• Title/Summary/Keyword: Petrochemical industry

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[Retracted]Does Perceived Organizational Support and Job Resourcefulness Lead to Innovation? Mediation Model of Psychological Empowerment

  • Nadeem, AKHTAR
    • The Journal of Asian Finance, Economics and Business
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    • v.10 no.2
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    • pp.61-71
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    • 2023
  • The purpose of this study is to examine the relationship between POS, JR, and Innovation, and to explore the role of job psychological empowerment as a mediator in this relationship. A structured questionnaire was distributed to 25 companies in the petrochemical industry. PLS-SEM 4 was used to analyze the data of 100 valid responses. These findings suggest that employee empowerment (EMPOW) fully mediates the relationship between job resourcefulness (JR) and Innovation (INNOV). The total effect of JR on INNOV is also significant, with a beta coefficient of 0.234 and a t-value of 3.375. However, when the mediating influence of EMPOW is taken into account, the effect of JR on INNOV is no longer significant, with a beta coefficient of 0.100 and a t-value of 1.610. This suggests that EMPOW plays a key role in the relationship between JR and INNOV and that JR may not have a direct impact on Innovation. The study informs the development of interventions or strategies for promoting Innovation in organizations by identifying key factors that facilitate or inhibit the innovation process. The study further contributes to the development of new theories or models on the relationship between perceived organizational support, job resourcefulness, psychological empowerment, and Innovation.

A study on the effect of changes in the level of environmental regulation of the importing country on export performance (수입국 환경제도수준 변화가 수출에 미치는 영향 연구)

  • Yun-Seop Hwang;Cheon Yu
    • Korea Trade Review
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    • v.45 no.4
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    • pp.65-81
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    • 2020
  • Under New Climate Regime, countries are trying to enhance environmental regulations to meet international standards. This study is designed to examine the relationship between the relative level of environmental regulation of the importing countries and the export performance at the industrial level. Panel data from 2009 to 2018 was established for 12 top export industries and empirical analysis was conducted. For the analysis method, panel OLS, Hausman-Taylor, and panel GLS were used based on the results of the Hausman verification. The dependent variable is the export performance of each industry. As the independent variables, the relative level of environmental regulation, GDP per capita of the importing country, exchange rate, FTA agreement, and physical distance from the importing country were used. Results show that the relative level of environmental regulation has a negative effect on export performance of semiconductors, displays, special machines, general machines, electric appliances, and home appliances. On the other hand, there are no relationship between the relative level of environmental regulation of the importing country and export performance of automobile, petroleum refining, petrochemical, shipbuilding, and communication equipment industries.

A review of chloride induced stress corrosion cracking characterization in austenitic stainless steels using acoustic emission technique

  • Suresh Nuthalapati;K.E. Kee;Srinivasa Rao Pedapati;Khairulazhar Jumbri
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.688-706
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    • 2024
  • Austenitic stainless steels (ASS) are extensively employed in various sectors such as nuclear, power, petrochemical, oil and gas because of their excellent structural strength and resistance to corrosion. SS304 and SS316 are the predominant choices for piping, pressure vessels, heat exchangers, nuclear reactor core components and support structures, but they are susceptible to stress corrosion cracking (SCC) in chloride-rich environments. Over the course of several decades, extensive research efforts have been directed towards evaluating SCC using diverse methodologies and models, albeit some uncertainties persist regarding the precise progression of cracks. This review paper focuses on the application of Acoustic Emission Technique (AET) for assessing SCC damage mechanism by monitoring the dynamic acoustic emissions or inelastic stress waves generated during the initiation and propagation of cracks. AET serves as a valuable non-destructive technique (NDT) for in-service evaluation of the structural integrity within operational conditions and early detection of critical flaws. By leveraging the time domain and time-frequency domain techniques, various Acoustic Emission (AE) parameters can be characterized and correlated with the multi-stage crack damage phenomena. Further theories of the SCC mechanisms are elucidated, with a focus on both the dissolution-based and cleavage-based damage models. Through the comprehensive insights provided here, this review stands to contribute to an enhanced understanding of SCC damage in stainless steels and the potential AET application in nuclear industry.

Well-to-Wheel Greenhouse Gas Emissions Analysis of Hydrogen Fuel Cell Vehicle - Hydrogen Produced by Naphtha Cracking (나프타 기반 수소 연료전지 자동차의 전과정 온실가스 발생량 분석)

  • Kim, Myoungsoo;Yoo, Eunji;Song, Han Ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.2
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    • pp.157-166
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    • 2017
  • The Fuel Cell Electric Vehicle(FCEV) is recently evolving into a new trend in the automobile industry due to its relatively higher efficiency and zero greenhouse gas(GHG) emission in the tailpipe, as compared to that of the conventional internal combustion engine vehicles. However, it is important to analyze the whole process of the hydrogen's life cycle(from extraction of feedstock to vehicle operation) in order to evaluate the environmental impact of introducing FCEV upon recognizing that the hydrogen fuel, which is used in the fuel cell stack, is not directly available from nature, but instead, it should be produced from naturally available resources. Among the various hydrogen production methods, ${\sim}54.1%^{8)}$ of marketed hydrogen in Korea is produced from naphtha cracking process in the petrochemical industry. Therefore, in this study, we performed a well-to-wheels(WTW) analysis on the hydrogen fuel cycle for the FCEV application by using the GREET program from the US Argonne National Laboratory with Korean specific data. As a result, the well-to-tank and well-to-wheel GHG emissions of the FCEV are calculated as 45,638-51,472 g $CO_2eq/GJ$ and 65.0-73.4 g $CO_2eq/km$, respectively

