl ether. A diesel LI based on biodiesel and fatty acid methyl ester was tested among DME LI candidates. The long-term storage stability and physical properties of the optimum LI for DME were determined.

• 한국분무공학회지
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• 제16권3호
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• pp.152-158
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• 2011

Fast pyrolysis of biomass is one of the most promising technologies for converting biomass to liquid fuels. The pyrolysis oil, also known as the bio crude oil (BCO), have been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of BCO in diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the BCO. One of the easiest way to adopt BCO to diesel engine without modifications is the use of BCO/diesel emulsions. In this study, a diesel engine operated with diesel, bio diesel (BD), and BCO/diesel emulsion was experimentally investigated. Performance and emission characteristics of a diesel engine fuelled by BCO/diesel emulsion were examined. Results showed that stable engine operation was possible with emulsion and engine output power was comparable to diesel and bio diesel operation. Long term validation of adopting BCO in diesel engine is still needed because the oil is acid, with consequent problems of corrosion especially in the injection system.