• Title/Summary/Keyword: Petrochemical refining method

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A Comparison on the Characteristics of Benzene Exposure between the Coal chemical and Petrochemical refining method during Turnaround (석유 및 석탄화학의 대보수작업중 벤젠노출 특성 비교)

  • Chung, Eun-Kyo;Yu, Gye-Muk;Shin, Jung-Ah;Kwon, Ji-Woon;Park, Hyun-Hee;Chung, Kwang-Jae;Lee, Jong-Han;Lee, In-Seop;Kang, Seong-Kyu;Ryu, Hyang-Woo;Kim, Young-Sun;Lee, Byung-Kyu;Jang, Jae-Kil;Kim, Won;Kim, Jung-Man
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.20 no.3
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    • pp.147-155
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    • 2010
  • This study was conducted to investigate the benzene exposure levels in coal chemical and petrochemical refining industries during BTX turnaround (TA) processes where benzene was being produced. Three companies producing benzene were selected, one coal chemical and two petrochemical industries. TA processes were classified into three stages: shut down, maintenance, and start up. Data was analyzed by classifying the refining method into 2 groups (Petrochemistry, Coal chemistry) for 823 workers. Comparing the data from petrochemical industries with data from a coal chemical refining industry, while benzene concentration levels of long-term samples during TA were not statistically different (p> 0.05), those levels of short-term samples were significantly different (p< 0.001). About 4.79 % of data in petrochemical industries exceed the occupational exposure limits (OELs) of benzene, 1 ppm. In a coal refining methods, about 15.7% exceeded the benzene OELs. The benzene concentrations in maintenance and start up stage of TA for petrochemical refineries were higher than those in a coal chemical refinery (p <0.01). These findings suggest that the coal chemical refining site requires more stringent work practice controls compare to petrochemical refining sites during TA processes. Personal protective equipments including organic respirators should be used by TA workers to protect them from benzene overexposure.

Rapid Compositional Analysis of Naphtha by Near-Infrared Spectroscopy

  • 구민식;정호일;이준식
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1189-1193
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    • 1998
  • The determination of total paraffin, naphthene, and aromatic (PNA) contents in naphtha samples, which were directly obtained from actual refining process, has been studied using near-infrared (NIR) spectroscopy. Each of the total PNA concentrations in naphtha has been successfully analyzed using NIR spectroscopy. Partial least squares (PLS) regression method has been utilized to quantify the total PNA contents in naphtha from the NIR spectral bands. The NIR calibration results showed an excellent correlation with those of conventional gas chromatography (GC). Due to its rapidity and accuracy, NIR spectroscopy is appeared as a new analytical technique which can be substituted for the conventional GC method for the quantitative analysis of petrochemical products including naphtha.

Analysis Characteristic of Non-point source in Petrochemical (석유화학업종에서의 비산배출원 배출 특성 분석)

  • Chiwan, Ku;Seunghyo, An;Byungchol, Ma
    • Journal of the Korean Institute of Gas
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    • v.26 no.6
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    • pp.45-51
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    • 2022
  • Technologies for collecting and treating pollutants from point sources are steadily being developed, but Non-point sources, it is difficult to develop emission treatment technologies and effective emission coefficients. However, since non-point sources make up about 60% of domestic emissions, and first of all, the method of calculating emissions should be reasonable, and the workplace should develop emission reduction technologies based on this. This study suggest the effectiveness and improvement of the emission coefficient currently used for the petrochemical industry with high emissions. The emission characteristics of non-point sources emission were confirmed by analyzing the LDAR (Leak Detection And Repair) data of OO company located in Yeosu, Jeollanam-do over the past five years. As a result, there was no difference in discharge characteristics according to fluid phase, but it was confirmed that there was a difference in the size of the device and the characteristics of each manufacturer. In addition, it was confirmed that the emission coefficient applied in the petrochemical industry was larger than that of the refining industry, and improvement measures were suggested. Through these studies, it is expected that emission coefficients specialized in the petrochemical industry can be applied and that the workplace itself will contribute to the development of technologies that can drastically reduce them.

A study on the effect of changes in the level of environmental regulation of the importing country on export performance (수입국 환경제도수준 변화가 수출에 미치는 영향 연구)

  • Yun-Seop Hwang;Cheon Yu
    • Korea Trade Review
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    • v.45 no.4
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    • pp.65-81
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    • 2020
  • Under New Climate Regime, countries are trying to enhance environmental regulations to meet international standards. This study is designed to examine the relationship between the relative level of environmental regulation of the importing countries and the export performance at the industrial level. Panel data from 2009 to 2018 was established for 12 top export industries and empirical analysis was conducted. For the analysis method, panel OLS, Hausman-Taylor, and panel GLS were used based on the results of the Hausman verification. The dependent variable is the export performance of each industry. As the independent variables, the relative level of environmental regulation, GDP per capita of the importing country, exchange rate, FTA agreement, and physical distance from the importing country were used. Results show that the relative level of environmental regulation has a negative effect on export performance of semiconductors, displays, special machines, general machines, electric appliances, and home appliances. On the other hand, there are no relationship between the relative level of environmental regulation of the importing country and export performance of automobile, petroleum refining, petrochemical, shipbuilding, and communication equipment industries.