Optimization of Reaction Conditions for the High Purity Hydrogen Production Process Using By-Product Gases in Steel Works (철강산업 부생가스를 이용한 고순도 수소 제조 공정의 반응 조건 최적화)

  • CHOI, HANSEUL;KIM, JOONWOO;KIM, WOOHYOUNG;KIM, SUNGJOONG;KOH, DONGJUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.6
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    • pp.621-627
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    • 2016
  • Low-priced hydrogen is required in petrochemical industry for producing low-sulfur oil, and upgrading low-grade crude oil since environmental regulations have been reinforced. Steel industry can produce hydrogen from by-product gases such as Blast Furnace Gas (BFG), Coke Oven Gas (COG), and Linze Donawitz Gas (LDG) with water gas shift (WGS) reaction by catalysis. In this study, we optimized conditions for WGS reaction with commercial catalysts by BFG and LDG. In particular, the influence on activity of gas-hourly-space-velocity, and $H_2O/CO$ ratios at different temperatures were investigated. As a result, 99.9%, and 97% CO conversion were showed with BFG, and LDG respectively under $350^{\circ}C$ High Temperature Shift (HTS), $200^{\circ}C$ Low Temperature Shift (LTS), 3.0 of $H_2O/CO$, and $1500h^{-1}$ of GHSV. Furthermore, 99.9% CO conversion lasted for 250 hours with BFG as feed gas.

A Study on the Characteristics of Production and Using for Acidic Chemicals with High Accident Frequency (화학사고 빈도가 높은 산 계열 물질의 취급 특성 연구)

  • Kim, Ki-Joon;Lee, Jin-Seon;Yoon, Young-Sam;Jung, Mi-Suk;Yoon, Junheon;Seok, Kwang-Seol
    • Korean Journal of Hazardous Materials
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    • v.2 no.1
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    • pp.1-5
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    • 2014
  • Acidic chemicals like sulfuric acid, nitric acid and hydrogen chloride take up 37% of the total chemical accidents which took place for the past 10 years. When an acidic chemical leak happens, fume is generated, diffusing into the air, which might cause serious damage to health of local residents and the environment. However, we have only little reference data for production and using of acidic chemicals. In this study, we investigated characteristics of production and using for acidic chemicals with high accident frequency. As a results, domestic chemical accidents were categorized according to chemical types and production, using, and handling characteristics of acidic chemicals were identified. Sulfuric acid was handled in the largest amount, followed in the order of hydrogen chloride, nitric acid, acrylic acid, and hydrogen fluoride. Sulfuric acid is used in the industry of manufacturing composite fertilizer and mainly used for manufacturing fertilizer. Hydrogen chloride is used in the industry of manufacturing basic chemicals for petrochemical family and mainly used for pH regulator. It is expected that this results could be used as preliminary data for making decisions on facilities required intensive management in order to prevent chemical accidents and prepare countermeasures against such accidents.

Performance Evaluation for the A/O Pure-Oxygen Biofilm (POB) Process on the Removal of Organics and TKN in the Industrial Wastewater (혐기/호기 순산소 생물막공법에 의한 산업폐수의 유기물 및 TKN 제거 성능평가)

  • Jang, Am;Kim, Hong Suck;Kim, In S.
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.837-847
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    • 2000
  • For the treatment of wastewaters generated from beer industry and petrochemical company with high organic and nitrogen contents, laboratory scale of A/O Pure-Oxygen Biofilm (POB) process was developed and studied by means of the comparative economic analysis with extended aeration process. When the wastewater of beer company was initially treated by the A/O POB process in the ranges of 70 to 150 mg TOC/L diluted with tap water, higher than 92% of TOC removal was accomplished in the all ranges. In case of petrochemical wastewater, the initial TOC removal was as low as 52%, though, it increased to 86% after 32 days of operation and also the TKN removal marked 71% after 27 days. Continuous high removal rates were monitored in both the TOC and TKN parameters during the experimental period. Due to the cost for PSA (Pressure Swing Adsorption) setting and biomass supporting media installation, the initial construction cost of A/O POB process was 2.9 times higher than that of extended aeration process. However, the advantages such as low sludge production, no need for sludge recycling and low energy consumption allow the A/O POB process to have 2.5 times lower operation and maintenance costs. Consequently, in the long term of operation, it is likely that A/O POB process would show higher performance as well as cost effectiveness compared to extended aeration process.

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Case Study of Cost Effect Analysis for Toxic Compounds to Developing Effluent Limitation Standards : Focus on 1,4-Dichlorobenzene (수질유해물질 배출허용기준 설정에 따른 배출시설 비용영향 분석사례 연구: 1,4-Dichlorobenzene을 중심으로)

  • Kim, Kyeongjin;Kim, Wongi;Heo, Jin;Kim, Kwangin;Kim, Jaehoon;Kim, Sanghun;Yeom, Icktae
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.557-565
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    • 2010
  • Recently, regulations on toxic compounds in aquatic environment have been strengthened in korea due to the increasing public awareness of the water quality. Typically, these regulations include introduction of emerging toxic compounds and stricter effluent limitations for the already regulated compounds. However, too strict regulations may cause excessive burden on the industry. Therefore it is also important to assess the economic impacts when the new effluent limitation guidelines are introduced. The estimation of the additional cost for the wastewater dischargers to meet the new guidelines are based on the selected treatment technology to handle the hazardous substances and the regulatory levels for effluent limitations. To explore the procedures for cost estimation in enforcing new effluent limitations, a case study was performed specially for 1,4-dichlorobenzene. The pollutants of concern are surveyed for different industrial categories and various treatment technologies. For a given pollutant, the general performances of the treatment technologies are surveyed and a representative technology is selected. For a given technology, the capital cost and annual Operation and Maintenance (O&M) cost was calculated. The calculation of baseline costs to operate ordinary treatment technologies is also important. The ratio between the cost for introducing new treatment process and the baseline cost required for conventional technology was used to evaluate the economic impact on the industry. For 1,4-dichlorobenzene, steam stripping and activated carbon processes were selected as the specific treatment technologies. The cost effects to the regulation of the compound were found to be 6.4% and 14.5% increase in capital cost and O&M cost, respectively, at the flow rate over $2,000m^3/d$ for the categories of synthetic resin and other plastics manufacturing industry. For the case of petrochemical basic compounds manufacturing industry, the cost increases were 5.8% and 12.4%, respectively. It was suggested that cost effect analysis to evaluate the economic impacts of new effluent limitations on the industry is crucial to establish more balanced and reasonable effluent limitations to manage the industrial wastewater containing emerging toxic compounds in the wastewater.

A Study of Environment Analysis and Entry Plan for Medium and Small Enterprises' Vietnam Advance (중소기업의 베트남 진출을 위한 환경분석 및 진입 방안에 관한 연구)

  • Choi, Seung-Il;Kim, Dong-Il
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.1
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    • pp.307-313
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    • 2010
  • Recently in Korea, or companies considering overseas expansion is often already begun. Past, enterprise's overseas economic cooperation fund(OECF) was consisted of overseas economic cooperation fund(OECF) of most large enterprise leading but medium and small enterprises as well as large enterprise is recognized for factor that competitive power security through overseas economic cooperation fund(OECF) is indispensable by economy opening Tuesday such as deregulation of great foreign enemy environment change and a technology and capital introduction. In the case of Korea, that advance of the China is going through bottleneck among by far bank Vietnam advance gradually expand. Therefore, in this study, I wished to quote plan for efficient and desirable Vietnam advance strategy establishment regarding our country enterprise's Vietnam advance through economy, politics, social environment analysis. In this study, can do on the basis of Vietnam advance connection domestic?outside literature investigation and virtue study through theoretical investigation according to these purpose and behaved theoretical investigation and lift construction materials allied industry, labor-intensive manufacturing industry, fisheries farm produce cultivation, processing household mascot etc. as energy industry, refined oil and petrochemical industry, electric-power industry, other field by our country medium and small enterprise.

A Study on the Early Warning Model of Crude Oil Shipping Market Using Signal Approach (신호접근법에 의한 유조선 해운시장 위기 예측 연구)

  • Bong Keun Choi;Dong-Keun Ryoo
    • Journal of Navigation and Port Research
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    • v.47 no.3
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    • pp.167-173
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    • 2023
  • The manufacturing industry is the backbone of the Korean economy. Among them, the petrochemical industry is a strategic growth industry, which makes a profit through reexports based on eminent technology in South Korea which imports all of its crude oil. South Korea imports whole amount of crude oil, which is the raw material for many manufacturing industries, by sea transportation. Therefore, it must respond swiftly to a highly volatile tanker freight market. This study aimed to make an early warning model of crude oil shipping market using a signal approach. The crisis of crude oil shipping market is defined by BDTI. The overall leading index is made of 38 factors from macro economy, financial data, and shipping market data. Only leading correlation factors were chosen to be used for the overall leading index. The overall leading index had the highest correlation coefficient factor of 0.499 two months ago. It showed a significant correlation coefficient five months ago. The QPS value was 0.13, which was found to have high accuracy for crisis prediction. Furthermore, unlike other previous time series forecasting model studies, this study quantitatively approached the time lag between economic crisis and the crisis of the tanker ship market, providing workers and policy makers in the shipping industry with an framework for strategies that could effectively deal with the crisis.